Molybdenum isotope composition of the upper mantle and its origin:insight from mid-ocean ridge basalt

The molybdenum(Mo)isotope system is pivotal in reconstructing marine redox changes throughout Earth’s history and has emerged as a promising tracer for igneous and metamorphic processes.Understanding its composition and variation across major geochemical reservoirs is essential for its application in investigating high-temperature processes.However,there is debate regarding theδ^(98/95)Mo value of the Earth’s mantle,with estimates ranging from sub-chondritic to super-chondritic values.Recent analyses of global mid-ocean ridge basalt(MORB)glasses revealed significantδ^(98/95)Mo variations attributed to mantle heterogeneity,proposing a two-component mixing model to explain the observed variation.Complementary studies confirmed the sub-chondriticδ^(98/95)Mo of the depleted upper mantle,suggesting remixing of subduction-modified oceanic crust as a plausible mechanism.These findings underscore the role of Mo isotopes as effective tracers for understanding dynamic processes associated with mantle-crustal recycling.

Microearthquake reveals the lithospheric structure at midocean ridges and oceanic transform faults

Mid-ocean ridge and oceanic transforms are among the most prominent features on the seafloor surface and are crucial for understanding seafloor spreading and plate tectonic dynamics,but the deep structure of the oceanic lithosphere remains poorly understood.The large number of microearthquakes occurring along ridges and transforms provide valuable information for gaining an indepth view of the underlying detailed seismic structures,contributing to understanding geodynamic processes within the oceanic lithosphere.Previous studies have indicated that the maximum depth of microseismicity is controlled by the 600-℃isotherm.However,this perspective is being challenged due to increasing observations of deep earthquakes that far exceed this suggested isotherm along mid-ocean ridges and oceanic transform faults.Several mechanisms have been proposed to explain these deep events,and we suggest that local geodynamic processes(e.g.,magma supply,mylonite shear zone,longlived faults,hydrothermal vents,etc.)likely play a more important role than previously thought.

Sedimentary Environment Analysis of Ancient Sand Ridges from Zk23 Hole in the East China Sea

Abstract： Based on the analysis of core samples from the hole of Zk23 in the East China Sea Continental Shelf and by means of sedimentary stratigraphy, biostratigraphy and chronostratigraphy, the authors consider that the fine-sand deposition in borehole was part of buried ancient estuary sand ridges of the Yangtze River. The deposition history of study area around the hole before and after the glacial period as well as postglacial period is made clear after our research： （1） the estuarine sublayer -undersea delta facies strata was deposited under the fast sea level rise about 15 kaB.P; （2） sand ridges mostly consisting of fine-sand, were formed when the sea level was the fluctuant range of 60 - 80 m of isoba during the deglacial period around 15 - 12 kaB.P; （3） first silty clay and clay silt strata above the sand ridges were deposited during the period when the sea level rose fast from 12 to 7 kaB.P, and then it keeps stable to the present.

Calcium isotopic signatures of depleted mid-ocean ridge basalts from the northeastern Pacific

A number of high-temperature processes(e.g.,melt-rock reactions,metasomatism,partial melting)can produce signifi cant Ca isotopic fractionation and heterogeneity in the mantle,but the mechanism for such fractionation remains obscure.To investigate the eff ect of mantle partial melting on Ca isotopic fractionation,we reported high-precision Ca isotopic compositions of depleted mid-ocean ridge basalts(MORBs)from the East Pacifi c Rise and Ecuador Rift in the northeastern Pacifi c.Theδ44/40 Ca of these MORB samples exhibit a narrow variation from 0.84‰to 0.88‰with an average of 0.85‰±0.03‰,which are similar to those of reported MORBs(0.83‰±0.11‰)and back-arc basin basalts(BABBs,0.80‰±0.08‰)in literature,but are lower than the estimate value for the bulk silicate Earth(BSE,0.94‰±0.05‰).The lowδ44/40 Ca signatures of MORB samples in this study cannot be caused by fractional crystallization,since intermediate-mafi c diff erentiation has been demonstrated having only limited eff ects on Ca isotopic fractionation.Instead,the off set ofδ44/40 Ca between MORBs and the BSE is most likely produced by mantle partial melting.During this process,the light Ca isotopes are preferentially transferred to the melt,while the heavy ones tend to stay in the residue,which is consistent with the fact thatδ44/40 Ca of melt-depleted peridotites increases with partial melting in literature.The behavior of Ca isotopes during mantle partial melting is closely related to the inter-mineral(Cpx and Opx)Ca isotopic fractionation and melting mineral modes.Mantle partial melting is one of the common processes that can induce lowerδ44/40 Ca values in basalts and Ca isotopic heterogeneity in Earth’s mantle.

