Given the rapid urbanization worldwide, Urban Heat Island(UHI) effect has been a severe issue limiting urban sustainability in both large and small cities. In order to study the spatial pattern of Surface urban heat i...Given the rapid urbanization worldwide, Urban Heat Island(UHI) effect has been a severe issue limiting urban sustainability in both large and small cities. In order to study the spatial pattern of Surface urban heat island(SUHI) in China’s Meihekou City, a combination method of Monte Carlo and Random Forest Regression(MC-RFR) is developed to construct the relationship between landscape pattern indices and Land Surface Temperature(LST). In this method, Monte Carlo acceptance-rejection sampling was added to the bootstrap layer of RFR to ensure the sensitivity of RFR to outliners of SUHI effect. The SHUI in 2030 was predicted by using this MC-RFR and the modeled future landscape pattern by Cellular Automata and Markov combination model(CA-Markov). Results reveal that forestland can greatly alleviate the impact of SUHI effect, while reasonable construction of urban land can also slow down the rising trend of SUHI. MC-RFR performs better for characterizing the relationship between landscape pattern and LST than single RFR or Linear Regression model. By 2030, the overall SUHI effect of Meihekou will be greatly enhanced, and the center of urban development will gradually shift to the central and western regions of the city. We suggest that urban designer and managers should concentrate vegetation and disperse built-up land to weaken the SUHI in the construction of new urban areas for its sustainability.展开更多
A random walk Monte Carlo (RWMC) simulation model of catalytic particle was established on the basis of the structures of bismuth molybdate catalysts and mechanisms of catalytic reactions with propylene selective ox...A random walk Monte Carlo (RWMC) simulation model of catalytic particle was established on the basis of the structures of bismuth molybdate catalysts and mechanisms of catalytic reactions with propylene selective oxidation and ammoxidation. The simulation results show that rationality of the RWMC model is proved on the basis of pulse experimental data. One of the most remarkable factors affecting catalytic behavior is the transfer of bulk lattice oxygen, which decides the rate of ammonia-consuming and propylene-consuming. The selectivity of main products reaches the maximum after the reduction of catalysts to a certain degree. It is inferred that catalytic performance improves greatly if the ratio of capacity for dehydrogenation from adsorbed propylene molecule on catalytically active site of molybdenum metal-imido group (Mo=NH) to that on catalytically active site of molybdenum metal-oxo group (Mo=O) becomes much higher.展开更多
In this paper, an importance sampling maximum likelihood(ISML) estimator for direction-of-arrival(DOA) of incoherently distributed(ID) sources is proposed. Starting from the maximum likelihood estimation description o...In this paper, an importance sampling maximum likelihood(ISML) estimator for direction-of-arrival(DOA) of incoherently distributed(ID) sources is proposed. Starting from the maximum likelihood estimation description of the uniform linear array(ULA), a decoupled concentrated likelihood function(CLF) is presented. A new objective function based on CLF which can obtain a closed-form solution of global maximum is constructed according to Pincus theorem. To obtain the optimal value of the objective function which is a complex high-dimensional integral,we propose an importance sampling approach based on Monte Carlo random calculation. Next, an importance function is derived, which can simplify the problem of generating random vector from a high-dimensional probability density function(PDF) to generate random variable from a one-dimensional PDF. Compared with the existing maximum likelihood(ML) algorithms for DOA estimation of ID sources, the proposed algorithm does not require initial estimates, and its performance is closer to CramerRao lower bound(CRLB). The proposed algorithm performs better than the existing methods when the interval between sources to be estimated is small and in low signal to noise ratio(SNR)scenarios.展开更多
基金Under the auspices of National Natural Science Foundation of China(No.41977411,41771383)Technology Research Project of the Education Department of Jilin Province(No.JJKH20210445KJ)。
文摘Given the rapid urbanization worldwide, Urban Heat Island(UHI) effect has been a severe issue limiting urban sustainability in both large and small cities. In order to study the spatial pattern of Surface urban heat island(SUHI) in China’s Meihekou City, a combination method of Monte Carlo and Random Forest Regression(MC-RFR) is developed to construct the relationship between landscape pattern indices and Land Surface Temperature(LST). In this method, Monte Carlo acceptance-rejection sampling was added to the bootstrap layer of RFR to ensure the sensitivity of RFR to outliners of SUHI effect. The SHUI in 2030 was predicted by using this MC-RFR and the modeled future landscape pattern by Cellular Automata and Markov combination model(CA-Markov). Results reveal that forestland can greatly alleviate the impact of SUHI effect, while reasonable construction of urban land can also slow down the rising trend of SUHI. MC-RFR performs better for characterizing the relationship between landscape pattern and LST than single RFR or Linear Regression model. By 2030, the overall SUHI effect of Meihekou will be greatly enhanced, and the center of urban development will gradually shift to the central and western regions of the city. We suggest that urban designer and managers should concentrate vegetation and disperse built-up land to weaken the SUHI in the construction of new urban areas for its sustainability.
基金国家自然科学基金,the Fundamental Research Foundation of SINOPEC
文摘A random walk Monte Carlo (RWMC) simulation model of catalytic particle was established on the basis of the structures of bismuth molybdate catalysts and mechanisms of catalytic reactions with propylene selective oxidation and ammoxidation. The simulation results show that rationality of the RWMC model is proved on the basis of pulse experimental data. One of the most remarkable factors affecting catalytic behavior is the transfer of bulk lattice oxygen, which decides the rate of ammonia-consuming and propylene-consuming. The selectivity of main products reaches the maximum after the reduction of catalysts to a certain degree. It is inferred that catalytic performance improves greatly if the ratio of capacity for dehydrogenation from adsorbed propylene molecule on catalytically active site of molybdenum metal-imido group (Mo=NH) to that on catalytically active site of molybdenum metal-oxo group (Mo=O) becomes much higher.
基金supported by the basic research program of Natural Science in Shannxi province of China (2021JQ-369)。
文摘In this paper, an importance sampling maximum likelihood(ISML) estimator for direction-of-arrival(DOA) of incoherently distributed(ID) sources is proposed. Starting from the maximum likelihood estimation description of the uniform linear array(ULA), a decoupled concentrated likelihood function(CLF) is presented. A new objective function based on CLF which can obtain a closed-form solution of global maximum is constructed according to Pincus theorem. To obtain the optimal value of the objective function which is a complex high-dimensional integral,we propose an importance sampling approach based on Monte Carlo random calculation. Next, an importance function is derived, which can simplify the problem of generating random vector from a high-dimensional probability density function(PDF) to generate random variable from a one-dimensional PDF. Compared with the existing maximum likelihood(ML) algorithms for DOA estimation of ID sources, the proposed algorithm does not require initial estimates, and its performance is closer to CramerRao lower bound(CRLB). The proposed algorithm performs better than the existing methods when the interval between sources to be estimated is small and in low signal to noise ratio(SNR)scenarios.