A novel thermoregulated phosphine ligand used for the Rh-catalyzed hydroformylation of mixed C_(11-12) olefins in aqueous/organic biphasic system

A novel thermoregulated phosphine ligand PhP(CHCHO)CH(n=22) was synthesized and used for the Rh-catalyzed hydroformylation of mixed Colefins in aqueous/organic biphasic system.Under the optimized conditions,pressure =5 MPa (H:CO=1:1),phosphine/Rh =13(molar ratio),reaction time =6 h and temperature =130℃,the conversion of Colefins and the yield of aldehyde are 99%and 94%,respectively.The catalyst retained in aqueous phase can be easily separated from the product-containing organic phase by simple phase separation and the catalytic activity remains almost constant after four consecutive cycles.

An experimental study on metal precipitation driven by fluid mixing: implications for genesis of carbonate-hosted lead–zinc ore deposits

A type of carbonate-hosted lead–zinc(Pb–Zn)ore deposits, known as Mississippi Valley Type(MVT)deposits, constitutes an important category of lead–zinc ore deposits. Previous studies proposed a fluid-mixing model to account for metal precipitation mechanism of the MVT ore deposits, in which fluids with metal-chloride complexes happen to mix with fluids with reduced sulfur, producing metal sulfide deposition. In this hypothesis, however, the detailed chemical kinetic process of mixing reactions, and especially the controlling factors on the metal precipitation are not yet clearly stated. In this paper, a series of mixing experiments under ambient temperature and pressure conditions were conducted to simulate the fluid mixing process, by titrating the metal-chloride solutions, doping withor without dolomite, and using NaHS solution. Experimental results, combined with the thermodynamic calculations, suggest that H_2S, rather than HS^-or S^(2-),dominated the reactions of Pb and/or Zn precipitation during the fluid mixing process, in which metal precipitation was influenced by the stability of metal complexes and the pH. Given the constant concentrations of metal and total S in fluids, the pH was a primary factor controlling the Pb and/or Zn metal precipitation. This is because neutralizing or neutralized processes for the ore-forming fluids can cause instabilities of Pb and/or Zn chloride complexes and re-distribution of sulfur species, and thus can facilitate the hydrolysis of Pb and Zn ions and precipitation of sulfides. Therefore, a weakly acidic to neutral fluid environment is most favorable for the precipitation of Pb and Zn sulfides associated with the carbonate-hosted Pb–Zn deposits.

Study on Direct Reduction Characteristics of Iron Ore Coal Mixed Pellets

In order to get DRI iron ore coal mixed pellets are reduced isothermally. The mechanisms of reduction desulphurization, iron oxide reduction and the structure regenesis of the coal mixed pellets during reduction have been studied. The effect of various processing factors on the quality of DRI and economy technological indices including compression strength, desulphurization rate, recovery rate, reaction fraction, carbon content and metallization are also researched.

Mixed Conduction in BaCe0.8Pr0.2O3-α Ceramic

BaCe0.8Pr0.2O3-α ceramic was synthesized by high temperature solid-state reaction. The structural characteristics and the phase purity of the crystal were determined using powder X-ray diffraction analysis. By using the methods of AC impedance spectroscopy, gas concentration cell and electrochemical pumping of hydrogen, the conductivity and ionic transport number of BaCe0.8Pr0.2O3-α were measured, and the electrical conduction behavior of the material was investigated in different gases in the temperature range of 500-900℃. The results indicate that the material was of a single perovskite-type orthorhombic phase. From 500℃ to 900 ℃, electronic-hole conduction was dominant in dry and wet oxygen, air or nitrogen, and the total conductivity of the material increased slightly with increasing oxygen partial pressure in the oxygen partial pressure range studied. Ionic conduction was dominant in wet hydrogen, and the total conductivity was about one or two orders of magnitude higher than that in hydrogen-free atmosphere （oxygen, air or nitrogen）

