The method of energy dispersion in magnetic field is used to analyze the energy spread of the triple-pulse electron beam generated by the Dragon-II linear induction accelerator.A sector magnet is applied for energy an...The method of energy dispersion in magnetic field is used to analyze the energy spread of the triple-pulse electron beam generated by the Dragon-II linear induction accelerator.A sector magnet is applied for energy analysis of the electron beam,with a bending radius of 300 mm and a deflection angle of 90°.For each pulse,the time-resolved and integral images of the electron position at the output port of beam-bending line are recorded by a streak camera and a CCD camera,respectively.Experimental results demonstrate an energy spread of less than ±2.0%for the electron pulses.The cavity voltage waveforms obtained by different detectors are also analyzed for comparison.展开更多
The variations in the wave energy and the amplitude along the energy dispersion paths of the barotropic Rossby waves in zonally symmetric basic flow are studied by solving the wave energy equation,which expresses that...The variations in the wave energy and the amplitude along the energy dispersion paths of the barotropic Rossby waves in zonally symmetric basic flow are studied by solving the wave energy equation,which expresses that the wave energy variability is determined by the divergence of the group velocity and the energy budget from the basic flow.The results suggest that both the wave energy and the amplitude of a leading wave increase significantly in the propagating region that is located south of the jet axis and enclosed by a southern critical line and a northern turning latitude.The leading wave gains the barotropic energy from the basic flow by eddy activities.The amplitude continuously climbs up a peak at the turning latitude due to increasing wave energy and enlarging horizontal scale(shrinking total wavenumber).Both the wave energy and the amplitude eventually decrease when the trailing wave continuously approaches southward to the critical line.The trailing wave decays and its energy is continuously absorbed by the basic flow.Furthermore,both the wave energy and the amplitude oscillate with a limited range in the propagating region that is located near the jet axis and enclosed by two turning latitudes.Both the leading and trailing waves neither develop nor decay significantly.The jet works as a waveguide to allow the waves to propagate a long distance.展开更多
To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantit...To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantitative analysis of pyrite materials.Additionally,the k factor of pyrite is calculated experimentally.To develop an appropriate non-standard quantitative analysis model for pyrite materials,the experimentally calculated k factor is compared with that estimated from the non-standard quantitative analytical model of the instrument software.The experimental findings demonstrate that the EDS attached to a TEM can be employed for precise quantitative analysis of micro-and nanoscale regions of pyrite materials.Furthermore,it serves as a reference for improving the results of the EDS quantitative analysis of other sulfides.展开更多
Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic activity.For example,in...Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic activity.For example,increasing the binding of the*COOH to the active site will generally increase the*CO desorption energy.Breaking this relationship may be expected to dramatically improve the intrinsic activity of CO_(2)RR,but remains an unsolved challenge.Herein,we addressed this conundrum by constructing a unique atomic dispersed hetero-pair consisting of Mo-Fe di-atoms anchored on N-doped carbon carrier.This system shows an unprecedented CO_(2)RR intrinsic activity with TOF of 3336 h−1,high selectivity toward CO production,Faradaic efficiency of 95.96%at−0.60 V and excellent stability.Theoretical calculations show that the Mo-Fe diatomic sites increased the*COOH intermediate adsorption energy by bridging adsorption of*COOH intermediates.At the same time,d-d orbital coupling in the Mo-Fe di-atom results in electron delocalization and facilitates desorption of*CO intermediates.Thus,the undesirable correlation between these steps is broken.This work provides a promising approach,specifically the use of di-atoms,for breaking unfavorable relationships based on understanding of the catalytic mechanisms at the atomic scale.展开更多
The three-dimensional nonlinear quasi-geostrophic potential vorticity equation is reduced to a linear form in the stream function in spherical coordinates for the permanent wave solutions consisting of zonal wavenumbe...The three-dimensional nonlinear quasi-geostrophic potential vorticity equation is reduced to a linear form in the stream function in spherical coordinates for the permanent wave solutions consisting of zonal wavenumbers from 0 to n and rn vertical components with a given degree n.This equation is solved by treating the coefficient of the Coriolis parameter square in the equation as the eigenvalue both for sinusoidal and hyperbolic variations in vertical direction. It is found that these solutions can represent the observed long term flow patterns at the surface and aloft over the globe closely. In addition, the sinusoidal vertical solutions with large eigenvalue G are trapped in low latitude,and the scales of these trapped modes are longer than 10 deg. lat. even for the top layer of the ocean and hence they are much larger than that given by the equatorial β-plane solutions.Therefore such baroclinic disturbances in the ocean can easily interact with those in the atmosphere.Solutions of the shallow water potential vorticity equation are treated in a similar manner but with the effective depth H=RT/g taken as limited within a small range for the atmosphere.The propagation of the flow energy of the wave packet consisting of more than one degree is found to be along the great circle around the globe both for barotropic and for baroclinic flows in the atmosphere.展开更多
