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Chaotic Motion Analysis for a Coupled Magnetic-Flow-Mechanical Model of the Rectangular Conductive Thin Plate
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作者 Xinzong Wang Xiaofang Kang Qingguan Lei 《Computer Modeling in Engineering & Sciences》 SCIE EI 2023年第11期1749-1771,共23页
The chaotic motion behavior of the rectangular conductive thin plate that is simply supported on four sides by airflow andmechanical external excitation in a magnetic field is studied.According to Kirchhoff’s thin pl... The chaotic motion behavior of the rectangular conductive thin plate that is simply supported on four sides by airflow andmechanical external excitation in a magnetic field is studied.According to Kirchhoff’s thin plate theory,considering geometric nonlinearity and using the principle of virtualwork,the nonlinearmotion partial differential equation of the rectangular conductive thin plate is deduced.Using the separate variable method and Galerkin’s method,the system motion partial differential equation is converted into the general equation of the Duffing equation;the Hamilton system is introduced,and the Melnikov function is used to analyze the Hamilton system,and obtain the critical surface for the existence of chaos.The bifurcation diagram,phase portrait,time history response and Poincarémap of the vibration system are obtained by numerical simulation,and the correctness is demonstrated.The results showthatwhen the ratio of external excitation amplitude to damping coefficient is higher than the critical surface,the system will enter chaotic state.The chaotic motion of the rectangular conductive thin plate is affected by different magnetic field distributions and airflow. 展开更多
关键词 Rectangular conductive thin plate CHAOTIC AIRFLOW magnetic field Melnikov function Galerkin’s method
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DYNAMIC BEHAVIORS OF CONDUCTIVE CIRCULAR PLATE IN TIME-VARYING MAGNETIC FIELDS 被引量:4
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作者 Yuanwen Gao1 Bang Xu(Key Laboratory of Mechanics on Western Disaster and Environment,College of Civil Engineering and Mechanics,Lanzhou University,Lanzhou 730000,China) 《Acta Mechanica Solida Sinica》 SCIE EI 2010年第1期66-76,共11页
In this study, we proposed an analytical solution for eddy currents as well as electromagnetic forces of a conductive circular plate in a time varying magnetic field. Specifically, an analytical series solution for ed... In this study, we proposed an analytical solution for eddy currents as well as electromagnetic forces of a conductive circular plate in a time varying magnetic field. Specifically, an analytical series solution for eddy currents in a circular plate subjected to an axisymmetrie time varying magnetic field has been proposed based on the T-method that has been widely used in the eddy current analysis of conductive and superconductive structures. Accordingly, the dynamic response, the dynamic instability and the magnetic damping of a circular plate in a transverse transient magnetic field as well as a stationary in-plane magnetic field have also been obtained. The analytical series solution proposed in this work as well as the subsequent numerical analysis not only confirmed the emergence of dynamic instability of a circular plate in a strong transverse magnetic field, but also demonstrated the existence of magneto-damping of a circular conductive plate in an in-plane magnetic field. The method developed in this paper provides a potential new possible way by which the analysis of the electromagnetic coupling problems of conductive structures can be simplified. 展开更多
