Geology,Geochemistry and Zircon U-Pb Geochronology of Porphyries in the Dabate Mo-Cu Deposit,Western Tianshan,China:Petrogenesis and Tectonic Implications

The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the Dabate district with the intent to constrain their tectonic setting and petrogenesis. Porphyries in the Dabate district include granite porphyry I（gray white color with large phenocrysts）, granite porphyry II（pink color with small phenocrysts） and quartz porphyry. Granite porphyry II is the Cu and Mo ore-bearing granitoid in the Dabate deposit. LA-ICPMS zircon U-Pb analyses indicate that granite porphyry II was emplaced at 284.2±1.8 Ma. Granite porphyry I and II have similar geochemical features and are both highly fractionated granites：（1） They have high SiO2 content（70.93–80.18 wt% and 72.14–72.64 wt%, respectively）, total alkali（7.58–8.95 wt% and 9.35–9.68 wt%, respectively）, mafic index（0.95–0.98 and 0.93–0.94, respectively） and felsic index（0.79–0.94 and 0.89–0.91, respectively）;（2） They are characterized by pronounced negative Eu anomaly, ＂seagullstyle＂ chondrite-normalized REE patterns and ＂tetrad effect＂ of REE;（3） They are rich in Rb, K, Th, Ta, Zr, Hf, Y and REE, but depleted in Sr, P, Ti and Nb. The magma of granite porphyries in Dabate can be interpreted to have been generated by partial melting of the upper crust due to mantle-derived magma underplating in a post-collisional extensional setting.

Isotope Geochemical Characteristics and Material Sources of Tin--Bearing Porphyries in South China

Tin-bearing porphyries in South China can be divided into the F-rich and F-poorsubtypes. They are high-silica (SiO_2>71%), peraluminous (A/NKC>1.0) and rich inincompatible elements (Rb, Zr, U, W, Sn) and have weak Ce (δCe=0.68-0.82) and strong Eu(δEu=0.01-0.38) negative anomalies. Meantime, they also have low δ_(Nd)(-6.3- -8.4), high^(207)Pb/^(204)Pb (15.588-15.790), medium to high (^(87)Sr/^(86)Sr)_i (0.7084-0.7287) and relatively highδ^(18)O(9.1-10.3‰). These characteristics clearly suggest that the two subtypes of tin-bearingporphyries were derived from the crustal materials. Their differences lie only in the existence ofcertain different components in their source materials. Therefore, there is only one type oftin-bearing prophyry in South China. that is continental crust transformation type.

Indosinian Tectonic Setting of the Southern Yidun Arc: Constraints from SHRIMP Zircon Chronology and Geochemistry of Dioritic Porphyries and Granites

A mass of granitoid and dioritic intrusions are distributed in the southern Yidun Arc, among which the representative Indosinian intrusions include the Dongco and Maxionggou granitoid intrusions in Daocheng County and hypabyssal intrusions intruding into arc volcanic rocks near the Xiangcheng town. The Dongco and Maxionggou granitoid intrusions consist mainly of porphyraceous monzogranites, megacryst monzogranites and aplite granites. The Xiangcheng hypabyssal intrusions are composed dominantly of dioritic porphyries. SHRIMP zircon ages of 224±3 Ma and 222±3 Ma have been obtained for the Dongco granitoid intrusion and the Xiangcheng dioritic porphyries, respectively. The Xiongcheng dioritic porphyries show a calc-alkaline geochemical feature, and are characterized by higher Sr/Y ratios, depletive Nb, Ta, P and Ti, enriched LILEs, and lower εNd （t） （=-3.27）, suggesting that they might be derived from mantle source magmas that were obviously contaminated by continent crustal materials. However, the Dongco and Maxionggou granitoids belong to high-potassium calcalkaline series with a per-metaluminous feature, and are characterized by higher CaO/（∑FeO＋MgO） and Al2O3/（∑FeO＋ MgO） ratios, lower （La/Yb）n and Sr/Y ratios, depletive Nb, Ta, Sr, P and Ti, enriched LILEs, and very low εNd （t） （=-8.10）, indicating that the granitoids might be derived from partial melting of continental crust materials mainly of graywacke. Petrogenesis of Dongco and Maxionggou granitoids implies that there was an oceanic crust between the Zongza continental block （ZCB） and western margin of the Yangtze Craton （WMYZC）. And the oceanic crust slab subducted westward during the Indosinian Epoch, producing an Andes-type continent marginal arc and a backarc basin at the WMSCC. Then the oceanic basin closed and a sinistrally lateral collision occurred at ca. 224 Ma-222 Ma between the ZCB and the WMYZC, causing partial melting of sediments in the back-arc basin to generate granitoid magmas of the Dongco and Maxionggou intrusions.

