Advanced Functional Electromagnetic Shielding Materials:A Review Based on Micro‑Nano Structure Interface Control of Biomass Cell Walls

Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and hierarchical.Due to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EMI shielding materials.Despite concerted efforts on the EMI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EMI shielding materials.In particular,a more comprehensive study and summary of the factors influencing biomass EMI shielding materials including the pore structure adjustment,preparation process,and micro-control would be valuable.The preparation methods and characteristics of wood,bamboo,cellulose and lignin in EMI shielding field are critically discussed in this paper,and similar biomass EMI materials are summarized and analyzed.The composite methods and fillers of various biomass materials were reviewed.this paper also highlights the mechanism of EMI shielding as well as existing prospects and challenges for development trends in this field.

Recent progress on fabrication, spectroscopy properties, and device applications in Sn-doped CdS micro-nano structures

One-dimensional semiconductor materials possess excellent photoelectric properties and potential for the construction of integrated nanodevices. Among them, Sn-doped CdS has different micro-nano structures, including nanoribbons,nanowires, comb-like structures, and superlattices, with rich optical microcavity modes, excellent optical properties, and a wide range of application fields. This article reviews the research progress of various micrometer structures of Sn-doped CdS, systematically elaborates the effects of different growth conditions on the preparation of Sn-doped CdS micro-nano structures, as well as the spectral characteristics of these structures and their potential applications in certain fields. With the continuous progress of nanotechnology, it is expected that Sn-doped CdS micro-nano structures will achieve more breakthroughs in the field of optoelectronics and form cross-integration with other fields, jointly promoting scientific, technological, and social development.

NONLINEAR EFFECT OF LOCAL ROUGH WALL ON LARGE EDDY STRUCTURE IN BOUNDARY LAYER

Based on the building of a theoretical model for the large eddy structure, the nonlinear effect of the local rough wall on the large eddy structure in the boundary layer is studied by direct numerical simulation. Numerical results show that factors of the local rough feature, the distributing structure and the intensity, etc. play an important role in the evolution of the large eddy structure in the boundary layer.

On Sea Surface Roughness Parameterization and Its Effect on Tropical Cyclone Structure and Intensity

A new parameterization scheme of sea surface momentum roughness length for all wind regimes, including high winds, under tropical cyclone （TC） conditions is constructed based on measurements from Global Positioning System （GPS） dropsonde. It reproduces the observed regime transition, namely, an increase of the drag coefficient with an increase in wind speed up to 40 m s-1 , followed by a decrease with a further increase in wind speed. The effect of this parameterization on the structure and intensity of TCs is evaluated using a newly developed numerical model, TCM4. The results show that the final intensity is increased by 10.5% （8.9%） in the maximum surface wind speed and by 8.1 hPa （5.9 hPa） in the minimum sea surface pressure drop with （without） dissipative heating. This intensity increase is found to be due mainly to the reduced frictional dissipation in the surface layer and little to do with either the surface enthalpy flux or latent heat release in the eyewall convection. The effect of the new parameterization on the storm structure is found to be insignificant and occurs only in the inner core region with the increase in tangential winds in the eyewall and the increase in temperature anomalies in the eye. This is because the difference in drag coefficient appears only in a small area under the eyewall. Implications of the results are briefly discussed.

Surface Roughness Modification of Free Standing Single Crystal Silicon Microstructures Using KrF Excimer Laser Treatment for Mechanical Performance Improvement

Single crystal silicon freestanding structures for tensile and fatigue testing were treated with KrF excimer laser to improve surface roughness and accordingly mechanical performance. Sample thickness was 5 μm. Localized laser treatment was successful in eliminating the scallops developed during Bosch process and in reducing surface roughness. Harsh irradiation at laser energies up to 4 J/cm2 was only possible due to localized treatment without significant vibrations occurring on the freestanding samples that led to fracture in preliminary experiments at energies as low as 0.16 J/cm2. Finite element analysis was used to investigate the temperature distribution on the irradiated structures. Atomic force microscopy (AFM) and Raman spectroscopy were also used to assess surface roughness, crystallinity changes and surface stresses developing on surfaces subjected to perpendicular laser irradiation. At a high energy (3.2 J/cm2) the top surface showed a decrease of roughness compared to fabricated samples. Raman spectroscopy showed the dominance of crystalline silicon after laser irradiation. The effects of laser energy, number of

Superamphiphobic, light-trapping FeSe2 particles with a micro-nano hierarchical structure obtained by an improved solvothermal method

Wettability and the light-trapping effect of FeSe2 particles with a micro-nano hierarchical structure have been inves- tigated. Particles are synthesized by an improved solvothermal method, wherein hexadecyl trimetbyl ammonium bromide （CTAB） is employed as a surfactant. After modifying the particles with heptadecafluorodecyltrimethoxy-silane （HTMS）, we find that the water contact angle （WCA） of the FeSe2 particles increases by 6.1~ and the water sliding angle （WSA） decreases by 2.5~ respectively, and the diffuse reflectivity decreases 29.4% compared with similar FeSe2 particles synthe- sized by the conventional method. The growth process of the particles is analyzed and a growth scenario is given. Upon altering the PH values of the water, we observe that the superhydrophobic property is maintained quite consistently across a wide PH range of 1-14. Moreover, the modified particles were also found to be superoleophobic. To the best of our knowledge, there is no systematic research on the wettability of FeSe2 particles, so our research provides a reference for other researchers.