关键词 dynamic response circular conductive plate series solution for eddy current Bessel function
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Principal and internal resonance of rectangular conductive thin plate in transverse magnetic field 被引量:2
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作者 Jing Li Yuda Hu 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2018年第4期257-266,299,共11页
The principle and 1:3 internal resonance of a rectangular thin plate in a transverse magnetic field is investigated.Based on the magneto-elastic vibration equation and electromagnetic force expressions of the thin pla... The principle and 1:3 internal resonance of a rectangular thin plate in a transverse magnetic field is investigated.Based on the magneto-elastic vibration equation and electromagnetic force expressions of the thin plates,the nonlinear magneto-elastic vibration differential equations of rectangular plates under external excitation in a transverse magnetic field are derived.For a rectangular plate with one side fixed and three other sides simply supported,the two-degree-offreedom nonlinear Duffing vibration differen-tial equations are proposed by the method of Galerkin.The method of multiple scales is adopted to solve the model equations and obtain four first-order ordinary differential equations governing modulation of the amplitudes and phase angles involved via the first-order or the second-order primary-internal reso-nances.With a numerical example,the amplitude frequency response curves,time history responses,phase portraits and Poincare maps of the first two order vibration modes via principle-internal resonance are respectively captured.And the effects of external excitation amplitudes,magnetic field intensities and thicknesses on the vibration of system are discussed.The results show that the response is dominated by the low mode when principle-internal resonance occurs.The internal resonance provides a mechanism for transferring energy from a high mode to a low mode. 展开更多
关键词 MAGNETO elastic conductive thin plate Principle-internal RESONANCE Multiple scales GALERKIN method
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MULTI-FIELD COUPLING BEHAVIOR OF SIMPLY-SUPPORTED CONDUCTIVE PLATE UNDER THE CONDITION OF A TRANSVERSE STRONG IMPULSIVE MAGNETIC FIELD 被引量:3
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作者 Zhu Linli Zhang Jianping Zheng Xiaojing 《Acta Mechanica Solida Sinica》 SCIE EI 2006年第3期203-211,共9页