Magma Dynamics of Axial Melt Lens at Fast-Spreading Mid-Ocean Ridges

Multichannel seismic studies performed at fastspreading mid-ocean ridges revealed the presence of a thin(tens to hundreds of meters high), narrow(< 1-2 km wide) axial melt lens(AML) in the mid-crust, which is underlain by crystal/melt mush that is in turn laterally surrounded by a transition zone of mostly solidified material. In order to shed light on the complexity of magmatic and metamorphic processes ongoing within and at the roof of axial melt lenses, we have focused on the petrological and geochemical record provided by fossilized AMLs. Of particular significance is Hole 1256D in the equatorial Pacific drilled by the International Ocean Discovery Program(IODP), where for the first time, the transition between sheeted dikes and gabbros in intact fast-spreading crust was penetrated, providing a drill core with a more or less continuous record of the upper part of an AML(Teagle et al., 2006;Koepke et al., 2008). This can be regarded as rosetta stone to answer longstanding questions on the complex magmatic evolution within an AML, as well as on metamorphic and anatectic processes ongoing at the roof of a dynamic AML, rising upward in the midcrust as a consequence of a replenishment event. The plutonic rocks drilled from Hole 1256D consist of quartz-bearing gabbros, diorites and tonalites, which might represent the upper part of a fossilized AML. The gabbros and diorites are consistent with modeled products of MORB fractional crystallization, composed of mixed melt and cumulate in varying ratios. Modeled trace elements support a model in which the tonalites originated from low-degree partial melting of the sheeted dikes overlying the AML, rather than extreme fractional crystallization(Erdmann et al., 2015;Zhang et al., 2017a). Therefore, the upper part of AML, largely composed of low density and high-viscosity felsic magmas, may serve as a barrier to eruptible MORB melts in the lower part of AML. Zoning of apatites from three different lithologies, tonalites, diorites, and gabbros, is common and shows a consistent evolution trend with depletion in Cl and REEs from core to rim. The cores are usually homogenous in composition and interpreted as magmatic origin, whereas zones with lower Cl and REEs are disseminated with heterogeneous concentrations, indicating exchanges with hydrothermal fluids. The high-Cl apatite core indicates assimilation of high-Cl brines at a magmatic stage, which is interpreted as immiscibility product from cycling seawater-derived fluids at a high temperature(Zhang et al., 2017b). The variation of F/Cl and Br/Cl ratios of bull rocks may reflect the mixing between MORB magmas and seawater-derived fluids, crystallization of apatite and amphibole, and/or extraction of magmatic fluids(Zhang et al., 2017c).

Model Forming of Mesoarchean Gridino Mafic Dyke Swarm during Subduction "Mid-Ocean Ridge – Continent"

The high-pressure metamorphosed Gridino dyke swarm comprises a major group of Mesoarchean 2.87-2.82 Ga mafic dykes intruded within the Mesoarchean continental crust of the Kola craton(the Belomorian tectonic province

TEM investigations of South Atlantic Ridge 13.2°S hydrothermal area

According to the exploration contract about polymetallic sulfides in the SWIR （Southwest Indian Ridge） signed by China with the International Seabed Authority, to delineate sulfide minerals and estimate resource quantity are urgent tasks. We independently developed our first coincident loop Transient Electromagnetic Method （TEM） device in 2010, and gained the TEM data for seafloor sulfide at South Atlantic Ridge 13.2°S in June 2011. In contrast with the widely applied CSEM （Marine controlled-source electromagnetic） method, whose goal is to explore hydrocarbons （oil/gas） of higher resistivity than seawater from 102 to 103 m below the sea floor, the TEM is for low resistivity minerals, and the target depth is from 0 to 100 m below the sea floor. Based on the development of complex sulfide geoelectrial models, this paper analyzed the TEM data obtained, proposing a new method for seafloor sulfide detection. We present the preliminary trial results, in the form of apparent resistivity sections for both half-space and full-space conditions. The results cor- respond well with the observations of the actual hydrothermal vent area, and the detection depth reached 50-100m below the bed, which verified the capability of the equipment.

