期刊文献+
共找到491篇文章
< 1 2 25 >
每页显示 20 50 100
An Almost Sure Central Limit Theorem for Weighted Sums of Mixing Sequences
1
作者 ZOU GUANG-YU ZHANG YONG 《Communications in Mathematical Research》 CSCD 2012年第4期359-366,共8页
In this paper, we prove an almost sure central limit theorem for weighted sums of mixing sequences of random variables without stationary assumptions. We no longer restrict to logarithmic averages, but allow rather ar... In this paper, we prove an almost sure central limit theorem for weighted sums of mixing sequences of random variables without stationary assumptions. We no longer restrict to logarithmic averages, but allow rather arbitrary weight sequences. This extends the earlier work on mixing random variables 展开更多
关键词 almost sure central limit theorem weighted sums mixing sequence logarithmic average
下载PDF
THE MIXING OF GAS-LIQUID FLOW WITH VAPOR AND GAS-SOLID FLOW
2
作者 林多敏 蔡树棠 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1990年第6期513-518,共6页
In the industrial production, the mixing of gas-liquid flow with vapor and gas-solid flow is a very common problem. In the process of the mixing, solid particle-clusters will form, and will have steady radii when the ... In the industrial production, the mixing of gas-liquid flow with vapor and gas-solid flow is a very common problem. In the process of the mixing, solid particle-clusters will form, and will have steady radii when the effect of the gathering of particles is balanced withthat of the breaking of particle-clusters. Then, the population distribution function of size of particles per unit length per unit volume is introduced, and its governingequation is derived on the analogy of the molecular kinetic theory. Finally, when the gas flow is very slow, the expression of steady average radius of particle-clusters is obtained. 展开更多
关键词 THE mixing OF GAS-LIQUID FLOW WITH vapor AND GAS-SOLID FLOW GAS
下载PDF
A G^E/Equation of State Mixing Rule for Vapor-Liquid Equilibria
3
作者 屈一新 汪文川 +5 位作者 Lee Y.Y. Chung K.Y. Lee Y.W. 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1998年第3期14-28,共15页
A new excess Gibbs free energy/equation of state type mixing 0rule was derived byremoving the infinite pressure boundary condition imposed by Wong and Sandler.The mixing rulewas extensively tested in terms of a compre... A new excess Gibbs free energy/equation of state type mixing 0rule was derived byremoving the infinite pressure boundary condition imposed by Wong and Sandler.The mixing rulewas extensively tested in terms of a comprehensive data base,consisting of 52 simple nonpolar-nonpolar,carbon dioxide containing,hydrocarbon-hydrocarbon,CFC,polar-polar,nonpolar-polarbinary and multicomponent systems.Focused on the complete predictive capability,a comparisonbetween the Wong-Sandler and the mixing rule proposed was conducted.The results indicate that thenew mixing rule is in general superior to the Wong-Sandler’s,and the binary interaction parameteras required by the latter is removed,which reduces computing effort and is reliable in predictions ofvapor-liquid equilibria from low pressures to high pressures. 展开更多
关键词 vapor-LIQUID EQUILIBRIA EQUATION of state mixing RULE
下载PDF
Evidence of vapor shielding effect on heat flux loaded on flowing liquid lithium limiter in EAST 被引量:1
4
作者 Chenglong LI Guizhong ZUO +13 位作者 R MANIGI K TRITZ D ANDRUCZYK Bin ZHANG Ruirong LIANG D OLIVER Zhen SUN Wei XU Xiancai MENG Ming HUANG Zhongliang TANG Binfu GAO Ning YAN Jiansheng HU 《Plasma Science and Technology》 SCIE EI CAS CSCD 2022年第9期45-51,共7页
