Redetermination of the Depositional Age of the Haerdaban Group in the Northern Margin of the Yili Block,Western Tianshan,NW China:Implications for Regional Tectonics and Pb-Zn Mineralization

The Yili Block in the Western Tianshan orogen is a key area for understanding the early crustal formation and evolution of the Central Asian orogenic belt,due to the widely-distributed Precambrian rocks.Also,it hosts a lot of medium–to large-scale sedimentary exhalative(SEDEX)Pb-Zn deposits that mainly occur in Proterozoic metamorphosed clasticcarbonate rocks.In this study,LA-ICP-MS U-Pb analyses were carried out on detrital zircons in siltstones of the Precambrian Haerdaban Group in the Haerdaban Pb-Zn deposit and magmatic zircons in the diorite dyke that cuts through the strata and orebodies.The maximum depositional age of the siltstones was determined to be about 604 Ma,the diorite having formed at approximately 500 Ma.As such,the Haerdaban Group was most likely formed in the Neoproterozoic Sinian,rather than the previously considered Mesoproterozoic Changchengian.Detrital materials of the Haerdaban Group were mostly derived from the Nanhua–Sinian mafic dykes and granitic rocks around Lake Sayram at the northern margin of the Yili Block.It is proposed that the Yili Block,together with the Kazakhstan and Central Tianshan blocks and the Tarim Craton,might all pertain to the same Rodinia supercontinent,which has great potential for targeting large to super-large SEDEX Pb-Zn deposits.

Mineralization Ages of the Jiapigou Gold Deposits,Jilin

The Jiapigou gold deposits are typical vein type deposits associated withArchaean greenstone belts in China. According to the crosscutting relationships between dykesand auriferous veins, single hydrothermal zircon U-Pb dating and quartz K-Ar,^(40)Ar-^(39)Ar andRb-Sr datings, the main mineralization stage of the Jiapigou deposit has been determined to be2469-2475 Ma, while mineralization superimposition on the gold deposit occurred in1800-2000 Ma and 130-272 Ma. They form a mineralization framework of one oldermetallogenic epoch (Late Archaean-Early Proterozoic) and one younger metallogenic epoch(Mesozoic) of gold deposits in Archaean greenstone belts in China.

Study on Mineralization Age of Xiaoban Gold Deposit, Fujian Province

The Xiaoban gold deposit is a large-size deposit recently found in middlearea of Fujian Province. It belongs to magmatic hydrothermal type occurred in Mayuan Groupmetamorphic rocks of Middle Proterozoic and is controlled by low angle fault (detachment)structures. The contents of Au in Mayuan Group metamorphic rocks, Caledonian-Indosinian deformedgranite and early Yanshanian granite are higher with Au enrichment coefficient of 2. 06-5.68, 5.11and 6.67 than those in other geological bodies. And the higher enrichment coefficients (>2) of Ag,S, Sn and Te are similar to those of gold ore. Meanwhile, the distribution of Au in Mayuan Groupmetamorphic rocks and early Yanshanian granite with a low D-value (0.58 and 0.67) is favorable togold mineralization. REE characteristics of gold ore, ratios of (LREE/HREE), (La/Sm)_n, (Yb/Lu)_n,(La/Tb)_n and (Sm/Nd)_n are similar to Mayuan Group metamorphic rocks, only non or little normal Euabnormal of ore is dissimilar to metamorphic rocks. The δ(^(34)S) of the gold ore, with a highhomogenization, is (-4.7X10^(-3) - (-2.7X 10^(-3)). The study of inclusion indicates 180-249℃ ofmineralization temperature, 3. 69 %-11. 81 % of salinities and 0. 869-0.991 g/cm^3 of densities ofmineralization fluid. Based on hydrogen and oxygen isotope (δ(^(18)O) = 11. 0 X 10^(-3) -11.7 X10^(-3), δ(D) = (-48 X 10^(-3)) - (-62 X 10^(-3))) and initial w(^(87)Sr)/w(^(86)Sr) =0. 715,combining to the analysis of geological history, regional metamorphism and magamtic activity, theauthors confirm that the source for the ore fluid was mainly from magmatic, partly from metamorphicwater, and with a little influence of meteoric water. Isotopic dating made on Rb-Sr isochron age of182 Ma, by using alteration minerals of gold-ores from the deposit, indicates that themineralization occurs in early Yanshanian epoch. This is close to the age of 187 Ma of the Anchunmagmatite with a similar alteration and gold mineralization to the Xiaoban gold deposit. The age ofearly Yanshanian epoch of the Xiaoban gold is indentical with the characteristics of southern Chinagold metal-logenic belt and the geotectonic evolution of the transition from paleo-Asian system andpaleo-Tethyan system to paleo-Pacific active continental margin in eastern Asia.

