A numerical estimation of the impact of Stokes drift on upper ocean temperature

The impact of Stokes drift on the mixed layer temperature variation was estimated by taking into account an advective heat transport term induced by the Stokes drift in the equation of mixed layer temperature and using the oceanic and wave parameters from a global ocean circulation model （HYCOM） and a wave model （Wave Watch III）. The dimensional analysis and quantitative estimation method were conducted to assess the importance of the effect induced by the Stokes drift and to analyze its spatial distribution and seasonal variation characteristics. Results show that the contribution of the Stokes drift to the mixed layer temperature variation at mid-to-high latitudes is comparable with that of the mean current, and a substantial part of mixed layer temperature change is induced by taking the Stokes drift effect into account. Although the advection heat transport induced by the Stokes drift is not the leading term for the mixed layer temperature equation, it cannot be neglected and even becomes critical in some regions for the simulation of the upperocean temperature.

Temperature-dependent Hydrothermal Synthesis of Two Distinct Three-dimensional Copper Complexes

Two distinct copper coordination polymers, namely [Cu^Ⅱ2（2,5-pydc）2（bpp）2]·H2O（1） and Cu2^ⅠCu^Ⅱ（2,5-pydc）2（bpp）2（2）（2,5-pydc = pyridine-2,5-dicarboxylic acid, bpp = 1,3-bi（4-pyridyl）propane）, have been successfully synthesized through hydrothermal conditions under different temperatures. Single-crystal X-ray structural analysis revealed that both complexes 1 and 2 are 3D frameworks. Complex 1 is an 8-connected 2-fold interpenetrating network based on [Cu（2,5-pydc）]4 molecular building block（MBB）, and also can be simplified as a 4-connected net if the Cu（Ⅱ） ion is regarded as an independent node, whereas 2 shows a（4,4）-connected non-interpenetrated framework which contains mixed valence Cu（Ⅰ/Ⅱ） centers. The results demonstrate that temperature plays a significant role in the final structures of the complexes.

Room Temperature Modulated Structure of Ca and K co-Doped LaMnO_3

A series of perovskite compounds of La1-x-yCaxKyMnO3 was prepared by hydrothermal disproportionation reaction of MnO2. The three oxidation states of manganese（Mn3＋, Mn4＋ and Mn5＋） can stably exist in the compounds. Under room temperature conditions, twice and three times modulated structure produced by the charge ordering can be observed by X-ray diffraction（XRD）, select area electron diffraction（SAED） and high resolution transmission electron microscopy（HR-TEM）. The splits of the diffraction peaks of the single crystals confirmed by synchrotron X-ray diffraction experiment are in accordance with those of the powder sample. The existence of the different oxidation states of Mn3＋, Mn4＋ and Mn5＋ can be considered to be the dominating reason of the complicated room temperature modulated structure.

Verification of an operational ocean circulation-surface wave coupled forecasting system for the China＇s seas

An operational ocean circulation-surface wave coupled forecasting system for the seas off China and adjacent areas（OCFS-C） is developed based on parallelized circulation and wave models. It has been in operation since November 1, 2007. In this paper we comprehensively present the simulation and verification of the system, whose distinguishing feature is that the wave-induced mixing is coupled in the circulation model. In particular, with nested technique the resolution in the China＇s seas has been updated to（1/24）° from the global model with（1/2）°resolution. Besides, daily remote sensing sea surface temperature（SST） data have been assimilated into the model to generate a hot restart field for OCFS-C. Moreover, inter-comparisons between forecasting and independent observational data are performed to evaluate the effectiveness of OCFS-C in upper-ocean quantities predictions, including SST, mixed layer depth（MLD） and subsurface temperature. Except in conventional statistical metrics, non-dimensional skill scores（SS） is also used to evaluate forecast skill. Observations from buoys and Argo profiles are used for lead time and real time validations, which give a large SS value（more than 0.90）. Besides, prediction skill for the seasonal variation of SST is confirmed. Comparisons of subsurface temperatures with Argo profiles data indicate that OCFS-C has low skill in predicting subsurface temperatures between 100 m and 150 m. Nevertheless, inter-comparisons of MLD reveal that the MLD from model is shallower than that from Argo profiles by about 12 m, i.e., OCFS-C is successful and steady in MLD predictions. Validation of 1-d, 2-d and 3-d forecasting SST shows that our operational ocean circulation-surface wave coupled forecasting model has reasonable accuracy in the upper ocean.