A lithium(Li)vapour layer was formed around a flowing liquid Li limiter to shield against the plasma incident power and reduce limiter heat flux in the EAST tokamak.The results revealed that after a plasma operation o... A lithium(Li)vapour layer was formed around a flowing liquid Li limiter to shield against the plasma incident power and reduce limiter heat flux in the EAST tokamak.The results revealed that after a plasma operation of a few seconds,the layer became clear,which indicated a strong Li emission with a decrease in the limiter surface temperature.This emission resulted in a dense vapour around the limiter,and Li ions moved along the magnetic fleld to form a green shielding layer on the limiter.The plasma heat flux loaded on the limiter,measured by the probe installed on the limiter,was approximately 52%lower than that detected by a fast-reciprocating probe at the same radial position without the limiter in EAST.Additionally,approximately 42%of the parallel heat flux was dissipated directly with the enhanced Li radiation in the discharge with the liquid metal infused trenches(LIMIT)limiter.This observation revealed that the Li vapour layer exhibited an excellent shielding effect to liquid Li on plasma heat flux,which is a possible beneflt of liquid-plasma-facing components in future fusion devices. 展开更多
关键词 liquid Li limiter Li vapor shielding heat flux EAST
下载PDF
Discrete formulation of mixed finite element methods for vapor deposition chemical reaction equations
5
作者 罗振东 周艳杰 朱江 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2007年第5期665-675,共11页
The vapor deposition chemical reaction processes, which are of extremely extensive applications, can be classified as a mathematical model by the following governing nonlinear partial differential equations containing... The vapor deposition chemical reaction processes, which are of extremely extensive applications, can be classified as a mathematical model by the following governing nonlinear partial differential equations containing velocity vector, temperature field, pressure field, and gas mass field. The mixed finite element (MFE) method is employed to study the system of equations for the vapor deposition chemical reaction processes. The semidiscrete and fully discrete MFE formulations are derived. And the existence and convergence (error estimate) of the semidiscrete and fully discrete MFE solutions are demonstrated. By employing MFE method to treat the system of equations for the vapor deposition chemical reaction processes, the numerical solutions of the velocity vector, the temperature field, the pressure field, and the gas mass field can be found out simultaneously. Thus, these researches are not only of important theoretical means, but also of extremely extensive applied vistas. 展开更多
关键词 vapor deposition chemical reaction equation the mixed finite element method semidiscrete formulation fully discrete formulation
下载PDF
Experimental study on explosion limit of M15 methanol-gasoline mixture
6
作者 TAN Yingxin SUN Yanlong +2 位作者 ZHANG Huarong LIU Haihong RAO Yonghong 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2021年第4期390-395,共6页
The explosion characteristics of M15 methanol-gasoline mixture was experimental test by using FRTA explosion limit instrument.The effect of temperature on the explosion area of the sample was studied.The results show ... The explosion characteristics of M15 methanol-gasoline mixture was experimental test by using FRTA explosion limit instrument.The effect of temperature on the explosion area of the sample was studied.The results show that the lower explosion limit of M15 methanol-gasoline mixture is 1.716%and the upper explosion limit is 11.451%at the initial temperature of 80℃.The lower explosion limit of M15 methanol-gasoline is in the range of 1.711%-1.760%with the initial temperature from 25℃to 100℃,and the upper explosion limit of the sample changes between 11.253%and 11.451%.Considering experimental error and precision,it can be approximated that the temperature has little influence on the explosion area of M15 methanol-gasoline mixture. 展开更多