Fractional crystallization processes of magma beneath the Carlsberg Ridge(57°–65°E)

Fractional crystallization of basaltic magma at variable depths influences strongly the geochemical compositions of mid-ocean ridge basalts(MORBs),especially at slow-spreading mid-ocean ridges.The Carlsberg Ridge is a typical slow-spreading ridge located in the northwestern Indian Ocean.In this study,we conducted petrological,geochemical and modelling studies of MORBs collected along the Carlsberg Ridge from 57°-65°E to understand the fractional crystallization processes of magma and the controls on variations in MORB geochemistry.Our results show that the mantle sources beneath the Carlsberg Ridge are heterogeneous even on the local scale of a segment;such heterogeneity may be ubiquitous beneath the Carlsberg Ridge.Mantle heterogeneity may be caused by the enriched components resulting in the"DUPAL"anomaly,whereas the effect of pyroxenite on mantle heterogeneity is negligible.The parental melts experienced crystallization of olivine,plagioclase and clinopyroxene prior to eruption,which played a significant role in the major and trace element variations in MORBs from the Carlsberg Ridge.The liquid lines of descent(LLDs),deduced from the forward modelling of three parental magma compositions using the Petrolog3 program at pressures between 1 atm and 10 kbar,demonstrate that clinopyroxene joined the olivine and plagioclase cotectic.The over-enrichment in highly incompatible elements relative to LLDs may be caused by the processes of replenishment-tapping-crystallization in magma chambers.The calculated crystallization pressures suggest that parental magmas beneath the Carlsberg Ridge experienced moderateto high-pressure crystallization and that crystallization beneath the slow-spreading Carlsberg Ridge may start at upper mantle depths.

Use of portable X-ray fluorescence in the analysis of surficial sediments in the exploration of hydrothermal vents on the Southwest Indian Ridge

Hydrothermal plumes released from the eruption of sea floor hydrothermal fluids contain large amounts of oreforming materials. They precipitate within certain distances from the hydrothermal vent. Six surficial sediment samples from the Southwest Indian Ridge（SWIR） were analyzed by a portable X-ray fluorescence（PXRF） analyzer on board to find a favorable method fast and efficient enough for sea floor sulfide sediment geochemical exploration. These sediments were sampled near, at a moderate distance from, or far away from hydrothermal vents. The results demonstrate that the PXRF is effective in determining the enrichment characteristics of the oreforming elements in the calcareous sediments from the mid-ocean ridge. Sediment samples（〉40 mesh） have high levels of elemental copper, zinc, iron, and manganese, and levels of these elements in sediments finer than 40 mesh are lower and relatively stable. This may be due to relatively high levels of basalt debris/glass in the coarse sediments, which are consistent with the results obtained by microscopic observation. The results also show clear zoning of elements copper, zinc, arsenic, iron, and manganese in the surficial sediments around the hydrothermal vent. Sediments near the vent show relatively high content of the ore-forming elements and either high ratios of copper to iron content and zinc to iron content or high ratios of copper to manganese content and zinc to manganese content. These findings show that the content of the ore-forming elements in the sediments around hydrothermal vents are mainly influenced by the distance of sediments to the vent, rather than grain size. In this way, the PXRF analysis of surface sediment geochemistry is found to satisfy the requirements of recognition geochemical anomaly in mid-ocean ridge sediments. Sediments with diameters finer than 40 mesh should be used as analytical samples in the geochemical exploration for hydrothermal vents on mid-oceanic ridges. The results concerning copper, zinc, arsenic, iron, and manganese and their ratio features can be used as indicators in sediment geochemical exploration of seafloor sulfides.