Synergistic Effect in Mixed Capillary Gas Chromatographic Stationap Phases Containing Heptakis(2,3,6-tri-o-pentyl)-β-cyclodextrin and Dibenzo-18-crown-6

used－silical capillary columns containing heptakis（2、3、6－tri－o－pentyl）-β-cyclodextrinand dibenzo-18-crown-6 were prepared．By studying the selectivity of mixed stationary phases forsome solute pairs.as well as comparing with the heptakis（2．3、6-tri-O-pentyl）-β-cyclodextrin and thedibenzo-18-crown-6 used as individual stationary phase、the synergistic effects were observed.These effects were affected by the column temperature．mixed ratio and linear velocity of carrier gas．

Ce_xTi_(1-x)O_2 Mixed Oxides Supported CuO Catalyst for NO Reduction by CO

Ce x Ti 1- x O 2 mixed oxides of different mole ratios ( x =0, 0.1, 0.2～0.9, 1.0) were prepared by co precipitation of TiCl 4 with Ce(NO 3) 3 and then loaded with different amounts of CuO. The effects of CuO on NO+CO reaction were investigated, and the structure and reductive properties of various CuO/Ce x Ti 1- x O 2 were characterized by the methodologies of BET, TPR and XRD. The results show that different Ce/Ti mole ratios and calcination temperatures induce changes of structure and reductive properties of the Ce x Ti 1- x O 2 mixed oxides. When x =0.1～0.5, amorphous CeTi 2O 6 phase mainly forms at 650 ℃ compared to the formation of CeTi 2O 6 which crystallizes at 800 ℃. When x >0.6, some TiO 2 enters the CeO 2 lattice and a CeO 2 TiO 2 solid solution is formed. The activity of 6%CuO/Ce x Ti 1- x O 2 calcined at 650 ℃ is largely affected by the x values, which is the highest when x =0.3, 0.4 and 0.9. The NO conversion reaches 70% at a reaction temperature of 150 ℃. By comparison, the x values have little effect on the activity of 6%CuO/Ce x Ti 1- x O 2 calcined at 800 ℃ . There are strong interactions between CuO and CeTi 2O 6, i.e., formation of the CeTi 2O 6 phase shifts the CuO reduction peak temperature from 380 to 200 ℃, and CuO, in turn, shifts the CeTi 2O 6 reduction peak temperature from 600 to 300 ℃.

On the Mixed Propagator Approach to ρ-ω Mixing

The mixed propagator (MP) approach to ρ-ω mixing is discussed. It is found that under the pole-approximation assumption the results of MP approach is not compatible both with the effective Lagrangian theory andwith the experiment measurement criterion. To overcome these inconsistent, we propose a new MP approach in whichthe physical states of ρ and ω are determined by the requirement of experimental measurement to meson resonance. Interms of this new MP approach, the EM pion form factor Fπ and form factors of ρo →π0γ and of ω→πo γ are derived.The results of Fπ are in good agreement with data. The form factor of ρo →π0γ exhibits a hidden charge-asymmetryenhancement effect which agrees with the prediction of the effective Lagrangian theory.

MIXED MODE SCC OF 18-8 STAINLESS STEEL IN BOILING 42% MgCl_2 SOLUTION

A series of mixed mode tests were carried out on 18-8 stainless steel in boiling 42% MgCl_2 solution.The results show that for any K_Ⅱ/K_Ⅰ ratio,the SCC direction coin- cides well with the crack tip maximum normal stress plane,while the SCC resistance of the material reduces as the ratio of K_Ⅱ/K_Ⅰ increases.The experimental results were discussed in the light of anode dissolving mechanism and the effect of mixed mode loading on crack tip stress and strain.It is concluded that for fracture analysis if mixed mode cracks were simply taken into account as mode Ⅰ cracks,and only mode Ⅰ testing results as mode Ⅰ fracture criter- ion were employed,it may not be safe.