In order to study the multi-field coupling mechanical behavior of the simply-supported conductive rectangular thin plate under the condition of an externally lateral strong impulsive magnetic field, that is the dynami... In order to study the multi-field coupling mechanical behavior of the simply-supported conductive rectangular thin plate under the condition of an externally lateral strong impulsive magnetic field, that is the dynamic buckling phenomenon of the thin plates in the effect of the magnetic volume forces produced by the interaction between the eddy current and the magnetic fields, a FEM analysis program is developed to characterize the phenomena of magnetoelastic buckling and instability of the plates. The critical values of magnetic field for the three different initial vibrating modes are obtained, with a detailed discussion made on the effects of the lengththickness ratio a/h of the plate and the length-width ratio a/b as well as the impulse parameter on the critical value BOcr of the applied magnetic field. 展开更多
关键词 multi-field coupling conductive thin plate impulsive magnetic field eddy current dynamic buckling magnetic volume forces
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Copper Ions Removal from Wastewater by Electrocoagulation Using Cement-based Cathode Plates
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作者 YOU Song WU Jing +5 位作者 WANG Shizhe WANG Wei LI Qiong ZAHNG Ganggang DING Qinjun WANG Luoxin 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第2期387-393,共7页
The present work uses PEO solution to well disperse carbon fiber and identifies percolation thresholds of carbon fiber and carbon black which are used as conductive fillers.The resultant cathode plates have an average... The present work uses PEO solution to well disperse carbon fiber and identifies percolation thresholds of carbon fiber and carbon black which are used as conductive fillers.The resultant cathode plates have an average compressive strength of 27.3 MPa and flexural strength of 29.09 MPa,which demonstrate excellent mechanical properties.The Cu^(2+)removal efficiency was measured at different current densities in EC process with cement-based cathode plate,while the voltage changes were recorded.The results showed that the cement-based cathode plate operated stably and achieved 99.7%removal of 1 L of simulated wastewater with a Cu^(2+)concentration of 200 ppm at a current density of 8 m A/cm^(2)for 1 h.Characterization of floc and tested cathode plates,SEM and EDS analyses,and repeatability testing of the tested plates demonstrate the reusability of the plates,proving that cement-based plates can effectively replace metal cathode plates,reduce the cost of EC and improve the applicability of EC devices. 展开更多
关键词 ELECTROCOAGULATION cathode plate cement-based conductive materials copper ions repeatability
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ANALYSIS ON DYNAMIC CHARACTERISTICS FOR FERROMAGNETIC CONDUCTING PLATES IN A TRANSVERSE UNIFORM MAGNETIC FIELD
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作者 Zheng, XJ Liu, X 《Acta Mechanica Solida Sinica》 SCIE EI 2000年第1期9-16,共8页