Investigation on Surface Plasmon Polaritons and Localized Surface Plasmon Production Mechanism in Micro-Nano Structures

The simulation mechanism of surface plasmon polaritons(SPPs)and localized surface plasmon(LSP)in different structures was studied,including the Au reflection grating(Au grating),Au substrate with dielectric ribbons grating(Au substrate grating),and pure electric conductor(PEC)substrate with Au ribbons grating(Au ribbons grating).And the characteristics of the Smith-Purcell radiation in these structures were presented.Simulation results show that SPPs are excited on the bottom surface of Au substrate grating grooves and LSP is stimulated on the upper surface both of Au ribbons grating grooves and Au grating grooves.Owing to the irreconcilable contradiction between optimizing the grating diffraction radiation efficiency and optimizing the SPPs excitation efficiency in the Au substrate grating,only 40-times enhancement of the radiation intensity was obtained by excited SPPs.However,the LSP enhanced structure overcomes the above problem and gains much better radiation enhancement ability,with about 200-times enhancement obtained in the Au ribbons grating and more than 500-times enhancement obtained in the Au grating.The results presented here provide a way of developing miniature,integratable,tunable,high-power-density radiation sources from visible light to ultraviolet rays at room temperature.

ON THE MECHANISM OF TURBULENT COHERENT STRUCTURE（II）──A PHYSICAL MODEL OF COHERENT STRUCTURE FOR THE ROUGH BOUNDARY LAYER

In this paper, the differences of turbulent coherent structure beween the smooth and rough boundary lavers are analysed.Based on the discussing the transient properties from the smooth wall tothe rough wall,the physicalmodel of coherent structure for the rough boundary layer are established.The width of slwly-moving turbulent spot and the bursting time are obtained,which are in agreement with experimental results.

Extension of Rough Set on Granular Structures and Axiomatic Characterizations

In granular computing granular structures represent knowledge on universe,in this paper several important granular structures are considered.In a general granular structure the notions of interior point, accumulation point and boundary point etc are proposed,by use of these notions and referring to topological method,the lower and upper approximations of a subset of universe are defined such that they are one kind of generalization of the existing approximations based on some special granular structure.Basic properties of new rough set approximations are investigated.Furthermore,granular structures on universe are characterized by the lower and upper approximation operators.

Potential application of functional micro-nano structures in petroleum

This paper takes micro-nano motors and metamaterials as examples to introduce the basic concept and development of functional micro nano structures, and analyzes the application potential of the micro-nano structure design and manufacturing technology in the petroleum industry. The functional micro-nano structure is the structure and device with special functions prepared to achieve a specific goal. New functional micro-nano structures are classified into mobile type(e.g. micro-nano motors) and fixed type(e.g. metamaterials), and 3 D printing technology is a developed method of manufacturing. Combining the demand for exploration and development in oil and gas fields and the research status of intelligent micro-nano structures, we believe that there are 3 potential application directions:(1) The intelligent micro-nano structures represented by metamaterials and smart coatings can be applied to the oil recovery engineering technology and equipment to improve the stability and reliability of petroleum equipment.(2) The smart micro-nano robots represented by micro-motors and smart microspheres can be applied to the development of new materials for enhanced oil recovery, effectively improving the development efficiency of heavy oil, shale oil and other resources.(3) The intelligent structure manufacturing technology represented by 3 D printing technology can be applied to the field of microfluidics in reservoir fluids to guide the selection of mine flooding agents and improve the efficiency of mining.

Synthesis and electrochemical performance of micro-nano structured Li Fe1-xMnxPO4/C(0≤x≤0.05)cathode for lithium-ion batteries

Micro-nano structured Li Fe（1-x）MnxPO4/C（0≤x≤0.05）cathodes were prepared by spray drying,followed by calcination at 700°C.The spherical Li Fe（1-x）MnxPO4/C（0≤x≤0.05）particles with the size of 0.5 to5.0μm are composed of lots of nanoparticles of 20 to 30 nm,and have the well-developed interconnected pore structure.In contrast,when Mn doping content is 3 mol%（x=0.03）,the Li Fe（0.97）Mn（0.03）PO4/C demonstrates maximum specific surface area of 31.30 m^2/g,more uniform pore size and relatively better electrochemical performance.The initial discharge capacities are 161.59,157.04 and 153.13 m Ah/g at a discharge rate of 0.2,0.5 and 1 C,respectively.Meanwhile,the discharge capacity retentions are～100%after 120 cycles.The improved electrochemical performance should be attributed to higher specific surface,smaller polarization voltage,and a high Li~＋diffusion rate due to the micro-nano porous structure and lattice expansion produced by Mn doping.