Variations in wave energy and amplitude for Rossby waves are investigated by solving the wave energy equation for the quasigeostrophic barotropic potential vorticity model.The results suggest that compared with rays i...Variations in wave energy and amplitude for Rossby waves are investigated by solving the wave energy equation for the quasigeostrophic barotropic potential vorticity model.The results suggest that compared with rays in the nondivergent barotropic model,rays in the divergent model can have enhanced meridional and zonal propagation,accompanied by a more dramatic variability in both wave energy and amplitude,which is caused by introducing the divergence effect of the free surface in the quasigeostrophic model.For rays propagating in a region enclosed by a turning latitude and a critical latitude,the wave energy approaches the maximum value inside the region,while the amplitude approaches the maximum at the turning latitude.Waves can develop when both the wave energy and amplitude increase.For rays propagating in a region enclosed by two turning latitudes,the wave energy approaches the minimum value at one turning latitude and the maximum value at the other latitude,while the total wavenumber approaches the maximum value inside the region.The resulting amplitude increases if the total wavenumber decreases or the wave energy increases more significantly and decreases if the total wavenumber increases or the wave energy decreases more significantly.The matched roles of the energy from the basic flow and the divergence of the group velocity contribute to the slightly oscillating wave energy,which causes a slightly oscillating amplitude as well as the slightly oscillating total wavenumber.展开更多
An electromagnetic parametrically excited rolling pendulum energy harvester with self-tuning mechanisms subject to multi-frequency excitation is proposed and investigated in this paper.The system consists of two uncou...An electromagnetic parametrically excited rolling pendulum energy harvester with self-tuning mechanisms subject to multi-frequency excitation is proposed and investigated in this paper.The system consists of two uncoupled rolling pendulum.The resonance frequency of each the rolling pendulum can be automatically tuned by adjusting its geometric parameters to access parametric resonance.This harvester can be used to harvest the energy at low frequency.A prototype is developed and evaluated.Its mathematical model is derived.A cam with rolling follower mechanism is employed to generate multi-frequency excitation.An experimental study is conducted to validate the proposed concept.The experimental results are confirmed by the numerical results.The harvester is successfully tuned when the angular velocity of the cam is changed from 1.149 to 1.236 Hz.展开更多
The interaction between tropical cyclone(TC)and the large-scale mean flows such as the inter-tropical convergence zone(ITCZ)is investigated using a three-dimensional primitive equation model.Once a TC develops in the ...The interaction between tropical cyclone(TC)and the large-scale mean flows such as the inter-tropical convergence zone(ITCZ)is investigated using a three-dimensional primitive equation model.Once a TC develops in the vicinity of the ITCZ region where satisfies both barotropic and baroclinic instabilities,the southeastward energy dispersion from the TC may disturb the ITCZ and thus help its breakdown.Cumulus convection can be organized in the region of cyclonic circulation,and the interaction between convective heating and the perturbation circulation may enhance the development of the waves,leading to the generation of a new tropical cyclone to the east.While the TC moves to the high latitude,the ITCZ will reform.Though repeating of this process,a synoptic-scale wave train oriented in the northwest-southeast direction can be generated and self-maintained.The results suggest that the mutual interaction among the low-frequency background flow,wave train pattern and TCs provides a possible mechanism for the origin of the summer synoptic scale wave train pattern over the western North Pacific.展开更多
For the first time, we derive the dispersion energy for a molecule which involves the anisotropic dipole interaction by virtue of the invariant eigen-operator method, which greatly simplifies the usual calculation if ...For the first time, we derive the dispersion energy for a molecule which involves the anisotropic dipole interaction by virtue of the invariant eigen-operator method, which greatly simplifies the usual calculation if one uses the Schroedinger equation.展开更多
Nuclear energy is a low-carbon,safe,efficient,and sustainable clean energy.The new generation of nuclear energy systems operate in harsher environments under higher working temperatures and irradiation doses,while tra...Nuclear energy is a low-carbon,safe,efficient,and sustainable clean energy.The new generation of nuclear energy systems operate in harsher environments under higher working temperatures and irradiation doses,while traditional nuclear power materials cannot meet the requirements.The development of high-performance nuclear power materials is a key factor for promoting the development of nuclear energy.Oxide dispersion strengthened(ODS)steel contains a high number density of dispersed nano-oxides and defect sinks and exhibits excellent high temperature creep performance and irradiation swelling resistance.Therefore,ODS steel has been considered as one of the most promising candidate materials for fourth-generation nuclear fission reactor cladding tubes and nuclear fusion reactor blankets.The preparation process significantly influences microstructure of ODS steel.This paper reviews the development and perspective of several preparation processes of ODS steel,including the powder metallurgy process,improved powder metallurgy process,liquid metal forming process,hybrid process,and additive forging.This paper also summarizes and analyzes the relationship between microstructures and the preparation process.After comprehensive consideration,the powder metallurgy process is still the best preparation process for ODS steel.Combining the advantages and disadvantages of the above preparation processes,the trend applied additive forging for extreme manufacturing of large ODS steel components is discussed with the goal of providing a reference for the application and development of ODS steel in nuclear energy.展开更多
The optical reflectance and transmittance spectra in the wavelength range of 300-2500 nm are used to compute the absorption coefficient of zinc oxide films annealed at different post-annealing temperatures 400, 500 an...The optical reflectance and transmittance spectra in the wavelength range of 300-2500 nm are used to compute the absorption coefficient of zinc oxide films annealed at different post-annealing temperatures 400, 500 and 600°C.The values of the cross point between the curves of the real and imaginary parts of the optical conductivity ɑ_1 and ɑ_1 with energy axis of films exhibit values that correspond to optical gaps and are about 3.25-3.3 eV. The maxima of peaks in plots dR/dλ and dT/dλ versus wavelength of films exhibit optical gaps at about 3.12-3.25 eV.The values of the fundamental indirect band gap obtained from the Tauc model are at about 3.14-3.2 eV. It can be seen that films annealed at 600°C have the minimum indirect optical band gap at about 3.15 eV. The films annealed at 600°C have Urbach's energy minimum of 1.38 eV and hence have minimum disorder. The dispersion energy d of films annealed at 500°C has the minimum value of 43 eV.展开更多
