Geographical origin identification of winter jujube(Ziziphus jujuba Dongzao')by using multi-element fingerprinting with chemometrics

Winter jujube(Ziziphus jujuba'Dongzao')is greatly appreciated by consumers for its excellent quality,but brand infringement frequently occurs in the market.Here,we first determined a total of 38 elements in 167 winter jujube samples from the main winter jujube producing areas of China by inductively coupled plasma mass spectrometer(ICP-MS).As a result,16 elements(Mg,K,Mn,Cu,Zn,Mo,Ba,Be,As,Se,Cd,Sb,Ce,Er,Tl,and Pb)exhibited significant differences in samples from different producing areas.Supervised linear discriminant analysis(LDA)and orthogonal projection to latent structures discriminant analysis(OPLS-DA)showed better performance in identifying the origin of samples than unsupervised principal component analysis(PCA).LDA and OPLS-DA had a mean identification accuracy of 87.84 and 94.64%in the testing set,respectively.By using the multilayer perceptron(MLP)and C5.0,the prediction accuracy of the models could reach 96.36 and 91.06%,respectively.Based on the above four chemometric methods,Cd,Tl,Mo and Se were selected as the main variables and principal markers for the origin identification of winter jujube.Overall,this study demonstrates that it is practical and precise to identify the origin of winter jujube through multi-element fingerprint analysis with chemometrics,and may also provide reference for establishing the origin traceability system of other fruits.

Design of low-alloying and high-performance solid solution-strengthened copper alloys with element substitution for sustainable development

Solid solution-strengthened copper alloys have the advantages of a simple composition and manufacturing process,high mechanical and electrical comprehensive performances,and low cost;thus,they are widely used in high-speed rail contact wires,electronic component connectors,and other devices.Overcoming the contradiction between low alloying and high performance is an important challenge in the development of solid solution-strengthened copper alloys.Taking the typical solid solution-strengthened alloy Cu-4Zn-1Sn as the research object,we proposed using the element In to replace Zn and Sn to achieve low alloying in this work.Two new alloys,Cu-1.5Zn-1Sn-0.4In and Cu-1.5Zn-0.9Sn-0.6In,were designed and prepared.The total weight percentage content of alloying elements decreased by 43%and 41%,respectively,while the product of ultimate tensile strength(UTS)and electrical conductivity(EC)of the annealed state increased by 14%and 15%.After cold rolling with a 90%reduction,the UTS of the two new alloys reached 576 and 627MPa,respectively,the EC was 44.9%IACS and 42.0%IACS,and the product of UTS and EC(UTS×EC)was 97%and 99%higher than that of the annealed state alloy.The dislocations proliferated greatly in cold-rolled alloys,and the strengthening effects of dislocations reached 332 and 356 MPa,respectively,which is the main reason for the considerable improvement in mechanical properties.

Design of high-temperature superconductors at moderate pressures by alloying AlH3 or GaH3

Since the discovery of hydride superconductors,a significant challenge has been to reduce the pressure required for their stabilization.In this context,we propose that alloying could be an effective strategy to achieve this.We focus on a series of alloyed hydrides with the AMH_(6)composition,which can be made via alloying A15 AH_(3)(A=Al or Ga)with M(M=a group IIIB or IVB metal),and study their behavior under pressure.Seven of them are predicted to maintain the A15-type structure,similar to AH_(3)under pressure,providing a platform for studying the effects of alloying on the stability and superconductivity of AH_(3).Among these,the A15-type phases of AlZrH_(6)and AlHfH_(6)are found to be thermodynamically stable in the pressure ranges of 40–150 and 30–181 GPa,respectively.Furthermore,they remain dynamically stable at even lower pressures,as low as 13 GPa for AlZrH_(6)and 6 GPa for AlHfH_(6).These pressures are significantly lower than that required for stabilizing A15 AlH3.Additionally,the introduction of Zr or Hf increases the electronic density of states at the Fermi level compared with AlH3.This enhancement leads to higher critical temperatures(Tc)of 75 and 76 K for AlZrH_(6)and AlHfH_(6)at 20 and 10 GPa,respectively.In the case of GaMH_(6)alloys,where M represents Sc,Ti,Zr,or Hf,these metals reinforce the stability of the A15-type structure and reduce the lowest thermodynamically stable pressure for GaH_(3) from 160 GPa to 116,95,80,and 85 GPa,respectively.Particularly noteworthy are the A15-type GaMH_(6)alloys,which remain dynamically stable at low pressures of 97,28,5,and 6 GPa,simultaneously exhibiting high Tc of 88,39,70,and 49 K at 100,35,10,and 10 GPa,respectively.Overall,these findings enrich the family of A15-type superconductors and provide insights for the future exploration of high-temperature hydride superconductors that can be stabilized at lower pressures.

