为充分运用互联网技术培养大学生的创新能力,在对"慕课"MOOC(Massive Open Online Courses)网络教学理念的研究基础上,通过对网络学习模式进行更广泛的探索,提出"慕斯"(Mobile Open Online School,即移动在线开放校...为充分运用互联网技术培养大学生的创新能力,在对"慕课"MOOC(Massive Open Online Courses)网络教学理念的研究基础上,通过对网络学习模式进行更广泛的探索,提出"慕斯"(Mobile Open Online School,即移动在线开放校园,简称MOOS)网络教学新理念,突破单一的课程学习模式,实现网络学习的横向拓展,构建以现代大学生需求为驱动的网络学习生态系统。该文探讨基于MOOS理念构建药学网络学习平台,以期提高药学生的创新思维与能力。展开更多
Plasmonic nonmetal semiconductors with localized surface plasmon resonance(LSPR)effects possess extended light-response ranges and can act as highly efficient H2 generation photocatalysts.Herein,an LSPR-enhanced 0D/2D...Plasmonic nonmetal semiconductors with localized surface plasmon resonance(LSPR)effects possess extended light-response ranges and can act as highly efficient H2 generation photocatalysts.Herein,an LSPR-enhanced 0D/2D CdS/MoO3‒x heterojunction has been synthesized by the growth of 0D CdS nanoparticles on 2D plasmonic MoO3‒x elliptical nanosheets via a simple coprecipitation method.Taking advantage of the LSPR effect of the MoO3‒x elliptical nanosheets,the light absorption of the CdS/MoO3‒x heterojunction was extended from 600 nm to the near-infrared region(1400 nm).Furthermore,the introduction of 2D plasmonic MoO3‒x elliptical nanosheets not only provided a platform for the growth of CdS nanoparticles,but also contributed to the construction of an LSPR-enhanced S-scheme structure due to the interface between the MoO3‒x and CdS,accelerating the separation of light-induced electrons and holes.Therefore,the CdS/MoO3‒x heterojunction exhibited higher photocatalytic H2 generation activity than pristine CdS under visible light irradiation,including under 420,450,550,and 650 nm monochromic light,as well as improved photo-corrosion performance.展开更多
Constructing Z-scheme heterojunction to improve the separation efficiency of photogenerated carriers of photocatalysts has gained extensive attention.In this work,we fabricated a novel Z-scheme MoO3/Bi2O4 heterojuncti...Constructing Z-scheme heterojunction to improve the separation efficiency of photogenerated carriers of photocatalysts has gained extensive attention.In this work,we fabricated a novel Z-scheme MoO3/Bi2O4 heterojunction photocatalyst by a hydrothermal method.XPS analysis results indicated that strong interaction between MoO3 and Bi2O4 is generated,which contributes to charge transfer and separation of the photogenerated carriers.This was confirmed by photoluminescence(PL)and electrochemical impedance spectroscopy(EIS)tests.The photocatalytic performance of the as-synthesized photocatalysts was evaluated by degrading rhodamine B(RhB)in aqueous solution under visible light irradiation,showing that 15%MoO3/Bi2O4(15-MB)composite exhibited the highest photocatalytic activity,which is 2 times higher than that of Bi2O4.Besides,the heterojunction photocatalyst can keep good photocatalytic activity and stability after five recycles.Trapping experiments demonstrated that the dominant active radicals in photocatalytic reactions are superoxide radical( O2-)and holes(h+),indicating that the 15-MB composite is a Z-scheme photocatalyst.Finally,the mechanism of the Z-scheme MoO3/Bi2O4 composite for photo-degrading RhB in aqueous solution is proposed.This work provides a promising strategy for designing Bi-based Z-scheme heterojunction photocatalysts for highly efficient removal of environmental pollutants.展开更多
The surface plasmonic resonance(SPR)effect of Bi can effectively improve the light absorption abilities and photogenerated charge carrier separation rate.In this study,a novel ternary heterojunction of g-C3N4/Bi2MoO6/...The surface plasmonic resonance(SPR)effect of Bi can effectively improve the light absorption abilities and photogenerated charge carrier separation rate.In this study,a novel ternary heterojunction of g-C3N4/Bi2MoO6/Bi(CN/BMO/Bi)hollow microsphere was successfully fabricated through solvothermal and in situ reduction methods.The results revealed that the optimal ternary 0.4 CN/BMO/9 Bi photocatalyst exhibited the highest photocatalytic efficiency toward rhodamine B(RhB)degradation with nine times that of pure BMO.The DRS and valence