Geochronology, Geochemistry, and Sr–Nd–Hf Isotopes of the Balazha Ore-Bearing Porphyries： Implications for Petrogenesis and Geodynamic Setting of Late Cretaceous Magmatic Rocks in the Northern Lhasa Block, Tibet

The study of Late Cretaceous magmatic rocks, developed as a result of magmatism and related porphyry mineralization in the northern Lhasa block, is of significance for understanding the associated tectonic setting and mineralization. This paper reports zircon chronology, zircon Hf isotope data, wholerock Sr–Nd isotope data, and geochemistry data of Balazha porphyry ores in the northern Lhasa block. Geochemical features show that Balazha ore-bearing porphyries in the northern Lhasa block belong to high-Mg# adakitic rocks with a formation age of ～90 Ma; this is consistent with the Late Cretaceous magmatic activity that occurred at around 90 Ma in the region. The age of adakitic rocks is similar to the molybdenite Re–Os model age of the ore-bearing porphyries in the northern Lhasa block, indicating that the diagenesis and mineralization of both occurred during the same magmatism event in the Late Cretaceous. The Hf and Sr–Nd isotope data indicate that these magmatic rocks are the product of crust–mantle mixing. Differing proportions of materials involved in such an event form different types of medium-acid rocks, including ore-bearing porphyries. Based on regional studies, it has been proposed that Late Cretaceous magmatism and porphyry mineralization in the northern Lhasa block occurred during collision between the Lhasa and Qiangtang blocks.

THE GENETIC CHARACTERISTICS OF THE CUPREOUS PORPHYRIES IN SHANYANG DISTRICT, SHANXI PROVINCE

The cupreous porphyries occurring in Shanyang District, Shanxi Province, were geotectonically developed in Qinling orogenic belt during Yenshan epoch. Their K/Na= 0. 84～ 2. 74, δ=2. 48～3. 70, DI =70. 19 ～80. 69,δEu≈1,δ34S is approximately consistent with

Petrogenesis of Quebrada de la Mina and Altar North porphyries (Cordillera of San Juan, Argentina): Crustal assimilation and metallogenic implications

We investigate the geology of Altar North(Cu-Au) and Quebrada de la Mina(Au) porphyry deposits located in San Juan Province(Argentina), close to the large Altar porphyry copper deposit(995 Mt,0.35% Cu, 0.083 g/t Au), to present constraints on the magmatic processes that occurred in the parental magma chambers of these magmatic-hydrothermal systems. Altar North deposit comprises a plagioclase-amphibole-phyric dacite intrusion(Altar North barren porphyry) and a plagioclaseamphibole-biotite-phyric dacite stock(Altar North mineralized porphyry, 11.98 ± 0.19 Ma). In Quebrada de la Mina, a plagioclase-amphibole-biotite-quartz-phyric dacite stock(QDM porphyry,11.91±0.33 Ma) crops out. High Sr/Y ratios(92-142) and amphibole compositions of Altar North barren and QDM porphyries reflect high magmatic oxidation states(fO_2= NNO+1.1 to+1.6) and high fH_2O conditions in their magmas. Zones and rims enriched in anorthite(An_(37-48))), SrO(0.22-0.33 wt.%)and FeO(0.21-0.37 wt.%) in plagioclase phenocrysts are evidences of magmatic recharge processes in the magma chambers. Altar North and Quebrada de la Mina intrusions have relatively homogeneous isotopic compositions(^(87)Sr/^(86)Sr_(t)= 0.70450-0.70466, ε_(ND)(t) = +0.2 to +1.2) consistent with mixed mantle and crust contributions in their magmas. Higher Pb isotopes ratios(^(207)Pb/^(204)Pb=15.6276-15.6294) of these intrusions compared to other porphyries of the district, reflect an increase in the assimilation of high radiogenic Pb components in the magmas. Ages of zircon xenocrysts(297,210,204,69 Ma) revealed that the magmas have experienced assimilation of Miocene, Cretaceous, Triassic and Carboniferous crustal rocks.Fluids that precipitated sulfides in the Altar deposit may have remobilized Pb from the host rocks, as indicated by the ore minerals being more radiogenic(207Pb/204 Pb = 15.6243-15.6269) than their host intrusions. Au/Cu ratio in Altar porphyries(average Au/Cu ratio of 0.14 ×10^(-4)by weight in Altar Central)is higher than in the giant Miocene porphyry deposits located to the south: Los Pelambres, Rio Blanco and Los Bronces(Chile) and Pachon(Argentina). We suggest that the increase in Au content in the porphyries of this region could be linked to the assimilation of high radiogenic Pb components in the magmas within these long-lived maturation systems.

