Accelerated plasma degradation of organic pollutants in milliseconds and examinations by mass spectrometry

The rapid degradation of organic pollutants,process monitoring and online controlling to obtain advanced products and decreased by-products are great and challenging tasks in environmental treatments.Herein,an accelerated plasma degradation in milliseconds was achieved by combining electrospray-based acceleration and plasma-based degradation.Taking the degradation of chloroaniline as an example,97%of the degradation can be achieved in milliseconds.The velocity distribution of droplets was determined to be 40-50 m/s after being degraded for 0.30 ms,which exhibited different degradation behaviors in different milliseconds.Simultaneously,by virtue of the real-time and on-line detection ability of ambient mass spectrometry,intermediates,by-products and advanced products were monitored.Therefore,degradation mechanisms for different degradation times were proposed,which would provide theoretical guidance on obtaining efficient and green degradation.The fabrication,examining and understanding of accelerated plasma degradation not only enlarged application of accelerated reactions,but also promoted green and efficient degradation for environmental treatments.

Millisecond dynamics of colloidal suspension studied by X-ray photon correlation spectroscopy at the Shanghai Synchrotron Radiation Facility

X-ray photon correlation spectroscopy(XPCS)has emerged as a powerful tool for probing the nanoscale dynamics of soft condensed matter and strongly correlated materials owing to its high spatial resolution and penetration capabilities.This technique requires high brilliance and beam coherence,which are not directly available at modern synchrotron beamlines in China.To facilitate future XPCS experiments,we modified the optical setup of the newly commissioned BL10U1 USAXS beamline at the Shanghai Synchrotron Radiation Facility(SSRF).Subsequently,we performed XPCS measurements on silica suspensions in glycerol,which were opaque owing to their high concentrations.Images were collected using a high frame rate area detector.A comprehensive analysis was performed,yielding correlation functions and several key dynamic parameters.All the results were consistent with the theory of Brownian motion and demonstrated the feasibility of XPCS at SSRF.Finally,by carefully optimizing the setup and analyzing the algorithms,we achieved a time resolution of 2 ms,which enabled the characterization of millisecond dynamics in opaque systems.

Numerical study on the fracturing mechanism of shock wave interactions between two adjacent blast holes in deep rock blasting

With the application of electronic detonators, millisecond blasting is regarded as a signifi cant promising approach to improve the rock fragmentation in deep rock blasting. Thus, it is necessary to investigate the fracturing mechanisms of short-delay blasting. In this work, a rectangle model with two circle boreholes is modeled as a particles assembly based on the discrete element method to simulate the shock wave interactions induced by millisecond blasting. The rectangle model has a size of 12 × 6 m (L × W) and two blast holes have the same diameter of 12 cm. The shock waves are simplifi ed as time-varying forces applied at the particles of walls of the two boreholes. Among a series of numerical tests in this study, the spacing between two adjacent boreholes and delay time of millisecond blasting are considered as two primary variables, and the decoupling charge with a coeffi cient of 1.5 is taken into account in each case. The results show that stress superposition is not a key factor for improving rock fragmentation (tensile stress interactions rather than compressive stress superposition could aff ect the generation of cracks), whereas collision actions from isolated particles or particles with weakened constraints play a crucial role in creating the fracture network. The delay time has an infl uence on causing cracks in rock blasting, however, whether it works heavily depends on the distance between the two holes.

Influence of millisecond time,charge length and detonation velocity on blasting vibration

The law of blasting vibration caused by blasting in rock is very complex.Traditional numerical methods cannot well characterize all the influencing factors in the blasting process.The effects of millisecond time,charge length and detonation velocity on the blasting vibration are discussed by analyzing the characteristics of vibration wave generated by finite length cylindrical charge.It is found that in multi-hole millisecond blasting,blasting vibration superimpositions will occur several times within a certain distance from the explosion source due to the propagation velocity difference of P-wave and S-wave generated by a short column charge.These superimpositions will locally enlarge the peak velocity of blasting vibration particle.The magnitude and scope of the enlargement are closely related to the millisecond time.Meanwhile,the particle vibration displacement characteristics of rock under long cylindrical charge is analyzed.The results show that blasting vibration effect would no longer increase when the charge length increases to a certain extent.This indicates that the traditional simple calculation method using the maximum charge weight per delay interval to predict the effect of blasting vibration is unreasonable.Besides,the effect of detonation velocity on blasting vibration is only limited in a certain velocity range.When detonation velocity is greater than a certain value,the detonation velocity almost makes no impact on blasting vibration.