Magnesium alloys as alternative anode materials for rechargeable magnesium-ion batteries:Review on the alloying phase and reaction mechanisms

Magnesium-ion batteries(MIBs)are promising candidates for lithium-ion batteries because of their abundance,non-toxicity,and favorable electrochemical properties.This review explores the reaction mechanisms and electrochemical characteristics of Mg-alloy anode materials.While Mg metal anodes provide high volumetric capacity and dendrite-free electrodeposition,their practical application is hindered by challenges such as sluggish Mg^(2+)ion diffusion and electrolyte compatibility.Alloy-type anodes that incorporate groups XIII,XIV,and XV elements have the potential to overcome these limitations.We review various Mg alloys,emphasizing their alloying/dealloying reaction mechanisms,their theoretical capacities,and the practical aspects of MIBs.Furthermore,we discuss the influence of the electrolyte composition on the reversibility and efficiency of these alloy anodes.Emphasis is placed on overcoming current limitations through innovative materials and structural engineering.This review concludes with perspectives on future research directions aimed at enhancing the performance and commercial viability of Mg alloy anodes and contributing to the development of high-capacity,safe,and cost-effective energy storage systems.

Role of alloying and heat treatment on microstructure and mechanical properties of cast Al-Li alloys:A review

Due to the prominent advantages of low density,high elastic modulus,high specific strength and specific stiffness,cast Al-Li alloys are suitable metallic materials for manufacturing complex large-sized components and are ideal structural materials for aerospace,defense and military industries.On the basis of the microstructural characteristics of cast Al-Li alloys,exploring the role of alloying and micro-alloying can stabilize their dominant position and further expand their application scope.In this review,the development progress of cast Al-Li alloys was summarized comprehensively.According to the latest research highlights,the influence of alloying and heat treatment on the microstructure and mechanical properties was systematically analyzed.The potential methods to improve the alloy performance were concluded.In response to the practical engineering requirements of cast Al-Li alloys,the scientific challenges and future research directions were discussed and prospected.

Structure and corrosion behavior of FeCoCrNiMo high-entropy alloy coatings prepared by mechanical alloying and plasma spraying

FeCoCrNiMox composite powders were prepared using the mechanical alloying technique and made into high-entropy alloy(HEA)coatings with the face-centered cubic phase using plasma spraying to address the element segregation problem in HEAs and pre-pare uniform HEA coatings.Scanning electron microscopy,transmission electron microscopy,and X-ray diffractometry were employed to characterize these coatings’microstructure and phase composition.The hardness,elastic modulus,and fracture toughness of coatings were tested,and the corrosion resistance was analyzed in simulated seawater.Results show that the hardness of the coating is HV0.1606.15,the modulus of elasticity is 128.42 GPa,and the fracture toughness is 43.98 MPa·m^(1/2).The corrosion potential of the coating in 3.5wt%NaCl solution is-0.49 V,and the corrosion current density is 1.2×10^(−6)A/cm^(2).The electrochemical system comprises three parts:the electrolyte,the adsorption and metallic oxide films produced during immersion,and the FeCoNiCrMo HEA coating.Over in-creasingly long periods,the corrosion reaction rate increases first and then decreases,the corrosion product film comprising metal oxides reaches a dynamic balance between formation and dissolution,and the internal reaction of the coating declines.