关键词 M15 methanol-gasoline mixture explosion limits vapor explosion gas explosion
下载PDF
Extension of Huron-Vidal-type Mixing Rule to Three-parameter Harmens-Knapp Cubic Equation of State
7
作者 HANXiao-hong WANGQin CHENGuang-ming CUIXiao-long 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2005年第2期209-212,共4页
In this paper was extended the HV-type mixing rules to Harmens-Knapp cubic equation state(HK CEOS). The new HV-type mixing rule with HK CEOS was tested for Vapor-liquid equilibrium(VLE) of different polar and nonpolar... In this paper was extended the HV-type mixing rules to Harmens-Knapp cubic equation state(HK CEOS). The new HV-type mixing rule with HK CEOS was tested for Vapor-liquid equilibrium(VLE) of different polar and nonpolar systems. The tested results are in good agreement with existing experimental data within a wide range of temperatures and pressures. In comparison with the VDW mixing rule, the new mixing rule gives much better predictions for the VLE of nonpolar and polar systems. 展开更多
关键词 Equation of state Activity coefficient vapor-liquid equilibrium mixing rule
下载PDF
A New Excess Free Energy Mixing Rule for Representing Vapor-Liquid Equilibria of Mixed Refrigerants
8
作者 YE Gongran FANG Yibo +4 位作者 YAN Yuhao LIU Ying OUYANG Hongsheng GUO Zhikai HAN Xiaohong 《Journal of Thermal Science》 SCIE EI CAS CSCD 2024年第3期1161-1173,共13页
A suitable mixing rule is important for vapor liquid equilibrium(VLE)investigations for mixed refrigerants.In this work,a new excess free energy mixing rule(MRv)was proposed at zero pressure based on the linear relati... A suitable mixing rule is important for vapor liquid equilibrium(VLE)investigations for mixed refrigerants.In this work,a new excess free energy mixing rule(MRv)was proposed at zero pressure based on the linear relationship between dimensionless parameter 1/(u-1)and a.MRv mixing rule was explicit adopted variable liquid molar volume.The applicable temperature range of MRv could be extended by means of an empirical method to estimate the liquid molar volume for components at high temperatures.Three mixing rules modified Huron-Vidal mixing rule(MHV1),Wong-Sandler mixing rule(WS),and MRv at two reference pressures were used to compare the VLE data in the calculation of 37 mixed refrigerants.Results demonstrated that MRv had a relatively similar accuracy to MHV1 and WS for component and pressure calculation.Moreover,the average excess Gibbs free energy using the MRv mixing rule for the 37 selected mixed refrigerants(0.0013)was much lower than those using the MHV1(0.0078)and WS(0.0809)mixing rules,which was very valuable for the design and optimization of thermodynamic systems using mixed refrigerants. 展开更多
关键词 mixed refrigerant vapor liquid equilibrium(VLE) mixing rule REPRODUCIBILITY
原文传递
Recent advance on VOCs oxidation over layered double hydroxides derived mixed metal oxides 被引量:10
9
作者 Shuangde Li Dongdong Wang +1 位作者 Xiaofeng Wu Yunfa Chen 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2020年第4期550-560,共11页