A Petrogenetic Model of Basalts from the Northern Central Indian Ridge:3-11°S

Mid-Ocean Ridge Basalts （MORB） from the Northern Central Indian Ridge （NCIR） were recovered between latitudes 3° and 11° S and are olivine tholeiite with higher abundances of K and Rb. They are of typical transitional MORB （T-MORB） variety and appear to have been generated from an enriched-mantle peridotite source. The primitive NCIR MORBs having Mg^# 〉 0.68 are the product of partial melting at an estimated pressure of - 1 GPa. It is inferred that the magma was subsequently modified at a pressure 〉 1 GPa by crystal fractionation and spinel was the first mineral to crystallize followed by separation of relatively Fe-rich olivine with subsequent decrease in pressure. During progressive fractionation at lower pressure （between 1-0.5 GPa）, the bulk composition of the magma became systematically depleted in MgO, and enriched in ∑FeO, TiO2, P2Os and Na20. There was, however, limited gradual depletion in Al2O3 and CaO and concomitant enrichment in K20. With the progressive fractionation these basalts became gradually enriched in V, Co, Y, Zr and to some extent in Sr, and depleted in Ni and Cro In addition, the T_JtEE of the magma also increased with fractionation, without any change in （La/Yb）n value.

Three-Dimensional Mantle Flow and Temperature Structure Beneath the Shatsky Rise Ridge-Ridge-Ridge Triple Junction

The Shatsky Rise ridge-ridge-ridge triple junction is an ancient triple junction in the Western Pacific Ocean whose initial geodynamic process is poorly understood and can only be inferred based on indirect geological and geophysical constraints.In this paper,we present three-dimensional numerical models that simulate the Shatsky Rise triple junction and calculate its coupled mantle flow and temperature structure.The mantle flow velocity field shows several distinctive features:1)stronger mantle upwelling closer to the ridge axis and triple junction;2)greater upwelling velocity at the faster-spreading ridges;and 3)the most significant increase in upwelling velocity for the slowest-spreading ridge toward the triple junction.The calculated mantle temperature field also reveals distinctive characteristics:1)sharp increases in the mantle temperature with depth and increases toward the spreading ridges and triple junction;2)the faster-spreading ridges are associated with higher temperatures at depth and identical distances from the triple junction;and 3)the slowest-spreading ridge shows the greatest increase in the along-ridge-axis temperature toward the triple junction.Compared to many present-day triple junctions with slower spreading rates,the along-ridge-axis velocity and thermal fields of the Shatsky Rise are more altered due to the presence of the triple junction.

Singularity of lithosphere mass density over the mid-ocean ridges and implication on floor depth and heat flow

The relation of heat flow and floor depth across the mid-ocean ridges versus lithosphere age can be described by linear functions of square root of age according to plate thermal conductive Half Space Models(HSM).However,one of the long-standing problems of these classical models is the discrepancies between predicted and observed heat flow and floor depth for very young and very old lithosphere.There have been several recent attempts to overcome this problem:one model incorporates temperature-and pressure-dependent parameters and the second model includes an additional low-conductivity crustal layer or magma rich mantle layer(MRM).Alternatively,in the current paper,the ordinary density of lithosphere in the plate conductive models is substituted with a reduction of lithosphere density towards axis that features the irregularity and nonlinearity of plates across the mid-ocean ridges.A new model is formulated incorporating the new form of density for predicting both peak heat flow and floor depth.Simple solutions of power-law forms derived from the model can significantly improve the predicting results of heat flow and floor depth over the mid-ocean ridges.Several datasets in the literature were reutilized for model validation and comparison.These datasets include both earlier datasets used for original model calibration and the more recently compiled high-quality datasets with both sedimentary and crustal loading corrections.The results indicate that both the heat flow and the slope(first orderderivative)of sea floor approach infinity(undifferentiability or singularities)around the mid-ocean ridges.These singularities are partially due to the boundary condition as it has been already known in the literature and partially to the reduction of density of lithosphere as discovered for the first time in the current research.

川东平行岭谷区露天矿山生态修复研究——以达州市为例

矿产资源的开发利用为促进经济发展和社会进步做出了很大贡献,但也造成了不同程度的生态破坏问题。矿山生态环境修复有利于推动区域生态环境持续优化,促进矿业经济绿色发展。川东平行岭谷区是长江上游生态屏障的重要一环,本文以达州市为例,分析了区内地质环境条件和露天矿山主要生态环境问题,探讨了矿山生态修复措施,以期为川东平行岭谷区露天矿山生态修复提供参考。

