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Room Temperature Modulated Structure of Ca and K co-Doped LaMnO_3
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作者 HOU Chang-min HUANG Ke-ke +2 位作者 HU Bin YUAN Hong-ming FENG Shou-hua 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2012年第5期784-787,共4页
A series of perovskite compounds of La1-x-yCaxKyMnO3 was prepared by hydrothermal disproportionation reaction of MnO2. The three oxidation states of manganese(Mn3+, Mn4+ and Mn5+) can stably exist in the compound... A series of perovskite compounds of La1-x-yCaxKyMnO3 was prepared by hydrothermal disproportionation reaction of MnO2. The three oxidation states of manganese(Mn3+, Mn4+ and Mn5+) can stably exist in the compounds. Under room temperature conditions, twice and three times modulated structure produced by the charge ordering can be observed by X-ray diffraction(XRD), select area electron diffraction(SAED) and high resolution transmission electron microscopy(HR-TEM). The splits of the diffraction peaks of the single crystals confirmed by synchrotron X-ray diffraction experiment are in accordance with those of the powder sample. The existence of the different oxidation states of Mn3+, Mn4+ and Mn5+ can be considered to be the dominating reason of the complicated room temperature modulated structure. 展开更多
关键词 modulated structure mixed valence state room temperature
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