band of the X-ray photoelectron spectroscopy spectrum demonstrate that the band structure of 0.4 CN/BMO/9 Bi is a z-scheme structure.Quenching experiments also provided solid evidence that the·O^2-(at-0.33 eV)is the main species during dye degradation,and the conduction band of g-C3N4 is only the reaction site,demonstrating that the transfer of photogenerated charge carriers of g-C3N4/Bi2 MoO 6/Bi is through an indirect z-scheme structure.Thus,the enhanced photocatalytic performance was mainly ascribed to the synergetic effect of heterojunction structures between g-C3N4 and Bi2MoO6 and the SPR effect of Bi doping,resulting in better optical absorption ability and a lower combination rate of photogenerated charge carriers.The findings in this work provide insight into the synergism of heterostructures and the SPR absorption ability in wastewater treatment.展开更多
Reducing CO_(2) to hydrocarbon fuels by solar irradiation provides a feasible channel for mitigating excessive CO_(2) emissions and addressing resource depletion.Nevertheless,severe charge recombi‐nation and the high...Reducing CO_(2) to hydrocarbon fuels by solar irradiation provides a feasible channel for mitigating excessive CO_(2) emissions and addressing resource depletion.Nevertheless,severe charge recombi‐nation and the high energy barrier for CO_(2) photoreduction on the surface of photocatalysts com‐promise the catalytic performance.Herein,a 2D/2D Bi_(2)MoO_(6)/BiOI composite was fabricated to achieve improved CO_(2) photoreduction efficiency.Charge transfer in the composite was facilitated by the van der Waals heterojunction with a large‐area interface.Work function calculation demon‐strated that S‐scheme charge transfer is operative in the composite,and effective charge separation and strong redox capability were revealed by time‐resolved photoluminescence and electron para‐magnetic resonance spectroscopy.Moreover,the intermediates of CO_(2) photoreduction were identi‐fied based on the in situ diffuse reflectance infrared Fourier‐transform spectra.Density functional theory calculations showed that CO_(2) hydrogenation is the rate‐determining step for yielding CH_(4) and CO.Introducing Bi_(2)MoO_(6) into the composite further decreased the energy barrier for CO_(2) photoreduction on BiOI by 0.35 eV.This study verifies the synergistic effect of the S‐scheme heterojunction and van der Waals heterojunction in the 2D/2D composite.展开更多
Referring to the construction way of Lax-Wendroff scheme, new IRS (Implicit Residual Smoothing) schemes have been developed for hyperbolic, parabolic and hyperparabolic equations. These IRS schemes have 2nd-order or 3...Referring to the construction way of Lax-Wendroff scheme, new IRS (Implicit Residual Smoothing) schemes have been developed for hyperbolic, parabolic and hyperparabolic equations. These IRS schemes have 2nd-order or 3 rd-order time accuracy, and can extend the stability region of basic explicit time-stepping scheme greatly and thus can permit higher CFL number in the calculation of flow field. The, central smoothing and upwind-bias smoothing techniques have been developed tao. Based on one-dimensional linear model equation, it has been found that the scheme is unconditionally stable according to the von-Neumann analysis. The limitation of Dawes' method, which has been applied in turbomachinery widespreadly, has been discussed on solving steady flow and viscous flow. It is shown that stable solution of this method is not completely independent with the value of time step. In the end, numerical results by using IRS schemes and Dawes' method as well as TVD ( total variation diminishing) scheme and four-stage Runge-Kutta technique are presented to verify, the analytical conclusions.展开更多