A New Potential Caledonian–Indosinian Ore Concentration Area:Evidence from Diagenesis and Mineralization Ages of the Miao'ershan–Yuechengling Region

Objective The Miao＇ershan-Yuechengling composite granite, located in northern Guangxi at the western section of the Nanling Range, is a multi-period and multi-stage composite pluton with an exposed area of more than 3000 km2 （Fig. 1）. Paleozoic and Proterozoic strata are exposed around it, and magmatic activities mainly occurred during the Caledonian and Indosinian periods. Till now, more than one hundred W-Sn-Mo-Pb-Zn-Cu （U） deposits and ore occurrences have been discovered along the inner and outer contact zones of this granite. Through recent years＇ research, we infer that this area is not only a preferred area for studying granite and mineralization in Caledonian and lndosinian periods, but also a potential Caledonian- lndosinian ore-concentrated area.

The Late Cretaceous Crustal Magmatism of the Geza Arc Metallogenic Belt in Yunnan Province,and Zircon Ages and Hf Isotopic Evidence of the Porphyry Cu-Mo Mineralization

Objective The Geza arc in Yunnan Province,located in the southern Yidun arc,is an important part of the Sanjiang tectonic-magmatic belts in southwestern China and is a newly discovered copper polymetallic ore-concentrating district.Recent studies show that the newly discovered Yanshanian porphyry Cu-Mo polymetallic mineralization superimposed in the Indosinian porphyry copper belt in this area.

Petrogenesis of Oligocene Granitoids and its Implications on Beryllium Mineralization at Pagele,Nianqingtanggula Mountain(Central Tibet)

The newly discovered Oligocene granitoids(33.1-28.7 Ma)at Pagele are magmatic rocks related to beryllium mineralization during the India-Asia late-collisional stage.This discovery provides an ideal example to study the latecollisional orogeny and beryllium prospecting in the Lhasa terrane.The Oligocene granitoids include porphyritic granodiorite,StageⅠ,ⅡandⅢgranites,and granitic pegmatite.Geochemical analysis shows that the porphyritic granodiorite is characterized by high SiO_(2),K_(2)O,totalΣREE contents,and(La/Yb)N ratios;while the latter two by higher SiO_(2),lowerΣREE and(La/Yb)N ratios.Notably,the granitic pegmatite has extremely high Y/Ho,low K/Rb and Zr/Hf,and distinct REE tetrad effect(1.14-1.21).This study suggests that the porphyritic granodiorite may be derived from partial melting of beryllium-rich materials composed of Lhasa ancient crust(70%-80%)and enriched Lhasa lithospheric mantle(20%-30%)under the tearing subduction of Indian slab.The three-stage granites and granitic pegmatite,which contain higher beryllium contents or beryls,were likely generated by highly fractionation of the porphyritic granodioritic magma or other homologous magma.Considering the possible genetic and spatial link between Indian slab tear and rifts,we suggest that highly-fractionated granites in rifting systems represent important Be prospecting targets in the Lhasa terrane.