GENESIS OF THE ALKALI-RICH PORPHYRIES IN YUNNAN

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Petrogenesis of Paleoproterozoic diorite porphyries inLuojiazhuang, western Shandong： constraints fromLA-ICP-MS zircon U-Pb geochronology and geochemistry

Based on the study of LA-ICP-MS zircon U-Pb geochronology and whole-rock geochemistry for theLuojiazhuang diorite porphyries in Menying , western Shandong , the analyzed zircons exhibit oscillatory zoning in the cathodoluminescence images and have high Th/U ratios （0. 15-1.53） , indicating a magmatic origin.In addition, most of the zircons have narrow metamorphic edges, suggesting that late metamorphic eventsmay exist. The youngest group of magmatic zircon 207Pb/206Pb ages rangng from 2 384 Ma to 2 234 Ma, yieldinga weighted mean age of 2 353 ± 14 Ma, which represents the forming age of the diorite porphyries, as theEarly Paleoproterozoic. Geochemically , the samples are characterized by low Si〇2（54. 54% and 55. 47% ）,high MgO （5.22% and 5.49% ） and Mg# values （58 and 59） . Moreover , they show enrichment of light rareearth elements and large ion lithophile elements （ Rb , Ba and K） , depletion of heavy rare earth elements andhigh field strength elements （Nb, Ta , Zr and Hf） , positive anomaly of Pb , and negative anomaly of Ti. Thefact implies that the Luojiazhuang diorite porphyries might derive from partial melting of mantle and mixed with an amount of continental crust material. In summary , they may tectonic setting that stretching along the east-＂west direction at the North China Craton in the Early Paleoproterozoic.

Geochronology and geochemistry of Dongxigao diorite porphyries: implications for Late Neoarchean tectonic evolution of eastern North China Craton

Zircon LA-ICP-MS U-Pb age and whole-rock geochemistry data are presented for the Dongxigao diorite porphyries in Pingyi,western Shandong,to restrict its petrogenesis. The zircons from the Dongxigao diorite porphyries exhibit striped absorption and oscillatory growth zoning in the cathodoluminescence images,which have upward-type characteristics of rare earth elements( REEs) with positive anomaly of Ce and negative anomaly of Eu,and have high Th / U ratios( 0. 06--0. 91),indicating its magma origin. Zircon LA-ICP-MS UPb dating indicates that^(207) Pb /^(206) Pb ages of 16 spots of zircons are between 2476 Ma and 2701 Ma,yielding a weighted mean age of 2 481 ± 8 Ma,which represents the formation age of Dongxigao diorite porphyries,i. e.Late Neoarchaean. Geochemically,the samples have low contents of SiO_2( 54. 94% and 54. 86%) and high amounts of MgO( 7. 19% and 7. 58%) and Mg~#values( 66. 47 and 67. 59). Additionally,the Dongxigao diorite porphyries show enrichment of LREEs and prominent negative Eu anomaly( δEu = 0. 89 and 0. 91),and they are characterized by enrichment of large ion lithophile elements( LILEs)( e. g. Cs,Rb and Ba),depletion of high field strength elements( HFSEs)( e. g. Nb,Ta,Zr,Hf and Ti),and positive anomaly of K and Pb. The results imply that the Dongxigao diorite porphyries dominantly derived from partial melting of enriched lithospheric mantle with attributes of arc magma,and the magma source area was mixed with amounts of continental crust material,it suggests that they formed in transformation tectonic setting changing from compression to intraplate extension.