日光温室番茄东西垄向模式下群体光环境及产量分布特征

为探索日光温室番茄宜机化栽培模式,采用东西垄向(1.8 m垄距,密度3.3株/m^(2))栽培模式,在起垄、移栽机械作业下研究不同栽培垄番茄群体光环境、产量、品质特征。结果表明:在日光温室(净跨8.5 m)番茄东西方向起垄模式下,同一栽培垄南侧行番茄群体的透光率较北侧高50%以上,南侧行番茄单果重、单株产量和总产量均显著高于北侧行20%左右,品质也优于北侧行。不同栽培垄番茄行间透光率由北向南逐渐升高,行内平均透光率除第1垄较低外,其他3垄间没有显著差异。不同垄之间番茄叶片最大光化学量子产量Fv/Fm也没有显著差异。番茄产量分布在栽培垄之间呈现出由北向南逐渐增加的趋势,不同垄之间果实品质没有显著差异,番茄5穗果总产量达到71866 kg/hm^(2)。

城市建成环境对公共交通为导向的开发效能的影响规律与优化建议

为识别城市建成环境影响的内在规律,提出优化建议以提高公共交通为导向的开发效能,选取福州市地铁1、2号线共47个站点作为研究对象,分析建成环境与公共交通为导向的开发之中,交通、经济、社会、环境效能等4个维度的相关性.研究结果表明:岗位密度、公共服务设施密度、道路密度、公交站点密度和市中心可达性等13项建成环境指标与公共交通为导向的开发中的交通、环境、社会效能存在显著的相关关系,并可以建立岭回归模型;而在建成环境指标与TOD的经济效能之间未发现明显的相关性.进一步选取福州市商业中心站点——东街口站作为典型案例,从TOD效能的4个维度系统分析站点周边的建成环境,提出优化核心区域的慢行系统、提升站点与公交的接驳功能、营造系统化的绿地与开敞空间、完善社区公共服务功能等系列优化对策,为今后公共交通为导向的开发当中的类似问题提供借鉴与参考.

印度洋东经90°海岭表层沉积物浮游有孔虫分布特征及其影响因素

对东印度洋90°海岭附近海域82个表层沉积物样品中的浮游有孔虫进行鉴定统计分析,揭示了研究区表层沉积物中浮游有孔虫区域分布特征,并对其影响因素进行了初步探讨。研究表明,东印度洋90°海岭附近海域表层沉积物中浮游有孔虫呈现典型的热带-亚热带组合特征,共鉴定出浮游有孔虫30种。运用聚类分析,得到3个浮游有孔虫组合:组合类群Ⅰ主要分布在5°~10°N的孟加拉湾南部开阔海域,主要种属包括Globigerinoides sacculifer, Globigerinoides ruber, Neogloboquadrina dutertrei,体现了生产力及海水盐度对有孔虫组合的影响;组合类群Ⅱ主要在5°N至5°S,沿东经90°海岭分布。主要种属包括Globigerinoides ruber,Globorotalia menardii,Neogloboquadrina dutertrei,体现了水深及生产力对有孔虫组合的影响;组合类群Ⅲ对称分布在组合类群Ⅱ两侧水深较深的海域,主要种属包括Globorotalia tumida, Globorotalia menardi, Pulleniatina obliquiloculata,体现了水深对有孔虫组合特征的影响。根据有孔虫组合类群分布特征,推断水深、盐度及生产力是影响本海域浮游有孔虫分布的最主要因素。

Genesis of ^(230)Th excess in basalts from mid-ocean ridges and ocean islands:Constraints from the global U-series isotope database and major and rare earth element geochemistry