Effect of solution treatment on the microstructure,phase transformation behavior and functional properties of NiTiNb ternary shape memory alloys fabricated via laser powder bed fusion in-situ alloying

Post-heat treatment is commonly employed to improve the microstructural homogeneity and enhance the mechanical performances of the additively manufactured metallic materials.In this work,a ternary(NiTi)91Nb9(at.%)shape memory alloy was produced by laser powder bed fusion(L-PBF)using pre-alloyed NiTi and elemental Nb powders.The effect of solution treatment on the microstructure,phase transformation behavior and mechanical/functional performances was investigated.The in-situ alloyed(NiTi)91Nb9 alloy exhibits a submicron cellular-dendritic structure surrounding the supersaturated B2-NiTi matrix.Upon high-temperature(1273 K)solution treatment,Nb-rich precipitates were precipitated from the supersaturated matrix.The fragmentation and spheroidization of the NiTi/Nb eutectics occurred during solution treatment,leading to a morphological transition from mesh-like into rod-like and sphere-like.Coarsening of theβ-Nb phases occurred with increasing holding time.The martensite transformation temperature increases after solution treatment,mainly attributed to:(i)reduced lattice distortion due to the Nb expulsion from the supersaturated B2-NiTi,and(ii)the Ti expulsion from theβ-Nb phases that lowers the ratio Ni/Ti in the B2-NiTi matrix,which resulted from the microstructure changes from non-equilibrium to equilibrium state.The thermal hysteresis of the solutionized alloys is around 145 K after 20%pre-deformation,which is comparable to the conventional NiTiNb alloys.A short-term solution treatment(i.e.at 1273 K for 30 min)enhances the ductility and strength of the as-printed specimen,with the increase of fracture stress from(613±19)MPa to(781±20)MPa and the increase of fracture strain from(7.6±0.1)%to(9.5±0.4)%.Both the as-printed and solutionized samples exhibit good tensile shape memory effects with recovery rates>90%.This work suggests that post-process heat treatment is essential to optimize the microstructure and improve the mechanical performances of the L-PBF in-situ alloyed parts.

Review of Sc microalloying effects in Al-Cu alloys

Artificially controlling the solid-state precipitation in aluminum (Al) alloys is an efficient way to achieve well-performed properties,and the microalloying strategy is the most frequently adopted method for such a purpose.In this paper,recent advances in lengthscale-dependent scandium (Sc) microalloying effects in Al-Cu model alloys are reviewed.In coarse-grained Al-Cu alloys,the Sc-aided Cu/Sc/vacancies complexes that act as heterogeneous nuclei and Sc segregation at the θ′-Al_(2)Cu/matrix interface that reduces interfacial energy contribute significantly to θ′precipitation.By grain size refinement to the fine/ultrafine-grained scale,the strongly bonded Cu/Sc/vacancies complexes inhibit Cu and vacancy diffusing toward grain boundaries,promoting the desired intragranular θ′precipitation.At nanocrystalline scale,the applied high strain producing high-density vacancies results in the formation of a large quantity of (Cu Sc,vacancy)-rich atomic complexes with high thermal stability,outstandingly improving the strength/ductility synergy and preventing the intractable low-temperature precipitation.This review recommends the use of microalloying technology to modify the precipitation behaviors toward better combined mechanical properties and thermal stability in Al alloys.

Role of micro-Ca/In alloying in tailoring the microstructural characteristics and discharge performance of dilute Mg-Bi-Sn-based alloys as anodes for Mg-air batteries

The influence of micro-Ca/In alloying on the microstructural charac teristics,electrochemical behaviors and discharge properties of extruded dilute Mg-0.5Bi-0.5Sn-based(wt.%)alloys as anodes for Mg-air batteries are evaluated.The grain size and texture intensity of the Mg-Bi-Sn-based alloys are significantly decreased after the Ca/In alloying,particularly for the In-containing alloy.Note that,in addition to nanoscale Mg_(3)Bi_(2)phase,a new microscale Mg_(2)Bi_(2)Ca phase forms in the Ca-containing alloy.The electrochemical test results demonstrate that Ca/In micro-alloying can enhance the electrochemical activity.Using In to alloy the Mg-Bi-Sn-based alloy is effective in restricting the cathodic hydrogen evolution(CHE)kinetics,leading to a low self-corrosion rate,while severe CHE occurred after Ca alloying.The micro-alloying of Ca/In to Mg-Bi-Sn-based alloy strongly deteriorates the compactness of discharge products film and mitigates the"chunk effect"(CE),hence the cell voltage,anodic efficiency as well as discharge capacity are greatly improved.The In-containing alloy exhibits outstanding discharge performance under the combined effect of the modified microstructure and discharge products,thus making it a potential anode material for primary Mg-air battery.

