Novel and efficient Mn(OAc)_(3)·2 H_(2)O promoted radical addition-[4+1]cyclization relay of 3-indolymethanols and phosphites was disclosed,which afforded 1,2-oxaphospholoindole derivatives in moderate to good yi...Novel and efficient Mn(OAc)_(3)·2 H_(2)O promoted radical addition-[4+1]cyclization relay of 3-indolymethanols and phosphites was disclosed,which afforded 1,2-oxaphospholoindole derivatives in moderate to good yields.Based on the experimental and computational studies,a mechanism involving radical addition and intramolecular cyclization cascade was proposed.展开更多
A manganese (Ⅲ)-promoted oxidative radical cascade reaction of easily accessible arylboronic acids with isocyanides to construct diimide derivatives was studied. This protocol provides a new way to synthesis of acety...A manganese (Ⅲ)-promoted oxidative radical cascade reaction of easily accessible arylboronic acids with isocyanides to construct diimide derivatives was studied. This protocol provides a new way to synthesis of acetyl diimide derivatives. New C-C, C-N and C=O bonds were formed in one step.展开更多
基金the National Natural Science Foundation of China(Nos.21772138 and 21672157)the project of scientific and technologic infrastructure of Suzhou(No.SZS201708)PAPD。
文摘Novel and efficient Mn(OAc)_(3)·2 H_(2)O promoted radical addition-[4+1]cyclization relay of 3-indolymethanols and phosphites was disclosed,which afforded 1,2-oxaphospholoindole derivatives in moderate to good yields.Based on the experimental and computational studies,a mechanism involving radical addition and intramolecular cyclization cascade was proposed.
基金the National Natural Science Foundation of China(Nos. 21772137, 21672157, 21372174)the Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions (No. 16KJA150002)+2 种基金the Ph.D. Programs Foundation of PAPDthe project of scientific and technologic infrastructure of Suzhou (No. SZS201708)Soochow University for financial support
文摘A manganese (Ⅲ)-promoted oxidative radical cascade reaction of easily accessible arylboronic acids with isocyanides to construct diimide derivatives was studied. This protocol provides a new way to synthesis of acetyl diimide derivatives. New C-C, C-N and C=O bonds were formed in one step.