Petrogenesis and tectonic implications of the Early Cretaceous Dagushan adakitic porphyries in the Anshan area,North China Craton

The eastern part of the North China Craton suffered significant lithospheric thinning since the Mesozoic,and petrogenesis of the Dagushan adakitic diorite porphyries provides an excellent opportunity to investigate the lithospheric thinning mechanism and geodynamic setting.The zircon LA-ICP-MS U–Pb geochronology reveals that the representative Dagushan adakitic porphyry was formed at 120.5±0.5 Ma.The Dagushan diorite porphyries are characterized by the relatively high contents of SiO_(2)(64.25–65.70 wt%),Al_(2) O_(3)(15.00–15.38 wt%),Sr(333–491 ppm),low contents of Y(6.50–10.3 ppm),and Yb(0.57–0.85 ppm),and resultant high Sr/Y(47–57)and La/Yb(37–55)ratios,exhibiting geochemical characteristics of typical adakites.Moreover,the relatively high Mg O contents(MgO=2.23–2.29 wt%)and Mg numbers(Mg^(#)-=54–56)of the Dagushan adakitic rocks imply that the pristine adakitic magma interacted with mantle peridotite.However,the zircon Hf isotopic signatures(εHf(t)=-19.0 to-28.0;TDM2=2378–2944 Ma)suggest an ancient lower crustal source.Therefore,it is proposed that the Dagushan adakitic rock was probably generated by partial melting of delaminated lower crust which was triggered by the Tan-Lu Fault Zone,and the interaction of pristine adakitic magma with mantle peridotite during the ascent finally generated the Dagushan high Mg^(#)adakitic rocks.It is suggested that delamination was an important mechanism for lithospheric thinning of the NCC.

Geochemical Characteristics and Genesis of Topaz-Bearing Porphyries in Yangbin Area of Taishun County, Zhejiang Province

The host rocks of the porphyry tin deposits in the Yangbin area are prince-pally topaz-bearing porphyry dikes about 2 km long and 2-20m wide.Three lithologic types are identified for the dikes:topaz-bearing potassium feldspar granitic porphyry,topaz-bearing monzonitic granitic porphyry and topaz-bearing quartz porphyry.The con-tent of topaz in the rocks ranges from 10 to 20 vol.%.Porphyritic texture is characteristic,with quartz,potassium feldspar and albite as main phenocryst minerals.The phenocryst occupies 10-20vol% of the rocks.The rock groundmass consists of subhedrak topaz,quartz and protolithionite.Topaz has a unit-cell parameter b=8.797(A)^°,and F:OH=1.92:0.18, indicating a F-rich variety formed at high temperature .The topaz-bearing porphyries occurring in this area are strongly peraluminous (A/NKC=1.574-12.94)，with high ra-tios of F/C1(146-303) and Rb/Sr(5-122).They are rich in incompatible elements (Sn,313×10^-6-1042×10^-6;W,6×10^-6-218×10^-6;Nb,27×10^-6-54×10^-6),but poor in compatible elements (Sr,10×10^-6-28×10^-6;Ba,58×10^-6-73×10^-6;V,3×10^-6-10×10^-6,Cl,150×10^-6-226×10^-6).The rocks are also characterized by high total REE amount (281.69×10^-6-319.76×10^-6);with strong Eu depletion (&Eu=0.01-0.03)and low ratio of LREE/HREE(0.78-0.84).In summary ,the authors propose propose an idea of S-type genesis for the topaz-bearing porphyries with tin mineralization,instead of I-type.