The Effect of Cell Size and Surface Roughness on the Compressive Properties of ABS Lattice Structures Fabricated by Fused Deposition Modeling

Researchers looking to improve the surface roughness of acrylonitrile butadiene styrene(ABS)parts fabricated by fused deposition modeling(FDM)have determined that acetone smoothing not only achieves improved surface roughness but increases compressive strength as well.However,the sensitivity of ABS parts to acetone smoothing has not been explored.In this study we investigated FDM-fabricated ABS lattice structures of various cell sizes subjected to cold acetone vapor smoothing to determine the combined effect of cell size and acetone smoothing on the compressive properties of the lattice structures.The acetone-smoothed specimens performed better than the as-built specimens in both compression modulus and maximum load,and there was a decrease in those compressive properties with decreasing cell size.The difference between as-built and acetone-smoothed specimens was found to increase with decreasing cell size for the maximum load.

Comparative Response of CRL-11372 Cells to Surface Roughness and Crystalline Structure of the Surfaces Developed by Sandblasting,Etching,and TiO_(2) Coating on Commercially Pure Ti Discs

The aim of this study was to evaluate the adhesion of human fetal osteoblast cells (CRL-11372) in vitro at 24 h on commercially pure titanium (cp Ti) metal surfaces’ crystalline structure and surface roughnesses that are modified by polishing, sand blasting (with alumina (Al2O3)), sand blasting and coating (with titanium oxide (TiO2)), and sand blasting and etching (with oxalic acid). Modified surfaces were characterized quantitatively by a non-contacting optical profilometer in terms of their Rz and Ra values and surface profile diagrams were obtained. These surfaces were characterized qualitatively by scanning electron microscope (SEM) micrographs. The crystalline structures of the coatings were characterized by X-ray diffraction (XRD). CRL-11372 cells were cultured for 24 h and evaluated for their mean total cell counts. Cell morphologies were examined by SEM micrographs. Data were compared by Kruskal-Wallis test followed by Post Hoc LSD test comparisons. SEM micrographs showed variations among the topographies of the surfaces and the morphologies of the cells adhered to these four different surfaces. Cell adhesion was affected by neither Ti chemical composition nor surface roughness within the Ra and Rz parameters used.

Micro-nanostructural designs of bifunctional electrocatalysts for metal-air batteries

Water-based rechargeable metal-air batteries play an important role in the storage and conversion of renewable electric energy.However,the sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)have limited the practical application of rechargeable metal-air batteries.Most of reviews were focused on single functional electrocatalysts while few on bifunctional electrocatalysts.It is indispensable but challenging to design a bifunctional electrocatalyst that is active and stable to the two reactions.Recently,attempts to develop high active bifunctional electrocatalysts for both ORR and OER increase rapidly.Much work is focused on the micro-nano design of advanced structures to improve the performance of bifunctional electrocatalyst.Transition-metal materials,carbon materials and composite materials,and the methods developed to prepare micro-nano structures,such as electrochemical methods,chemical vapor deposition,hydrothermal methods and template methods are reported in literatures.Additionally,many strategies,such as adjustments of electronic structures,oxygen defects,metal-oxygen bonds,interfacial strain,nano composites,heteroatom doping etc.,have been used extensively to design bifunctional electrocatalysts.To well understand the achievements in the recent literatures,this review focuses on the micro-nano structural design of materials,and the related methods and strategies are classed into two groups for the improvement of intrinsic and apparent activities.The fine adjustment of nano structures and an in-depth understanding of the reaction mechanism are also discussed briefly.

Generalized model for laser-induced surface structure in metallic glass

The details of the special three-dimensional micro-nano scale ripples with a period of hundreds of microns on the surfaces of a Zr-based and a La-based metallic glass irradiated separately by single laser pulse are investigated.We use the small-amplitude capillary wave theory to unveil the ripple formation mechanism through considering each of the molten metallic glasses as an incompressible viscous fluid.A generalized model is presented to describe the special morphology,which fits the experimental result well.It is also revealed that the viscosity brings about the biggest effect on the monotone decreasing nature of the amplitude and the wavelength of the surface ripples.The greater the viscosity is,the shorter the amplitude and the wavelength are.