In this paper, a set of basic equations for free vibration of ferromagnetic conducting plates in a transverse magnetic field are presented, in which the coupled effects of magnetization and eddy current on the mechani... In this paper, a set of basic equations for free vibration of ferromagnetic conducting plates in a transverse magnetic field are presented, in which the coupled effects of magnetization and eddy current on the mechanical behavior of the plate are included. Based on the quantitative analyses on the vibration frequency and the values of the critical magnetic field for several supporting conditions of the plate, the effects of the conductivity, the magnetic permeability, the thickness of the plate and supporting conditions on the vibration frequency of the plate and the critical magnetic field are discussed. 展开更多
关键词 ferromagnetic conducting plate MAGNETOELASTICITY effect of eddy current vibration frequency stability
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Preparation of Electrically Conductive Filler for Anisotropic Conductive Adhesive 被引量:3
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作者 华丽 安兵 +3 位作者 吴懿平 吴丰顺 王佳 何敬强 《上海交通大学学报》 EI CAS CSCD 北大核心 2007年第S2期127-130,138,共5页
The preparation process of electrically conductive filler for anisotropic conductive adhesive was performed and discussed.The spherical filler contains tri-layer structures: resin core,Ni-P intermediate coating layer,... The preparation process of electrically conductive filler for anisotropic conductive adhesive was performed and discussed.The spherical filler contains tri-layer structures: resin core,Ni-P intermediate coating layer,Au outer coating layer.The 4 μm resin spherical cores were synthesized by monodispersion polymerization method.Then they were contributed to electrical conductivity by electrolessly plating Ni-P layer and gold layer.These particles have good corrosion resistance,high stability,and enough mechanical strength.When mixed with thermosetting epoxy resin to produce anisotropic conductive adhesive(ACA),it can realize a good conductive bonding between bumps on dies and pads on substrates.This environmentally friendly conductive material offers numerous advantages over conventional solder technology and is an ideal substitute for the lead-contained solder in electronics packaging. 展开更多
关键词 anisotropic conductive adhesive(ACA) monodispersion POLYMERIZATION MICROSPHERE ELECTROLESS PLATING
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Analysis of steady heat conduction for 3D axisymmetric functionally graded circular plate 被引量:3
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作者 刘五祥 《Journal of Central South University》 SCIE EI CAS 2013年第6期1616-1622,共7页
The thermal conduction behavior of the three-dimensional axisymmetric functionally graded circular plate was studied under thermal loads on its top and bottom surfaces. Material properties were taken to be arbitrary d... The thermal conduction behavior of the three-dimensional axisymmetric functionally graded circular plate was studied under thermal loads on its top and bottom surfaces. Material properties were taken to be arbitrary distribution functions of the thickness. A temperature function that satisfies thermal boundary conditions at the edges and the variable separation method were used to reduce equation governing the steady state heat conduction to an ordinary differential equation (ODE) in the thickness coordinate which was solved analytically. Next, resulting variable coefficients