Catalytic oxidation is regarded as one of the most promising strategies for volatile organic compounds(VOCs)purification.Mixed metal oxides(MMOs),after topological transformation using layered double hydroxides(LDHs)a... Catalytic oxidation is regarded as one of the most promising strategies for volatile organic compounds(VOCs)purification.Mixed metal oxides(MMOs),after topological transformation using layered double hydroxides(LDHs)as precursors,are extensively used as catalysts for VOCs oxidation due to their uniformity advantage.This review summarizes the developments in the LDH-derived VOCs heterogeneous catalytic oxidation over the last 10 years.Particularly,it addresses the VOCs abatement performance over MMO,noble metal/MMO,core-shell structured MMO,and integral MMO film catalysts originating from LDHs.Moreover,it highlights the water vapor effect and oxidation mechanism.This review indicates that LDH-based catalysts are a category of important VOCs oxidation materials. 展开更多
关键词 Volatile organic compounds oxidation Layered double hydroxides mixed metal oxides Water vapor Oxidation mechanism
下载PDF
Effect of Water Vapor Absorption on Measurements of Atmospheric Nitrate Radical by LP-DOAS 被引量:3
10
作者 Su-wen Li Wen-qing Liu +3 位作者 Pin-hua Xie Yi-jun Yang De-bao Chen Zheng Li 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2008年第5期433-437,共5页
During the measurement of atmospheric nitrate radical by long-path differential optical absorption spectroscopy, water vapor strong absorption could affect the measurement of nitrate radical and detection limits of sy... During the measurement of atmospheric nitrate radical by long-path differential optical absorption spectroscopy, water vapor strong absorption could affect the measurement of nitrate radical and detection limits of system. Under the tropospheric condition, the optical density of water vapor absorption is non-linearly dependent on column density. An effective method was developed to eliminate the effect of water vapor absorption. Reference spectra of water vapor based on the daytime atmospheric absorption spectra, when fitted together with change of cross section with water vapor column densities, gave a more accurate fitting of water vapor absorptions, thus its effect on the measurements of nitrate radical could be restricted to a minimum and detection limits of system reached 3.6 ppt. The modified method was applied during an intensive field campaign in the Pearl River Delta, China. The NO3 concentration in polluted air masses varied from 3.6 ppt to 82.5 ppt with an average level of 23.6±1.8 ppt. 展开更多
关键词 Nitrate radical Water vapor absorption Long-path differential optical absorption spectroscopy Detection limit
下载PDF
Spatio-temporal variation in transpiration responses of maize plants to vapor pressure deficit under an arid climatic condition 被引量:4
11
作者 ZHAO Wenzhi JI Xibin 《Journal of Arid Land》 SCIE CSCD 2016年第3期409-421,共13页
The transpiration rate of plant is physically controlled by the magnitude of the vapor pressure deficit(VPD) and stomatal conductance. A limited-transpiration trait has been reported for many crop species in differe... The transpiration rate of plant is physically controlled by the magnitude of the vapor pressure deficit(VPD) and stomatal conductance. A limited-transpiration trait has been reported for many crop species in different environments, including Maize(Zea mays L.). This trait results in restricted transpiration rate under high VPD, and can potentially conserve soil water and thus decrease soil water deficit. However, such a restriction on transpiration rate has never been explored in maize under arid climatic conditions in northwestern China. The objective of this study was to examine the transpiration rate of field-grown maize under well-watered conditions in an arid area at both leaf and whole plant levels, and therefore to investigate how transpiration rate responding to the ambient VPD at different spatial and temporal scales. The transpiration rates of maize at leaf and plant scales were measured independently