Improved catalytic performance of Ni catalysts for steam methane reforming in a micro-channel reactor

Milliseconds process to produce hydrogen by steam methane reforming （SMR） reaction, based on Ni catalyst rather than noble catalyst such as Pd, Rh or Ru, in micro-channel reactors has been paid more and more attentions in recent years. This work aimed to further improve the catalytic performance of nickel-based catalyst by the introduction of additives, i.e., MgO and FeO, prepared by impregnation method on the micro-channels made of metal-ceramic complex substrate. The prepared catalysts were tested in the same micro-channel reactor by switching the catalyst plates. The results showed that among the tested catalysts Ni-Mg catalyst had the highest activity, especially under harsh conditions, i.e., at high space velocity and/or low reaction temperature. Moreover, the catalyst activity and selectivity were stable during the 12 h on stream test even when the ratio of steam to carbon （SIC） was as low as 1.0. The addition of MgO promoted the active Ni species to have a good dispersion on the substrate, leading to a better catalytic performance for SMR reaction.

Vibration Superposition in Tunnel Blasting with Millisecond Delay

According to explosion dynamics and elastic wave theory, the models of particle vibration velocity for simultaneous blasting and milliseeond blasting are built. In the models, influential factors such as delay interval and charge quantity, are considered. The calculated vibration velocity is compared with the field test results, which shows that the theoretical values are close to the experimental ones. Meanwhile, the particle vibration velocity decreases quickly with time due to the damping of rock mass and has a harmonic motion, and the particle vibration velocity of millisecond blasting has short interval. The superposition of particle vibration velocities may reduce vibration because of wave interference, or magnify the surrounding rock response to the blastinginduced vibration.

The Process of a Laser-Supported Combustion Wave Induced by Millisecond Pulsed Laser on Aluminum Alloy

We study the process of a laser-supported combustion wave （LSCW） when an aluminum alloy is irradiated by a millisecond pulse laser based on the method of laser shadowgraphy. Under the condition of different laser parameters, the obtained results include the velocity, ignition threshold of LSCW and the variation law. The speed of LSCW increases with the laser energy under the same irradiation laser pulse width, and the speed of LSCW reduces with the increase of the laser pulse width under the same irradiation laser energy. Moreover, the ignition time of LSCW becomes shorter by increasing the laser number of the pulse and is not effected by changing the frequencies, when keeping the laser pulse width and energy unchanged. The results of the study can be applied in the laser propulsion technology and metal surface laser heat treatment, etc.

Effects of dynamo magnetic fields on observational properties of accreting millisecond X-ray pulsars

In this paper,we have investigated accreting millisecond X-ray pulsars,which are rapidly rotating neutron stars in low-mass X-ray binaries.These systems exhibit coherent X-ray pulsations that arise when the accretion flow is magnetically channeled to the stellar surface.Here,we have developed the fundamental equations for an accretion disk around accreting millisecond X-ray pulsars in the presence of a dynamo generated magnetic field in the inner part of the disk.We have also formulated the numerical method for the structure equations in the inner region of the disk and the highest accretion rate is enough to form the inner region of the disk,which is overpowered by radiation pressure and electron scattering.Finally,we have examined our results with the effects of dynamo magnetic fields on accreting millisecond X-ray pulsars.

Astrophysics: Macroobject Shell Model

The model proposes that Nuclei of all macroobjects (Galaxy clusters, Galaxies, Star clusters, Extrasolar systems) are made up of Dark Matter Particles (DMP). These Nuclei are surrounded by Shells composed of both Dark and Baryonic matter. This model is used to explain various astrophysical phenomena: Multi-wavelength Pulsars;Binary Millisecond Pulsars;Gamma-Ray Bursts;Fast Radio Bursts;Young Stellar Object Dippers;Starburst Galaxies;Gravitational Waves. New types of Fermi Compact Stars made of DMP are introduced: Neutralino star, WIMP star, and DIRAC star. Gamma-Ray Pulsars are rotating Neutralino and WIMP stars. Merger of binary DIRAC stars can be a source of Gravitational waves.

Investigating the Thermal Stress of Millisecond Pulsed Laser Irradiation on Charge-Coupled Devices

In this study, a two-dimensional model describing thermal stress on a charge-coupled device (CCD) induced by ms laser pulses was examined. Considering the nonlinearity of the CCD’s material parameters and the melting phase transition process of aluminum electrode materials was considered by using equivalent specific heat capacity method, the physical process where a laser pulse irradiating a CCD pixel array was simulated using COMSOL Multiphysics software. The temperature field and thermal stress field were calculated and analyzed. In order to clarify the mechanism producing damage on the CCD detector, Raman spectra from silicon were measured with a micro-Raman spectrometer to determine stress change in the CCD chip. The procedure presented herein illustrates a method for evaluating strain in a CCD after laser irradiation.

Influence of delay interval on blasting efficiency of parallel hole cuts with an empty hole

Time interval of short delay ignition is an important factor to affect theefficiency of blasting cuts. The motion process of rock pieces in the cut cavity is analyzed, amechanical model to calculate the delay time of parallel hole cuts is presented for tunnel blasting,and a theoretical method to determine the volume ratio (the clearage rate) of the rock pieceswithin the cut cavity at different moments is proposed for the blasting cut with an empty hole.Numerical analysis results show that the optimal delay interval is proportional to the boreholedepth. The suggested results are of practical value to the optimal design of the delay interval inmillisecond blasting related to the parallel hole cuts with an empty hole.