This paper presents a comparative study on Magnetic-Dispersion based Energy Harvesting Systems (MD-EHS) on electrical conductors that supply power for a three-phase AC motor. It introduces two MD-EHS which are based o...This paper presents a comparative study on Magnetic-Dispersion based Energy Harvesting Systems (MD-EHS) on electrical conductors that supply power for a three-phase AC motor. It introduces two MD-EHS which are based on magnetic cores of different material, named, nanocrystalline, ferrite and iron powder. The first one consists of harvesting energy from magnetic flux through three symmetrical magnetic cores installed on each power conductors of a three-phase AC motor. The second one consists of a single magnetic core for harvesting energy from magnetic flux of only one of these conductors. Both ones have an AC/DC converter and a variable resistor based load. Experimental results have agreed with the theoretical analysis and show that the first proposed MD-EHS is capable of supplying 14 times more energy than the second MD-EHS, considering nanocrystalline cores and phase current of 3 A, and 7.5 times more energy, considering ferrite cores and phase current of 9 A. Such energy can be applied to various low-power devices, especially in wireless sensor network.展开更多
Mine disasters occur predominantly due to methane or coal dust explosion or a combination of both.Among the top ten worst coal mine disasters in India, nine are due to coal dust explosion. The current paper describes ...Mine disasters occur predominantly due to methane or coal dust explosion or a combination of both.Among the top ten worst coal mine disasters in India, nine are due to coal dust explosion. The current paper describes a general overview of the parameters causing dispersion leading to coal dust explosion,and computational fluid dynamics(CFD) simulation study to observe the effects of particle size on dispersion in Indian coal mines. Turbulent kinetic energy(TKE) and velocity vector path of dust-air mixture and dust-free air were simulated to understand their effects on coal dust dispersion. The TKE contours and velocity vector paths for dust-free air were uniform and symmetrical due to resistance-free path available. The TKE contours and velocity vector paths for dust-air mixture shows the asymmetrical distribution of contours, due to entrainment of air with dust particles. Vortices were observed in velocity vector paths which gradually diminish on increment of time sequence. These vortices are dead centres where velocity and coal dust particles concentration are both zero.展开更多
Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, ...Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, concentrations average in mg/L of metals such Fe (0.731), Mn (0.345), Cr (0.070), Cu (0.014) and concentrations of nutrients known to be pollutants and toxic for living or-ganisms. These heavy metals are dangerous to the lives, the local inhabitants and also a threat to aquatic life since this water is essential for the economical town, Abidjan. According to the Manganese concentration average (0.345 mg) values that higher than WHO (0.05 mg) value, the main likely source of pollu-tants is anthropogenic, industrial and agricultural. This study also shows the use of materials and lubricants near the lagoon that pollute this water.展开更多
A kind of excellent CdZnTe crystal has been grown in Yinnel Tech, Inc. in recent years. Based on these CdZnTe crystals and some new techniques, a portable energy-dispersive spectrometer has been constructed which has ...A kind of excellent CdZnTe crystal has been grown in Yinnel Tech, Inc. in recent years. Based on these CdZnTe crystals and some new techniques, a portable energy-dispersive spectrometer has been constructed which has yielded good results. CdZnTe detector has a 3% relative resolution in high-energy field and can detect gamma rays at room temperature. An integrated circuit based on preamplifier and shaping amplifier chips is connected to the detector. Voltage pulses are transformed into digital signals in MCA (multichannel analyzer) and are then transmitted to com- puter via USB bus. Data process algorithms are improved in this spectrometer. Fast Fourier transform (FFT) and nu- merical differentiation (ND) are used in energy peak’s searching program. Sampling-based correction technique is used in X-ray energy calibration. Modified Gaussian-Newton algorithm is a classical method to solve nonlinear curve fitting problems, and it is used to compute absolute intensity of each detected characteristic line.展开更多
BACKGROUND: Alpha-actinin ( a -actinin) plays a key role in neuronal growth cone migration during directional differentiation from neural stem cells (NSCs) to neurons. OBJECTIVE: To detect in situ microdistribut...BACKGROUND: Alpha-actinin ( a -actinin) plays a key role in neuronal growth cone migration during directional differentiation from neural stem cells (NSCs) to neurons. OBJECTIVE: To detect in situ microdistribution and quantitative expression of a -actinin during directional differentiation of NSCs to neurons in the temporal lobe cerebral cortex of neonatal rats. DESIGN, TIME AND SETTING: Between January 2006 and December 2008, culture and directional differentiation of NSCs were performed at Department of Histology and Embryology, Preclinical Medical College, China Medical University. Immune electron microscopy was performed at Department of Histology and Embryology and Department of Electron Micrology, Preclinical Medical College, China Medical University. Spectrum analysis was performed at Laboratory of Electron Microscopy, Mental Research Institute, Chinese Academy of Sciences. MATERIALS: Basic fibroblast growth factor, epidermal growth factor, brain-derived nerve growth factor, type-1 insulin like growth factor, and a -actinin antibody were provided by Gibco BRL, USA; rabbit-anti-rat nestin monoclonal antibody, rabbit-anti-rat neuron specific enolase polyclonal antibody, and EDAX-9100 energy dispersive X-ray analysis were provided by PHILIPS Company, Netherlands. METHODS: NSCs, following primary and passage culture, were differentiated with serum culture medium (DMEM/F12 + 10% fetal bovine serum + 2 ng/mL brain-derived nerve growth factor + 2 ng/mL type-1 insulin like growth factor). MAIN OUTCOME MEASURES: Expression of a -actinin in neuron-like cells was quantitatively and qualitatively detected with immunocytochemistry using energy dispersive X-ray analysis. RESULTS: Immunocytochemistry, combined with electron microscopy, indicated that positive α -actinin expression was like a spheroid particle with high electron density. In addition, the expression was gradually concentrated from the nuclear edge to the cytoplasm and expanded into developing neurites, during differentiation of neural stem cells to neurons. Conversely, energy dispersive X-ray analysis indicated that the more mature the neural differentiation was, and the greater the expression of α -actinin. CONCLUSION: The gradual increase of α -actinin expression is related to growth, development, and maturity of differentiated neuron-like cells, in neonatal rat frontal lobe cortex, at different differentiating time points of NSCs to neurons.展开更多