New Zircon U-Pb Age of the Badu Dolerite:Implications for Yanshanian Magmatic Gold Mineralization within the Youjiang Basin, Southwest China

Objective The Youjiang basin,also named"Dian-Qian-Gui Golden Triangle",contains a cluster of Carlin-like gold deposits(Deng and Wang,2016).Due to the uncertainty of mineralization age and the absence of coetaneous magmatic rocks(Chen et al.,2015),the relationship between magmatism and Au mineralization still remains controversial in recent years(Hou et al.,2016).The Late

Phosphogypsum Pyrolysis by Adding Mineralization Agent:Process and Mechanism

In order to decrease energy consumption for phosphogypsum(PG)pyrolysis process,a pilot-scale vertical-retort furnace was designed initiatively,and then mineralization agent was added to pyrolysis mixture.Calcium fluoride(CaF_(2))was proven to be a suitable mineralization agent,and the optimal parameters were:pyrolysis temperature 960℃,carbon-sulfur mole ratio 0.7,reaction time 50 min,and CaF_(2)dosage 4%by weight.Under this condition,PG decomposition and sulfur dioxide(SO_(2))conversion were up to 89.6%and 67.3%,respectively.CaF_(2)could lead to the formation of fluosilicate complexes,and facilitate PG decomposition at a low temperature.During pyrolysis process,calcium sulfide(CaS)was an inevitable intermediate substance,and only a part of total sulfur in the feedstock could be converted to SO_(2).

Characteristics of soil organic carbon mineralization and influence factor analysis of natural Larix olgensis forest at different ages

Soil organic carbon(SOC)mineralization is closely related to carbon source or sink of terrestrial ecosystem.Natural stands of Larix olgensis on the Jincang forest farm,Jilin Province were selected to investigate the dynamics of SOC mineralization and its correlations with other soil properties in a young forest and mid-aged forest at soil depths of 0–10,>10–20,>20–40 and>40–60 cm.The results showed that compared with a mid-aged forest,the SOC stock in the young forest was 32%higher.Potentially mineralizable soil carbon(C0)in the young forest was 1.1–2.5 g kg^-1,accounting for 5.5–8.1%of total SOC during the 105 days incubation period and 0.3–1.5 g kg^-1 in the mid-aged forest at different soil depths,occupying 2.8–3.4%of total SOC.There was a significant difference in C0 among the soil depths.The dynamics of the SOC mineralization was a good fit to a three-pool(labile,intermediate and stable)carbon decomposition kinetic model.The SOC decomposition rate for different stand ages and different soil depths reached high levels for the first 15 days.Correlation analysis revealed that the C0 was significantly positively related with SOC content,soil total N(TN)and readily available K(AK)concentration.The labile soil carbon pool was significantly related to SOC and TN concentration,and significantly negatively correlated with soil bulk density.The intermediate carbon pool was positively associated with TN and AK.The stable carbon pool had negative correlations with SOC,TN and AK.

MINERALIZATION AGES OF GOLD-HYDROTHERMAL DEPOSITS IN NORTHERN ZONE OF EASTERN KUNLUN MOUNTAINS BASED ON FISSION TRACK ANALYSIS

The age of mineralization in a mining area is a primary factor in various researches related to ore\|forming process. It is that the uncertainty of mineralization ages of gold ore deposits in northern zone of eastern Kunlun Mountains, Qinghai Province, restrains to probe the relationship of the deposits to the regional tectonic evolution. This paper documents the fission track method used to determine the ages of gold ore deposits in eastern Kunlun Mountains and considers the implication for the origin of the deposits.Eastern Kunlun Mountains is the northern part of the Qinghai—Tibet Plateau and is of three deep\|seated fault belts in about EW extension. This work mainly includes three gold ore districts. All of them, in the north of Mid\|Kunlun fault belt, belong to northern part of eastern Kunlun Mountains. The Yanjingou district, with geographical coordinate 96°00’E and 36°10’N, is located 60 km north of Hongqigou district . Both of them are large, typical tectonoalteration gold deposits and were formed in similar geological setting. Hongshuihe ore district is located 50 km east of Yanjingou district and includes tectonoalteration and magmatic cryptoexplosive gold deposits. Outcroped strata are dominantly Jinshuikou Group metamorphic rocks of Lower Proterozoic erathem. The occurrence area of igneous rocks, especially granitoid, accounts for about 90% in first two districts and become less in Hongshuihe district. The gold deposits occur in NW\|striking fault belts. The Rb\|Sr isochron age and K\|Ar isotopic age of Moyite relevant to the gold mineralization are respectively 228 25Ma and 207 1Ma. Rb\|Sr dating of diorite porphyrite is 209 09Ma. Sericite selected from Yanjingou orebody has 252 9Ma K\|Ar age. The ore in Hongqigou district has 197Ma K\|Ar age and 210Ma model age of Pb isotope of galena.