ODE due to arbitrary distribution of material properties along thickness coordinate was also solved by the Peano-Baker series. Some numerical examples were given to demonstrate the accuracy, efficiency of the present model, mad to investigate the influence of different distributions of material properties on the temperature field. The numerical results confirm that the influence of different material distributions, gradient indices and thickness of plate to temperature field in plate can not be ignored. 展开更多
关键词 functionally graded circular plate variable separation method steady heat conduction Peano-Baker series
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STAR CCM+ CFD Simulations of Enhanced Heat Transfer in High-Power Density Electronics Using Forced Air Heat Exchanger and Pumped Fluid Loop Cold Plate Fabricated from High Thermal Conductivity Materials 被引量:2
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作者 Kevin R. Anderson Matthew Devost +1 位作者 Watit Pakdee Niveditha Krishnamoorthy 《Journal of Electronics Cooling and Thermal Control》 2013年第4期144-154,共11页
As telecommunication and RF power electronics applications continue to push the envelope of waste heat dissipation, more and more, we see a need for active thermal control employing forced air electronic cooling fans ... As telecommunication and RF power electronics applications continue to push the envelope of waste heat dissipation, more and more, we see a need for active thermal control employing forced air electronic cooling fans in unison with pumped fluid loops in order to meet temperature and performance requirements. This research paper presents results of applying Computational Fluid Dynamics (CFD) commercial industry STAR-CCM+ software for heat transfer and fluid flow simulation of a novel heat exchanger/cold plate fabricated from k-core high thermal conductivity material in order to realize thermal control system hardware design for very much applications to very large power density (~1 kW/m2) electronics packaging scenarios. Trade studies involving different heat exchanger/cold plate materials, as well as vari- ous fault scenarios within a mock-up of a typical electronics system, are used to illustrate the upper bounds placed on the convective heat transfer coefficient. Agreement between our present findings and previous research in the field of electronics cooling is presented herein. 展开更多
关键词 CFD High THERMAL conductIVITY Heat SINK Cooling plate THERMAL Control
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Magneto-elastic combination resonances analysis of current-conducting thin plate 被引量:2
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作者 胡宇达 李晶 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2008年第8期1053-1066,共14页