Based on the traditional fifth-order weighted essentially non-oscillatory(WENO)scheme,a smoothness indicator is introduced to improve the capability of WENO schemes for resolving short waves.In the construction of the...Based on the traditional fifth-order weighted essentially non-oscillatory(WENO)scheme,a smoothness indicator is introduced to improve the capability of WENO schemes for resolving short waves.In the construction of the new smoothness indicator,the proportion of the first-order term in the original smoothness indicator is reduced by replacing the square of the first-order term with the product of the first-order and the third-order terms.To preserve the fifth-order of convergence rate,the smoothness indicator is combined with the method of Borges,et al.The numerical results show that the proposed schemes are more suitable for simulating turbulent flows or aeroacoustics problems than the previous fifth-order WENO schemes,thanks to its improved resolution on short waves.展开更多
In this paper, using nonuniform mesh and exponentially fitted difference method, a uniformly convergent difference scheme for an initial-boundary value problem of linear parabolic differential equation with the nonsmo...In this paper, using nonuniform mesh and exponentially fitted difference method, a uniformly convergent difference scheme for an initial-boundary value problem of linear parabolic differential equation with the nonsmooth boundary layer function with respect to small parameter e is given, and error estimate and numerical result are also given.展开更多
This work aimed to construct an epidemic model with fuzzy parameters.Since the classical epidemic model doesnot elaborate on the successful interaction of susceptible and infective people,the constructed fuzzy epidemi...This work aimed to construct an epidemic model with fuzzy parameters.Since the classical epidemic model doesnot elaborate on the successful interaction of susceptible and infective people,the constructed fuzzy epidemicmodel discusses the more detailed versions of the interactions between infective and susceptible people.Thenext-generation matrix approach is employed to find the reproduction number of a deterministic model.Thesensitivity analysis and local stability analysis of the systemare also provided.For solving the fuzzy epidemic model,a numerical scheme is constructed which consists of three time levels.The numerical scheme has an advantage overthe existing forward Euler scheme for determining the conditions of getting the positive solution.The establishedscheme also has an advantage over existing non-standard finite difference methods in terms of order of accuracy.The stability of the scheme for the considered fuzzy model is also provided.From the plotted results,it can beobserved that susceptible people decay by rising interaction parameters.展开更多
Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do ...Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do not involve any special data structure,and do not induce savings in memory requirements,they are easily implemented on existing codes and are recommended for 1D and 2D simulations when intensive testing is required.The multilevel technique can also be applied to balance laws,but in this case,numerical errors may be induced by the technique.We present a series of numerical tests that point out that the use of monotonicity-preserving interpolatory techniques eliminates the numerical errors observed when using the usual 4-point centered Lagrange interpolation,and leads to a more robust multilevel code for balance laws,while maintaining the efficiency rates observed forhyperbolic conservation laws.展开更多
We present a class of arbitrarily high order fully explicit kinetic numerical methods in compressible fluid dynamics,both in time and space,which include the relaxation schemes by Jin and Xin.These methods can use the...We present a class of arbitrarily high order fully explicit kinetic numerical methods in compressible fluid dynamics,both in time and space,which include the relaxation schemes by Jin and Xin.These methods can use the CFL number larger or equal to unity on regular Cartesian meshes for the multi-dimensional case.These kinetic models depend on a small parameter that can be seen as a"Knudsen"number.The method is asymptotic preserving in this Knudsen number.Also,the computational costs of the method are of the same order of a fully explicit scheme.This work is the extension of Abgrall et al.(2022)[3]to multidimensional systems.We have assessed our method on several problems for two-dimensional scalar problems and Euler equations and the scheme has proven to be robust and to achieve the theoretically predicted high order of accuracy on smooth solutions.展开更多