Chronology of the Tungsten Deposits in Southern Jiangxi Province, and Episodes and Zonation of the Regional W-Sn Mineralization-Evidence from High-precision Zircon U-Pb, Molybdenite Re-Os and Muscovite Ar-Ar Ages

Previous studies have obtained some petrogenetic and metallogenic chronological data with SHRIMP （sensitive high-resolution ion microprobe） zircon U-Pb, zircon LA-ICPMS （laser-ablation-inductively coupled plasma mass spectroscopy） U-Pb, molybdenite Re-Os isochron and muscovite Ar-Ar methods in southern Jiangxi Province and its adjacent areas. Based on these, the purpose of this paper is to study the petrogenetic and metallogenic ages and their time gap for different genetic types of W-Sn deposits, and thus to research their numerous episodes, zonal arrangement and their geodynamic background. The result shows that the large-scale W-Sn mineralization in southern Jiangxi Province occurred in the middle to late Jurassic （170-150 Ma）, the skarn W-Sn-polymetallic deposits formed much earlier （170-161 Ma）, and all of the wolframite-quartz vein type, greisen type, altered granite type and fractured zone type tungsten deposits formed in the late Jurassic （160-150 Ma）. In one ore field or ore district, greisen type tungsten deposits formed earlier than quartz vein type ones hosted in the endoor exo-contact zone; and quartz vein type hosted in the endocontact zone formed earlier than that of exocontact zone. There is no significant time difference between tungstentin mineralization and its intimately associated parent granite emplacement （1-6 Ma）. They all formed in the same rock-forming and ore-forming system and under the same geodynamic setting. Regionally, rock-forming and ore-forming processes of the W-Sn deposits in the Nanling region （include southern Jiangxi Province, southern Hunan Province, northern Guangdong Province and eastern Guangxi Zhuang Autonomous Region） exhibit numerous episodes. The mineralization in the Nanling region mainly occurred at （240-210） Ma, （170-150） Ma and （130-90） Ma. The tungsten-tin deposits in this region are centered by the largest scale in southern Jiangxi Province and southern Hunan Province, and become small in the east, west, south and north directions. This displays a zonal arrangement and temporal and spatial distribution regularity. Integrated with the latest research results, it is concluded that the W-Sn mineralization in southern Jiangxi Province and its adjacent areas corresponds to the second large-scale mineralization in South China. The Indosinian W-Sn mineralization formed under the extensional tectonic regime between collisional compressional stages, while the Yanshanian large-scale petrogenetic and metallogenic processes occurred in the Jurassic intraplate extensional geodynamic setting of lithosphere extension.

Early Mineralization Age of the Hengjian Uranium Deposit: Constraints from Zircon SIMS U-Pb Dating

Objective The Hengjian uranium deposit is a typical hydrothermal deposit in the Xiangshan uranium ore field.The uranium mineralization ages of the Xiangshan deposits are poorly constrained,and only a few mineralization ages using the pitchblende U–Pb method have been published.These ages are commonly discordant and dispersed for abundant inclusions and an open U–Pb system.Zircon grains after strong hydrothermal alteration are usually characterized by high common Pb contents,and their U–Pb isochron ages recorded the hydrothermal alteration event without interference of common Pb components.The Hengjian gray/grayish-green granite porphyry experienced strong alteration by hydrothermal fluids during the pervasive uranium mineralization in the Xiangshan uranium ore field.Uranium mineralization in the Hengjian deposit may had different stages,and strong hydromicatization alteration occurred at a relatively early stage.Their altered zircon U–Pb isochron ages possibly represent relatively early mineralization age of the Xiangshan uranium deposits.Altered zircon grains from the Hengjian granite porphyry were analyzed using the secondary ion mass spectrometry(SIMS)U-Pb method in this study,and U–Pb isochron ages were measured to constrain the relatively early mineralization age of the Hengjian uranium deposit.