Based on the Maxwell equations, the nonlinear magneto-elastic vibration equations of a thin plate and the electrodynamic equations and expressions of electromagnetic forces are derived. In addition, the magneto-elasti... Based on the Maxwell equations, the nonlinear magneto-elastic vibration equations of a thin plate and the electrodynamic equations and expressions of electromagnetic forces are derived. In addition, the magneto-elastic combination resonances and stabilities of the thin beam-plate subjected to mechanical loadings in a constant transverse magnetic filed are studied. Using the Galerkin method, the corresponding nonlinear vibration differential equations are derived. The amplitude frequency response equation of the system in steady motion is obtained with the multiple scales method. The excitation condition of combination resonances is analyzed. Based on the Lyapunov stability theory, stabilities of steady solutions are analyzed, and critical conditions of stability are also obtained. By numerical calculation, curves of resonance-amplitudes changes with detuning parameters, excitation amplitudes and magnetic intensity in the first and the second order modality are obtained. Time history response plots, phase charts, the Poincare mapping charts and spectrum plots of vibrations are obtained. The effect of electro-magnetic and mechanical parameters for the stabilities of solutions and the bifurcation are further analyzed, Some complex dynamic performances such as perioddoubling motion and quasi-period motion are discussed. 展开更多
关键词 MAGNETO-ELASTIC current-conducting thin plate combination resonance STABILITY multiple scales method
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AN ANALYTICAL SOLUTION OF HEAT CONDUCTION ON A LOCALLY NONUNIFORMLY HEATED SURFACE OF A PLATE WITH FINITE THICKNESS
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作者 王明锐 靳辉 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1996年第5期487-493,共7页
In engineering and technology, the following problem is often touched upon A certain portion of a plate with finite thickness is heated on its surface, so that the heat flux along the surface is distributed nonuniform... In engineering and technology, the following problem is often touched upon A certain portion of a plate with finite thickness is heated on its surface, so that the heat flux along the surface is distributed nonuniformly and varying with time. For this kind of heal conduction, there is no available analytical solution given in existing treatises concerning heat conduction. This paper presents an analytical solution of this problem, its calculation results are in good agreement with the experimental data. 展开更多
关键词 plate heat conduction analytical solution
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Conductive Polyacrylonitrile Fiber Prepared by Copper Plating with L-Ascorbic Acid as Reducing Agent
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作者 WANG Yunhong TAN Youzhi +2 位作者 XU Yajing GUO Lamei HUANG Liqian 《Journal of Donghua University(English Edition)》 CAS 2022年第6期519-526,共8页
Conductive polyacrylonitrile fibers were prepared by electroless copper plating under weak alkaline conditions,with L-ascorbic acid as reducing agent.The influences of CuSO_(4)·5H_(2)O,L-ascorbic acid,2,2′-bipyr... Conductive polyacrylonitrile fibers were prepared by electroless copper plating under weak alkaline conditions,with L-ascorbic acid as reducing agent.The influences of CuSO_(4)·5H_(2)O,L-ascorbic acid,2,2′-bipyridine and K_(4)Fe(CN)_(6) concentration on the conductivity and mass gain percentage of the fibers were studied.The morphological structure of the fibers was characterized by scanning electron microscopy(SEM),and the mechanical properties of the fibers were analyzed through the mechanical property test.The results showed that the optimal reaction conditions were as follows:26 g/L CuSO_(4)·5H_(2)O,26 g/L L-ascorbic acid,12 mg/L 2,2′-bipyridine,7 mg/L K 4Fe(CN)6,and 38℃.The volume resistivity of the conductive PAN fibers prepared by the process was only 3.84×10^(-3)Ω·cm. 展开更多
