Ti对Mo-Ti合金拉伸强度及显微组织的影响

采用粉末冶金方法制备Mo-Ti合金,研究合金元素添加方式及添加量对材料拉伸强度和显微组织的影响。结果表明,添加TiH2粉末所制备的合金的拉伸强度及相对密度均较添加纯Ti粉末的合金高,当添加量(质量分数)为0.8%时合金拉伸强度最高。显微组织分析结果表明,一部分Ti固溶到Mo基体,提高材料的拉伸强度,另一部分则与Mo及合金中的氧结合形成MoxTiyOz复合氧化物第二相粒子,起到细化晶粒及净化晶界的作用。

Mo-Ti体系合金的液相烧结与组织结构

设计了 Fe- Al烧结助剂进行 Mo- Ti体系合金的低温液相烧结 ,详细探讨合金在烧结过程中的组织结构变化以及 Mo- Ti合金的致密化机理。研究表明 ,Fe- Al添加剂对 Mo和 Ti的致密化均有明显的效果。Mo与 Ti在 Fe- Al添加剂的作用下发生了不完全的固溶反应 ,形成的部分 ( β- Ti,Mo)固溶体有效促进了不同组成配比的 Mo-

微量合金元素Ti、Zr对Mo金性能和显微组织的影响

采用粉末冶金法制备Mo-Zr、Mo-Ti合金,研究了Zr、Ti的添加方式及添加量对Mo的拉伸性能和显微组织的影响。结果表明,添加合金元素Zr、Ti大大提高了Mo的力学性能。合金元素Zr以纯Zr形式加入较以ZrH2形式为佳,其添加量在0.1%(质量分数,下同)时,合金性能最高。元素Zr仅有极少部分固溶到Mo基体中,大部分与合金中少量氧结合以ZrO2粒子相存在。合金元素Ti则以TiH2的方式添加为佳,添加量为0.8%时合金性能最高。元素Ti一部分固溶到Mo基体中,另一部分与Mo及合金中的少量氧结合以MoxTiyOz复合氧化物粒子相存在。

合金元素Ti对Mo合金性能及组织结构的影响

采用粉末冶金方法制备Ti含量为0.3%～1.0%的Mo-Ti合金。通过力学性能实验、光学显微镜观测和SEM分析,对Mo-Ti合金的性能和组织结构进行研究分析。结果表明,在Mo粉中添加TiH2所制备的合金比纯钼金属具有更好的拉伸性能,并且当Ti含量为0.8%时合金的力学性能最好;合金元素Ti除部分固溶到钼基体外,还在晶粒之间和晶粒内部生成(Mo,Ti)xOy弥散相,这些(Mo,Ti)xOy弥散相的生成,一方面净化了晶界氧,使晶粒之间的孔隙减少,同时也阻止晶粒在烧结时的晶粒长大,有利于合金性能的提高;但Ti添加量过多时,会使晶界之间产生过量的(Mo,Ti)xOy质点,使晶粒之间的结合能力减弱,对合金性能产生不利影响。

Mo-Ti微合化热轧高强钢的组织与性能

对一种Mo-Ti微合金钢进行了热轧实验,研究了不同工艺条件下的组织特征、析出行为及低温冲击性能。结果表明,随着终轧温度及终冷温度的降低,实验钢的屈服强度和抗拉强度均有所升高;当终轧温度较高时,细小的析出物主要在冷却及模拟卷取过程中产生,当终轧温度较低时,细小的析出物主要由应变诱导析出及冷却、模拟卷取过程的析出物组成;实验钢的组织以铁素体为主,随着终轧温度及终冷温度的降低,晶粒尺寸明显细化,同时,组织中渗碳体及钛的碳化物等岛状物的尺寸也变小,大角度晶界比例增加,低温冲击裂纹由脆性断裂变为韧性断裂;当终轧温度为800~810℃,终冷温度分别为615℃和500℃时,实验钢的屈服强度分别为738 MPa及768 MPa,抗拉强度分别为857 MPa和872 MPa,伸长率为18%~19%,其韧脆转变温度低于-70℃,实验钢具有良好的强度及韧性指标。

Microstructure,mechanical properties and dry wear resistance of β-type Ti-15Mo-xNb alloys for biomedical applications