Simultaneously improving thermal conductivity,mechanical properties and metal fluidity through Cu alloying in Mg-Zn-based alloys

Mg-Zn-based alloys have been widely used in computer,communication,and consumer(3C)products due to excellent thermal conductivity.However,it is still a challenge to balance their mechanical performance and thermal conductivity.Here,we investigate microstructure,mechanical performance,thermal conductivity and metal fluidity of Mg-5Zn(wt.%)alloy after Cu alloying by experimental and simulation methods.First,Mg-5Zn alloy consist ofα-Mg matrix and interdendritic MgZn phases.As the Cu content increases,however,MgZn phases disappear but intragranular Mg_(2)Cu and interdendritic MgZnCu phases appear in Mg-5Zn-Cu alloys.Besides,the grain size ofα-Mg phase is refined and the volume fraction of MgZnCu phase increases as the Cu content increases.Second,Cu addition is found to improve thermal conductivity of Mg-5Zn alloy remarkably.Especially,Mg-5Zn-4Cu alloy exhibits the best thermal conductivity of 124 W/(m·K),which is mainly due to the significant reduction in both solid solubility of Zn in theα-Mg matrix and lattice distortion ofα-Mg matrix.Moreover,a stable crystal structure of MgZnCu phase also contributes to an increased thermal conductivity based on first principles and molecular dynamics simulations.Third,Cu addition simultaneously enhances strength and ductility of Mg-5Zn alloy.Tensile yield strength and elongation of Mg-5Zn-6Cu alloy reach 117 MPa and 18.0%,respectively,which is a combined result of refinement,solution,second phase,and dislocation strengthening.Finally,combined with a phase field simulation,we found that Cu addition enhances metal fluidity of Mg-5Zn alloy.On the one hand,Cu alloying not only delays dendrite growth but also prolongs solidification time.On the other hand,MgZnCu phase stabilizes the dendrite growth of theα-Mg phases by reducing energy consumption during solidification of liquid metal.This work demonstrates that Cu alloying is an ideal strategy for synergistically improving the thermal conductivity,mechanical performance and metal fluidity of Mg-based alloys.

Mitigated reaction kinetics between lithium metal anodes and electrolytes by alloying lithium metal with low-content magnesium

Lithium(Li)metal is regarded as a promising anode candidate for high-energy-density rechargeable batteries.Nevertheless,Li metal is highly reactive against electrolytes,leading to rapid decay of active Li metal reservoir.Here,alloying Li metal with low-content magnesium(Mg)is proposed to mitigate the reaction kinetics between Li metal anodes and electrolytes.Mg atoms enter the lattice of Li atoms,forming solid solution due to the low amount(5 wt%)of Mg.Mg atoms mainly concentrate near the surface of Mg-alloyed Li metal anodes.The reactivity of Mg-alloyed Li metal is mitigated kinetically,which results from the electron transfer from Li to Mg atoms due to the electronegativity difference.Based on quantitative experimental analysis,the consumption rate of active Li and electrolytes is decreased by using Mgalloyed Li metal anodes,which increases the cycle life of Li metal batteries under demanding conditions.Further,a pouch cell(1.25 Ah)with Mg-alloyed Li metal anodes delivers an energy density of 340 Wh kg^(-1)and a cycle life of 100 cycles.This work inspires the strategy of modifying Li metal anodes to kinetically mitigate the side reactions with electrolytes.

N-S EQUATION CALCULATIONS ON MULTI-ELEMENT AIRFOILS WITH ZONAL PATCHED GRIDS

For a complex flow about multi-element airfoils a mixed grid method is set up. C-type grids are produced on each element′s body and in their wakes at first, O-type grids are given in the outmost area, and H-type grids are used in middle additional areas. An algebra method is used to produce the initial grids in each area. And the girds are optimized by elliptical differential equation method. Then C-O-H zonal patched grids around multi-element airfoils are produced automatically and efficiently. A time accurate finite-volume integration method is used to solve the compressible laminar and turbulent Navier-Stokes (N-S) equations on the grids. Computational results prove the method to be effective.