Modal Experiments and Finite Element Analysis of the Bolted Structure Considering Interface Stiffness and Prtension

It is particularly important to evaluate natural frequencies and natural modes of the structure of bolted joints to avoid the failures of the structure due to the resonance. The vibration characteristics of bolted structures are closely connected to surface roughness of contact interfaces, the magnitude of pretension of the bolts and the number of clamping bolts. In this paper, the effect of the factors above on the natural frequencies of bolted structures is sys- tematically investigated by experiments. Then, the finite element method is applied to analyze the effect. Finally, the numerical method is validated by experimental measurements of the natural frequencies.

Nonlinear constitutive models of rock structural plane and their applications

Structural planes play an important role in controlling the stability of rock engineering,and the influence of structural planes should be considered in the design and construction process of rock engineering.In this paper,mechanical properties,constitutive theory,and numerical application of structural plane are studied by a combination method of laboratory tests,theoretical derivation,and program development.The test results reveal the change laws of various mechanical parameters under different roughness and normal stress.At the pre-peak stage,a non-stationary model of shear stiffness is established,and threedimensional empirical prediction models for initial shear stiffness and residual stage roughness are proposed.The nonlinear constitutive models are established based on elasto-plastic mechanics,and the algorithms of the models are developed based on the return mapping algorithm.According to a large number of statistical analysis results,empirical prediction models are proposed for model parameters expressed by structural plane characteristic parameters.Finally,the discrete element method(DEM)is chosen to embed the constitutive models for practical application.The running programs of the constitutive models have been compiled into the discrete element model library.The comparison results between the proposed model and the Mohr-Coulomb slip model show that the proposed model can better describe nonlinear changes at different stages,and the predicted shear strength,peak strain and shear stiffness are closer to the test results.The research results of the paper are conducive to the accurate evaluation of structural plane in rock engineering.

Material Mechanical Properties Necessary for the Structural Intervention of Concrete Structures

Structural intervention involves the restoration and/or upgrading of the mechanical performances of structures. In addition to concrete and steel, which are typical materials for concrete structures, various ber-reinforced polymers (FRPs), cementitious materials with bers, polymers, and adhesives are often applied for structural intervention. In order to predict structural performance, it is necessary to develop a generic method that is applicable to not only to steel, but also to other materials. Such a generic model could provide information on the mechanical properties required to improve the structural performance. External bonding, which is a typical scheme for structural intervention, is not applied for new structures. It is necessary to clarify material properties and structural details in order to achieve better bonding strength at the interface between the substrate concrete and an externally bonded material. This paper presents the mechanical properties of substrate concrete and relevant intervention material for the fol- lowing purposes: ① to achieve better shear strength and ultimate deformation of a member after struc- tural intervention;and ② to achieve better debonding strength for external bonding. This paper concludes that some of the mechanical properties and structural details for intervention materials that are necessary for improvement in mechanical performance in structures with structural intervention are new, and differ from those of structures without intervention. For example, high strength and stiff- ness are important properties for materials in structures without structural intervention, whereas high fracturing strain and low stiffness are important properties for structural intervention materials.

Approximations by Ideal Minimal Structure with Chemical Application

The theory of rough set represents a non-statistical methodology for analyzing ambiguity and imprecise information.It can be characterized by two crisp sets,named the upper and lower approximations that are used to determine the boundary region and accurate measure of any subset.This article endeavors to achieve the best approximation and the highest accuracy degree by using the minimal structure approximation space MSAS via ideal J.The novel approach(indicated by JMSAS)modifies the approximation space to diminish the bound-ary region and enhance the measure of accuracy.The suggested method is more accurate than Pawlak’s and EL-Sharkasy techniques.Via illustrated examples,several remarkable results using these notions are obtained and some of their properties are established.Several sorts of near open(resp.closed)sets based on JMSAS are studied.Furthermore,the connections between these assorted kinds of near-open sets in JMSAS are deduced.The advantages and disadvan-tages of the proposed approach compared to previous ones are examined.An algorithm using MATLAB and a framework for decision-making problems are verified.Finally,the chemical application for the classification of amino acids(AAs)is treated to highlight the significance of applying the suggested approximation.

Wind tunnel simulation of wind loading on a solid structure of revolution

The wind tunnel simulations of wind loading on a solid structure of revolution with one smooth and five rough surfaces were conducted using wind tunnel tests. Timemean and fluctuating pressure distributions on the surface were obtained, and the relationships between the roughness Reynolds number and pressure distributions were analyzed and discussed. The results show that increasing the surface roughness can significantly affect the pressure distribution, and the roughness Reynolds numbers play an important role in the change of flow patterns. The three flow patterns of subcritical, critical and supercritical flows can be classified based on the changing patterns of both the mean and the fluctuating pressure distributions. The present study suggests that the wind tunnel results obtained in the supercritical pattern reflect more closely those of full-scale solid structure of revolution at the designed wind speed.