The development of energy storage devices with high energy density relies heavily on thick film electrodes,but it is challenging due to the limited ion transport kinetics inherent in thick electrodes.Here,we report on...The development of energy storage devices with high energy density relies heavily on thick film electrodes,but it is challenging due to the limited ion transport kinetics inherent in thick electrodes.Here,we report on the preparation of a directional vertical array of micro-porous transport networks on LTO electrodes using a femtosecond laser processing strategy,enabling directional ion rapid transport and achieving good electrochemical performance in thick film electrodes.Various three-dimensional(3D)vertically aligned micro-pore networks are innovatively designed,and the structure,kinetics characteristics,and electrochemical performance of the prepared ion transport channels are analyzed and discussed by multiple characterization and testing methods.Furthermore,the rational mechanisms of electrode performance improvement are studied experimentally and simulated from two aspects of structural mechanics and transmission kinetics.The ion diffusion coefficient,rate performance at 60 C,and electrode interface area of the laser-optimized 60-15%micro-porous transport network electrodes increase by 25.2 times,2.2 times,and 2.15 times,respectively than those of untreated electrodes.Therefore,the preparation of 3D micro-porous transport networks by femtosecond laser on ultra-thick electrodes is a feasible way to develop high-energy batteries.In addition,the unique micro-porous transport network structure can be widely extended to design and explore other high-performance energy materials.展开更多
The issue of plastic pollution has attracted widespread social attention.Gelatin is valued as a degradable bio-based material,especially as an edible active packaging material.However,the commonly used solution-castin...The issue of plastic pollution has attracted widespread social attention.Gelatin is valued as a degradable bio-based material,especially as an edible active packaging material.However,the commonly used solution-casting filmforming technology limits the mass production of gelatin films.In order to improve the production efficiency and enhance the commercial value of gelatin films,in this study,fish gelatin(FG)particles were successfully blended with essential oils(EOs)to prepare active films by melt extrusion technique,a common method for commercial plastics,and applied to bread preservation.FG and EOs showed good compatibility with each other.The elongation at break was enhanced in all samples of films containing EOs.The addition of EOs weakened the oxygen barrier properties of the FG films.The gelatin films containing clove EO showed the highest DPPH radical scavenging rate of 39.38%.The films containing oregano EO showed the highest antibacterial activity,with 98.84%and 99.86% against S.aureus and E.coli,respectively.The bread preservation results showed a slower microbial growth rate in the samples preserved by the active films.The bread samples preserved in commercial PE film showed mold on day 3,and the bread samples preserved in active gelatin film showed mold visible to the naked eye by day 7.This study demonstrates the potential of gelatin-based activated films for commercial application in baked goods preservation.展开更多
Based on the changes in the European energy market and EU goals for CO2 reduction, the fossil fired power plants, especially the high effective combined cycle power plants, are faced with new challenges. Flexible load...Based on the changes in the European energy market and EU goals for CO2 reduction, the fossil fired power plants, especially the high effective combined cycle power plants, are faced with new challenges. Flexible load requirements associated with frequent shutdowns especially in plants with peak load area are the results. In addition, large reserve capacities have to be retained for short-terms needs which can be quickly start operation. For this reason, preservation procedures play an increasingly important role. They should provide a good protective effect with the most simple handling and flexible management system. The preservation using FFA （film forming amines）, for example, octadecylamine become more and more attraction. With the lecture, a first insight into the preservation process using octadecylamine will be given to the operators of boiler and turbine plants. Especially in the view of the further increase in supply of renewable energy and related flexibility requirements in the existing power plants, an efficient and sustainable preservation technology will be presented.展开更多
基金supported by the National Natural Science Foundation of China(52275463,51772240)the National Key Research and Development Program of China(2021YFB3302000)the Key Research and Development Projects of Shaanxi Province,China(2018ZDXM-GY-135)。
文摘The development of energy storage devices with high energy density relies heavily on thick film electrodes,but it is challenging due to the limited ion transport kinetics inherent in thick electrodes.Here,we report on the preparation of a directional vertical array of micro-porous transport networks on LTO electrodes using a femtosecond laser processing strategy,enabling directional ion rapid transport and achieving good electrochemical performance in thick film electrodes.Various three-dimensional(3D)vertically aligned micro-pore networks are innovatively designed,and the structure,kinetics characteristics,and electrochemical performance of the prepared ion transport channels are analyzed and discussed by multiple characterization and testing methods.Furthermore,the rational mechanisms of electrode performance improvement are studied experimentally and simulated from two aspects of structural mechanics and transmission kinetics.The ion diffusion coefficient,rate performance at 60 C,and electrode interface area of the laser-optimized 60-15%micro-porous transport network electrodes increase by 25.2 times,2.2 times,and 2.15 times,respectively than those of untreated electrodes.Therefore,the preparation of 3D micro-porous transport networks by femtosecond laser on ultra-thick electrodes is a feasible way to develop high-energy batteries.In addition,the unique micro-porous transport network structure can be widely extended to design and explore other high-performance energy materials.
