The isothermal and non-isothermal experiments were performed to construct the continuous cooling transformation (CCT) and temperature time transformation (TTT) diagrams of four industrial mold fluxes through visua...The isothermal and non-isothermal experiments were performed to construct the continuous cooling transformation (CCT) and temperature time transformation (TTT) diagrams of four industrial mold fluxes through visual observations in an experimental apparatus based on the single hot thermocouple technique (SHTT). The results of the CCT diagrams indicate that ① the crystallization temperature of mold fluxes lowers as the cooling rate increases, ② the mold fluxes have larger critical cooling rate, higher crystallization temperature, and less onset time of crystallization when the basicity increases or the viscosity decreases, ③ the influences of the melting points of the mold fluxes on their crystallization tendency are not significant. Isothermal tests show that the onset time of crystallization decreases at first, and then increases, and finally represents a "C" shape with increasing isothermal temperature. The TTT diagrams of four industrial mold fluxes were divided into two separate "C" shape regions. The crystal phase of C20A selected was analyzed by X-ray diffraction, which is cuspidine (Ca4 Si2 O7F2 ) over I 100 ℃ and calcium silicon oxide fluoride (Ca2SiO2F2) below 1 100℃. When compared with the TTT diagram, the CCT diagram can provide a more realistic estimate of the critical cooling rate of the mold fluxes. Thus, both the CCT and TTT diagrams can unambiguously describe the crystallization phenomena of the mold fluxes.展开更多
The corundum plates with a groove were used to freeze molten flux into solid slice to simulate the flux film formed in continuous casting mold,and thereby to study the formation mechanism of flux film with different s...The corundum plates with a groove were used to freeze molten flux into solid slice to simulate the flux film formed in continuous casting mold,and thereby to study the formation mechanism of flux film with different surface roughness.The effect of some factors on the surface roughness of flux film,such as reheating rate,cooling rate,flux film thickness and crystallization ratio,was discussed.展开更多
The corundum plates with a groove were used to freeze molten flux into solid slice to simulate the flux film formed in continuous casting mold, and thereby to study the formation mechanism of flux film with different ...The corundum plates with a groove were used to freeze molten flux into solid slice to simulate the flux film formed in continuous casting mold, and thereby to study the formation mechanism of flux film with different surface roughness. The effect of some factors on the surface roughness of flux film, such as reheating rate, cooling rate, flux film thickness and crystallization ratio, was discussed.展开更多
基金Item Sponsored by National Natural Science Foundation of China (50574109)
文摘The isothermal and non-isothermal experiments were performed to construct the continuous cooling transformation (CCT) and temperature time transformation (TTT) diagrams of four industrial mold fluxes through visual observations in an experimental apparatus based on the single hot thermocouple technique (SHTT). The results of the CCT diagrams indicate that ① the crystallization temperature of mold fluxes lowers as the cooling rate increases, ② the mold fluxes have larger critical cooling rate, higher crystallization temperature, and less onset time of crystallization when the basicity increases or the viscosity decreases, ③ the influences of the melting points of the mold fluxes on their crystallization tendency are not significant. Isothermal tests show that the onset time of crystallization decreases at first, and then increases, and finally represents a "C" shape with increasing isothermal temperature. The TTT diagrams of four industrial mold fluxes were divided into two separate "C" shape regions. The crystal phase of C20A selected was analyzed by X-ray diffraction, which is cuspidine (Ca4 Si2 O7F2 ) over I 100 ℃ and calcium silicon oxide fluoride (Ca2SiO2F2) below 1 100℃. When compared with the TTT diagram, the CCT diagram can provide a more realistic estimate of the critical cooling rate of the mold fluxes. Thus, both the CCT and TTT diagrams can unambiguously describe the crystallization phenomena of the mold fluxes.
文摘The corundum plates with a groove were used to freeze molten flux into solid slice to simulate the flux film formed in continuous casting mold,and thereby to study the formation mechanism of flux film with different surface roughness.The effect of some factors on the surface roughness of flux film,such as reheating rate,cooling rate,flux film thickness and crystallization ratio,was discussed.
文摘The corundum plates with a groove were used to freeze molten flux into solid slice to simulate the flux film formed in continuous casting mold, and thereby to study the formation mechanism of flux film with different surface roughness. The effect of some factors on the surface roughness of flux film, such as reheating rate, cooling rate, flux film thickness and crystallization ratio, was discussed.