Criteria for an advanced assessment of quality of moulding sands with organic binders and reclamation process products

Reclamation of used moulding and core sands has been defined as a treatment of waste moulding refractory materials, enabling a recovery of at least one of the components having properties similar to those of the fresh component, and reuse for production of casting moulds and cores. However, at present, there is a lack of a reclaimed material assessment index, which could be applied to each type of moulding sand and reclaim. Modern investigation methods and equipment for the estimation of the quality of the moulding sands matrices with organic binders, in their circulation process, are presented in this paper. These methods, utilizing the special equipment combined with the author's investigation methods developed in the Faculty of Foundry Engineering, AGH - University of Science and Technology, allow the better estimation of the matrix quality both in an aspect of its application as a fresh sand substitute in the preparation of moulding sands, and also with regard to the environmental protection. The most important criteria for the technological assessment of the reclaimed materials and the quality of sands with organic binders are presented in this paper.

Influence of wet activation of used inorganic binder on cyclically refreshed water glass moulding sands hardened by microwaves

The paper presents the research results of using an innovative method to reclaim the waste moulding sands containing water glass. Two of the examined processes are connected with "dry" or "wet" activation of inorganic binder in waste moulding sand mixtures physically hardened by microwave radiation. The sand mixtures consisting of high-silica sand and water-glass with average molar module 2.5, were subjected to the following cyclical process: mixing the components, compacting, microwave heating, cooling-down, thermally loading the mould to 800 °C, cooling-down to ambient temperature, and knocking-out. After being knocked-out, the waste moulding sands were subjected to either dry or wet activation of the binder. To activate thermally treated inorganic binder, each of the examined processes employed the surface phenomenon usually associated to mechanical reclamation. The study also covered possible use of some elements of wet reclamation to rehydrate waste binder. To evaluate the effectiveness of the two proposed methods of waste binder activation, selected strength and technological parameters were measured. After each subsequent processing cycle, the permeability, tensile strength and bending strength were determined. In addition, the surface of activated sand grains was examined with a scanning electron microscope. Analysis of the results indicates that it is possible to re-activate the used binder such as sodium silicate, and to stabilize the strength parameters in both activation processes. Permeability of the refreshed moulding sands strongly depends on the surface condition of high-silica grains. The wet activation process by wetting and buffering knocked-out moulding sands in closed humid environment makes it possible to reduce the content of refreshing additive in water-glass. The moulding sands cyclically prepared in both processes do not require the addition of fresh high-silica sand. The relatively high quality achieved in the refreshed moulding sands allows them to be reused for manufacture of next moulds. Thus, the two proposed methods for cyclically processing used moulding sands containing sodium silicate, subject to microwave hardening, are suitable for economic and ecological circulation moulding mixtures.

Biodegradable materials as binders for IVth generation moulding sands

This paper focuses on the possibility of using the biodegradable materials as binders(or parts of binders' compositions) for foundry moulding and core sands. Results showed that there is a great possibility of using available biodegradable materials as foundry moulding sand binders. Using biodegradable materials as partial content of new binders, or additives to moulding sands may not only decrease the toxicity and increase reclamation ability of tested moulding sands, but also accelerate the biodegradation rate of used binders, and the new biodegradable additive(PCL) did not decrease the strength and thermal properties. In addition, using polycaprolactone(PCL) as a biodegradable material may improve the flexibility of moulding sands with polymeric binder and reduce toxicity.

Investigations of physicochemical properties of dusts generated in mechanical reclamation process of spent moulding sands with alkaline resins

Mechanical reclamation processes of spent moulding sands generate large amounts of postreclamation dusts mainly containing rubbed spent binding agents and quartz dusts. The amount of postreclamation dusts, depending in the reclamation system effi ciency and the reclaim dedusting system, can reach 5%-10% in relation to the total reclaimed spent moulding sand. The proper utilization of such material is a big problem facing foundries these days. This study presents the results of investigations of physicochemical properties of post- reclamation dusts. All tested dusts originated from various Polish cast steel plants applying the mechanical reclamation process of moulding sands with alkaline resins, obtained from different producers. Different dusts, delivered from foundries, were tested to determine their chemical composition, granular characterization, physicochemical and energetic properties. Presented results confi rmed assumptions that it is possible to utilize dusts generated during mechanical reclamation of used sands with organic resins as a source of energy.

Development tendencies of moulding and core sands

Further development of the technology for making moulding and core sands will be strictly limited by tough requirements due to protection of the natural environment. These tendencies are becoming more and more tense, so that we will reach a point when even processes, that from technological point of view fulfill high requirements of the foundry industry, must be replaced by more ecologically-friendly solutions. Hence, technologies using synthetic resins as binding materials will be limited. This paper presents some predictable development tendencies of moulding and core sands. The increasing role of inorganic substances will be noticed, including silicate binders with significantly improved properties, such as improved knock-out property or higher reclamation strength. Other interesting solutions might also be moulding sands bonded by geo-polymers and phosphate binders or salts and also binders based on degradable biopolymers. These tendencies and the usefulness of these binders are put forward in this paper.