Zircon SIMS U-Pb Age of the Shaxinan Melagabbro, Eastern Tianshan and Constraints on Fe-Ti-V Oxide Mineralization

Objective The late Paleozoic Fe-Ti-V oxide deposit of the eastern Tianshan is an important orthomagmatic deposit type in the Central Asia Orogenic Belt （CAOB）. A series of Fe-Ti -V oxide deposits and mineralized mafic-ultramafic intrusions have been recognized recently, such as those in Hongliangzi, Weiya, Yaxi, Shaxinan and Shaxi on the Central Tianshan massif, and Niumaoquan on the southern margin of the Harlik belt （Shi et al., 2018a）. Only a few Fe -Ti-V oxide deposits in the eastern Tianshan （e.g., Weiya and Niumaoquan） have been studied, and their chronology need to be further constrained for study of regional Fe-Ti- V oxide metallogenic mechanism and variation of mantlederived magmas during the orogenic process.

Robust Timing Constraints for Granitic Magmatism and Hydrothermal Mineralization in the Tieshanlong W-Sn Ore Field,Eastern Nanling Range,South China

The Tieshanlong ore field is an important part of the Nanling Range,which is famous worldwide for its W-Sn mineralization.Notably,the mineralization age of the Tieshanlong ore field is not well constrained,and our field investigation reveals that granitic emplacement occurred at different stages.However,previous studies have not distinguished these multiple stages of magmatism.The Tieshanlong granite complex is closely related to the Huangsha quartz vein-type W-Sn deposit and Tongling skarn-type Cu-W-Sn deposit in this field.Through field investigations and isotopic age analyses,this work studies the relationship between multistage magmatic activity and mineralization in the Tieshanlong ore field.LA-ICP-MS zircon U-Pb isotope analyses revealed that the first-and second-staged granites formed at 154.2±0.6 Ma(MSDW=1.4)and 151.2±0.4 Ma(MSDW=1.5),with zirconε_(Hf)(t)values ranging from-13.1 to-10.5 and from-14.7 to-11.1,respectively.These data suggest that the Tieshanlong granite complex was derived from the partial melting of ancient crustal material.LA-ICP-MS U-Pb dating of wolframite and cassiterite reveals that W-Sn mineralization occurred at 160-150 Ma,which agrees well with the U-Pb dating results of the second-staged granite within analytical errors.The magmatic activity in this ore field can be divided into three stages:175-154 Ma,154-150 Ma and 150-145 Ma.The quartz vein-and skarn-type W-Sn mineralization is closely related to second-staged fine-grained twomica granite,and formed earlier than skarn-type Cu-mineralization.This study establishes a metallogenic model for the Tieshanlong ore field,and this model has important practical significance for identifying concealed W-Sn(-Cu)deposits around other granitic complexes in the Nanling Range.

The Exploration of Teaching Historical Narratives Through Edith Wharton’s The Age of Innocence

Wharton’s novels serve as compelling cases for understanding the complexities of late 19th-century American society.The paper uses The Age of Innocence as an example to examine detailed depiction of the era’s social hierarchy,fashion,architecture,and the intricate social rituals that defined New York’s upper class.It explores the constraints and dilemmas women faced within a patriarchal society,highlighting Wharton’s personal experiences and her critical stance on the social norms of her time.The characters of Newland Archer,May Welland,and Ellen Olenska are analyzed to reveal the pressures of societal expectations and the struggles for individual desires within a rigid social structure.Additionally,the paper proposes various teaching methods,including contextual understanding,literary analysis with a historical focus,and historical research projects,to enhance students’comprehension of the cultural and historical context of the novel.These methods aim to immerse students in the narrative and promote their understanding of the Gilded Age’s social dynamics.