using a gas exchange system and sapflow instrument, respectively. Results showed significant variations in transpiration responses of maize to VPD among different spatio-temporal scales. A two-phase transpiration response was observed at leaf level with a threshold of 3.5 k Pa while at the whole plant level, the daytime transpiration rate was positively associated with VPD across all measurement data, as was nighttime transpiration response to VPD at both leaf and whole plant level, which showed no definable threshold vapor pressure deficit, above which transpiration rate was restricted. With regard to temporal scale, transpiration was most responsive to VPD at a daily scale, moderately responsive at a half-hourly scale, and least responsive at an instantaneous scale. A similar breakpoint(about 3.0 k Pa) in response of the instantaneous leaf stomatal conductance and hourly canopy bulk conductance to VPD were also observed. At a daily scale, the maximum canopy bulk conductance occurred at a VPD about 1.7 k Pa. Generally, the responsiveness of stomatal conductance to VPD at the canopy scale was lower than that at leaf scale. These results indicate a temporal and spatial heterogeneity in how maize transpiration responses to VPD under arid climatic conditions. This could allow a better assessment of the possible benefits of using the maximum transpiration trait to improve maize drought tolerance in arid environment, and allow a better prediction of plant transpiration which underpin empirical models for stomatal conductance at different spatio-temporal scales in the arid climatic conditions. 展开更多
关键词 maize limited transpiration trait gas exchange sap flow stomatal conductance vapor pressure deficit
下载PDF
Limits on Heavy Neutrino Mass from Neutrinoless ββDecays of ^(76)Ge and ^(82)Se 被引量:1
12
作者 WU Huifang SONG Changliang 《Chinese Physics Letters》 SCIE CAS CSCD 1992年第9期453-455,共3页
With calculated nuclear shell-model wave functions,the nuclear matrix elements of the 0vββdecay mediated by heavy Majorana neutrino in ^(76)Ge and ^(82)Se are discussed.The results show that the lower limit of heavy... With calculated nuclear shell-model wave functions,the nuclear matrix elements of the 0vββdecay mediated by heavy Majorana neutrino in ^(76)Ge and ^(82)Se are discussed.The results show that the lower limit of heavy neutrino mass is about α^(2) x l0^(6) GeV with a mixing parameterα. 展开更多
关键词 mixing DECAY limit
下载PDF
Optimization Method for Evaluating Wind Power Penetration Limit Constrained by Load Following Capacity 被引量:3
13
作者 Zechun HU Zijiao HAN +1 位作者 Fang ZHANG Xu XIE 《电力系统自动化》 EI CSCD 北大核心 2013年第19期10-14,60,共6页
关键词 功率极限 容量约束 负载 评估 穿透 优化 跟踪能力 混合整数规划
下载PDF
Optical and Electrical Properties of Polyimide Thin Films Doped-Cu-phthalocyanine Polymerized by Vapor Phase Deposition
14
作者 ZHENGJian-bang WANGYuan 《Semiconductor Photonics and Technology》 CAS 2005年第2期94-98,共5页
Using Cu-phthalocyanine(CuPc),4,4’-diaminodiphenyl ether and pyromellitic dianhydride as monomer materials, polyimide(PI) thin films doped-CuPc have been prepared onto glass substrate by vapor phase co-deposition... Using Cu-phthalocyanine(CuPc),4,4’-diaminodiphenyl ether and pyromellitic dianhydride as monomer materials, polyimide(PI) thin films doped-CuPc have been prepared onto glass substrate by vapor phase co-deposition polymerization under a vacuum of 2×10-3Pa and thermal curing of polyamic acid film in at temperature of 150-200℃ for 60min. In this process, the polymerization can be carried out through controlling the stoichiometric ratio, heating time and deposition rates of the three monomers. IR spectrum identifies the designed chemical structure of the polymer. The absorption of polyimide doped-CuPc is very intense in vis-range and near-infrared by UV-Vis spectrum. And, the PI films doped-CuPc polymerized by vapor phase deposition have uniformity, fine thermal stability and good nonlinear optical properties, and the third-order optical nonlinear susceptibility χ(3) with degenerate four-wave mixing can be 1.984×10-9ESU. 展开更多
