The title compound ttris-(diisopropyldithiophosphato)tris-μ-disulfidoμ3,-sulfido-cvclo-trimolybdenumj (3Mo-Mo) [diisopropyldithiophosphate], [Mo3S7 (S2P(iprO)2)3] [S2P(iprO)2] (Mr=1365. 39) is an ionic species which...The title compound ttris-(diisopropyldithiophosphato)tris-μ-disulfidoμ3,-sulfido-cvclo-trimolybdenumj (3Mo-Mo) [diisopropyldithiophosphate], [Mo3S7 (S2P(iprO)2)3] [S2P(iprO)2] (Mr=1365. 39) is an ionic species which consists of a discretecluster cation [Mo3S7 (S2P (iprO)2)3] + (ipr = isopropyl) and an anion [S2P (iprO)2]-It was synthesized from the reaction of (NH4)2MoS4 with HS2P (iprO)2. Crystallo-graphic data for its crystal: space group for 7356 independent reflec-'tions with The structure analysis reveals that the cation contains a typical(Mo3 (μ3,-S) (μ-S2)3]+ cluster core in which three molybdenum atoms form an isoscelestriangle;the structure of the free diisopropyldithiophosphate anion [S2P (iprO)2]- isdifferent obviously from the coordinated one.展开更多
Ionic liquids(ILs)have attracted intensive attention and have been used widely in many applications because of their diversified properties,which are caused by the special structure of the ILs.Ionic clusters are one o...Ionic liquids(ILs)have attracted intensive attention and have been used widely in many applications because of their diversified properties,which are caused by the special structure of the ILs.Ionic clusters are one of the typical structures that exist widely in the IL system.They are stable under certain conditions and change under other conditions.Ionic clusters are a typical mesoscale phenomenon in mesoscience.In this review,we summarize our recent progress related to ionic clusters,including the ionic-cluster structure,changing mechanisms,and their effect on the physicochemical properties.IL cluster investigation based on mesoscience is very important,will provide new insight into the structures and properties of ILs,and will boost further exploration of IL applications.展开更多
The crystal structures of two new trinuclear Mo-S cluster compounds[Mo3S7(TDT)3](Et4N)2·DMF1 and[Mo3S3(O)2(TDT)3](Et4N)2 2 with bianion TDT(S2C6H3CH32-) as ligands are reported in this paper.There is a weak inter...The crystal structures of two new trinuclear Mo-S cluster compounds[Mo3S7(TDT)3](Et4N)2·DMF1 and[Mo3S3(O)2(TDT)3](Et4N)2 2 with bianion TDT(S2C6H3CH32-) as ligands are reported in this paper.There is a weak interaction between the cluster anions through S atoms(μ-S or S of TDT ligands) in each unit cell of these two compounds.Moreover,the mutual transformation between these two compounds by the cluster reaction is discussed.Crystal data:for 1 space group=P1,a=12.996(4),b=18.100(8),c=12.530(4),α=91.57(3),β=97.42(3),γ=69.04(3)°,Z=2,5309 reflections,R=0.052;for 2 space group C2/c,a=26.504(9),b=22.177(5),c=17.355(9),β=108.43(9)°,Z=8,2999 reflections,R=0.079.展开更多
Two mononuclear metal-organic complexes, [Co（Hmpdc）2（H2O）4]·4H2O 1 and [Ni（Hfmpdc）2（H2O）4]·6H2O 2, were prepared from 2,6-dimethylpyridine-3,5-dicarboxylic acid （Hzmpdc） and 4-furyl-2,6-dimethylpyr...Two mononuclear metal-organic complexes, [Co（Hmpdc）2（H2O）4]·4H2O 1 and [Ni（Hfmpdc）2（H2O）4]·6H2O 2, were prepared from 2,6-dimethylpyridine-3,5-dicarboxylic acid （Hzmpdc） and 4-furyl-2,6-dimethylpyridine-3,5-dicarboxylic acid （H2fmpdc） with M（NO3）2 salts, respectively, and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and photoluminescent measurement. Complex 1 crystallizes in triclinic, space group P1 with a = 7.634（5）, b = 8.695（5）, c = 10.757（6）A, α = 69.647（7）, β = 69.957（8）, γ = 83.733（7）°, V = 628.9（7）A^3, Dc = 1. 561 g/cm^3,μ（MoKa） = 0.763 mm^-1, F（000） = 309, Z = 1, the final R = 0.0553 and wR = 0.1469 for 1909 observed reflections （Ⅰ 〉 2σ（Ⅰ））. Complex 2 crystallizes in monoclinic, space group P21/n with a = 9.5934（16）, b = 12.422（2）, c = 14.826（3） A, β = 105.201（2）°, V = 1705.0（5）A3, Dc = 1. 479 g/cm^3,μ（MoKa） = 0.655 mm^-1, F（000） = 796, Z = 2, the final R= 0.0351 and wR = 0.0889 for 2387 obsevved reflections （Ⅰ 〉 2σ（Ⅰ））. In the crystal structures of 1 and 2, diverse supramolecular motifs from 1-D chains/ladders to 3-D networks are constructed from corresponding distinct [M^Ⅱ（H2O）8] ion clusters as the second building units, respectively. The solid state compounds of 1 and 2 show similar photoluminescent spectra with emission maximum at ca.展开更多
文摘The title compound ttris-(diisopropyldithiophosphato)tris-μ-disulfidoμ3,-sulfido-cvclo-trimolybdenumj (3Mo-Mo) [diisopropyldithiophosphate], [Mo3S7 (S2P(iprO)2)3] [S2P(iprO)2] (Mr=1365. 39) is an ionic species which consists of a discretecluster cation [Mo3S7 (S2P (iprO)2)3] + (ipr = isopropyl) and an anion [S2P (iprO)2]-It was synthesized from the reaction of (NH4)2MoS4 with HS2P (iprO)2. Crystallo-graphic data for its crystal: space group for 7356 independent reflec-'tions with The structure analysis reveals that the cation contains a typical(Mo3 (μ3,-S) (μ-S2)3]+ cluster core in which three molybdenum atoms form an isoscelestriangle;the structure of the free diisopropyldithiophosphate anion [S2P (iprO)2]- isdifferent obviously from the coordinated one.