Impact of Moisture Variation on Some Foundry Properties of Fori Silica Sand

Moulding Sand for metal casting is usually sourced from either natural deposit or synthetic mix of refractory sand grain binder and moisture. Each of the mix constituent is important in determining the characteristics of sand. The binding agent is responsible for bendability thereby determining the size of voids within the sand grain, while moisture level determines the plasticity of the foundry sand. Tests using American Foundry Society (AFS) Standard were followed in carrying out the experiment on Fori sand deposit to determine its suitability for foundry use. The sand was collected from the river bank of Fori, in Fori Community, Maiduguri, Borno State. The experimental test equipment includes: laboratory sand mixer, sand rammer, universal strength testing machine, permeability-meter, oven, mouldability machine, and as well as quick moisture teller. The chemical composition of the materials was carried out using atomic absorption spectrophotometer (AAS) model PG990AFG. The silica content in the material sample is about 78.65%, and with the traces of other elements, such as CaO (1.07%), Fe2O3 (0.76%), Al2O3 (15.81%), MgO (1.01%), TiO2 (2.21%), K2O (3.87%), and Na2O (1.16%), respectively. These percentages are within acceptable limits. The results of the physical properties revealed that the sand sample has clay content of 15.32% which is above the standard range of 10% - 12% recommended for natural moulding sands required for producing good quality castings. Other foundry properties of Forinatural moulding sand conducted include “moisture content” in the following ranges of percentages, 7.6%, 6.5%, 5.8%, 4.2% and 2.9% with the corresponding value of green compressive strength of (43.95, 53.47, 69.56, 68.21 and 61.16 KN/m2), dry compressive strength (93.50, 96.52, 105.50, 146.50 and 152.49 KN/m2), and permeability No. of 340, 390, 410, 430 and 440 respectively. It is clear from the test that, the lower the moisture content, the higher the dry compressive strength of the materials. The refractoriness value of the materials is 1400 ℃. The results of the physical and other foundry properties carried out show that Forisilica sand is suitable for casting non-ferrous alloys like bronze, brass and aluminium, and cast iron.

Performance of digital patternless freeze-casting sand mould

Digital patternless freeze-casting technology is a new approach for obtaining frozen sand moulds using digital milling technology. The change law of tensile strength and air permeability of frozen sand moulds (100-mesh and 200-mesh silica sand, and zircon sand moulds) under different freezing temperatures and water contents was studied. Results show that with the decrease of freezing temperature and the increase of water contents, the tensile strength and air permeability of the sand moulds are gradually improved. Meanwhile, computed tomography technology was used to characterize the shape and size of the water film between the sand particles mixed with 4wt.% water. The results show that in silica sand moulds, the form of water film is lumpy, and 200-mesh silica sand moulds have more water films and higher proportion of small-sized water films than 100-mesh silica sand moulds, while in zircon sand moulds, the form of water film is membranous. At the same freezing temperature and water content, the tensile strength of zircon sand mould is the highest, and 100-mesh silica sand mould is the lowest. A comparative solidification experiment of A356 aluminum alloy was carried out in frozen sand mould and resin sand mould. The results show that the primary α-Al phase appears in the form of equiaxed and eutectic silicon phase is needle-like in freezing sand mould casting, but the primary α-Al phase grows in the form of dendrites, and the eutectic silicon phase is coarse needle-like in the resin sand mould casting. The difference of microstructure is caused by the different cooling rate. The cooling rate of A356 aluminum alloy in frozen sand mould is higher than that in resin sand mould.

A new numerical simulation model for high pressure squeezing moulding

High pressure squeeze is the most popular moulding process applied in modern moulding machines.Because of the unique characters of moulding sand and nonlinearity of squeezing process,the mechanical model is of key importance for computer simulation.Drucker-Prager/Cap is a typical soil mechanical theory model and it was used to simulate the squeezing process in this study,while ABAQUS software is used to simulate dynamic stress/strain evolution during the process.The simulation agrees well with the experimental results.We conclude that Drucker-Prager/Cap is an appropriate model for the squeezing compaction of moulding sand,and that the associated nonlinearity can be solved well with ABAQUS software.