关键词 L-ascorbic acid CuSO_(4)·5H_(2)O redox copper plating conductive fiber
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基于LBM的低导热材料板强化沸腾换热机理分析 被引量:1
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作者 曹海亮 刘红贝 +2 位作者 张子阳 赵晓亮 郭赛 《郑州大学学报(工学版)》 CAS 北大核心 2024年第3期103-110,共8页
为进一步强化沸腾换热,通过在固体加热器的上壁面附近嵌入多段低导热材料板,实现了沸腾换热的受热面上的温度随空间的交替变化。采用单组分多相LBM,考察了低导热材料板的数量和间隙间距对沸腾换热性能和气泡动力学的影响,从微观角度揭... 为进一步强化沸腾换热,通过在固体加热器的上壁面附近嵌入多段低导热材料板,实现了沸腾换热的受热面上的温度随空间的交替变化。采用单组分多相LBM,考察了低导热材料板的数量和间隙间距对沸腾换热性能和气泡动力学的影响,从微观角度揭示了添加低导热材料板强化沸腾换热的机理。结果表明:气泡动态行为随间隙间距的增大而发生变化,会出现气泡合并、独立生长等气泡脱离过程。结合气泡动态行为、温度场和流场分析,发现气泡首先会在间隙受热面处成核生长,脱离气泡的涡流可以促进生长气泡在受热面的横向迁移和合并过程,在一定间隙间距范围,气泡会相互融合形成较大的液桥,液桥的存在能够促进受热面气泡根部周围微层的蒸发,推动了间隙受热面处的冷流体再润湿过程。添加多段低导热材料板,间隙处热量积聚、气泡合并形成液桥、间隙受热面的再润湿、气泡横向迁移和多气泡的快速合并等这些过程的共同作用强化了沸腾换热性能。 展开更多
关键词 低导热材料板 气泡动力学 格子玻尔兹曼方法 气液两相流 强化换热
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基于无颗粒银导电墨水在不锈钢表面镀银工艺研究
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作者 杨堃 姚孟智 +3 位作者 杜佳玮 韩冬宁 孙小岚 李晓东 《表面技术》 EI CAS CSCD 北大核心 2024年第16期208-218,共11页
目的采用无颗粒银导电墨水对不锈钢表面进行镀银研究,以绿色环保工艺替代传统电镀银技术。方法主要研究适用于不锈钢基材的前驱体银源、络合剂种类、不锈钢前处理方法、烧结固化温度对不锈钢表面银层微观结构及性能的影响,获得不锈钢基... 目的采用无颗粒银导电墨水对不锈钢表面进行镀银研究,以绿色环保工艺替代传统电镀银技术。方法主要研究适用于不锈钢基材的前驱体银源、络合剂种类、不锈钢前处理方法、烧结固化温度对不锈钢表面银层微观结构及性能的影响,获得不锈钢基材上微观结构致密、性能良好的银层。采用X射线衍射仪、扫描电子显微镜、激光共聚焦显微镜、数字兆欧表对在不锈钢表面银膜层进行表征。结果不锈钢通过1,2丙二胺溶液处理后,采用银源草酸银为前驱体,此时银层微观结构最致密,具有最佳的附着力等级(5B)和最低的粗糙度(1.237μm),与1,2-丙二胺络合,乙醇为溶剂时,制备出的银层有机物挥发完全,微观结构致密,并且具有最低的接触电阻0.7Ω和粗糙度0.80μm。烧结固化温度为200℃时银层导电性最好。结论采用无颗粒银导电墨水对不锈钢表面进行镀银的新型工艺银层性能良好,可以简化传统电镀技术复杂的操作流程,减少传统电镀工艺所使用氰化物对人体造成的危害,并弥补应用受限的缺点。 展开更多
关键词 不锈钢 无颗粒银墨水 镀银 导电性 结合力
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8 kA稀土电解槽单侧电导及阴极优化数值模拟
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作者 龚姚腾 吕招东 +1 位作者 陈泽斌 逄启寿 《中国有色冶金》 CAS 北大核心 2024年第3期64-71,共8页
稀土电解槽导电板的分布位置对稀土电解槽的物理场会有影响,为探究稀土电解槽中导电板分布的最优位置,在本次仿真实验中为该导电板的分布引入一个等差数列的分布梯度,通过对不同分布梯度下的槽内物理场仿真数值进行比较,进而得到稀土电... 稀土电解槽导电板的分布位置对稀土电解槽的物理场会有影响,为探究稀土电解槽中导电板分布的最优位置,在本次仿真实验中为该导电板的分布引入一个等差数列的分布梯度,通过对不同分布梯度下的槽内物理场仿真数值进行比较,进而得到稀土电解槽导电板最优分布模型。在仿真过程中观察到阴极底部的尖角对实验结果影响较大,在其他条件保持不变的基础上将阴极底部由圆柱优化为半球形,通过与未优化的结构进行对比,验证新型电解槽结构的合理性。仿真结果显示:随着导电板由侧边位置向中间偏移,电解反应时槽内的温度与阳极电势基本保持不变,槽盖板与阳极间的电势差逐渐减小,槽内电流密度缓慢增大。当将阴极钼棒底部由柱状结构改为球状结构后,槽内电势分布更为均匀,电流密度相较于之前的结构也有所增加,优化后的结构能改善局部过热问题,同时也使得电解效率增大。 展开更多
关键词 稀土电解槽 单侧导电板 通电位置 阴极底部结构 物理场模拟 结构优化 局部过热 电解效率
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PEMFC金属双极板氮化物涂层的研究进展 被引量:1
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作者 侯强强 李希超 +5 位作者 孙贤伟 赵经香 韦守李 李硕 戴作强 郑莉莉 《材料热处理学报》 CAS CSCD 北大核心 2024年第1期11-21,共11页
质子交换膜燃料电池(PEMFC)金属双极板具有机械强度高、易加工、成本低等优势,但其在PEMFC的酸性环境中容易被腐蚀,从而会对其寿命及导电性产生不利的影响。通过采用氮化物涂层改性的双极板表面结构会变得更加致密,能够提高基体的耐腐... 质子交换膜燃料电池(PEMFC)金属双极板具有机械强度高、易加工、成本低等优势,但其在PEMFC的酸性环境中容易被腐蚀,从而会对其寿命及导电性产生不利的影响。通过采用氮化物涂层改性的双极板表面结构会变得更加致密,能够提高基体的耐腐蚀性能,从而提高燃料电池的工作寿命。本文从氮化物涂层的种类出发,回顾了近年来氮化物涂层的研究进展。然后介绍了涂层常见的制备方法,同时对其原理进行了分析,对不同的方法制备出的氮化物涂层进行了分析对比。随后总结了不同种类涂层的特点及存在的问题,对不同种类的涂层的耐腐蚀性能进行了比较。最后指出了氮化物涂层存在的问题,并对其未来的发展方向进行了展望。 展开更多