The full-spectrum least-squares(FSLS) method is introduced to perform quantitative energy-dispersive X-ray fluorescence analysis for unknown solid samples.Based on the conventional least-squares principle, this spectr...The full-spectrum least-squares(FSLS) method is introduced to perform quantitative energy-dispersive X-ray fluorescence analysis for unknown solid samples.Based on the conventional least-squares principle, this spectrum evaluation method is able to obtain the background-corrected and interference-free net peaks, which is significant for quantization analyses. A variety of analytical parameters and functions to describe the features of the fluorescence spectra of pure elements are used and established, such as the mass absorption coefficient, the Gi factor, and fundamental fluorescence formulas. The FSLS iterative program was compiled in the C language. The content of each component should reach the convergence criterion at the end of the calculations. After a basic theory analysis and experimental preparation, 13 national standard soil samples were detected using a spectrometer to test the feasibility of using the algorithm. The results show that the calculated contents of Ti, Fe, Ni, Cu, and Zn have the same changing tendency as the corresponding standard content in the 13 reference samples. Accuracies of 0.35% and 14.03% are obtained, respectively, for Fe and Ti, whose standard concentrations are 8.82% and 0.578%, respectively. However, the calculated results of trace elements (only tens of lg/g) deviate from the standard values. This may be because of measurement accuracy and mutual effects between the elements.展开更多
A facility and method for109 Cd radionuclide-induced energy-dispersive X-ray fluorescent(EDXRF) were developed to determine the Fe,Zn,Br,Rb,and Sr concentrations in the specimens of human prostatic fluid.Specimens of ...A facility and method for109 Cd radionuclide-induced energy-dispersive X-ray fluorescent(EDXRF) were developed to determine the Fe,Zn,Br,Rb,and Sr concentrations in the specimens of human prostatic fluid.Specimens of expressed prostatic fluid were obtained from 51 men(mean age 51 years,range 18–82 years) with apparently normal prostates using standard rectal massage procedure.Mean values(M ± SEL) for concentration of trace elements(mg L^(-1)) in human prostate fluid were:Fe 9.04 ±1.21,Zn 573 ± 35,Br 3.58 ± 0.59,Rb 1.10 ± 0.08,and Sr B 0.76.It was shown that the results of trace element analysis in the micro-samples(20 l L) are sufficiently representative for assessment of the Fe,Zn,Br,and Rb concentration in the prostate fluid.The facility for109 Cd radionuclide-induced EDXRF is comparatively compact and can be located in close proximity to the site of carrying out the massage procedure.The means of Zn and Rb concentration obtained for prostate fluid agree well with median of reported means.For the first time,the Fe and Br concentrations,as well as the upper limit of the Sr concentration,were determined in the human prostate fluid.展开更多
Transmission electron microscopy (TEM) is a very powerful technique for materials characteriza-tion, providing information relating to morphology, composition, and crystal structure. Selected area diffraction patterns...Transmission electron microscopy (TEM) is a very powerful technique for materials characteriza-tion, providing information relating to morphology, composition, and crystal structure. Selected area diffraction patterns (SADPs) are crystallographic data that can be obtained using a TEM in-strument. Conventional identification through SADP/TEM is tricky and tedious, thereby increasing the difficulty of phase identification. To establish a procedure for phase identification of known and unknown phases, in this study we examined two samples: one, a known phase, was Si with alignment;the other, unknown, was the TixOy phase at the 96.4Au-3Ni-0.6Ti interlayer/ yttria-stabilized zirconia (YSZ) interface of a steel/96.4Au-3Ni-0.6Ti interlayer/YSZ joint. The procedures for phase identification of the known and unknown phases are described herein using a series of SADPs and energy dispersive spectrometry within TEM that would be useful for general researchers.展开更多
Ashcroft's local empty core (EMC) model pseudopotential in the second-order perturbation theory is used to study the electron dispersion relation, the Fermi energy, and deviation in the Fermi energy from free elect...Ashcroft's local empty core (EMC) model pseudopotential in the second-order perturbation theory is used to study the electron dispersion relation, the Fermi energy, and deviation in the Fermi energy from free electron value for the liquid alkali metals and their equiatomic binary alloys for the first time. In the present computation, the use of pseudo-alloy-atom model (PAA) is proposed and found successful. The influence of the six different forms of the local field correction functions proposed by Hartree (H), Vashishta Singwi (VS), Taylor (T), lehimaru-Utsumi (IU), Farid et al. (F), and Sarkar et al. (S) on the aforesaid electronic properties is examined explicitly, which reflects the varying effects of screening. The depth of the negative hump in the electron dispersion of liquid alkalis decreases in the order Li --→ K, except for Rb and Cs, it increases. The results of alloys are in predictive nature.展开更多
文摘The method of energy dispersion in magnetic field is used to analyze the energy spread of the triple-pulse electron beam generated by the Dragon-II linear induction accelerator.A sector magnet is applied for energy analysis of the electron beam,with a bending radius of 300 mm and a deflection angle of 90°.For each pulse,the time-resolved and integral images of the electron position at the output port of beam-bending line are recorded by a streak camera and a CCD camera,respectively.Experimental results demonstrate an energy spread of less than ±2.0%for the electron pulses.The cavity voltage waveforms obtained by different detectors are also analyzed for comparison.
