Preparation of high-purity neodymium chloride by solvent extraction in the mixer-settlers： A pilot-scale investigation

A novel purification process based on mixer-settlers for high-purity NdClwas developed. Acidic solution and pure NdClsolution were compared to scrub the less-extractable rare earths(REs)(La, Ce, and Pr)from loaded organic phase. The extractant with low-degree saponification was evaluated to remove the more-extractable element(Sm). Then the RE impurities(La, Ce, Pr, and Sm) in Nd were purified by an integrated process. Furthermore, effect of smuggling behavior on the purification of NdClin mixersettlers was studied. Based on the investigation mentioned above, the pilot-scale purification process for NdClwith a purity of 99.999% was developed, and the total recovery was about 99%.

Experimental Study on Aqueous Phase Entrainment in a Mixer-settler with Double Stirring Mode

The mixer-settler is a core device of solvent extraction for separating rare earth elements. There are some adverse effects like high rare earth accumulation and poor production efficiency during industrial production. Current researches usually focus on changing the structure of the mixer-settler without making a breakthrough towards gravity clarification. In this paper, in order to improve the efficiency of clarification, a mixer-settler with double stirring mode was designed and manufactured by adding a stirring device in the settler after reducing the volume of the settler. The innovation of this research involves adopting the ultraviolet-visible spectrophotometer to investigate the quantity of aqueous phase entrainment at the settler outlet in order to measure the clarification degree. Experimental results show that the clarification effect with stirring is better than that without stirring. The clarification effect is ameliorated as the stirring speed increases. Generally, the clarification effect shows a best condition when the offset distance is 12.5 cm, making the phase entrainment reduced to less than 0.1%. When the clearance over the tank bottom is 7 cm and 10 cm, respectively, the quantity of aqueous phase entrainment is better than the case with a clearance of 4 cm. The results show that the stirring paddle close to the mixed phase zone can better promote the two-phase separation.

Effect of Stirring on Oil-Water Separation in Rare Earth Mixer-Settler

Oil-water separation is critical to solvent extraction process of rare earth, which can directly affect the yield and quality of the product. The experiments measure the two-phase separation time in a beaker, mixing uniformity of two phases in the mixer and the oil phase entrainment at oil exit by the Karl Fischer method and numerical simulation for the mixersettler to study the combined effect of gravity and stirring. Experimental results show that relative to the static situation, the separation efficiency resulted from low-speed stirring is increased by 25%. The water content in the oil is a minimum at an offset distance L of 10 cm and the clearance off the tank bottom z of 10 cm is as low as 0.49%. Distribution images of oilwater separation at 2 s indicates that stirring is very conducive to the separation of the oil-water phase.

Analysis of the flow pattern and periodicity of gas–liquid–liquid three-phase flow in a countercurrent mixer-settler

In contrast to the concurrent mixer-settler,the interaction between the mixing and settling chambers have to be taken into account in the simulation of the countercurrent mixer-settler,and no work has been reported for this equipment.In this work,a three-phase flow model based on the Eulerian multiphase model,coupled with a sliding mesh model is proposed for a countercurrent mixer-settler.Based on this,the dispersed phase distribution,flow pattern,and pressure distribution are investigated,which can help to fill the gap in the operation mechanism.In addition,the velocity vector distribution at the phase port shows an intriguing phenomenon that two types of vectors with opposite directions are distributed on the left and right sides of the same plane,which indicates that the material exchange in the mixing and settling chambers is simultaneous.Analysis of this variation at this location by a fast Fourier transform(FFT)method reveals that it is mainly influenced by the mixing chamber and is consistent with the main period of the outlet flow fluctuations.Therefore,by monitoring the fluctuation of the outlet flow and then analyzing it by the FFT method,the state of the whole tank can be determined,which makes it promising for the design of control systems for countercurrent mixer-settlers.