Nitrogen monoxide(NO) emitted from automobile exhaust and other industrial sources contributes largely to a variety of environmental problems, such as the formation of acid rain and photochemical smog Therefore, the c...Nitrogen monoxide(NO) emitted from automobile exhaust and other industrial sources contributes largely to a variety of environmental problems, such as the formation of acid rain and photochemical smog Therefore, the catalytic reduction of NO has become one of the urgent environmental issues In the present study, a series of Au/Mn 2O 3/Al 2O 3 catalysts, with different Mn 2O 3 loadings, were prepared by deposition precipitation The crystallite size of Au before and after reaction was characterized by XRD The activity of catalysts in the selective catalytic reduction of NO using propane in the presence of oxygen was evaluated It is found that the catalytic activity of Au/Mn 2O 3/Al 2O 3 is higher than that of Au/Al 2O 3 and Cu ZSM 5 at feed gas(0 6%NO+1 2%C 3H 8+5%O 2+He) and GHSV 5?000?h展开更多
The pure bixbyite Mn 2O 3 was prepared by first applying in situ redox precipitation hydrothermal synthesis method under the very mild conditions, and characterized by XRD, TEM, BET and TGA. The effects of alkalinity,...The pure bixbyite Mn 2O 3 was prepared by first applying in situ redox precipitation hydrothermal synthesis method under the very mild conditions, and characterized by XRD, TEM, BET and TGA. The effects of alkalinity, crystallization time and temperature on the product were investigated. The results demonstrated that the alkalinity has an obvious effect on the product whereas the crystallization time and temperature has only a little influence on the product. Too low alkalinity results in no formation of product, and too high alkalinity leads to no formation of pure product with a smaller particle size. Under optimized conditions, the pure bixbyite Mn 2O 3 powder with a better morphology and distribution can be obtained. The average diameter of product is approximate to 80 nm. The normal LiMn 2O 4 spinel used as cathode material can be prepared using as synthesized bixbyite Mn 2O 3 as manganese precursor at 650 ℃ for 2 h by solid state reaction.展开更多
The catalytic performance of sulfided Mn/Al 2O 3 and Cu-Mn/Al 2O 3 catalysts for the ammonia decomposition has been studied by using a fixed-bed flow apparatus. It is found that the addition of copper component to Mn/...The catalytic performance of sulfided Mn/Al 2O 3 and Cu-Mn/Al 2O 3 catalysts for the ammonia decomposition has been studied by using a fixed-bed flow apparatus. It is found that the addition of copper component to Mn/Al 2O 3 catalyst can increase its catalytic activity for ammonia decomposition. The results of TPR indicate that the existence of copper component significantly improves the reduction of catalysts, which is beneficial to form active metal sulfide phase to catalyze the reduction of SO 2 to H 2S by hydrogen. X-ray diffraction results reveal that the Cu-Mn/Al 2O 3 catalyst (n Cu /n Mn =0.4) contains a CuMn 2O 4 phase before reaction, and displays MnS peaks after reaction.展开更多
A new mixed-valence trinuclear oxo-centered manganese complex Mn3O(O2CCC l3)6(py)2(H2O) was prepared by the reaction of NnBu4MnO4 with Mn(OAc)2·4H2O, t richloroacetic acid and pyridine in absolute EtOH. The cryst...A new mixed-valence trinuclear oxo-centered manganese complex Mn3O(O2CCC l3)6(py)2(H2O) was prepared by the reaction of NnBu4MnO4 with Mn(OAc)2·4H2O, t richloroacetic acid and pyridine in absolute EtOH. The crystal structure was det ermined. The complex crystallizes in monoclinic, space group P21/c, unit cell pa rameters, a=14.951(1), b=20.791(2), c=17.882(1),á=?=90a=102.67(1)展开更多
文摘Nitrogen monoxide(NO) emitted from automobile exhaust and other industrial sources contributes largely to a variety of environmental problems, such as the formation of acid rain and photochemical smog Therefore, the catalytic reduction of NO has become one of the urgent environmental issues In the present study, a series of Au/Mn 2O 3/Al 2O 3 catalysts, with different Mn 2O 3 loadings, were prepared by deposition precipitation The crystallite size of Au before and after reaction was characterized by XRD The activity of catalysts in the selective catalytic reduction of NO using propane in the presence of oxygen was evaluated It is found that the catalytic activity of Au/Mn 2O 3/Al 2O 3 is higher than that of Au/Al 2O 3 and Cu ZSM 5 at feed gas(0 6%NO+1 2%C 3H 8+5%O 2+He) and GHSV 5?000?h
文摘The pure bixbyite Mn 2O 3 was prepared by first applying in situ redox precipitation hydrothermal synthesis method under the very mild conditions, and characterized by XRD, TEM, BET and TGA. The effects of alkalinity, crystallization time and temperature on the product were investigated. The results demonstrated that the alkalinity has an obvious effect on the product whereas the crystallization time and temperature has only a little influence on the product. Too low alkalinity results in no formation of product, and too high alkalinity leads to no formation of pure product with a smaller particle size. Under optimized conditions, the pure bixbyite Mn 2O 3 powder with a better morphology and distribution can be obtained. The average diameter of product is approximate to 80 nm. The normal LiMn 2O 4 spinel used as cathode material can be prepared using as synthesized bixbyite Mn 2O 3 as manganese precursor at 650 ℃ for 2 h by solid state reaction.
文摘The catalytic performance of sulfided Mn/Al 2O 3 and Cu-Mn/Al 2O 3 catalysts for the ammonia decomposition has been studied by using a fixed-bed flow apparatus. It is found that the addition of copper component to Mn/Al 2O 3 catalyst can increase its catalytic activity for ammonia decomposition. The results of TPR indicate that the existence of copper component significantly improves the reduction of catalysts, which is beneficial to form active metal sulfide phase to catalyze the reduction of SO 2 to H 2S by hydrogen. X-ray diffraction results reveal that the Cu-Mn/Al 2O 3 catalyst (n Cu /n Mn =0.4) contains a CuMn 2O 4 phase before reaction, and displays MnS peaks after reaction.
文摘A new mixed-valence trinuclear oxo-centered manganese complex Mn3O(O2CCC l3)6(py)2(H2O) was prepared by the reaction of NnBu4MnO4 with Mn(OAc)2·4H2O, t richloroacetic acid and pyridine in absolute EtOH. The crystal structure was det ermined. The complex crystallizes in monoclinic, space group P21/c, unit cell pa rameters, a=14.951(1), b=20.791(2), c=17.882(1),á=?=90a=102.67(1)