Research progress of CO_(2) capture and mineralization based on natural minerals

Natural minerals,such as kaolinite,halloysite,montmorillonite,attapulgite,bentonite,sepiolite,forsterite,and wollastonite,have considerable potential for use in CO_(2) capture and mineralization due to their abundant reserves,low cost,excellent mechanical prop-erties,and chemical stability.Over the past decades,various methods,such as those involving heat,acid,alkali,organic amine,amino sil-ane,and ionic liquid,have been employed to enhance the CO_(2) capture performance of natural minerals to attain high specific surface area,a large number of pore structures,and rich active sites.Future research on CO_(2) capture by natural minerals will focus on the full utiliza-tion of the properties of natural minerals,adoption of suitable modification methods,and preparation of composite materials with high specific surface area and rich active sites.In addition,we provide a summary of the principle and technical route of direct and indirect mineralization of CO_(2) by natural minerals.This process uses minerals with high calcium and magnesium contents,such as forsterite(Mg_(2)SiO_(4)),serpentine[Mg_(3)Si_(2)O(OH)_(4)],and wollastonite(CaSiO_(3)).The research status of indirect mineralization of CO_(2) using hydro-chloric acid,acetic acid,molten salt,and ammonium salt as media is also introduced in detail.The recovery of additives and high-value-added products during the mineralization process to increase economic benefits is another focus of future research on CO_(2) mineralization by natural minerals.

Basalt Petrology, Water Chemistry, and Their Impact on the CO_(2) Mineralization Simulation at Leizhou Peninsula Sites, Southern China

Mineral carbonation, which precipitates dissolved carbon dioxide(CO_(2)) as carbonate minerals in basaltic groundwater environments, is a potential technique for negative emissions. The Leizhou Peninsula in southwest Guangdong province has extensive basalt, indicating a promising potential for CO_(2) storage through rapid mineralization. However, understanding of the basic geological setting, potential, and mechanisms of CO_(2) mineralization in the basalts of the Leizhou Peninsula is still limited. The mineralization processes associated with CO_(2)storage at two candidate sites in the area are investigated in this paper: Yongshi Farm and Tianyang Basin(of the dried maar lake). Petrography,rock geochemistry, basalt petrophysical properties, and groundwater hydrochemistry analyses are included in the study. Numerical simulation is used to examine the reaction process and its effects. The results show that basalts in the study areas mainly comprise plagioclase, pyroxene, and Fe–Ti oxides, revealing a total volume fraction exceeding 85%. Additionally, small amounts of quartz and fayalite are available, with volume fractions of 5.1% and 1.0%, respectively. The basalts are rich in divalent metal cations, which can form carbonate minerals, with an average of approximately 6.2 moles of metal cations per 1 kg of rock. The groundwater samples have a pH of 7.5–8.2 and are dominated by the Mg–Ca–HCO3 type. The basalts demonstrate a porosity range of 10.9% to 28.8%, with over 70% of interconnected pores. A 20-year geochemical simulation revealed that CO_(2) injection dissolves primary minerals, including anorthite, albite, and diopside, while CO_(2)mineralization dissolves precipitation secondary minerals, such as calcite, siderite, and dolomite. Furthermore, a substantial rise in pH from 7.6to 10.6 is observed in the vicinity of the injected well, accompanied by a slight reduction in porosity from 20% to 19.8%. Additionally, 36.8% of the injected CO_(2) underwent complete mineralization within five years, revealing an increasing percentage of 66.1% if the experimental period is extended to 20 years. The presence of abundant divalent metal cations in basalts and water-bearing permeable rocks in the Leizhou Peninsula supports the potential for mineral carbonation in basalts, as indicated by the geochemical simulation results. Additional research is necessary to identify the factors that influence the CO_(2) mineralization, storage, and sensitivity analysis of basalt in the Leizhou Peninsula.

Geology and mineralization of the Dongping supergiant alkalic-hosted Au-Te deposit(>100 t Au)in Northern Hebei Province,China:A review

The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization originally occurred at 400-380 Ma,simultaneous with emplacement of the Shuiquangou alkaline complex,and was overprinted by the hydrothermal activity in the Yanshanian.Isotope compositions of ores indicate metals of the deposit are mainly provided by the Shuiquangou complex.Ore-forming fluids are characterized by increasing oxygen fugacity and decreasing sulfur fugacity,while tellurium fugacity increased in the Stage II-2 and decreased in Stage II-3.These systematic changes are closely related to the processes of mineral precipitation and fluid evolution.Sulfide precipitation from Stage Ⅰ to Stage Ⅱ was triggered by fluid boiling,which leads to the precipitation of Pb-Bi-Te,due to decrement of sulfur fugacity.Condensation of gas phase containing high concentration of H_2Te leads to precipitation of Te-Au-Ag minerals and native tellurium.Based on these hypotheses,this paper present a polyphase metallogenic model as follow.During the Devonian,fluids were released from alkaline magmas,which carried ore-forming materials form the surrounding rocks and precipitate the early ores.During the Jurassic-Cretaceous,fluorine-rich fluids exsolved from highly factionated Shangshuiquan granite,which extracted and concentrated Au from the Shuiquangou complex and the Sanggan Group metamorphic rocks,and finally formed the Dongping gold deposit.