The rapid development of the global economy has led to the over-exploitation and burning of fossil fuels,causing a severe energy crisis and continuous CO_(2) emissions.Although solar energy is a clean and renewable re...The rapid development of the global economy has led to the over-exploitation and burning of fossil fuels,causing a severe energy crisis and continuous CO_(2) emissions.Although solar energy is a clean and renewable resource,it faces significant diurnal and seasonal variations and is difficult to store[1-4].Converting solar energy into storable chemical energy through photocatalysis is an effective way to address both energy scarcity and environmental issues.Photocatalytic CO_(2) reduction,with the development of high-efficiency photocatalysts as the key,offers a clean and environmentally friendly method to convert CO_(2) into valuable hydrocarbon fuels,providing a viable solution to the global energy crisis and climate change[5,6].展开更多
文摘为充分运用互联网技术培养大学生的创新能力,在对"慕课"MOOC(Massive Open Online Courses)网络教学理念的研究基础上,通过对网络学习模式进行更广泛的探索,提出"慕斯"(Mobile Open Online School,即移动在线开放校园,简称MOOS)网络教学新理念,突破单一的课程学习模式,实现网络学习的横向拓展,构建以现代大学生需求为驱动的网络学习生态系统。该文探讨基于MOOS理念构建药学网络学习平台,以期提高药学生的创新思维与能力。
文摘Plasmonic nonmetal semiconductors with localized surface plasmon resonance(LSPR)effects possess extended light-response ranges and can act as highly efficient H2 generation photocatalysts.Herein,an LSPR-enhanced 0D/2D CdS/MoO3‒x heterojunction has been synthesized by the growth of 0D CdS nanoparticles on 2D plasmonic MoO3‒x elliptical nanosheets via a simple coprecipitation method.Taking advantage of the LSPR effect of the MoO3‒x elliptical nanosheets,the light absorption of the CdS/MoO3‒x heterojunction was extended from 600 nm to the near-infrared region(1400 nm).Furthermore,the introduction of 2D plasmonic MoO3‒x elliptical nanosheets not only provided a platform for the growth of CdS nanoparticles,but also contributed to the construction of an LSPR-enhanced S-scheme structure due to the interface between the MoO3‒x and CdS,accelerating the separation of light-induced electrons and holes.Therefore,the CdS/MoO3‒x heterojunction exhibited higher photocatalytic H2 generation activity than pristine CdS under visible light irradiation,including under 420,450,550,and 650 nm monochromic light,as well as improved photo-corrosion performance.
基金supported by the Natural Science Foundation of Hubei Province(2016CFA078)the National Natural Science Foundation of China(51472194)~~
文摘Constructing Z-scheme heterojunction to improve the separation efficiency of photogenerated carriers of photocatalysts has gained extensive attention.In this work,we fabricated a novel Z-scheme MoO3/Bi2O4 heterojunction photocatalyst by a hydrothermal method.XPS analysis results indicated that strong interaction between MoO3 and Bi2O4 is generated,which contributes to charge transfer and separation of the photogenerated carriers.This was confirmed by photoluminescence(PL)and electrochemical impedance spectroscopy(EIS)tests.The photocatalytic performance of the as-synthesized photocatalysts was evaluated by degrading rhodamine B(RhB)in aqueous solution under visible light irradiation,showing that 15%MoO3/Bi2O4(15-MB)composite exhibited the highest photocatalytic activity,which is 2 times higher than that of Bi2O4.Besides,the heterojunction photocatalyst can keep good photocatalytic activity and stability after five recycles.Trapping experiments demonstrated that the dominant active radicals in photocatalytic reactions are superoxide radical( O2-)and holes(h+),indicating that the 15-MB composite is a Z-scheme photocatalyst.Finally,the mechanism of the Z-scheme MoO3/Bi2O4 composite for photo-degrading RhB in aqueous solution is proposed.This work provides a promising strategy for designing Bi-based Z-scheme heterojunction photocatalysts for highly efficient removal of environmental pollutants.