基金This study was jointly funded by the National Natural Science Foundation of China(Grant Nos.41505042 and 41805041)the National Program on Global Change and Air−Sea Interaction(Grant No.GASI-IPOVAI-03)+1 种基金the National Basic Research Program of China(Grant Nos.2015CB953601 and 2014CB953903)the Fundamental Research Funds for the Central Universities.
文摘The variations in the wave energy and the amplitude along the energy dispersion paths of the barotropic Rossby waves in zonally symmetric basic flow are studied by solving the wave energy equation,which expresses that the wave energy variability is determined by the divergence of the group velocity and the energy budget from the basic flow.The results suggest that both the wave energy and the amplitude of a leading wave increase significantly in the propagating region that is located south of the jet axis and enclosed by a southern critical line and a northern turning latitude.The leading wave gains the barotropic energy from the basic flow by eddy activities.The amplitude continuously climbs up a peak at the turning latitude due to increasing wave energy and enlarging horizontal scale(shrinking total wavenumber).Both the wave energy and the amplitude eventually decrease when the trailing wave continuously approaches southward to the critical line.The trailing wave decays and its energy is continuously absorbed by the basic flow.Furthermore,both the wave energy and the amplitude oscillate with a limited range in the propagating region that is located near the jet axis and enclosed by two turning latitudes.Both the leading and trailing waves neither develop nor decay significantly.The jet works as a waveguide to allow the waves to propagate a long distance.
基金Funded by the International Science&Technology Cooperation Program of Hubei Province of China(No.2022EHB024)。
文摘To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantitative analysis of pyrite materials.Additionally,the k factor of pyrite is calculated experimentally.To develop an appropriate non-standard quantitative analysis model for pyrite materials,the experimentally calculated k factor is compared with that estimated from the non-standard quantitative analytical model of the instrument software.The experimental findings demonstrate that the EDS attached to a TEM can be employed for precise quantitative analysis of micro-and nanoscale regions of pyrite materials.Furthermore,it serves as a reference for improving the results of the EDS quantitative analysis of other sulfides.
基金the National Natural Science Foundation of China(22279044,12034002,and 22202080)the Project for Self-Innovation Capability Construction of Jilin Province Development and Reform Commission(2021C026)+1 种基金Jilin Province Science and Technology Development Program(20210301009GX)the Fundamental Research Funds for the Central Universities.
文摘Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic activity.For example,increasing the binding of the*COOH to the active site will generally increase the*CO desorption energy.Breaking this relationship may be expected to dramatically improve the intrinsic activity of CO_(2)RR,but remains an unsolved challenge.Herein,we addressed this conundrum by constructing a unique atomic dispersed hetero-pair consisting of Mo-Fe di-atoms anchored on N-doped carbon carrier.This system shows an unprecedented CO_(2)RR intrinsic activity with TOF of 3336 h−1,high selectivity toward CO production,Faradaic efficiency of 95.96%at−0.60 V and excellent stability.Theoretical calculations show that the Mo-Fe diatomic sites increased the*COOH intermediate adsorption energy by bridging adsorption of*COOH intermediates.At the same time,d-d orbital coupling in the Mo-Fe di-atom results in electron delocalization and facilitates desorption of*CO intermediates.Thus,the undesirable correlation between these steps is broken.This work provides a promising approach,specifically the use of di-atoms,for breaking unfavorable relationships based on understanding of the catalytic mechanisms at the atomic scale.
文摘The three-dimensional nonlinear quasi-geostrophic potential vorticity equation is reduced to a linear form in the stream function in spherical coordinates for the permanent wave solutions consisting of zonal wavenumbers from 0 to n and rn vertical components with a given degree n.This equation is solved by treating the coefficient of the Coriolis parameter square in the equation as the eigenvalue both for sinusoidal and hyperbolic variations in vertical direction. It is found that these solutions can represent the observed long term flow patterns at the surface and aloft over the globe closely. In addition, the sinusoidal vertical solutions with large eigenvalue G are trapped in low latitude,and the scales of these trapped modes are longer than 10 deg. lat. even for the top layer of the ocean and hence they are much larger than that given by the equatorial β-plane solutions.Therefore such baroclinic disturbances in the ocean can easily interact with those in the atmosphere.Solutions of the shallow water potential vorticity equation are treated in a similar manner but with the effective depth H=RT/g taken as limited within a small range for the atmosphere.The propagation of the flow energy of the wave packet consisting of more than one degree is found to be along the great circle around the globe both for barotropic and for baroclinic flows in the atmosphere.
