The mean hyper fine field at the Fe nuclei in amorphous alloys Fe80-xTxB20(T=Co,Ni,Mn,V,Ti) by fitting the Moessbauer spectra is displayed. The behaviors of both the hyperfine field and the atomic magnetic moment in t...The mean hyper fine field at the Fe nuclei in amorphous alloys Fe80-xTxB20(T=Co,Ni,Mn,V,Ti) by fitting the Moessbauer spectra is displayed. The behaviors of both the hyperfine field and the atomic magnetic moment in these amorphous alloys and the relation between both the properties are discussed.展开更多
Magnetic anisotropies and hyperfine fields of amorphous a-Fe-(Co, Cr)-Zr alloys, their temperature and thermal stress effects were studied by using a Mossbauer spectroscopy. The results are in the following: A tensile...Magnetic anisotropies and hyperfine fields of amorphous a-Fe-(Co, Cr)-Zr alloys, their temperature and thermal stress effects were studied by using a Mossbauer spectroscopy. The results are in the following: A tensile stress field is easily created during the material production process, having the plane anisotropy to be increased for the alloys containing strong ferromagnetic coupling such as Fe-Co and Fe-Ni; a pressure stress field is easily produced, making the perpendicular anisotropy increase for the alloys containing antiferromagnetic coupling such as Fe-Cr and Fe-Mn. Introducing the new idea of attractive and repulsive forces, the fact was explained well that the dependence of anisotropies on the average outer electron concentration of 3d transition metal is similar to that of the average hyperfine field.展开更多
Magnetic anisotropies of the amorphous alloy Fe_(71)Ni_(10)B_(13)Si_(14)C_2 annealed in magnetic field have been studied using Mossbauer spectroscopy and X-ray diffraction.It is shown that the distribution of moments ...Magnetic anisotropies of the amorphous alloy Fe_(71)Ni_(10)B_(13)Si_(14)C_2 annealed in magnetic field have been studied using Mossbauer spectroscopy and X-ray diffraction.It is shown that the distribution of moments in the annealed sample are determined by both stress-produced and thermomagnetic treatment-induced magnetic anisotropies.展开更多
A series of M-Type barium hexaferrites with the general composition BaFe12-2xMoxZnxO19 were synthesized at 1100°C by a simple wet chemical mixture route. The properties of the prepared samples were examined by...A series of M-Type barium hexaferrites with the general composition BaFe12-2xMoxZnxO19 were synthesized at 1100°C by a simple wet chemical mixture route. The properties of the prepared samples were examined by X-ray diffraction, scanning electron microscopy, vibrating sample magnetometry, and Mössbauer spectroscopy. The diffraction patterns for all samples were found to agree well with the standard pattern of BaFe12O19 hexaferrite with no extraneous diffraction peaks. The products formed as well crystallized hexagonal platelet-like particles while the EDS measurements revealed the stoichiometric cationic ratios of the prepared samples. The spectral variations elucidated by Mössbauer spectroscopy were utilized to determine the different cation preferential site occupations as a function of x. Finally, the saturation magnetizations, magnetic anisotropies, and the anisotropy fields, determined from the magnetic measurements, showed consistency with the relative subspectral Mössbauer intensities and the single ion model for the anisotropy constant.展开更多
The mixed spinel ferrite system Mg0.95Mn0.05Fe2-2xTizxO4 （0 ≤x ≤ 0.7） was synthesized by the conventional solid-state reaction technique. The effect of Ti^4＋ doping was studied by using the Moessbauer spectroscop...The mixed spinel ferrite system Mg0.95Mn0.05Fe2-2xTizxO4 （0 ≤x ≤ 0.7） was synthesized by the conventional solid-state reaction technique. The effect of Ti^4＋ doping was studied by using the Moessbauer spectroscopy measurements at room temperature. From the analysis of the Moessbauer spectra, it is observed that s-electron density, electric field gradient （EFG）, quadrupole coupling constant （QCC） and the net hyperfine magnetic fields acting on the Moessbauer nuclei-FeA^3＋ and FeB^3＋ change with the increase of Ti^4＋ doping in Mg0.95Mn0.05Fe2O4. The hyperfine magnetic field decreases with the increase of Ti^4＋ doping.展开更多
Ⅰ. EXPERIMENT9Crl8 ball-bearing stainless steel has the following composition:C, 1 wt%; Cr, 18 wt%; Mn, 0.1 wt%; Si, 0.8 wt%; S, 0.03 wt%; P, 0.03 wt%, besides Fe. Its abilities of antichemical erosion and antielectr...Ⅰ. EXPERIMENT9Crl8 ball-bearing stainless steel has the following composition:C, 1 wt%; Cr, 18 wt%; Mn, 0.1 wt%; Si, 0.8 wt%; S, 0.03 wt%; P, 0.03 wt%, besides Fe. Its abilities of antichemical erosion and antielectrical-chemical erosion are due to the high content of Cr in it. In order to obtain high hardness and high wear resistance, higher content of C is included. Si is in展开更多
文摘The mean hyper fine field at the Fe nuclei in amorphous alloys Fe80-xTxB20(T=Co,Ni,Mn,V,Ti) by fitting the Moessbauer spectra is displayed. The behaviors of both the hyperfine field and the atomic magnetic moment in these amorphous alloys and the relation between both the properties are discussed.
