The Mo modified Ni/Al_2O_3 catalysts were prepared and sulfided at different temperatures, and their catalytic activity for thioetherification of mercaptans and olefins(or dienes), hydrogenation of dienes and olefins ...The Mo modified Ni/Al_2O_3 catalysts were prepared and sulfided at different temperatures, and their catalytic activity for thioetherification of mercaptans and olefins(or dienes), hydrogenation of dienes and olefins in the thioetherification process using fluidized catalytic cracking(FCC) naphtha as the feedstock was investigated. In order to disclose the correlation between the physicochemical characteristics of catalysts and their catalytic activity, the surface structures and properties of the catalysts sulfided at different temperatures were characterized by the high resolution transmission electronic microscopy(HRTEM), X-ray photoelectron spectroscopy(XPS) and H2-temperature programmed reduction(H_2-TPR) technique. The results showed that an increase of sulfurization temperature not only could promote the sulfurization degree of active metals on the catalysts, but also could adjust the micro-morphology of active species. These changes could improve the catalytic performance of thioetherification, and hydrogenation of dienes and olefins. However, an excess sulfurization temperature was more easily to upgrade the ability of the catalyst for hydrogenation of olefins, which could lead to a decrease of the octane number of the product. It was also showed that a moderate sulfurization temperature not only could improve the catalytic performance of thioetherification and hydrogenation of dienes but also could control hydrogenation of olefins.展开更多
Important technological and physics issues related to steady-state operationrequired for next step are being examined on Tore Supra, after a major upgrade of internalcomponents in order to increase the heat extraction...Important technological and physics issues related to steady-state operationrequired for next step are being examined on Tore Supra, after a major upgrade of internalcomponents in order to increase the heat extraction capability to 25 MW for 1000 s. Here, we showfirst experimental results, where all the plasma facing components were actively cooled duringpulses exceeding four minutes, with reactor-relevant heat load. New physics was observed innon-inductively driven plasmas, including a stationary peaked radial profile of the plasma densitygenerated by an anomalous inward pinch; and a regime characterized by sinusoidal oscillations ofcentral electron temperature, governed by non-linear coupling between heat transport and plasmacurrent analogous to a predator-prey mechanism.展开更多
基金support provided by the National Natural Science Foundation of China(Granted No.21276276)
文摘The Mo modified Ni/Al_2O_3 catalysts were prepared and sulfided at different temperatures, and their catalytic activity for thioetherification of mercaptans and olefins(or dienes), hydrogenation of dienes and olefins in the thioetherification process using fluidized catalytic cracking(FCC) naphtha as the feedstock was investigated. In order to disclose the correlation between the physicochemical characteristics of catalysts and their catalytic activity, the surface structures and properties of the catalysts sulfided at different temperatures were characterized by the high resolution transmission electronic microscopy(HRTEM), X-ray photoelectron spectroscopy(XPS) and H2-temperature programmed reduction(H_2-TPR) technique. The results showed that an increase of sulfurization temperature not only could promote the sulfurization degree of active metals on the catalysts, but also could adjust the micro-morphology of active species. These changes could improve the catalytic performance of thioetherification, and hydrogenation of dienes and olefins. However, an excess sulfurization temperature was more easily to upgrade the ability of the catalyst for hydrogenation of olefins, which could lead to a decrease of the octane number of the product. It was also showed that a moderate sulfurization temperature not only could improve the catalytic performance of thioetherification and hydrogenation of dienes but also could control hydrogenation of olefins.
文摘Important technological and physics issues related to steady-state operationrequired for next step are being examined on Tore Supra, after a major upgrade of internalcomponents in order to increase the heat extraction capability to 25 MW for 1000 s. Here, we showfirst experimental results, where all the plasma facing components were actively cooled duringpulses exceeding four minutes, with reactor-relevant heat load. New physics was observed innon-inductively driven plasmas, including a stationary peaked radial profile of the plasma densitygenerated by an anomalous inward pinch; and a regime characterized by sinusoidal oscillations ofcentral electron temperature, governed by non-linear coupling between heat transport and plasmacurrent analogous to a predator-prey mechanism.