关键词 Nonlinear optical materials Cu-phthalocyanine POLYIMIDE vapor phase deposition polymerization Degenerate four-wave mixing
下载PDF
Estimation of the Fatigue Endurance Limit of HMAC for Perpetual Pavements
15
作者 李宁 AAA Molenaar MFC van de Ven 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第4期645-649,共5页
A simplified procedure was described to estimate the FEL of three kinds of hot-mix asphalt concrete (HMAC) without doing any fatigue tests. The procedure required two fundamental properties of HMAC, tensile strength... A simplified procedure was described to estimate the FEL of three kinds of hot-mix asphalt concrete (HMAC) without doing any fatigue tests. The procedure required two fundamental properties of HMAC, tensile strength under different temperatures and strain rates, and flexural stiffness under different stain levels. This information can reliably be obtained in simple tests, which are the monotonic uniaxial tensile test (MUTT) and the four-point bending test (FPBT). A new parameter, the initial stress ratio Rinitial, was introduced to connect these two tests, which was defined as the ratio of applied initial stress and tensile strength of the specimen. At last the FEL can be expressed as a function of the initial flexural stiffness, frequency and temperature. Obviously, this procedure has the potential to be very useful in view of long-life pavement design and time consuming traditional fatigue tests. 展开更多
关键词 fatigue endurance limit hot-mix asphalt concrete tensile strength flexural stiffness initial stress ratio
下载PDF
含R1234yf混合工质汽液相平衡的混合规则评估与预测研究
16
作者 王林 江荣鼎 +2 位作者 张春晓 李修真 谈莹莹 《化工学报》 EI CSCD 北大核心 2024年第2期475-483,共9页
含R1234yf混合工质具有系统性能优良且对环境友好的特点,在当前制冷剂迭代中受到了广泛关注。汽液相平衡性质是混合工质的基础热物理性质,其理论计算至关重要。为提高含R1234yf混合工质汽液相平衡数据的计算精度,选取PR状态方程结合vdW... 含R1234yf混合工质具有系统性能优良且对环境友好的特点,在当前制冷剂迭代中受到了广泛关注。汽液相平衡性质是混合工质的基础热物理性质,其理论计算至关重要。为提高含R1234yf混合工质汽液相平衡数据的计算精度,选取PR状态方程结合vdW、WS、MHV1三种混合规则和NRTL活度系数模型评估了16种含R1234yf二元混合工质的汽液相平衡性质。结果表明,WS混合规则和MHV1混合规则计算性能优于vdW混合规则;vdW混合规则对大多数混合工质计算性能较好。最后提出一种预测模型预测含R1234yf混合工质汽液相平衡性质,预测的相对压力偏差值为0.49%,气相摩尔分数绝对偏差值为0.0031,预测偏差满足工程应用。 展开更多
关键词 R1234yf 混合物 汽液相平衡 混合规则 模型 预测
下载PDF
Relationship between Leaf Micro- and Macro-Nutrients in Top Canopy Trees in a Mixed Forest in the Upper Rio Negro in the Amazon Region
17
作者 M. A. Sobrado 《American Journal of Plant Sciences》 2014年第10期1423-1431,共9页
The mixed forests of the upper Rio Negro at the northern of the Amazon basin grow in oxisol soils that are extremely infertile. These areas exhibit deficiencies in several macro-nutrients, and may also be characterize... The mixed forests of the upper Rio Negro at the northern of the Amazon basin grow in oxisol soils that are extremely infertile. These areas exhibit deficiencies in several macro-nutrients, and may also be characterized by the shortage or toxic excess of some micronutrients. The overall goal of this research is to collect more comprehensive information regarding the micronutrient composition of the upper Rio Negro forests as well as discern the relationship between leaf micro- and macro-nutrients that may contribute to the homeostasis and balance of the ionome. Firstly, the nutrient composition within the oxisol soil and leaf tissues of two top canopy tree species from the mixed forests was determined. We then analyzed the relationship between