黑龙江多宝山铜矿区韧性剪切变形时代及其对铜矿化改造的约束

黑龙江多宝山斑岩铜矿主要赋存于奥陶纪花岗闪长岩中,少量发育于奥陶纪花岗闪长斑岩及奥陶系多宝山组安山岩中,铜矿化以浸染状、细脉-浸染状为主。成矿过程经历了斑岩期、剪切变形期。矿区发育韧性剪切变形带,多宝山组、花岗闪长岩、花岗闪长斑岩、安山质凝灰角砾岩及矿体均发生了剪切变形作用,沿剪切面发育绢云母新生矿物。绢云母的坪年龄和正反等时线年龄分别为280.1±1.2 Ma和281.4±1.3 Ma、281.3±1.3 Ma,在误差范围内基本一致,限定矿区韧性剪切变形的时间为早二叠世(约280 Ma)。多宝山斑岩铜矿床主要成矿作用形成于斑岩期,成矿时代为早奥陶世(约475 Ma),早二叠世的韧性剪切变形作用对原生斑岩铜矿化进行了改造,使矿石的铜进一步富集,品位相对增高。

赣南铁山垅钨矿田花岗斑岩地球化学特征、锆石U-Pb年龄及Hf同位素特征

赣南铁山垅钨矿田位于南岭钨锡多金属成矿带东段,已探获黑钨矿资源量超10万吨。铁山垅复式岩体包括主体似斑状黑云母花岗岩和补体细粒二云母花岗岩两部分,花岗斑岩呈脉状分布。矿田内花岗岩具有相似的地球化学特征,都属过铝质高钾钙碱性花岗岩类,表现出高硅、富铝、富碱、高钾、富成矿元素(W、Sn、Cu、Mo)和亏损Ba、Sr、Ti、P、REE、Eu,稀土配分曲线呈典型的“海鸥式”分布和M型四分组效应等特征。利用LA-ICP-MS锆石U-Pb定年方法获得花岗斑岩^(206)Pb/^(238)U年龄为146.7±0.5 Ma(MSDW=0.5),成岩时代属晚侏罗世。锆石的n(^(176)Lu)/n(^(177)Hf)=0.000973~0.001989,f_(Lu/Hf)=-0.97~-0.94,ε_(Hf)(t)=-17.9~-10.3,二阶段模式年龄(TDM2)为1.86~2.33 Ga,显示原岩为古元古代地壳。综合分析认为,铁山垅矿田岩浆活动可划分为170~155 Ma、155~150 Ma、150~145 Ma三个阶段,钨锡矿成矿主要集中在第二阶段,且第三阶段花岗斑岩与铜多金属矿成矿关系密切,推测铜岭矿区深部具有较大的找矿前景。

巴基斯坦新特提斯构造–岩浆演化与重要金属成矿作用

巴基斯坦在大地构造位置上处于印度、欧亚和阿拉伯三大板块的汇聚带,正同时发生着大陆碰撞和大洋俯冲作用,是研究地球系统深部圈层相互作用与成矿效应的绝佳天然实验室。但是,目前对于巴基斯坦构造演化与成矿作用的研究还不系统,对于巴基斯坦的大型–超大型矿床形成的背景和机制仍不清楚。笔者针对巴基斯坦不同类型的优势矿种开展了深入解剖和对比研究,系统梳理最新研究进展,围绕巴基斯坦新特提斯构造–岩浆演化与成矿作用响应的关键科学问题,分析铜矿、铬铁矿、铅锌矿以及碳酸岩有关的稀土矿床等重要金属成矿类型形成的构造环境以及与区域重大地质事件的耦合关系,总结巴基斯坦区域成矿规律,为资源潜力分析和境内外找矿勘查提供依据。

秘鲁Morococha斑岩-矽卡岩-浅成低温热液型矿床成矿地质特征与区域找矿方向

秘鲁中部Morococha地区位于中安第斯秘鲁中新世成矿带,是全球最具代表性的世界级斑岩-矽卡岩型和浅成低温热液型成矿系统之一。系统总结了该区斑岩型、矽卡岩型、浅成低温热液型等多种铜钼铅锌银多金属矿化成矿作用特征和最新的研究进展,结合区域岩浆-热液成矿作用过程,提出了下一步找矿方向。Morococha矿区位于秘鲁中部Yali穹隆北段,由中心部位的Toromocho斑岩型铜钼矿床及外围铅锌银金多金属矿脉组成。区内主要构造为北西向Morococha背斜,地层主要为二叠纪—三叠纪Mitu群火山碎屑岩、侏罗纪Pucara群碳酸盐岩、早白垩世Goyllarisquizga群海相碎屑岩和碳酸盐岩。矿区中新世岩浆活动主要为中中新世不含矿的闪长质侵入岩(14.3~14.1 Ma)和晚中新世与成矿有关的花岗闪长岩和长石斑岩岩株(9.4~7.7 Ma)。Morococha岩浆-热液系统(8.5~7.2 Ma)是其形成超大型斑岩型铜矿成矿的原因之一,铅锌银多金属矿化主要发生在斑岩型矿化之后约0.5 Ma,受区域构造控制。矿床在空间上显示出明显的金属分带特征,中心斑岩区域为富铜矿石,而远离斑岩区出现更多的富铅锌银矿石。秘鲁中部中新世成矿带分布着众多具有重要经济价值的脉状热液型铅锌银多金属矿床,总结近年来综合地质调查和研究成果,表明这些多金属矿床都属于斑岩-矽卡岩成矿系统的一部分,因此斑岩-矽卡岩型铜矿床及浅成低温热液型贵金属矿床是秘鲁中部重要的找矿方向。