Effect of Calcination Temperature on Structure and O_2 Desorption Properties of Ce_xPr_(1-x)O_(2-δ) Mixed Oxides

A series of CexPr1-xO2-δ (x=0, 0.5, 0.9, 1.0) mixed oxide calcined at different temperatures were synthesized by sol-gel method and characterized by Raman, XRD and O2-TPD techniques. When x=0.9, only a cubic phase CeO2 is observed. When x=0.5, the compound was combined by Pr6O11 and CeO2 mixed oxides. For CexPr1-xO2-δ (x=0.5, 0.9)samples 465 cm-1 Raman peak is attributed to the Raman active F2g mode of CeO2. The broad peak at about 570 cm-1 can be linked to lattice defects resulting in oxygen vacancies. The crystallite size of the samples increased as increasing the calcined temperature. But the increased value of Ce0.9Pr0.1O2-δ and Ce0.5Pr0.5O2-δ is smaller than single CeO2 and Pr6O11 obviously. It reveals that the insertion of Pr atom into the ceria lattice could enhance the sintering resistance and thermal stability of the mixed oxides. Calcination temperatures had great effect on the peak intensity for CeO2 but less effect on Ce0.8Pr0.2O2-δ in Raman spectra, and it may be caused by the colors transformation of the mixed oxides. The result of O2-TPD experiment indicates that the formation of solid solution has elevation the stabilization and thermal stability of the mixed oxides.

Leaching of low grade zinc oxide ores in Ida^(2-)-H_2O system

Ida2--H2O system（iminodiacetate aqueous solution） was used to leach a low grade zinc oxide ore for Zn extraction.The effects of leaching time,liquid-solid ratio（L/S）,total concentration of Ida2-（[Ida2-]T）,leaching temperature and pH on Zn leaching recovery and the dissolution of impurities such as Ca,Mg,Cu,Ni,Fe,Pb and Cd were investigated.Results show that Ca,Mg and Fe in ores were hardly dissolved in alkalescent iminodiacetate aqueous solution,while valuable metals such as Cu,Ni,Pb and Cd were partly dissolved into leaching liquor with Zn.The recovery of Zn reaches 76.6% when the ores were leached for 4 h at 70 ℃ by 0.9 mol/L iminodiacetate aqueous solution with pH of 8 and L/S of 5：1.

基于Monte Carlo模拟的Mixed Logit模型求解研究

Mixed Logit模型因能有效地避免其他离散选择模型的限制而被广泛地运用于交通领域,但由于它概率形式的非封闭性而导致了复杂的求解过程。从理论上证明利用Monte Carlo模拟方法求解Mixed Logit模型具有一定的合理性,并给出具体的求解步骤,可有效简化Mixed Logit模型的求解过程。

一种基于停止-转发MIX的统计型攻击

为了增强匿名系统的匿名性,更好地保护用户的通信隐私,基于停止-转发MIX提出一种新的统计型攻击算法.算法将攻击者的连续观察时间划分成t个周期,每个周期统计MIX节点输出信息包的接收者集合,称之为一个观察集合,获得t个观察集合后,采用概率统计、集合运算等方法,确定目标发送者的接收者集合.指出采用填充包技术防御该攻击时,可以增加攻击所需的观察集合数,降低攻击的有效性.

(α,δ)-弱刚性环上的Ore扩张（英文）

本文研究(α,δ)-弱刚性环上的Ore扩张环R[x;α,δ]的弱对称性、弱zip性、幂零p.p.性和幂零Baer性.利用对多项式的逐项分析的方法,证明了如果R是(α,δ)-弱刚性环和半交换环,则Ore扩张环R[x;α,δ]是弱对称的(弱zip的,幂零p.p.的,幂零Baer的)当且仅当R是弱对称的(弱zip的,幂零p.p.的,幂零Baer的).这些结果统一和扩展了前面已有的相关结论.

