A novel bovine serum albumin （BSA） imprinted Mn-doped ZnS quantum dots （Mn：ZnS QDs） is firstly reported. The molecular imprinted polymer （MIP） functionalized Mn：ZnS QDs （Mn：ZnS @SiO2@MIP） include the prepar...A novel bovine serum albumin （BSA） imprinted Mn-doped ZnS quantum dots （Mn：ZnS QDs） is firstly reported. The molecular imprinted polymer （MIP） functionalized Mn：ZnS QDs （Mn：ZnS @SiO2@MIP） include the preparation of Mn：ZnS QDs, the coating of silica on the surface of Mn：ZnS QDs, and the functional polymerization by sol-gel reaction using 3-aminophenylboronic acid as the functional and cross-linking monomer in the presence of BSA （Mn：ZnS@SiO2@MIP-BSA）, and then the elution of the imprinted BSA on the surface of Mn：ZnS@SiO2 QDs. The results showed that the phosphorescence of Mn：ZnS@SiO2@MIP is stronger quenched by BSA than that of non-imprinted one （Mn：ZnS@SiO2@NIP）, indicating that the selectivity of the imprinted Mn：ZnS quantum dots toward BSA is superior to that of non-imprinted one.展开更多
A simple one-bath strategy has been developed to synthesize a novel CdTe@SiO_2@MIP（molecularly imprinted and silica-functionalized CdTe quantum dots,MISFQDs）,in which a silica shell was coated on the surface of CdTe...A simple one-bath strategy has been developed to synthesize a novel CdTe@SiO_2@MIP（molecularly imprinted and silica-functionalized CdTe quantum dots,MISFQDs）,in which a silica shell was coated on the surface of CdTe quantum dots （CdTe@SiO_2 QDs） and then a polymer for selective recognition of 4-chlorophenol（4-CP） was constructed on the surface of CdTe@SiO_2 QDs using mercaptoacetic acid as stabilizer,3-aminopropyl-trimethoxysilane（APTES） as functional monomers and tetraethoxysilane（TEOS） as crosslink agent.The structures of CdTe@SiO_2@MIP were analyzed by ultraviolet-visible absorption. Fluorescence,FT-IR spectrum and powder X-ray diffraction.The application and characterization of the CdTe@SiO_2@MIP were investigated by experiments.All results indicated that the CdTe@SiO_2@MIP can selectively recognize 4-chlorophenol.展开更多
基金financial support from the Hubei Science Foundation(No.2010CDA061)
文摘A novel bovine serum albumin （BSA） imprinted Mn-doped ZnS quantum dots （Mn：ZnS QDs） is firstly reported. The molecular imprinted polymer （MIP） functionalized Mn：ZnS QDs （Mn：ZnS @SiO2@MIP） include the preparation of Mn：ZnS QDs, the coating of silica on the surface of Mn：ZnS QDs, and the functional polymerization by sol-gel reaction using 3-aminophenylboronic acid as the functional and cross-linking monomer in the presence of BSA （Mn：ZnS@SiO2@MIP-BSA）, and then the elution of the imprinted BSA on the surface of Mn：ZnS@SiO2 QDs. The results showed that the phosphorescence of Mn：ZnS@SiO2@MIP is stronger quenched by BSA than that of non-imprinted one （Mn：ZnS@SiO2@NIP）, indicating that the selectivity of the imprinted Mn：ZnS quantum dots toward BSA is superior to that of non-imprinted one.
基金the financial support from the Hubei Science Foundation(No.2010CDA061)the Science Foundation of the Education Department of Hubei Province(No.D200922005)
文摘A simple one-bath strategy has been developed to synthesize a novel CdTe@SiO_2@MIP（molecularly imprinted and silica-functionalized CdTe quantum dots,MISFQDs）,in which a silica shell was coated on the surface of CdTe quantum dots （CdTe@SiO_2 QDs） and then a polymer for selective recognition of 4-chlorophenol（4-CP） was constructed on the surface of CdTe@SiO_2 QDs using mercaptoacetic acid as stabilizer,3-aminopropyl-trimethoxysilane（APTES） as functional monomers and tetraethoxysilane（TEOS） as crosslink agent.The structures of CdTe@SiO_2@MIP were analyzed by ultraviolet-visible absorption. Fluorescence,FT-IR spectrum and powder X-ray diffraction.The application and characterization of the CdTe@SiO_2@MIP were investigated by experiments.All results indicated that the CdTe@SiO_2@MIP can selectively recognize 4-chlorophenol.