Magnetic Loop Oscillation Associated with a Large Type-Ⅳμ Burst and Millisecond Spike Emission

A rare large Type Ⅳμ burst, appeared above active region NOAA/USAF 5278 was observed at Yunnan Observatory with Phoenix Ⅱ Microwave Spectrometer at three frequencies (4 00, 2 84 and 1 42 GHz) on December 16, 1988. The burst consisted of 5 main peaks with a quasiperiod of 12 5 min, on which many complex millisecond spike emissions were superimposed. Within the first main peak there were 8 secondary peaks with a quasi period of 98s (at 4 00 GHz), 72s (2 84 GHz) and 60s (1 42 GHz). A semi quantitative explanation is given for the variation of the quasi period with frequency in terms of MHD modulated oscillations in the magnetic flux tube.

Polynomial regression calculation of the Earth's position based on millisecond pulsar timing

Prior to achieving high precision navigation of a spacecraft using X-ray observations, a pulsar rotation model must be built and analysis of the precise posi- tion of the Earth should be performed using ground pulsar timing observations. We can simulate time-of-arrival ground observation data close to actual observed values before using pulsar timing observation data. Considering the correlation between the Earth＇s position and its short arc section of an orbit, we use polynomial regression to build the correlation. Regression coefficients can be calculated using the least square method, and a coordinate component series can also be obtained; that is, we can calcu- late Earth＇s position in the Barycentric Celestial Reference System according to pulse arrival time data and a precise pulsar rotation model. In order to set appropriate param- eters before the actual timing observations for Earth positioning, we can calculate the influence of the spatial distribution of pulsars on errors in the positioning result and the influence of error source variation on positioning by simulation. It is significant that the threshold values of the observation and systematic errors can be established before an actual observation occurs; namely, we can determine the observation mode with small errors and reject the observed data with big errors, thus improving the positioning result.

Microwave Millisecond Spikes on July 30, 1997

The characteristics of the millisecond spikes with short durations and weak flux densities which were observed with high time resolution (1 ms) during a great type Ⅳ solar radio burst of 1990 July 30 are introduced. The time profiles of the spikes are statistically analyzed and the parameters of the spike source are also estimated.

Aggregation-induced conversion from TADF to phosphorescence of gold(I)complexes with millisecond lifetimes

Long-lived luminescent materials possess wide application prospects in various areas,but their constructions still face a huge challenge,especially the achievement in solution.Manipulating aggregate is an effective method to attain intriguing luminescence,thus it is expected to build long-lived materials in solution.In this work,a series of new gold(I)complexes were developed by employing unique carbazole and phosphine as the ligands,and these resulting systems exhibited rare long lifetimes of milliseconds in the aggregate state.It was well unveiled that these complexes emitted blue thermally activated delayed fluorescence(TADF)with the lifetimes of several microseconds in dilute solution;while orange-red phosphorescence with much longer lifetimes of several milliseconds were achieved in the aggregate state.To our knowledge,this is the first implementation of aggregation-induced conversion from TADF to phosphorescence.Based on their excellent luminescent properties,we successfully applied these complexes in cell imaging and inhibition of cancer cells.

Enhancement in wheat leaf photophosphorylation and photosynthesis by spraying low concentration of NaHSO_3

Spraying 1-2 mmol/L NaHSO3 on the leaf of wheat results in enhancement of photosynthesis in leaves for about 3 d. The amount of ATP has been increased and the millisecond delayed light emission of the leaves has been enhanced, showing that the transmembrane proton motive force related to photophosphorylation is increased. Spraying PMS (a cofactor catalyzing cycle photophosphorylation) and NaHSO3 separately or together on the leaves, 20% increase in photosynthesis has been observed in all the treatments. There is no additive effect when a mixture is applied, suggesting that the mechanism for NaHSO3 promotion of photosynthesis is similar to PMS, and both of them enhance the supply of ATP.

Relationship between components of proton motive force and photosynthesis

The proton motive force formed across the thylakoid membrane accompanying the photosynthetic electron transport can be used to synthesize ATP from ADP and inorganic phosphate for carbon assimilation. The mechanism of this important process has been intensively studied. However, there are still many aspects unsolved. For example: What is the ratio between the ATP and NADPH formed in noncyclic photophosphorylation and can it meet the requirement of carbon assimilation? Is there any localized proton within thylakoid membrane and is it related to the effi-

THE CONNECTION BETWEEN PROTONS RELEASED BY WATER OXIDATION AND CF_0 OF H^+-ATPase COMPLEX

There are two proton release sites on the photosynthetic electron transport chain. One is the protons released by water oxidation of the photosystem Ⅱ （PS Ⅱ） oxygen evolution complex located on the inner side of the thylakoid membrane (i. e. HH2O+), the other is the protons transferred across the thylakoid membrane and released on the inner side of