基金supported by the Program of Shanghai Tobacco Group Open Fund (20210105).
文摘The issue of plastic pollution has attracted widespread social attention.Gelatin is valued as a degradable bio-based material,especially as an edible active packaging material.However,the commonly used solution-casting filmforming technology limits the mass production of gelatin films.In order to improve the production efficiency and enhance the commercial value of gelatin films,in this study,fish gelatin(FG)particles were successfully blended with essential oils(EOs)to prepare active films by melt extrusion technique,a common method for commercial plastics,and applied to bread preservation.FG and EOs showed good compatibility with each other.The elongation at break was enhanced in all samples of films containing EOs.The addition of EOs weakened the oxygen barrier properties of the FG films.The gelatin films containing clove EO showed the highest DPPH radical scavenging rate of 39.38%.The films containing oregano EO showed the highest antibacterial activity,with 98.84%and 99.86% against S.aureus and E.coli,respectively.The bread preservation results showed a slower microbial growth rate in the samples preserved by the active films.The bread samples preserved in commercial PE film showed mold on day 3,and the bread samples preserved in active gelatin film showed mold visible to the naked eye by day 7.This study demonstrates the potential of gelatin-based activated films for commercial application in baked goods preservation.
文摘Based on the changes in the European energy market and EU goals for CO2 reduction, the fossil fired power plants, especially the high effective combined cycle power plants, are faced with new challenges. Flexible load requirements associated with frequent shutdowns especially in plants with peak load area are the results. In addition, large reserve capacities have to be retained for short-terms needs which can be quickly start operation. For this reason, preservation procedures play an increasingly important role. They should provide a good protective effect with the most simple handling and flexible management system. The preservation using FFA （film forming amines）, for example, octadecylamine become more and more attraction. With the lecture, a first insight into the preservation process using octadecylamine will be given to the operators of boiler and turbine plants. Especially in the view of the further increase in supply of renewable energy and related flexibility requirements in the existing power plants, an efficient and sustainable preservation technology will be presented.
文摘为探究不同厚度低密度聚乙烯保鲜膜对采后葡萄质构品质及贮藏特性的影响,以‘巨峰’葡萄为试材,分别用0(无包装组,CK)、0.02、0.03、0.04、0.05 mm和0.06 mm厚度的LDPE保鲜膜袋包装,于(1±1)℃低温下贮放42 d,每隔7 d测定其贮藏期质构品质及贮藏特性指标,进行相关性分析,并采用主成分分析法确定最佳保鲜膜厚度。结果表明:与CK组相比,不同厚度LDPE保鲜膜均能延缓葡萄掉粒率及失重率的上升,较好地保持葡萄色泽和亮度,同时能抑制水分、可溶性糖和可溶性蛋白含量的下降,延缓果皮和果肉硬度的降低。CK组、0.05 mm和0.06 mm LDPE组分别在贮藏28 d、35 d和35 d时失去商品价值,而0.02 mm、0.03 mm和0.04 mm LDPE组能将葡萄保鲜期延长至42 d。相关性分析显示,葡萄贮藏期间质构、感官和营养各指标之间密切相关。PCA结果显示,0.03 mm LDPE组置信圈较窄小,保鲜效果最好。综上,0.03 mm LDPE能较好地保持‘巨峰’葡萄的贮藏品质。