A Model for Predicting Dynamic Cutting Forces in Sand Mould Milling with Orthogonal Cutting

Cutting force is one of the research hotspots in direct sand mould milling because the cutting force directly a ects the machining quality and tool wear. Unlike metals, sand mould is a heterogeneous discrete deposition material. There is still a lack of theoretical research on the cutting force. In order to realize the prediction and control of the cut?ting force in the sand mould milling process, an analytical model of cutting force is proposed based on the unequal division shear zone model of orthogonal cutting. The deformation velocity relations of the chip within the orthogonal cutting shear zone are analyzed first. According to the flow behavior of granular, the unequal division shear zone model of sand mould is presented, in which the governing equations of shear strain rate, strain and velocity are estab?lished. The constitutive relationship of quasi?solid–liquid transition is introduced to build the 2D constitutive equation and deduce the cutting stress in the mould shear zone. According to the cutting geometric relations of up milling with straight cutting edge and the transformation relationship between cutting stress and cutting force, the dynamic cutting forces are predicted for di erent milling conditions. Compared with the experimental results, the predicted results show good agreement, indicating that the predictive model of cutting force in milling sand mould is validated. Therefore, the proposed model can provide the theoretical guidance for cutting force control in high e ciency mill?ing sand mould.

Iron casting skin management in no-bake mould – Effects of magnesium residual level and mould coating

The relative performance of coatings for furan resin sand moulds [P-toluol sulphonic acid(PTSA) as hardener] [FRS-PTSA moulds], was compared by analyzing the surface layer for degenerated graphite in Mg treated iron with 0.020 wt.% to 0.054 wt.% Mgres. It was found that the iron nodularising potential(Mg, Ce, La content) and whether the mould coatings contained S, or were capable of desulphurizing were important factors. These moulds have S in the PTSA binder, which aggravates graphite degeneration in the surface layer, depending strongly on the Mgres with lower Mgres increasing the layer thickness. The application of a mould coating strongly influenced graphite deterioration in the surface layer of castings. It either promoted graphite degeneration to less compact morphologies when using S-bearing coatings, or conversely, limited the surface layer thickness using desulphurization type coatings. Independently of the S-source at the metal – mould interface, the presence of sulphur had an adverse effect on graphite quality at the surface of Mg-treated irons, but its negative effect could also reach the graphite phase within the casting section. If the coatings employed desulphurization materials, such as Mg O, or a mixture(Ca O + Mg O + Talc) or Mgbearing Fe Si, they protected the graphite shape, improving graphite nodularity, at the metal – mould interface, and so decreased the average layer thickness in FRS-PTSA moulds. Fe Si Mg was highly efficient in minimizing the casting skin by improving graphite nodularity. It is presumed that the Mg O or(Mg O + Ca O + Talc) based coatings acted to remove any S released by the mould media. The Mg-Fe Si coatings also reacted with S from the mould but additionally supplemented the Mg nodularising potential prior to solidification. This dual activity is achievable with coatings containing active magnesium derived from fine Mg-Fe Si materials.

Experimental confirmation of physical metal penetration generation and press casting production considering molten metal's pressure control

This paper presents a technique for controlling the pressure of a molten metal when using a new type of iron casting method called sand mold press casting to realize high productivity and obtain high-quality products.The past test results using this method showed a casting yield of 90% to 95%,while conventional methods only show a casting yield of 60% to 70%.Although the press casting method does not require a sprue cup or runner channel casting defects such as metal penetration are often caused by the high pressure in the high-velocity pressing part of this casting process.Therefore,we proposed a pressure control method with a mathematical model of molten metal pressure,and with it we achieved experimental confirmation of the successful production of brake drums at different pressing temperatures.Results show that the proposed pressing control method can realize sound,penetration-free casting production.However,the theoretical analysis and design of this pressing process had not previously been studied sufficiently,and therefore this paper presents the theoretical design algorithm for the process as well as its experimental confirmation.

A novel application of fluidization-Integrating three processes in reclaiming foundry sand

Immersion of automotive parts in a fluidized bed of foundry sand is used to both strip the castings free from moulding sand and to heat-treat the castings at 500℃. The fluid bed is heated by hot gases from a burner directed first into a serpentine heat exchanger located near one side-wall of the rectangular tank, and then into a distributor consisting of horizontal sparger pipes having maintenance standpipes fixed into their upper surfaces.

Effective Factors on Forming Precision in Patternless Casting Manufacturing Technique

The patternless casting manufacturing (PCM) technique, which adopts a new concept of double scanning method, combines the principle of discreteness and deposition with resin-bonded sand technique. This paper is to evaluate the dimensional accuracy of sand mould on PCM. The two important factors—the liquid penetration rule in the space of particles and the shape and dimension of the agglomeration unit body, which influence the process parameters such as scanning speed, layer thickness, liquid flux on dimension accuracy, and surface qualities, were investigated systematically, thus the theoretical basis for these parameters was provided. Experiments on rapid manufacturing of sand mould were carried out, and the results of the free penetration and the constraint penetration well verified the relationship of the two factors and the process parameters.