基金financially supported by the Science Foundation of China University of Petroleum,Beijing(2462017YJRC048,2462018BJC005)the National Natural Science Foundation of China(51802351)~~
文摘The surface plasmonic resonance(SPR)effect of Bi can effectively improve the light absorption abilities and photogenerated charge carrier separation rate.In this study,a novel ternary heterojunction of g-C3N4/Bi2MoO6/Bi(CN/BMO/Bi)hollow microsphere was successfully fabricated through solvothermal and in situ reduction methods.The results revealed that the optimal ternary 0.4 CN/BMO/9 Bi photocatalyst exhibited the highest photocatalytic efficiency toward rhodamine B(RhB)degradation with nine times that of pure BMO.The DRS and valence band of the X-ray photoelectron spectroscopy spectrum demonstrate that the band structure of 0.4 CN/BMO/9 Bi is a z-scheme structure.Quenching experiments also provided solid evidence that the·O^2-(at-0.33 eV)is the main species during dye degradation,and the conduction band of g-C3N4 is only the reaction site,demonstrating that the transfer of photogenerated charge carriers of g-C3N4/Bi2 MoO 6/Bi is through an indirect z-scheme structure.Thus,the enhanced photocatalytic performance was mainly ascribed to the synergetic effect of heterojunction structures between g-C3N4 and Bi2MoO6 and the SPR effect of Bi doping,resulting in better optical absorption ability and a lower combination rate of photogenerated charge carriers.The findings in this work provide insight into the synergism of heterostructures and the SPR absorption ability in wastewater treatment.
文摘Reducing CO_(2) to hydrocarbon fuels by solar irradiation provides a feasible channel for mitigating excessive CO_(2) emissions and addressing resource depletion.Nevertheless,severe charge recombi‐nation and the high energy barrier for CO_(2) photoreduction on the surface of photocatalysts com‐promise the catalytic performance.Herein,a 2D/2D Bi_(2)MoO_(6)/BiOI composite was fabricated to achieve improved CO_(2) photoreduction efficiency.Charge transfer in the composite was facilitated by the van der Waals heterojunction with a large‐area interface.Work function calculation demon‐strated that S‐scheme charge transfer is operative in the composite,and effective charge separation and strong redox capability were revealed by time‐resolved photoluminescence and electron para‐magnetic resonance spectroscopy.Moreover,the intermediates of CO_(2) photoreduction were identi‐fied based on the in situ diffuse reflectance infrared Fourier‐transform spectra.Density functional theory calculations showed that CO_(2) hydrogenation is the rate‐determining step for yielding CH_(4) and CO.Introducing Bi_(2)MoO_(6) into the composite further decreased the energy barrier for CO_(2) photoreduction on BiOI by 0.35 eV.This study verifies the synergistic effect of the S‐scheme heterojunction and van der Waals heterojunction in the 2D/2D composite.
文摘Referring to the construction way of Lax-Wendroff scheme, new IRS (Implicit Residual Smoothing) schemes have been developed for hyperbolic, parabolic and hyperparabolic equations. These IRS schemes have 2nd-order or 3 rd-order time accuracy, and can extend the stability region of basic explicit time-stepping scheme greatly and thus can permit higher CFL number in the calculation of flow field. The, central smoothing and upwind-bias smoothing techniques have been developed tao. Based on one-dimensional linear model equation, it has been found that the scheme is unconditionally stable according to the von-Neumann analysis. The limitation of Dawes' method, which has been applied in turbomachinery widespreadly, has been discussed on solving steady flow and viscous flow. It is shown that stable solution of this method is not completely independent with the value of time step. In the end, numerical results by using IRS schemes and Dawes' method as well as TVD ( total variation diminishing) scheme and four-stage Runge-Kutta technique are presented to verify, the analytical conclusions.
基金Supported by the National Natural Science Foundation of China(50830201,11102179)the Nanjing University of Aeronautics and Astronautics Research Funding(NP 2011033)
文摘Based on the traditional fifth-order weighted essentially non-oscillatory(WENO)scheme,a smoothness indicator is introduced to improve the capability of WENO schemes for resolving short waves.In the construction of the new smoothness indicator,the proportion of the first-order term in the original smoothness indicator is reduced by replacing the square of the first-order term with the product of the first-order and the third-order terms.To preserve the fifth-order of convergence rate,the smoothness indicator is combined with the method of Borges,et al.The numerical results show that the proposed schemes are more suitable for simulating turbulent flows or aeroacoustics problems than the previous fifth-order WENO schemes,thanks to its improved resolution on short waves.