Based on 230Th-238U disequilibrium and major element data from mid-ocean ridge basalts(MORBs) and ocean island basalts(OIBs),this study calculates mantle melting parameters,and thereby investigates the origin of 230Th excess.(230Th/238U) in global MORBs shows a positive correlation with Fe8,Po,Na8,and Fmelt(Fe8 and Na8 are FeO and Na2O contents respectively after correction for crustal fractionation relative to MgO = 8 wt%,Po=pressure of initial melting and Fmelt=degree of melt),while 230Th excess in OIBs has no obvious correlation with either initial mantle melting depth or the average degree of mantle melting.Furthermore,compared with the MORBs,higher(230Th/238U) in OIBs actually corresponds to a lower melting degree.This suggests that the 230Th excess in MORBs is controlled by mantle melting conditions,while the 230Th excess in OIBs is more likely related to the deep garnet control.The vast majority of calculated initial melting pressures of MORBs with excess 230Th are between 1.0 and 2.5 GPa,which is consistent with the conclusion from experiments in recent years that DU】DTh for Al-clinopyroxene at pressures of 】1.0 GPa.The initial melting pressure of OIBs is 2.2-3.5 GPa(around the spinel-garnet transition zone),with their low excess 226Ra compared to MORBs also suggesting a deeper mantle source.Accordingly,excess 230Th in MORBs and OIBs may be formed respectively in the spinel and garnet stability field.In addition,there is no obvious correlation of K2O/TiO2 with(230Th/238U) and initial melting pressure(Po) of MORBs,so it is proposed that the melting depth producing excess 230Th does not tap the spinel-garnet transition zone.OIBs and MORBs in both(230Th/238U) vs.K2O/TiO2 and(230Th/238U) vs.Po plots fall in two distinct areas,indicating that the mineral phases which dominate their excess 230Th are different.Ce/Yb-Ce curves of fast and slow ridge MORBs are similar,while,in comparison,the Ce/Yb-Ce curve for OIBs shows more influence from garnet.The mechanisms generating excess 230Th in MORBs and OIBs are significantly different,with formation of excess 230Th in the garnet zone only being suitable for OIBs.

武当山十堰地区二叠纪E-MORB型玄武岩识别及构造意义

大比例尺构造—岩相填图和测试分析研究显示南秦岭武当山并非统一前寒武纪基底组成,在十堰和两郧断裂之间的黄龙—方滩及丹江口银洞山等地区识别和厘定出一套中生代混杂岩带,开展混杂岩带内物质组成和成因研究对正确认识武当山造山作用和区域构造演化有重要意义。本文重点对武当山十堰黄龙—方滩地区混杂岩带内玄武岩块体岩石成因及时代进行研究,岩石地球化学显示玄武岩块体为亚碱性拉斑玄武岩系列,具有中等Ti、Zr、Hf、Nd含量、弱轻稀土富集重稀土亏损的E-MORB(Enriched Mid-ocean ridge basalt,富集型洋中脊玄武岩)特征,其岩浆为尖晶石二辉橄榄岩低压、高度部分熔融形成,源区可能受富集地幔或俯冲作用等影响导致富集高场强不相容元素;锆石U-Pb测年表明其为中二叠世火山作用产物;区域地质特征及岩石成因研究共同指示该套E-MORB形成于洋中脊或附近海山环境。综上,武当山十堰地区中—晚二叠世存在洋盆,该成果为理解十堰黄龙—方滩混杂岩带成因机制和正确认识南秦岭显生宙构造属性提供了基础资料。

起垄栽培对夏玉米生态环境及生长发育的影响

研究了起垄栽培对夏玉米生态环境及生长发育的影响 结果表明 ,土壤垄作在一定程度上改进了耕层的土壤结构 ,提高了土壤温度 ,协调了土壤三相比 垄面 5 5cm以内土壤容重减少 1 2 5 % ,孔隙度增大 1 7 8% ,田间小气候改善 ,风速变大 ,基部CO2 的含量升高了 6 6 % 促进了根系的发育 ,干物质积累增多 ,叶面积指数增大 ,后期表现出较好的保绿性 ,茎鞘和叶片干重提高 ,输出减少 ,子粒灌浆速率增大 ,千粒重增加 2 6 7g ,单株地上部总干重增加 32g 同时 ,植株倒伏率和空秆率明显减少 ,株高、穗位高降低 ,收获指数提高 ,穗部性状较好 ,产量比平作增产 1 1 7% .

大垄栽培条件下的土壤环境与马铃薯产量

试验进行了大垄与小垄两种栽培模式下的一些土壤环境因子及马铃薯产量的差异研究,结果表明:大垄栽培改善了结薯区及根区的土壤生态环境,使该区的土壤容重和出苗后10￣25cm耕层土壤温度显著降低;使20￣30cm土壤含水量显著地增加;促进了养分释放;大垄栽培相对于小垄使马铃薯总产量和商品薯产量明显增加,且均达到极显著水平。大垄栽培使总产增加24.31%,商品薯产量增加得更大,达到61.74%。大垄栽培是可以在黑龙江省大范围推广的栽培方式。