Amorphous materials are one kind of nonequilibrium materials and have become one of the most active research fields.Compared with crystalline solids,the theory of amorphous materials is still in infancy because their ...Amorphous materials are one kind of nonequilibrium materials and have become one of the most active research fields.Compared with crystalline solids,the theory of amorphous materials is still in infancy because their characteristic of atomic arrangement is more like liquid and has no long-range periodicity.Recently,as the representative of amorphous materials,amorphous molybdenum sulfide(a-MoS_(x))with unique physical and chemical properties has been studied extensively.However,considerable debate surrounds the structure–property relationships of a-MoS_(x)owing to its diverse Mo-S motifs.Herein,we summarize recent discoveries and research results regarding a-MoS_(x),whose structural characteristics,synthetic strategies,formation criteria,and comprehensive applications are discussed in detail.Finally,this review is ended with our personal insights and critical outlooks over the development of a-MoS_(x).展开更多
基金the financial support from the Fundamental Research Program of Shanxi Province,China(No.202203021211130)the National Natural Science Foundation of China(Nos.51801132,52075359)。
基金the National Funds for Distinguished Young Scientists(No.61825503)the National Natural Science Foundation of China(Nos.51902101,61775101,and 61804082)+2 种基金the Youth Natural Science Foundation of Hunan Province(No.2021JJ40044)Natural Science Foundation of Jiangsu Province(No.BK20201381)Science Foundation of Nanjing University of Posts and Telecommunications(No.NY219144).
文摘Amorphous materials are one kind of nonequilibrium materials and have become one of the most active research fields.Compared with crystalline solids,the theory of amorphous materials is still in infancy because their characteristic of atomic arrangement is more like liquid and has no long-range periodicity.Recently,as the representative of amorphous materials,amorphous molybdenum sulfide(a-MoS_(x))with unique physical and chemical properties has been studied extensively.However,considerable debate surrounds the structure–property relationships of a-MoS_(x)owing to its diverse Mo-S motifs.Herein,we summarize recent discoveries and research results regarding a-MoS_(x),whose structural characteristics,synthetic strategies,formation criteria,and comprehensive applications are discussed in detail.Finally,this review is ended with our personal insights and critical outlooks over the development of a-MoS_(x).
基金National Natural Science Foundation of China(51674196,51601144,51701162)National Key Research and Development Program of China(2017YFB0702403)+1 种基金Innovative Talents Promotion Plan of Shaanxi(2019KJXX-071)Excellent Doctoral Innovation Fund of Xi’an University of Technology(310252071705)。