Monte Carlo simulation of reflection effects of multi-element materials on gamma rays

To study the effects of the gamma reflection of multi-element materials,gamma ray transport models of single-element materials,such as iron and lead,and multielement materials,such as polyethylene and ordinary concrete,were established in this study.Relationships among the albedo factors of the gamma photons and energies and average energy of the reflected gamma rays by material type,material thickness,incident gamma energy,and incidence angle of gamma rays were obtained by Monte Carlo simulation.The results show that the albedo factors of single-element and multi-element materials increase rapidly with an increase in the material thickness.When the thickness of the material increases to a certain value,the albedo factors do not increase further but rather tend to the saturation value.The saturation values for the albedo factors of the gamma photons,and energies and the reflection thickness are related not only to the type of material but also to the incident gamma energy and incidence angle of the gamma rays.At a given incident gamma energy,which is between 0.2 and 2.5 MeV,the smaller the effective atomic number of the multi-element material is,the higher the saturation values of the albedo factors are.The larger the incidence angle of the gamma ray is,the greater the saturation value of the gamma albedo factor,saturation reflection thickness,and average saturation energy of the reflected gamma photons are.

Effect of Heat Treatment on Electrical Conductivity of Multi-Element Cu Alloy

The effect of heat treatment on electrical conductivity of Cu alloy containing Ni, Al, and rare earth(Ce) alloying elements was studied by metallographic microscope, TEM, SEM/EDS and conductance instrument. The results indicate that heat treatment can improve the electrical conductivity of the material due to the reducing of the solid solution of Cr element in Cu matrix. The better conductivity was obtained after getting solid solution at 980 ℃ for 1 h, and then aging at 500 ℃ for 4 h.

Aerodynamic and Acoustic Optimization for Multi-element Airfoils

The paper is to integrate aerodynamic and aero-acoustic optimizatiom design of high lift devices,especially for two-element airfoils with slat.Aerodynamic analysis on flow field utilizes a high-order,high-resolution spatial differential method for large eddy simulation(LES),which can guarantee accuracy and efficiency.The aeroacoustic analysis for noise level is calculated with Ffowcs Williams-Hawkings(FW-H)integration formula.Fidelity of calculation is verified by standard models.Method of streamline-based Euler simulation(MSES)is used to obtain the aerodynamic characters.Based on the confirmation of numerical methods,detailed research has been conducted for the leading edge slat on multi-element airfoils.Various slot parameter influences on noise are analyzed.The results of the slot optimization parameters can be used in multi-element airfoil design.

A DDoS Attack Information Fusion Method Based on CNN for Multi-Element Data

Traditional distributed denial of service(DDoS)detection methods need a lot of computing resource,and many of them which are based on single element have high missing rate and false alarm rate.In order to solve the problems,this paper proposes a DDoS attack information fusion method based on CNN for multi-element data.Firstly,according to the distribution,concentration and high traffic abruptness of DDoS attacks,this paper defines six features which are respectively obtained from the elements of source IP address,destination IP address,source port,destination port,packet size and the number of IP packets.Then,we propose feature weight calculation algorithm based on principal component analysis to measure the importance of different features in different network environment.The algorithm of weighted multi-element feature fusion proposed in this paper is used to fuse different features,and obtain multi-element fusion feature(MEFF)value.Finally,the DDoS attack information fusion classification model is established by using convolutional neural network and support vector machine respectively based on the MEFF time series.Experimental results show that the information fusion method proposed can effectively fuse multi-element data,reduce the missing rate and total error rate,memory resource consumption,running time,and improve the detection rate.

Identifying Pathfinder Elements for Gold in Multi-Element Soil Geochemical Data from the Wa-Lawra Belt, Northwest Ghana: A Multivariate Statistical Approach

A multivariate statistical analysis was performed on multi-element soil geochemical data from the Koda Hill-Bulenga gold prospects in the Wa-Lawra gold belt, northwest Ghana. The objectives of the study were to define gold relationships with other trace elements to determine possible pathfinder elements for gold from the soil geochemical data. The study focused on seven elements, namely, Au, Fe, Pb, Mn, Ag, As and Cu. Factor analysis and hierarchical cluster analysis were performed on the analyzed samples. Factor analysis explained 79.093% of the total variance of the data through three factors. This had the gold factor being factor 3, having associations of copper, iron, lead and manganese and accounting for 20.903% of the total variance. From hierarchical clustering, gold was also observed to be clustering with lead, copper, arsenic and silver. There was further indication that, gold concentrations were lower than that of its associations. It can be inferred from the results that, the occurrence of gold and its associated elements can be linked to both primary dispersion from underlying rocks and secondary processes such as lateritization. This data shows that Fe and Mn strongly associated with gold, and alongside Pb, Ag, As and Cu, these elements can be used as pathfinders for gold in the area, with ferruginous zones as targets.