Phase evolution of(K,Na)NbO_3 powder prepared by high temperature mixing under hydrothermal conditions

（Na, K）NbO3 （KNN） powders were successfully prepared by high temperature mixing method （HTMM） under hydrothermal conditions to study the effect of reaction time on the formation of KNN for three K＋/（K＋ ＋Na＋） ratios of 0.6, 0.7 and 0.8. The products were characterized by X-ray diffraction （XRD）, scanning electron microscope （SEM）, transmission electron microscopy （TEM） and selected area electron diffraction （SAED）, to show the change of phase and morphology of the as-prepared particles with the K＋/（K＋ ＋ Na＋） molar ratio in the solution. Pure Na-rich KNN monoclinic phase and pure K-rich KNN orthorhombic phase could be obtained quickly after mixing the solutions at high temperature when the K＋/（K＋ ＋Na＋） molar ratio was either 0.6 or 0.8. When the K＋/（K＋ ＋Na＋） molar ratio was 0.7, however, the K-rich KNN orthorhombic phase grain formed first, followed by the Na-rich KNN monoclinic phase grain, with the two phases coexisting in the final product.

Experimental Study on Fatigue Performance of Gussasphalt Mixture

Four-point flexural fatigue test for Gussasphalt mixture specimen was carried out at a straincontrolled mode system. The results showed that the development of the tested stiffness modulus and phase angle of the mixtures with increasing load cycles exhibited three periods, initial generation, slow development and failure period. The fatigue crack generation zone formed in the third period, in which the macro mechanical properties were signifi cantly decreased. Moreover, we also analyzed the effects of asphalt content and mixing temperature on the fatigue life of the mixture. The results showed that the fi rst period when the specimen＇s initial stiffness modulus was reduced to 80% accounted for 5%-10% of the total fatigue life; the second period in which the reduction became slow and demonstrated a liner relationship with load cycles occupied 70%-85% of the fatigue life; and the third period was about 5%-10%. The results indicated that the lower the mixing temperature, the longer the fatigue life of Gussasphalt mixture. Besides, the increasing of asphalt content has a minor effect on the fatigue life of Gussasphalt mixture

Thermal performance and evaluation of a novel stratified and mixed flexible transformation solar heat storage unit

It is necessary to satisfy the flexible requirements of solar heat storage systems to provide efficient heating and constant-temperature domestic hot water at different periods.A novel heat storage tank with both stratified and mixing functions is proposed,which can realize the integration of stable stratification and rapid mixing modes.In this research,a three-dimensional heat transfer model of the heat storage tank with stratified and mixed dual modes was established,and a thermal performance test system for the tank was built in the State Key Laboratory of Green Building in Western China.Moreover,a new evaluation index representing the mixing speed is proposed.The stratification effect and mixing characteristics of the tank were studied under different comprehensive conditions.The results show that the exergy efficiency of the tank with a stratified pipe can be increased by 10%–15%compared to that of a conventional tank.Additionally,the recommended optimal flow rate range for well-stratified tanks is 4–6 L/min.The mixing nozzle of the tank reduces the mixing reaction coefficient by 0.27 and significantly reduces the mixing time.This study provides critical guidance to meet the flexible thermal needs of users and implement high-performance applications using the stratified and mixing modes of heat storage tanks.

The gelation rule of the polyol acetal derivatives in binary solvent mixtures

The gelation properties of polyol acetal derivatives including 2,4-（3,4-dichlorobenzylidene）-D-sorbitol（DCBS）, 1,3：2,4-di（3,4-dichlorobenzylidene）-D-sorbitol（DDCBS） and 1,3：2,5：4,6-tris（3,4-dichlorobenzylidene）-D-mannitol（TDCBM） in 35 single solvents and 39 binary solvent mixtures have been studied. FTIR and XRD results suggest that the self-assembly patterns of the gelator will not change in either the single solvent component or the corresponding solvent mixtures, but the critical gelation concentration（CGC）will be influenced. The results of SEM and rheology showed that the formation of true gels at saturated concentrations. Improving the heating temperature may promote the dissolving of gelators which are even insoluble at the temperature of the solvent boiling point and change the gelation behaviors. FloryHuggins parameter（x） was used to predict the gelation behavior of DCBS in the mixed solvents, and it is shown that the x values for the mixed solvents that can be gelled by DCBS are either greater or smaller than those for the selected good solvents.