leaf micronutrient composition with N and P levels of the two species and that of species inhabiting the Amazon caatinga. Extractable soil Zn, B, Mn and Cu were very low in the mixed forest. In contrast, Fe and Al levels were potentially toxic. The analysis of leaf N/P ratios revealed for the first time the co-limitation of N and P in the mixed forest. This contrasts with species from the adjacent Amazon caatinga toposequence that are characterized by strong N limitation. All micronutrients within leaves of species inhabiting the mixed forest were also found to have low concentrations. Moreover, Fe and Al were detected at concentrations well below those reported for accumulator species. This suggested that leaf ion homeostasis was maintained under potentially toxic soil Fe and Al conditions. Leaf micronutrient (Fe, Zn and B) contents mirrored that of leaf N and P contents, and comparable Fe/N, Fe/P, Zn/N, Zn/P, B/N as well as B/P ratios were found across species and forest types. Therefore, forest species exhibited the capability to maintain leaf nutrient balances under soil conditions with deficient or toxic levels of micronutrients. 展开更多
关键词 AMAZON Forests AMAZON Caatinga LEAF Ionome Homeostasis LEAF N-P and MICRONUTRIENTS Micro-Nutrient Deficiency MICRONUTRIENTS Toxicity mixed Forest N-P Co-limitation Plant NUTRIENT Balance Oxisol PODZOL
下载PDF
新型二元混合制冷工质对CO_(2)-[Cn-mim][Tf_(2)N](n=2,4,6,8)超额性质预测
18
作者 何丽娟 杨建滋 +1 位作者 韩雨泽 杨文轩 《高校化学工程学报》 EI CAS CSCD 北大核心 2024年第1期40-48,共9页
针对二氧化碳-离子液体(CO_(2)-ILs)体系热力学性质数据较少的问题,采用状态方程+活度系数法(EOS+γ法)计算了CO_(2)-[C_(2)-mim][Tf_(2)N]、CO_(2)-[C_(4)-mim][Tf_(2)N]、CO_(2)-[C_(6)-mim][Tf_(2)N]和CO_(2)-[C_(8)-mim][Tf_(2)N]4... 针对二氧化碳-离子液体(CO_(2)-ILs)体系热力学性质数据较少的问题,采用状态方程+活度系数法(EOS+γ法)计算了CO_(2)-[C_(2)-mim][Tf_(2)N]、CO_(2)-[C_(4)-mim][Tf_(2)N]、CO_(2)-[C_(6)-mim][Tf_(2)N]和CO_(2)-[C_(8)-mim][Tf_(2)N]4种新型制冷工质对的汽液相平衡数据。在相平衡基础上,通过SRK(Soave-Redlich-Kwong)状态方程+WS(Wong-Sandler)混合规则+UNIFAC活度系数模型,关联得出混合体系的超额吉布斯自由能GE、超额焓HE和超额熵SE。计算结果表明,CO_(2)-ILs制冷工质对的超额性质均随温度、压力、CO_(2)液相摩尔分数以及离子液体中阳离子上烷基链长度等因素变化,GE均为负值,最大值为-1066.88 J·mol^(-1),且GE随温度、压力和ILs阳离子碳基链长度增大而减小,HE均为正值,最大值为407.24 J·mol^(-1),且H^(E)随温度、CO_(2)溶解度及ILs阳离子碳基链长度增大而减小,SE最大值为7.88 J·mol^(-1)·K-1,且SE随温度和压力的增大而减小、随ILs阳离子碳基链长度增大而增大。根据汽液相平衡时计算的压力平均相对偏差,可证明所选模型在计算CO_(2)-[C_(n)-mim][Tf_(2)N](n=2,4,6,8)系统超额性质的准确性。 展开更多
关键词 汽液相平衡 SRK状态方程 WS混合规则 UNIFAC活度系数模型 超额性质预测
下载PDF
交混因子对CHF关系式开发及安全裕量影响研究
19
作者 刘晨伟 肖瑶 +2 位作者 张伟 陈硕 顾汉洋 《原子能科学技术》 EI CAS CSCD 北大核心 2024年第2期337-343,共7页
采用最小偏离泡核沸腾比(MDNBR)点法开发了与子通道分析程序FLICA-ⅢF匹配的临界热流密度(CHF)关系式,利用Owen准则确定了其DNBR限值并进行统计评估。在掌握了一套完整的CHF关系式开发方法后,对比分析了不同交混因子其对应关系式的预测... 采用最小偏离泡核沸腾比(MDNBR)点法开发了与子通道分析程序FLICA-ⅢF匹配的临界热流密度(CHF)关系式,利用Owen准则确定了其DNBR限值并进行统计评估。在掌握了一套完整的CHF关系式开发方法后,对比分析了不同交混因子其对应关系式的预测效果、DNBR限值以及实际最大功率。结果表明:基于实验获得的精确交混因子开发的CHF关系式具有更高的精确度与经济性。因此考虑格架交混效应的精细化子通道的工作是有价值和意义的。 展开更多
关键词 燃料组件 交混因子 CHF关系式 DNBR限值 安全裕量
下载PDF
三元混合制冷剂R290+R600a+N2汽液相平衡实验研究
20
作者 韩树康 祁影霞 +4 位作者 杨瀚宁 徐小雷 陶杰 王飞 刘业凤 《原子与分子物理学报》 北大核心 2024年第6期161-169,共9页
在氢气液化工艺中,预冷循环是重要的一环,其中混合制冷剂(mixed refrigerant,MR)预冷循环是单位能耗比较低的,故对MR性能的优化显得尤为重要.为此利用液相单相循环法搭建汽液相平衡(Vapor-liquid equilibrium,VLE)实验系统,研究了R290+R... 在氢气液化工艺中,预冷循环是重要的一环,其中混合制冷剂(mixed refrigerant,MR)预冷循环是单位能耗比较低的,故对MR性能的优化显得尤为重要.为此利用液相单相循环法搭建汽液相平衡(Vapor-liquid equilibrium,VLE)实验系统,研究了R290+R600a+N_(2)三元体系的VLE性质,在273.15 K~323.15 K的温度范围内,对三元混合工质R290+R600a+N_(2)进行实验研究,并获得18组实验数据.同时使用Peng-Pobinson-Stryjek-Vera (PRSV)状态方程结合van der Waals(vd W)混合法则对R290+R600a、R290+N_(2)、R600a+N_(2)三组二元体系的VLE文献数据进行了拟合计算,得到二元交互作用系数,拟合结果与文献数据吻合良好.以此为基础,推算该三元体系的VLE性质.最后将实验数据与计算结果对比表明,体系压力平均相对偏差AARDp为0.85%,系统组分R290、R600a和N_(2)的气相平均绝对偏差AADy_(1)、AADy_(2)和AADy_(3)分别为0.0064、0.0027和0.0063,证明实验结果数据合理可靠,可以满足工程上的应用. 展开更多
关键词 混合制冷剂 汽液平衡 热力学性质 仪器标定
下载PDF
上一页 1 2 25 下一页 到第
使用帮助 返回顶部