Effect of ball milling and electrolyte on the properties of high-voltage LiNi0.5Mn1.5O4 was investigated. Ball milling has significant effect on the synthesis and property of LiNi0.5Mn1.5O4. The X-ray diffraction（XRD...Effect of ball milling and electrolyte on the properties of high-voltage LiNi0.5Mn1.5O4 was investigated. Ball milling has significant effect on the synthesis and property of LiNi0.5Mn1.5O4. The X-ray diffraction（XRD） patterns indicate that LiNi0.5Mn1.5O4 cant be synthesized without ball milling even calcined at 900℃. When synthesized with ball milling, LiNi0.5Mn1.5O4 almost exhibits only one plateau at around 4.7V. With the increase of ball milling time, the capacity of (LiNi0.5Mn1.5O4) increases, but the cycling performance is not highly affected. The （electrochemical） property of (LiNi0.5Mn1.5O4) highly depends on the electrolyte. The stable and high-voltage-resistant （electrolyte） is much beneficial to enhancement of electrochemical property of LiNi0.5Mn1.5O4, such as coulombic efficiency and cycling performance.展开更多
文摘Effect of ball milling and electrolyte on the properties of high-voltage LiNi0.5Mn1.5O4 was investigated. Ball milling has significant effect on the synthesis and property of LiNi0.5Mn1.5O4. The X-ray diffraction（XRD） patterns indicate that LiNi0.5Mn1.5O4 cant be synthesized without ball milling even calcined at 900℃. When synthesized with ball milling, LiNi0.5Mn1.5O4 almost exhibits only one plateau at around 4.7V. With the increase of ball milling time, the capacity of (LiNi0.5Mn1.5O4) increases, but the cycling performance is not highly affected. The （electrochemical） property of (LiNi0.5Mn1.5O4) highly depends on the electrolyte. The stable and high-voltage-resistant （electrolyte） is much beneficial to enhancement of electrochemical property of LiNi0.5Mn1.5O4, such as coulombic efficiency and cycling performance.