文摘Magnetic anisotropies and hyperfine fields of amorphous a-Fe-(Co, Cr)-Zr alloys, their temperature and thermal stress effects were studied by using a Mossbauer spectroscopy. The results are in the following: A tensile stress field is easily created during the material production process, having the plane anisotropy to be increased for the alloys containing strong ferromagnetic coupling such as Fe-Co and Fe-Ni; a pressure stress field is easily produced, making the perpendicular anisotropy increase for the alloys containing antiferromagnetic coupling such as Fe-Cr and Fe-Mn. Introducing the new idea of attractive and repulsive forces, the fact was explained well that the dependence of anisotropies on the average outer electron concentration of 3d transition metal is similar to that of the average hyperfine field.
文摘Magnetic anisotropies of the amorphous alloy Fe_(71)Ni_(10)B_(13)Si_(14)C_2 annealed in magnetic field have been studied using Mossbauer spectroscopy and X-ray diffraction.It is shown that the distribution of moments in the annealed sample are determined by both stress-produced and thermomagnetic treatment-induced magnetic anisotropies.
基金supported by a generous grant from the Deanship of Scientific research at the University of Jordan under contract number 1404
文摘A series of M-Type barium hexaferrites with the general composition BaFe12-2xMoxZnxO19 were synthesized at 1100°C by a simple wet chemical mixture route. The properties of the prepared samples were examined by X-ray diffraction, scanning electron microscopy, vibrating sample magnetometry, and Mössbauer spectroscopy. The diffraction patterns for all samples were found to agree well with the standard pattern of BaFe12O19 hexaferrite with no extraneous diffraction peaks. The products formed as well crystallized hexagonal platelet-like particles while the EDS measurements revealed the stoichiometric cationic ratios of the prepared samples. The spectral variations elucidated by Mössbauer spectroscopy were utilized to determine the different cation preferential site occupations as a function of x. Finally, the saturation magnetizations, magnetic anisotropies, and the anisotropy fields, determined from the magnetic measurements, showed consistency with the relative subspectral Mössbauer intensities and the single ion model for the anisotropy constant.
基金Project supported by the Second Stage of Brain Korea 21 ProjectProject(RTI04-01-03) supported by the Regional Technology Innovation Program of the Ministry of Knowledge Economy (MKE),Korea
文摘The mixed spinel ferrite system Mg0.95Mn0.05Fe2-2xTizxO4 （0 ≤x ≤ 0.7） was synthesized by the conventional solid-state reaction technique. The effect of Ti^4＋ doping was studied by using the Moessbauer spectroscopy measurements at room temperature. From the analysis of the Moessbauer spectra, it is observed that s-electron density, electric field gradient （EFG）, quadrupole coupling constant （QCC） and the net hyperfine magnetic fields acting on the Moessbauer nuclei-FeA^3＋ and FeB^3＋ change with the increase of Ti^4＋ doping in Mg0.95Mn0.05Fe2O4. The hyperfine magnetic field decreases with the increase of Ti^4＋ doping.
基金Project supported by the National Natural Science Foundation of China
文摘Ⅰ. EXPERIMENT9Crl8 ball-bearing stainless steel has the following composition:C, 1 wt%; Cr, 18 wt%; Mn, 0.1 wt%; Si, 0.8 wt%; S, 0.03 wt%; P, 0.03 wt%, besides Fe. Its abilities of antichemical erosion and antielectrical-chemical erosion are due to the high content of Cr in it. In order to obtain high hardness and high wear resistance, higher content of C is included. Si is in