基金This study was jointly funded by the National Natural Science Foundation of China(Grant Nos.41805041 and 41505042)the National Program on Global Change and Air-Sea Interaction(GASI-IPOVAI-03)+1 种基金the National Basis Research Program of China(2015CB953601 and 2014CB953903)the Fundamental Research Funds for the Central Universities.
文摘Variations in wave energy and amplitude for Rossby waves are investigated by solving the wave energy equation for the quasigeostrophic barotropic potential vorticity model.The results suggest that compared with rays in the nondivergent barotropic model,rays in the divergent model can have enhanced meridional and zonal propagation,accompanied by a more dramatic variability in both wave energy and amplitude,which is caused by introducing the divergence effect of the free surface in the quasigeostrophic model.For rays propagating in a region enclosed by a turning latitude and a critical latitude,the wave energy approaches the maximum value inside the region,while the amplitude approaches the maximum at the turning latitude.Waves can develop when both the wave energy and amplitude increase.For rays propagating in a region enclosed by two turning latitudes,the wave energy approaches the minimum value at one turning latitude and the maximum value at the other latitude,while the total wavenumber approaches the maximum value inside the region.The resulting amplitude increases if the total wavenumber decreases or the wave energy increases more significantly and decreases if the total wavenumber increases or the wave energy decreases more significantly.The matched roles of the energy from the basic flow and the divergence of the group velocity contribute to the slightly oscillating wave energy,which causes a slightly oscillating amplitude as well as the slightly oscillating total wavenumber.
文摘An electromagnetic parametrically excited rolling pendulum energy harvester with self-tuning mechanisms subject to multi-frequency excitation is proposed and investigated in this paper.The system consists of two uncoupled rolling pendulum.The resonance frequency of each the rolling pendulum can be automatically tuned by adjusting its geometric parameters to access parametric resonance.This harvester can be used to harvest the energy at low frequency.A prototype is developed and evaluated.Its mathematical model is derived.A cam with rolling follower mechanism is employed to generate multi-frequency excitation.An experimental study is conducted to validate the proposed concept.The experimental results are confirmed by the numerical results.The harvester is successfully tuned when the angular velocity of the cam is changed from 1.149 to 1.236 Hz.
基金the National Key Basic Research Program of China(2015CB452803)the Key University Science Research Project of Jiangsu Province(14KJA170005)
文摘The interaction between tropical cyclone(TC)and the large-scale mean flows such as the inter-tropical convergence zone(ITCZ)is investigated using a three-dimensional primitive equation model.Once a TC develops in the vicinity of the ITCZ region where satisfies both barotropic and baroclinic instabilities,the southeastward energy dispersion from the TC may disturb the ITCZ and thus help its breakdown.Cumulus convection can be organized in the region of cyclonic circulation,and the interaction between convective heating and the perturbation circulation may enhance the development of the waves,leading to the generation of a new tropical cyclone to the east.While the TC moves to the high latitude,the ITCZ will reform.Though repeating of this process,a synoptic-scale wave train oriented in the northwest-southeast direction can be generated and self-maintained.The results suggest that the mutual interaction among the low-frequency background flow,wave train pattern and TCs provides a possible mechanism for the origin of the summer synoptic scale wave train pattern over the western North Pacific.
基金The project supported by the President Foundation of the Chinese Academy of Sciences and National Natural Science Foundation of China under Grant No. 10475056.
文摘For the first time, we derive the dispersion energy for a molecule which involves the anisotropic dipole interaction by virtue of the invariant eigen-operator method, which greatly simplifies the usual calculation if one uses the Schroedinger equation.
基金supported by the National Key Research and Development Program[Grant No.2018YFA0702900]the National Natural Science Foundation of China[Grant No.51774265]+4 种基金the National Science and Technology Major Project of China[Grant No.2019ZX06004010]the Strategic Priority Research Program of the Chinese Academy of Sciences[Grant No.XDC04000000]Ling Chuang Research Project of China National Nuclear CorporationProgram of CAS Interdisciplinary Innovation TeamYouth Innovation Promotion Association,CAS。
文摘Nuclear energy is a low-carbon,safe,efficient,and sustainable clean energy.The new generation of nuclear energy systems operate in harsher environments under higher working temperatures and irradiation doses,while traditional nuclear power materials cannot meet the requirements.The development of high-performance nuclear power materials is a key factor for promoting the development of nuclear energy.Oxide dispersion strengthened(ODS)steel contains a high number density of dispersed nano-oxides and defect sinks and exhibits excellent high temperature creep performance and irradiation swelling resistance.Therefore,ODS steel has been considered as one of the most promising candidate materials for fourth-generation nuclear fission reactor cladding tubes and nuclear fusion reactor blankets.The preparation process significantly influences microstructure of ODS steel.This paper reviews the development and perspective of several preparation processes of ODS steel,including the powder metallurgy process,improved powder metallurgy process,liquid metal forming process,hybrid process,and additive forging.This paper also summarizes and analyzes the relationship between microstructures and the preparation process.After comprehensive consideration,the powder metallurgy process is still the best preparation process for ODS steel.Combining the advantages and disadvantages of the above preparation processes,the trend applied additive forging for extreme manufacturing of large ODS steel components is discussed with the goal of providing a reference for the application and development of ODS steel in nuclear energy.