Effect of Al and Sc on deformation behavior of FeCoNi multi-element alloys

The effects of Al and Sc on mechanical properties of FeCoNi multi-element alloys(MEAs) were investigated by compressive tests. The microstructures of FeCoNi MEAs with different contents of Al and Sc were characterized and the strengthening mechanisms were discussed. The results show that FeCoNi MEA with a low content of Al has a face-centered cubic(FCC) structure. The yield strength increases linearly with the increase of Al content, which is largely caused by solid solution hardening. Further addition of Sc can promote the formation of a new phase in(FeCoNi)1-xAlx MEAs. A minor addition of Sc can significantly increase the yield strengths of(FeCoNi)1-xAlx MEAs with a low Al content and improve the compressive plasticity of(FeCoNi)1-xAlx MEAs with a high Al content.

Exploratory Data Analysis Applied in Mapping Multi-element Soil Geochemical Anomalies for Drill Target Definition:A Case Study from the Unpha Layered Non-magmatic Hydrothermal Pb-Zn Deposit,DPR Korea

A factor analysis was applied to soil geochemical data to define anomalies related to buried Pb-Zn mineralization.A favorable main factor with a strong association of the elements Zn,Cu and Pb,related to mineralization,was selected for interpretation.The median+2 MAD(median absolute deviation)method of exploratory data analysis(EDA)and C-A(concentration-area)fractal modeling were then applied to the Mahalanobis distance,as defined by Zn,Cu and Pb from the factor analysis to set the thresholds for defining multi-element anomalies.As a result,the median+2 MAD method more successfully identified the Pb-Zn mineralization than the C-A fractal model.The soil anomaly identified by the median+2 MAD method on the Mahalanobis distances defined by three principal elements(Zn,Cu and Pb)rather than thirteen elements(Co,Zn,Cu,V,Mo,Ni,Cr,Mn,Pb,Ba,Sr,Zr and Ti)was the more favorable reflection of the ore body.The identified soil geochemical anomalies were compared with the in situ economic Pb-Zn ore bodies for validation.The results showed that the median+2 MAD approach is capable of mapping both strong and weak geochemical anomalies related to buried Pb-Zn mineralization,which is therefore useful at the reconnaissance drilling stage.

Geochemical analysis of multi-element in archaeological soils from Tappe Rivi in Northeast Iran

Multi-element analysis in historical sites is a major issue in archaeological studies;however,this approach is almost unknown among Iranian scholars.Geochemical multi-element analysis of soil is very important to evaluate anthropogenic activities.The aim of this study consists of assessing the potential usefulness of multi-elemental soil analysis,obtained by Analytical Jena atomic absorption spectrophotometer(AAS) and ICP-MS,to recognize ancient anthropogenic features on the territory of Tappe Rivi(North Khorasan,Iran).For that purpose,a total of 80 ancient soil samples were sampled from each soil horizon and cultural layer.The research involved Fe,Al,Cd,Cu,Ni,Co,Cr,Pb,and P which trace element samples were extracted according to the International Standard ISO 11466 and phosphorus samples by Olsen method.Besides,the contamination of the soils was assessed based on enrichment factors(EFs) by using Fe as a reference element.This geochemical/archaeological approach highlights that the content of most elements in the Parthian and Sassanid ages were significantly higher than the contents of the elements in other zones,which shows that by the development of the eras,the content of the elements has also increased.Also,the accumulation of metals in the Rivi site was significantly higher than in the control area.Among the sampled zones,enrichment factor(EF) indicated that the enrichment of Cu and phosphate at the Parthian and Sassanid had the highest content.This result is important because it shows that the amount of metals and human activities are directly related to each other during different ages.