关键词 质子交换膜燃料电池 双极板 氮化物涂层 腐蚀 导电性
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热轧温度对1060/6201/1060复合板力学性能及导电性能的影响
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作者 杨磊 边丽萍 +4 位作者 冀宏亮 王鹏辉 王涛 梁伟 薛峰平 《热加工工艺》 北大核心 2024年第17期107-110,共4页
通过首道次大变形量热轧、再经两道次冷轧方式成功制备了1060/6201/1060三层复合板,详细考察了不同热轧温度对复合板力学性能及导电性能的影响。结果表明,随着热轧温度的升高,复合板的力学性能逐渐降低,导电率先升高后降低。在200℃热轧... 通过首道次大变形量热轧、再经两道次冷轧方式成功制备了1060/6201/1060三层复合板,详细考察了不同热轧温度对复合板力学性能及导电性能的影响。结果表明,随着热轧温度的升高,复合板的力学性能逐渐降低,导电率先升高后降低。在200℃热轧时,抗拉强度为257.21 MPa,导电率为57.45%IACS,综合性能最佳。在300、400℃轧制时,由于发生动态回复,析出相粗化,基体晶粒长大,复合板的强度降低,伸长率提高,导电率增加。 展开更多
关键词 6201铝合金 复合板 力学性能 导电性能
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超级柔韧性和优异电磁屏蔽性能的PVA-co-PE纳米纤维覆铜膜
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作者 陶德昌 文鑫 +5 位作者 李雪丽 严坤 赵青华 夏明 杨晨光 王栋 《材料导报》 EI CAS CSCD 北大核心 2024年第14期247-254,共8页
本工作通过紫外辐射诱导和化学还原反应相结合成功制备了具有多级结构的聚乙烯醇-聚乙烯(PVA-co-PE)纳米纤维覆铜膜,PVA-co-PE纳米纤维覆铜膜具有超级柔韧性能和电磁屏蔽性能,且具有多次循环压缩后性能不减的稳定性。首先通过紫外辐照... 本工作通过紫外辐射诱导和化学还原反应相结合成功制备了具有多级结构的聚乙烯醇-聚乙烯(PVA-co-PE)纳米纤维覆铜膜,PVA-co-PE纳米纤维覆铜膜具有超级柔韧性能和电磁屏蔽性能,且具有多次循环压缩后性能不减的稳定性。首先通过紫外辐照引入一定量的活化羟基,然后通过静电配位和铜粒子的化学还原作用,在纳米纤维膜上实现无钯镀铜。采用傅里叶红外光谱仪(AIR-FTIR)、能量色散型X射线荧光分析仪(EDX-7000)、扫描电子显微镜(SEM)等对样品进行结构性能分析。结果表明,成功实现PVA-co-PE纳米纤维覆铜膜的制备,SEM图表明,铜颗粒均匀分布于纳米纤维膜表面,并且薄膜由亲水转变为不易浸润。通过四探针仪器和矢量网络分析仪表征了薄膜材料的导电性和电磁屏蔽性能。结果表明,覆铜膜达到导体水平,吸波值达到47.3 dB。经过多次循环压缩后覆铜膜材料电磁屏蔽性能几乎不减,说明制得的纳米纤维覆铜膜具有优异的柔韧性和吸波稳定性,其在柔性智能可穿戴元器件领域具有广阔的应用空间。 展开更多
关键词 PVA-co-PE纳米纤维膜 化学镀铜 导电性 疏水性 电磁屏蔽
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预氧化碳纤维增强受电弓碳滑板材料的研究
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作者 赵阳 李杰 +3 位作者 杨泽锋 高国强 魏文赋 吴广宁 《铁道学报》 EI CAS CSCD 北大核心 2024年第6期56-64,共9页
利用预氧化碳纤维(OPF)和沥青、焦炭等为原料,采用热压、焙烧等工艺制备预氧化碳纤维增强受电弓碳滑板;研究不同OPF含量受电弓碳滑板导电导热以及力学性能;利用扫描电镜(SEM)、偏光显微镜(POM)、X射线衍射仪(XRD)等仪器对复合材料内部... 利用预氧化碳纤维(OPF)和沥青、焦炭等为原料,采用热压、焙烧等工艺制备预氧化碳纤维增强受电弓碳滑板;研究不同OPF含量受电弓碳滑板导电导热以及力学性能;利用扫描电镜(SEM)、偏光显微镜(POM)、X射线衍射仪(XRD)等仪器对复合材料内部结构进行观察。结果表明:滑板材料性能的提升与OPF/沥青间的共碳化界面以及界面处与基体中的微晶网络形成有关。OPF质量分数为1.5%的复合材料具有较好的导电导热以及力学性能,电导率和导热系数分别为279.33 S/cm和3.37 W/(m·K),抗压强度和抗折分别为155.00、48.85 MPa,且符合受电弓碳滑板性能要求。 展开更多
关键词 受电弓碳滑板 预氧化碳纤维 复合材料 导电导热性能 力学性能
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间歇超声搅拌辅助化学镀制备核壳型镍包铜粉
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作者 朱康杰 张涵 +4 位作者 赵珩宇 史文南 杨向民 张震 方斌 《电镀与涂饰》 CAS 北大核心 2024年第9期12-25,共14页
[目的]通过优化化学镀配方和工艺,提升镍包铜粉的分散均匀性和镀层品质,以增强其作为导电填料在电子浆料中的抗氧化和导电性能。[方法]先采用Pd Cl_(2)体系活化铜粉,然后在间歇超声搅拌辅助下,采用酸性体系进行化学镀镍,制备出核壳型镍... [目的]通过优化化学镀配方和工艺,提升镍包铜粉的分散均匀性和镀层品质,以增强其作为导电填料在电子浆料中的抗氧化和导电性能。[方法]先采用Pd Cl_(2)体系活化铜粉,然后在间歇超声搅拌辅助下,采用酸性体系进行化学镀镍,制备出核壳型镍包铜粉。利用扫描电子显微镜(SEM)和X射线衍射仪(XRD)分析了Ni镀层的微观形貌和晶体结构,研究了活化液组分、镀液配方和搅拌方式对化学镀的影响。通过扫描电镜观察、能谱面扫分析和热重分析,检验了在较优条件下制备的镍包铜粉的镍层包覆效果和抗氧化性能。[结果]铜粉活化的较优配方为:Pd Cl_(2)0.50 mmol/L,盐酸2.40 mol/L,聚氧乙烯20油醚2.0 g/L。铜粉化学镀镍的较优配方为:硫酸镍0.037 5 mol/L,乙酸钠0.15 mol/L,乙酸0.27 mol/L,聚氧乙烯20油醚2.0 g/L,聚乙烯吡咯烷酮1.5 g/L,还原剂溶液(次磷酸钠3.367 mol/L)滴加速率2.5 mL/h。化学镀过程中采用30 s超声振荡和30 s机械搅拌交替进行的间歇超声搅拌方式有利于制备出镀层均匀致密和颗粒分散性良好的镍包铜粉。[结论]在较优条件下制备的镍包铜粉具有镀覆率高、镍层致密、颗粒分散均匀、抗氧化性能好等优点。 展开更多
关键词 镍包铜粉 化学镀 间歇超声搅拌 导电填料 抗氧化性能
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