文摘The optical reflectance and transmittance spectra in the wavelength range of 300-2500 nm are used to compute the absorption coefficient of zinc oxide films annealed at different post-annealing temperatures 400, 500 and 600°C.The values of the cross point between the curves of the real and imaginary parts of the optical conductivity ɑ_1 and ɑ_1 with energy axis of films exhibit values that correspond to optical gaps and are about 3.25-3.3 eV. The maxima of peaks in plots dR/dλ and dT/dλ versus wavelength of films exhibit optical gaps at about 3.12-3.25 eV.The values of the fundamental indirect band gap obtained from the Tauc model are at about 3.14-3.2 eV. It can be seen that films annealed at 600°C have the minimum indirect optical band gap at about 3.15 eV. The films annealed at 600°C have Urbach's energy minimum of 1.38 eV and hence have minimum disorder. The dispersion energy d of films annealed at 500°C has the minimum value of 43 eV.
文摘This paper presents a comparative study on Magnetic-Dispersion based Energy Harvesting Systems (MD-EHS) on electrical conductors that supply power for a three-phase AC motor. It introduces two MD-EHS which are based on magnetic cores of different material, named, nanocrystalline, ferrite and iron powder. The first one consists of harvesting energy from magnetic flux through three symmetrical magnetic cores installed on each power conductors of a three-phase AC motor. The second one consists of a single magnetic core for harvesting energy from magnetic flux of only one of these conductors. Both ones have an AC/DC converter and a variable resistor based load. Experimental results have agreed with the theoretical analysis and show that the first proposed MD-EHS is capable of supplying 14 times more energy than the second MD-EHS, considering nanocrystalline cores and phase current of 3 A, and 7.5 times more energy, considering ferrite cores and phase current of 9 A. Such energy can be applied to various low-power devices, especially in wireless sensor network.
文摘Mine disasters occur predominantly due to methane or coal dust explosion or a combination of both.Among the top ten worst coal mine disasters in India, nine are due to coal dust explosion. The current paper describes a general overview of the parameters causing dispersion leading to coal dust explosion,and computational fluid dynamics(CFD) simulation study to observe the effects of particle size on dispersion in Indian coal mines. Turbulent kinetic energy(TKE) and velocity vector path of dust-air mixture and dust-free air were simulated to understand their effects on coal dust dispersion. The TKE contours and velocity vector paths for dust-free air were uniform and symmetrical due to resistance-free path available. The TKE contours and velocity vector paths for dust-air mixture shows the asymmetrical distribution of contours, due to entrainment of air with dust particles. Vortices were observed in velocity vector paths which gradually diminish on increment of time sequence. These vortices are dead centres where velocity and coal dust particles concentration are both zero.
文摘Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, concentrations average in mg/L of metals such Fe (0.731), Mn (0.345), Cr (0.070), Cu (0.014) and concentrations of nutrients known to be pollutants and toxic for living or-ganisms. These heavy metals are dangerous to the lives, the local inhabitants and also a threat to aquatic life since this water is essential for the economical town, Abidjan. According to the Manganese concentration average (0.345 mg) values that higher than WHO (0.05 mg) value, the main likely source of pollu-tants is anthropogenic, industrial and agricultural. This study also shows the use of materials and lubricants near the lagoon that pollute this water.
文摘A kind of excellent CdZnTe crystal has been grown in Yinnel Tech, Inc. in recent years. Based on these CdZnTe crystals and some new techniques, a portable energy-dispersive spectrometer has been constructed which has yielded good results. CdZnTe detector has a 3% relative resolution in high-energy field and can detect gamma rays at room temperature. An integrated circuit based on preamplifier and shaping amplifier chips is connected to the detector. Voltage pulses are transformed into digital signals in MCA (multichannel analyzer) and are then transmitted to com- puter via USB bus. Data process algorithms are improved in this spectrometer. Fast Fourier transform (FFT) and nu- merical differentiation (ND) are used in energy peak’s searching program. Sampling-based correction technique is used in X-ray energy calibration. Modified Gaussian-Newton algorithm is a classical method to solve nonlinear curve fitting problems, and it is used to compute absolute intensity of each detected characteristic line.