西藏多龙斑岩-浅成低温热液型铜(金)矿集区地质特征及找矿潜力分析

本文在总结多龙矿集区地质特征的基础上,开展了矿山深边部的潜力分析,以期为下一步的找矿预测提供勘查思路。多龙斑岩-浅成低温热液型铜(金)矿集区位于西藏班公湖-怒江成矿带的北西侧,主要由铁格隆南超大型斑岩-浅成低温热液型铜(金)矿床,拿若大型斑岩-隐爆角砾岩筒型铜(金)矿床,多不杂、波龙、多不杂西大型斑岩型铜(金)矿床,尕尔勤、地堡那木岗高硫化浅成低温热液型铜(金)矿点组成,共探获铜资源量超过1500万t,伴生金超250 t,伴生银3900 t。多龙矿集区形成于早白垩世(120 Ma)班公湖-怒江洋盆北向俯冲的陆缘弧环境,物质源区为壳幔混合源,成矿岩浆岩主要为中酸性的闪长玢岩-花岗闪长斑岩-花岗斑岩系列,具有弧岩浆特征。俯冲板片的折返是多龙矿集区深部岩浆形成和侵位的主要动力学机制,成矿后安山质火山岩(110 Ma)的覆盖对矿床起到重要的保存作用。多不杂矿区F2逆断层将矿体分割成上、下两部分,下部分矿体是找矿的重点方向。铁格隆南矿区深钻揭露了由南向北的逆冲断层,该逆冲断层将矿体错断并推覆到“红层”沉积之上,其下盘是寻找另一半隐伏矿体的方向。尕尔勤矿区大面积发育指示浅成低温热液成矿系统的“硅帽”,明显富集Au、Ag、As、Sb、Bi、Cu等元素,Au、As、Sb、Hg等呈现较好的元素组合异常,具有寻找浅成低温热液型矿床的潜力。地堡那木岗矿区发育高硫化浅成低温热液型蚀变(高岭石化、地开石化、明矾石化等)和矿物组合(铜蓝、蓝辉铜矿、斑铜矿等),且物探、化探、遥感异常套合良好,是未来矿产勘查的重点。区内逆冲断层对矿床的改造作用是未来研究的重点,对进一步的勘查评价具有重要的指导意义。

指示克里格矿产资源量三维估算方法应用研究——以安徽省某斑岩型铜金矿床为例

文章以安徽省某大型斑岩型铜金矿床为研究对象,基于指示克里格方法对矿床Cu资源量进行估算研究,并将估算结果与传统几何法和普通克里格方法估算结果进行对比分析,以评价指示克里格法的适用性与合理性。研究结果表明:指示克里格估算结果与其他两种方法相比虽有一定偏差,但均在误差范围内,表明指示克里格法适用于斑岩型铜金矿的资源量估算工作;指示克里格法由于考虑了品位数据的空间分布特征及特异值的影响,相比传统几何法、普通克里格法,估算结果中的平均品位和金属量均偏高;指示克里格方法更适用于品位分布连续性较差、特异值具有较高价值和意义的金属矿床。