基金This work was supported by the National Science Fund for Excellent Young Scholars(21722610)the National Natural Scien-tific Fund of China(91434203 and 21776281)+1 种基金the Beijing Natural Science Foundation(2182073,2184124)the Center for Meso-science,Institute of Process Engineering,Chinese Academy of Sciences(COM2015A003).
文摘Ionic liquids(ILs)have attracted intensive attention and have been used widely in many applications because of their diversified properties,which are caused by the special structure of the ILs.Ionic clusters are one of the typical structures that exist widely in the IL system.They are stable under certain conditions and change under other conditions.Ionic clusters are a typical mesoscale phenomenon in mesoscience.In this review,we summarize our recent progress related to ionic clusters,including the ionic-cluster structure,changing mechanisms,and their effect on the physicochemical properties.IL cluster investigation based on mesoscience is very important,will provide new insight into the structures and properties of ILs,and will boost further exploration of IL applications.
文摘The crystal structures of two new trinuclear Mo-S cluster compounds[Mo3S7(TDT)3](Et4N)2·DMF1 and[Mo3S3(O)2(TDT)3](Et4N)2 2 with bianion TDT(S2C6H3CH32-) as ligands are reported in this paper.There is a weak interaction between the cluster anions through S atoms(μ-S or S of TDT ligands) in each unit cell of these two compounds.Moreover,the mutual transformation between these two compounds by the cluster reaction is discussed.Crystal data:for 1 space group=P1,a=12.996(4),b=18.100(8),c=12.530(4),α=91.57(3),β=97.42(3),γ=69.04(3)°,Z=2,5309 reflections,R=0.052;for 2 space group C2/c,a=26.504(9),b=22.177(5),c=17.355(9),β=108.43(9)°,Z=8,2999 reflections,R=0.079.
基金supported by the NNSFC (No. 20701041)the Key Project of Chinese Ministry of Education (No. 208116)+1 种基金the Natural Science Foundation of CQ CSTC (No. 2007BB5228)the Scientific and Technological Project of CQEC (No. KJ080829).
文摘Two mononuclear metal-organic complexes, [Co（Hmpdc）2（H2O）4]·4H2O 1 and [Ni（Hfmpdc）2（H2O）4]·6H2O 2, were prepared from 2,6-dimethylpyridine-3,5-dicarboxylic acid （Hzmpdc） and 4-furyl-2,6-dimethylpyridine-3,5-dicarboxylic acid （H2fmpdc） with M（NO3）2 salts, respectively, and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and photoluminescent measurement. Complex 1 crystallizes in triclinic, space group P1 with a = 7.634（5）, b = 8.695（5）, c = 10.757（6）A, α = 69.647（7）, β = 69.957（8）, γ = 83.733（7）°, V = 628.9（7）A^3, Dc = 1. 561 g/cm^3,μ（MoKa） = 0.763 mm^-1, F（000） = 309, Z = 1, the final R = 0.0553 and wR = 0.1469 for 1909 observed reflections （Ⅰ 〉 2σ（Ⅰ））. Complex 2 crystallizes in monoclinic, space group P21/n with a = 9.5934（16）, b = 12.422（2）, c = 14.826（3） A, β = 105.201（2）°, V = 1705.0（5）A3, Dc = 1. 479 g/cm^3,μ（MoKa） = 0.655 mm^-1, F（000） = 796, Z = 2, the final R= 0.0351 and wR = 0.0889 for 2387 obsevved reflections （Ⅰ 〉 2σ（Ⅰ））. In the crystal structures of 1 and 2, diverse supramolecular motifs from 1-D chains/ladders to 3-D networks are constructed from corresponding distinct [M^Ⅱ（H2O）8] ion clusters as the second building units, respectively. The solid state compounds of 1 and 2 show similar photoluminescent spectra with emission maximum at ca.