基金Supported by:the National Natural Science Foundation of China,No.39970383the Project for Science and Technology from Educational Committee of Liaoning Province,No.202013132Technological Program for Colleges and Universities of Liaoning Educational Committee,No.[2008]84
文摘BACKGROUND: Alpha-actinin ( a -actinin) plays a key role in neuronal growth cone migration during directional differentiation from neural stem cells (NSCs) to neurons. OBJECTIVE: To detect in situ microdistribution and quantitative expression of a -actinin during directional differentiation of NSCs to neurons in the temporal lobe cerebral cortex of neonatal rats. DESIGN, TIME AND SETTING: Between January 2006 and December 2008, culture and directional differentiation of NSCs were performed at Department of Histology and Embryology, Preclinical Medical College, China Medical University. Immune electron microscopy was performed at Department of Histology and Embryology and Department of Electron Micrology, Preclinical Medical College, China Medical University. Spectrum analysis was performed at Laboratory of Electron Microscopy, Mental Research Institute, Chinese Academy of Sciences. MATERIALS: Basic fibroblast growth factor, epidermal growth factor, brain-derived nerve growth factor, type-1 insulin like growth factor, and a -actinin antibody were provided by Gibco BRL, USA; rabbit-anti-rat nestin monoclonal antibody, rabbit-anti-rat neuron specific enolase polyclonal antibody, and EDAX-9100 energy dispersive X-ray analysis were provided by PHILIPS Company, Netherlands. METHODS: NSCs, following primary and passage culture, were differentiated with serum culture medium (DMEM/F12 + 10% fetal bovine serum + 2 ng/mL brain-derived nerve growth factor + 2 ng/mL type-1 insulin like growth factor). MAIN OUTCOME MEASURES: Expression of a -actinin in neuron-like cells was quantitatively and qualitatively detected with immunocytochemistry using energy dispersive X-ray analysis. RESULTS: Immunocytochemistry, combined with electron microscopy, indicated that positive α -actinin expression was like a spheroid particle with high electron density. In addition, the expression was gradually concentrated from the nuclear edge to the cytoplasm and expanded into developing neurites, during differentiation of neural stem cells to neurons. Conversely, energy dispersive X-ray analysis indicated that the more mature the neural differentiation was, and the greater the expression of α -actinin. CONCLUSION: The gradual increase of α -actinin expression is related to growth, development, and maturity of differentiated neuron-like cells, in neonatal rat frontal lobe cortex, at different differentiating time points of NSCs to neurons.
基金supported by the National Key R&D Project of China(No.2017YFC0602100)the National Natural Science Foundation of China(No.41774147)Sichuan Science and Technology Support Program(No.2015GZ0272)
文摘The full-spectrum least-squares(FSLS) method is introduced to perform quantitative energy-dispersive X-ray fluorescence analysis for unknown solid samples.Based on the conventional least-squares principle, this spectrum evaluation method is able to obtain the background-corrected and interference-free net peaks, which is significant for quantization analyses. A variety of analytical parameters and functions to describe the features of the fluorescence spectra of pure elements are used and established, such as the mass absorption coefficient, the Gi factor, and fundamental fluorescence formulas. The FSLS iterative program was compiled in the C language. The content of each component should reach the convergence criterion at the end of the calculations. After a basic theory analysis and experimental preparation, 13 national standard soil samples were detected using a spectrometer to test the feasibility of using the algorithm. The results show that the calculated contents of Ti, Fe, Ni, Cu, and Zn have the same changing tendency as the corresponding standard content in the 13 reference samples. Accuracies of 0.35% and 14.03% are obtained, respectively, for Fe and Ti, whose standard concentrations are 8.82% and 0.578%, respectively. However, the calculated results of trace elements (only tens of lg/g) deviate from the standard values. This may be because of measurement accuracy and mutual effects between the elements.
文摘A facility and method for109 Cd radionuclide-induced energy-dispersive X-ray fluorescent(EDXRF) were developed to determine the Fe,Zn,Br,Rb,and Sr concentrations in the specimens of human prostatic fluid.Specimens of expressed prostatic fluid were obtained from 51 men(mean age 51 years,range 18–82 years) with apparently normal prostates using standard rectal massage procedure.Mean values(M ± SEL) for concentration of trace elements(mg L^(-1)) in human prostate fluid were:Fe 9.04 ±1.21,Zn 573 ± 35,Br 3.58 ± 0.59,Rb 1.10 ± 0.08,and Sr B 0.76.It was shown that the results of trace element analysis in the micro-samples(20 l L) are sufficiently representative for assessment of the Fe,Zn,Br,and Rb concentration in the prostate fluid.The facility for109 Cd radionuclide-induced EDXRF is comparatively compact and can be located in close proximity to the site of carrying out the massage procedure.The means of Zn and Rb concentration obtained for prostate fluid agree well with median of reported means.For the first time,the Fe and Br concentrations,as well as the upper limit of the Sr concentration,were determined in the human prostate fluid.
文摘Transmission electron microscopy (TEM) is a very powerful technique for materials characteriza-tion, providing information relating to morphology, composition, and crystal structure. Selected area diffraction patterns (SADPs) are crystallographic data that can be obtained using a TEM in-strument. Conventional identification through SADP/TEM is tricky and tedious, thereby increasing the difficulty of phase identification. To establish a procedure for phase identification of known and unknown phases, in this study we examined two samples: one, a known phase, was Si with alignment;the other, unknown, was the TixOy phase at the 96.4Au-3Ni-0.6Ti interlayer/ yttria-stabilized zirconia (YSZ) interface of a steel/96.4Au-3Ni-0.6Ti interlayer/YSZ joint. The procedures for phase identification of the known and unknown phases are described herein using a series of SADPs and energy dispersive spectrometry within TEM that would be useful for general researchers.
文摘Ashcroft's local empty core (EMC) model pseudopotential in the second-order perturbation theory is used to study the electron dispersion relation, the Fermi energy, and deviation in the Fermi energy from free electron value for the liquid alkali metals and their equiatomic binary alloys for the first time. In the present computation, the use of pseudo-alloy-atom model (PAA) is proposed and found successful. The influence of the six different forms of the local field correction functions proposed by Hartree (H), Vashishta Singwi (VS), Taylor (T), lehimaru-Utsumi (IU), Farid et al. (F), and Sarkar et al. (S) on the aforesaid electronic properties is examined explicitly, which reflects the varying effects of screening. The depth of the negative hump in the electron dispersion of liquid alkalis decreases in the order Li --→ K, except for Rb and Cs, it increases. The results of alloys are in predictive nature.