In order to study the effect of element Nb on the microstructure and properties of the biomedical β-type Ti-Mo based alloys,Ti-15Mo-xNb（x=5,10,15 and 20 in %） alloys were investigated.The dry wear resistance of β-type Ti-15Mo-xNb alloys against Gr15 ball was investigated on CJS111A ball-disk wear instrument.Experimental results indicate that crystal structure and morphology of the Ti-15Mo-xNb alloys are sensitive to their Nb contents.Ti-15Mo-xNb alloys match those for β phase peaks and no any phases are found.The Vickers hardness values of all the Ti-15Mo-xNb alloys are higher than HV200.The compression yield strength of the Ti-15Mo-5Nb alloy is the lowest and that of the Ti-15Mo-10Nb alloy is the highest.For all the Ti-15Mo-xNb alloys,the friction coefficient is not constant but takes a higher value.In dry condition,SEM study reveals deep parallel scars on the wear surfaces of all the Ti-15Mo-xNb alloys under different loads.The friction coefficient of the Ti-15Mo-5Nb alloy under 1 N is the lowest.The wear principal mechanism for Ti-15Mo-xNb alloys is adhesive wear.

Effect of Nb addition on microstructure,mechanical properties and castability of β-type Ti-Mo alloys

To develop novel β-type biomedical titanium alloys,a series of Ti-15Mo-xNb alloys（x=0,5,10 and 15,mass fraction in%） were designed and prepared by using vacuum arc melting method.The present study focused on the effect of Nb addition on the microstructure,mechanical properties and castability of Ti-15 Mo alloy.Phase analysis and microstructure observation show that all the alloys consist of single β phase and the equiaxed β grain is refined with increasing Nb content.These β-type Ti-15Mo-xNb alloys exhibit good plasticity and rather low compression elastic modulus（in the range of 18.388-19.365 GPa）.After Nb addition,the compression yield strength of the alloys increases.With increasing Nb content,the micro-hardness of the alloys decreases.The alloys exhibit obvious fibrous strip microstructure after cold compression deformation.The castability test shows that the castability of the alloys after Nb addition decreases and that of the Ti-15 Mo alloy is the highest（92.01%）.

Microstructural,mechanical and shape memory characterizations of Ti-Mo-Sn alloys

As a β stabilizing element in Ti-based alloys,the effect of Mo on phase constitution,microstructure,mechanical and shape memory properties was investigated.Different compositions of Ti-xMo-3Sn alloys(where x=2,4,6,at.%) were prepared by arc melting.A binary composition of Ti-6 Mo alloy was also prepared for comparison.Ti-xMo-3Sn alloys show low hardness and high ductility with 90% reduction in thickness while Ti-6 Mo alloy shows high hardness,brittle behavior,and poor ductility.Field emission scanning electron microscopy(FESEM) reveals round morphology of athermal ω(ωath) precipitates.The presence of ωath phase is also confirmed by X-ray diffraction(XRD)in both as-cast and solution-treated and quenched conditions.The optical microscopy(OM) and FESEM show that the amount of martensite forming during quenching decreases with an increase in Mo content,which is also due to β→ω transformation.The hardness trends reinforce the presence of ωath too.The shape memory effect(SME) of 9% is the highest for Ti-6 Mo-3Sn alloy.The SME is trivial due to ωath phase formation;however,the increase in SME is observed with an increase in Mo content,which is due to the reverse transformation from ωath and the stress-induced martensitic transformation.In addition,a new and very simple method was designed and used for shape memory effect measurement.

Oxidation resistance of Si-coated TZM alloy prepared through combined process of plasma spray and laser surface melting

Plasma thermal spraying ofSi coating layer ontitanium-zirconium-molybdenum （Ti-Zr-Mo）,TZM alloy,was conducted for the surface protection of the Mo substrate that is unstable in air at high temperatures. Although the plasma thermal spraying alone could protect the Mo alloy from oxidation at a high temperature for a short time, the post laser surface melting process further improved the oxidation resistance of Si-coated alloy. In the case of the post laser treated specimen,MoSi compounds, mainly MoSi2 phases, were formed during the additional annealing process, and the oxidation resistance could be even further enhanced. The corrosion behaviors of Si-coated specimens in 3.5%NaCl solution were also investigated;however,nosignificant variations with respect to the post treatment procedure were found.