The role of surface waves in the ocean mixed layer

Previously, most ocean circulation models have overlooked the role of the surface waves. As a result, these models have produced insufficient vertical mixing, with an under - prediction of the ,nixing layer （ML） depth and an over - prediction of the sea surface temperature （SST）, particularly during the summer season. As the ocean surface layer determines the lower boundary conditions of the atmosphere, this deficiency has severely limited the performance of the coupled ocean - atmospheric models and hence the climate studies. To overcome this shortcoming, a new parameterization for the wave effects in the ML model that will correct this systematic error of insufficient mixing. The new scheme has enabled the mixing layer to deepen, the surface excessive heating to be corrected, and an excellent agreement with observed global climatologic data. The study indicates that the surface waves are essential for ML formation, and that they are the primer drivers of the upper ocean dynamics; therefore, they are critical for climate studies.

Hopf^＊-代数的Ore扩张

对Hopf*-代数的Ore扩张何时保持*-结构给出了充分必要条件.讨论了群代数、量子群"ax+b"以及量子群Uq(sl(2))上的Hopf*-结构和Ore扩张.

Dynamics of Ore-Forming Processesof the Stratabound Skarn Copper Depositsof Tongling, Anhui Province

The skarn and ore bodies of the stratabound skarn copper deposits of Tongling, Anhui Province, are both controlled by definite stratigraphic horizons, and they are concordant with the strata. They occur as layers and layer-like bodies in permeable carbonate rocks of the Middle-Upper Carboniferous Huanglong and Chuanshan Formations which are underlain by impermeable shale or siliceous rocks of the Upper Devonian Wutong Formation. The authors study the dynamics of ore-forming processes of the ore deposits with the dynamic model of coupled transport and reaction, and the following results are obtained: The salinity gradient and flow rate of the ore-forming fluids can both promote the mixing and reaction of juvenile water and formation water, and the permeable strata are favourable sites for the intense transport-reaction of mixing and the formation of deposits. (2) As isothermal transport-reaction took place along the bedding of strata, the moving transport-reaction front formed at the contact between the ore-forming fluids and the rocks advanced slowly along the permeable strata, and then stratiform skarn and ore bodies concordant with the strata were formed. (3) The gradient transport-reaction taking place across the isotherms in the cross-bedding direction caused the mineralogical composition to alter gradually from magnesian skarn to sulphide ore bodies.

Ore k-型图的1-因子

定义给定非负整数k,若图G中每一对不相邻的顶点u和v,都有d(u)+d(v)≥| V(G)|+k,则称G为Ore k-型图.

Peierls stress for <110>{001} mixed dislocation in SrTiO_3 within framework of constrained path approximation

The core structure of （110）{001} mixed disloca- tion in perovskite SrTiO3 is investigated with the modified two-dimensional Peierls-Nabarro dislocation equation con- sidering the discreteness effect of crystals. The results show that the core structure of mixed dislocation is independent of the unstable energy in the （100） direction, but closely related to the unstable energy in the （110） direction which is the direction of total Burgers vector of mixed dislocation. Furthermore, the ratio of edge displacement to screw one nearly equals to the tangent of dislocation angle for differ- ent unstable energies in the （110） direction. Thus, the con- strained path approximation is effective for the （110）{001} mixed dislocation in SrTiO3 and two-dimensional equation can degenerate into one-dimensional equation that is only related to the dislocation angle. The Peierls stress for （110） {001 } dislocations can be expediently obtained with the one-dimensional equation and the predictive values for edge, mixed and screw dislocations are 0.17, 0.22 and 0.46 GPa, respectively.

The Evolutionary History of Ore-forming Processes of Metallic Ore Deposits in Northern Guangxi

The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian.

The Forming Conditions of and Ore-searching Direction for B, Mg,Pb, Zn and Au Deposits in the Liaoji Proterozoic Rift

The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These deposits were formed as the result of late mobilization, transportation and concentfation of the previously enriched ore-forming mate- rials in several ore-bearing formations formed during the rift stage. So the metallogeny of these deposits in the rift shows both inheritance and new generation of the ore-forming materials. In future ore-searching practice, attentions should be paid on the studies of the ore-bearing formations in the rift, on the multiple stages of metallogeny and and on multiple derivations of the ore-forming materials.