Petrogenesis, oxidation state and volatile content of Dongga tonalite in the Gangdese belt, Xizang: Implication for porphyry Cu mineralization

The Gangdese belt in Xizang has experienced both Jurassic subduction and Cenozoic continental collision processes, making it a globally renowned region for magmatic rocks and porphyry copper deposits. Numerous Jurassic intrusions have been identified in the belt. Apart from the quartz diorite porphyry in the large Xietongmen deposit, the Cu mineralization potential of other Jurassic intrusions in this belt remains unclear. This study presents zircon U–Pb dating and trace elements, apatite major and trace elements as well as published whole-rock geochemical and isotopic data of the Dongga tonalite in the central part of the Gangdese belt, aiming to reveal the petrogenesis, oxidation state, volatile content, and Cu mineralization potential of this intrusion. The Dongga tonalite has a zircon U–Pb age of 179.4 ± 0.9 Ma. It exhibits high whole-rock V/Sc values(8.76–14.6), relatively low apatite CeN/CeN*ratios(1.04–1.28), elevated zircon(Eu/Eu*)Nvalues(an average of 0.44), high Ce4+/Ce3+values(205–1896), and high ?FMQ values(1.3–3.7), collectively suggesting a high magmatic oxygen fugacity. The Dongga tonalite features amphibole phenocrysts, relatively high whole-rock Sr/Y ratios(20.3–58.9), and lower zircon Ti temperatures (502–740 ℃), reflecting a high magmatic water content. Estimation of magmatic sulfur content(0.002–0.024 wt%) based on apatite SO3contents indicates an enriched magma sulfur content. Combined with previous studies and the collected Sr–Nd–Hf isotopes, the Dongga tonalite is derived from juvenile lower crust related with subduction of the Neo-Tethys oceanic slab. When compared with Xietongmen orebearing porphyries, the Dongga tonalite exhibits remarkable similarities with the Xietongmen ore-bearing porphyries in terms of magma source, tectonic background, magmatic redox state, and volatile components, which indicates that the Dongga tonalite has a high porphyry Cu mineralization potential, and therefore, provides important guidance for the future mineralization exploration.

Characteristics of Gold Mineralization at the Baguiomo Gold Panning Site, Koudougou Region, Burkina Faso, West Africa

The Birimian Baguiomo formations are located in the northern part of the Boromo greenstone belt. In this belt, the volcanic rocks (tholeiitic basalt, calcalkaline basalt, andesite) hosting the gold mineralization are located in the Kwademen-Baguiomo shear zone. This mineralization, located only a few kilometers from the Kwademen gold deposit, is uncharacterized and, together with the latter, could constitute a gold potential capable of being economically exploitable. It is in this sense that this work is carried out with a view to characterizing the gold mineralization of the Baguiomo gold panning site. To carry out this work, we have made direct field measurements, combined with microstructures, and combined all this with data from geochemical rock analysis of the basalts that are the main host formations. Geochemical data show that tholeitic basalts formed from a mantle plume that was emplaced in an oceanic plateau context. Calc-alkaline basalts and andesites are comparable to Paleoproterozoic tholeitic basalts (PTH3), which are slightly enriched in light rare earths. Fertility tests show that these basalts concentrate between 3 and 6 ppb of gold at the time of accretion, which is sufficient for remobilization of this primary gold during the Eburnian orogeny to yield a deposit of around 4 - 5 Moz. Gold mineralization is associated with pyrite crystals when the latter are disseminated in the rock mass, whereas it is associated with hematite in quartz veins concordant with S1 shear deformation. It is mainly the pyrite crystals in the pressure shadows that contain the gold grains, whose development would be synchronous with micro-shear zone reactivation during the first phase of D1B deformation. The second phase of D2B deformation, which is a crenulation or fracture schistosity, does not significantly affect the shear deformation that controls mineralization.