内蒙古敖汉地区中生代花岗质岩浆活动与金钼多金属成矿作用

内蒙古敖汉地区处于华北克拉通与兴蒙造山带的过渡区,是华北地台北缘一个重要的金钼多金属矿化集中区,近年来找矿成果丰硕。在对撰山子和金厂沟梁大型金矿、白土营子大型钨钼多金属矿以及近年新发现的八家大型锌银铅矿和腾克力钼矿的地质地球化学特征系统分析的基础上,文章探讨了矿床成因与区域构造岩浆演化,提出了本区金钼多金属成矿潜力与找矿方向。结果显示,敖汉地区金钼多金属成矿与印支期、燕山期花岗质岩浆侵位密切相关,成矿主要发生于三叠纪和晚侏罗世—早白垩世,具有多期多阶段性特征。印支期和燕山期成矿岩体总体均属于准铝质-弱过铝质高钾钙碱性系列花岗岩,表现为轻稀土富集的右倾配分特征,大离子亲石元素富集,高场强元素亏损,分别形成于古亚洲洋和古太平洋构造域影响下的伸展背景。金矿床成因类型主要为岩浆热液脉型,钼矿床成因类型主要为斑岩型,受构造-岩浆岩联合控制,印支期和燕山期中酸性岩浆岩及北西向-近南北向断裂是重要的找矿标志。撰山子金矿具有良好的斑岩-矽卡岩型金铜矿床找矿前景,金厂沟梁和撰山子金矿区及外围具有寻找浅成低温热液型金多金属矿床的潜力。借鉴白土营子钨钼多金属矿田和八家锌银铅矿床的找矿经验,应注重综合利用地质、地化、物探等手段在覆盖区寻找钨铅锌银多金属矿床。

东秦岭钼多金属成矿带夜长坪斑岩-矽卡岩型钼钨矿床磁铁矿成因类型与指示意义

夜长坪超大型斑岩-矽卡岩型钼钨矿床位于东秦岭钼多金属成矿带,保存了完整的矽卡岩形成演化及成矿作用的重要信息。通过详细的野外地质调查及镜下鉴定,将夜长坪钼钨矿床中的磁铁矿划分为3种类型:晚矽卡岩阶段形成以他型粒状或以聚合体形式与黑云母、绢云母、黏土等矿物共生的Mt1型磁铁矿;氧化物阶段形成半自形至自形与石榴子石、透闪石、阳起石等矿物共生的Mt2型磁铁矿;呈稠密浸染状与辉钼矿等硫化物共生,或产出在石英多金属硫化物脉中的Mt3型磁铁矿。电子探针及LA-ICP-MS原位测试分析结果显示:Mt1~Mt3型磁铁矿FeO平均含量逐渐升高,Mt1型磁铁矿富Si、Mg、Na等元素,具有最高的V、Cr、Ti、Al和Mo含量。Mt2型磁铁矿Ti元素含量明显降低,Si含量略有下降,具有最高含量的Mg和Mn。Mt3型磁铁矿中Ti、Si、Na、Ca元素含量均最低。磁铁矿元素变化特征显示,Fe元素易被Si、Ca、Al等元素替换;随磁铁矿的结晶,成矿流体中逐渐富集Mo等成矿元素。磁铁矿成因判别图解显示,Mt1型磁铁矿与另外2种磁铁矿形成物质来源略有不同,Mt1型磁铁矿更偏向于岩浆热液成因,Mt2型磁铁矿和Mt3型磁铁矿则更偏向于变质热液成因,随着Mt2型磁铁矿的形成,赋矿围岩参与成矿的程度逐渐增强。从早期较高温的Mt1型磁铁矿至晚期较低温的Mt3型磁铁矿,V和Ti具有较为明显的正相关关系;流体-岩石作用程度判别图解显示交代作用逐渐增强。因此,在夜长坪钼钨矿床氧逸度的变化和流体-岩石作用程度的逐渐增强是控制成矿的主要因素。

河北省涿鹿县杏园矿区矿床成因及找矿标志

本研究通过系统的地质、地球化学及地球物理分析,深入探讨了河北省涿鹿县杏园矿区的成矿背景、矿床特征及其找矿指标。利用先进的地质勘查技术,首次明确揭示了矿区内斑岩型与热液脉型矿床的共生关系及其空间分布规律,提出了新的成矿模型和勘查方向。研究结果不仅深化了对杏园矿区成矿规律的理解,而且对指导未来的地质勘查工作,推动矿产资源的合理开发与利用具有重要意义。