文摘In this paper, using nonuniform mesh and exponentially fitted difference method, a uniformly convergent difference scheme for an initial-boundary value problem of linear parabolic differential equation with the nonsmooth boundary layer function with respect to small parameter e is given, and error estimate and numerical result are also given.
基金the support of Prince Sultan University for paying the article processing charges(APC)of this publication.
文摘This work aimed to construct an epidemic model with fuzzy parameters.Since the classical epidemic model doesnot elaborate on the successful interaction of susceptible and infective people,the constructed fuzzy epidemicmodel discusses the more detailed versions of the interactions between infective and susceptible people.Thenext-generation matrix approach is employed to find the reproduction number of a deterministic model.Thesensitivity analysis and local stability analysis of the systemare also provided.For solving the fuzzy epidemic model,a numerical scheme is constructed which consists of three time levels.The numerical scheme has an advantage overthe existing forward Euler scheme for determining the conditions of getting the positive solution.The establishedscheme also has an advantage over existing non-standard finite difference methods in terms of order of accuracy.The stability of the scheme for the considered fuzzy model is also provided.From the plotted results,it can beobserved that susceptible people decay by rising interaction parameters.
基金supported by Grant PID2020-117211GB-I00funded by MCIN/AEI/10.13039/501100011033+4 种基金by Grant CIAICO/2021/227funded by the Generalitat Valencianasupported by the Ministerio de Ciencia e Innovacion of Spain(Grant Ref.PID2021-125709OB-C21)funded by MCIN/AEI/10.13039/501100011033/FEDER,UEby the Generalitat Valenciana(CIAICO/2021/224).
文摘Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do not involve any special data structure,and do not induce savings in memory requirements,they are easily implemented on existing codes and are recommended for 1D and 2D simulations when intensive testing is required.The multilevel technique can also be applied to balance laws,but in this case,numerical errors may be induced by the technique.We present a series of numerical tests that point out that the use of monotonicity-preserving interpolatory techniques eliminates the numerical errors observed when using the usual 4-point centered Lagrange interpolation,and leads to a more robust multilevel code for balance laws,while maintaining the efficiency rates observed forhyperbolic conservation laws.
基金funded by the SNF project 200020_204917 entitled"Structure preserving and fast methods for hyperbolic systems of conservation laws".
文摘We present a class of arbitrarily high order fully explicit kinetic numerical methods in compressible fluid dynamics,both in time and space,which include the relaxation schemes by Jin and Xin.These methods can use the CFL number larger or equal to unity on regular Cartesian meshes for the multi-dimensional case.These kinetic models depend on a small parameter that can be seen as a"Knudsen"number.The method is asymptotic preserving in this Knudsen number.Also,the computational costs of the method are of the same order of a fully explicit scheme.This work is the extension of Abgrall et al.(2022)[3]to multidimensional systems.We have assessed our method on several problems for two-dimensional scalar problems and Euler equations and the scheme has proven to be robust and to achieve the theoretically predicted high order of accuracy on smooth solutions.
文摘The rapid development of the global economy has led to the over-exploitation and burning of fossil fuels,causing a severe energy crisis and continuous CO_(2) emissions.Although solar energy is a clean and renewable resource,it faces significant diurnal and seasonal variations and is difficult to store[1-4].Converting solar energy into storable chemical energy through photocatalysis is an effective way to address both energy scarcity and environmental issues.Photocatalytic CO_(2) reduction,with the development of high-efficiency photocatalysts as the key,offers a clean and environmentally friendly method to convert CO_(2) into valuable hydrocarbon fuels,providing a viable solution to the global energy crisis and climate change[5,6].
