Two new isostructural multi-metal beryllium borates, m^3 Li Na4Be4B10O24F(M = Sr(1), Cd(2)), have been synthesized by spontaneous crystallization. The structures were verified by single-crystal X-ray crystallogr...Two new isostructural multi-metal beryllium borates, m^3 Li Na4Be4B10O24F(M = Sr(1), Cd(2)), have been synthesized by spontaneous crystallization. The structures were verified by single-crystal X-ray crystallography. The compounds crystallize in the trigonal space group R 3, with a = b = 9.4645(1) A, c = 38.842(8) A, V = 3013.2(6) A3, Z = 6, F(000) = 2568, Dc = 3.005 g/cm^3, Mr = 908.9, R = 0.0327, w R = 0.0678, μ = 8.160 mm-1 for Sr3 Li Na4Be4B10O24F and a = b = 9.3019(8) A, c = 37.782(7) A, V = 2831.12(9) A3, Z = 6, F(000) = 2748, Dc = 3.459 g/cm^3, Mr = 983.24, R = 0.0158, w R = 0.0455, μ = 3.586 mm-1 for Cd3 Li Na4Be4B10O24F. The structures are characterized by an infinite two-dimensional [Be8B16O40F2]∞ double layer bridged by [B12O24] groups like a sandwich structure, while the cations reside in tunnels along different directions. UV-vis-IR diffuse reflectance spectroscopy demonstrates that their cut-off edges are below 200 nm. Thermal analysis shows that they melt incongruently and their melting points are around 740-770 ℃.展开更多
Morphology of zinc alloy layer,from zincate solution with zinc sulfate and zinc oxide respectively,together with the consequent deposit was observed with SEM and back scattering electron image.EDS was applied to analy...Morphology of zinc alloy layer,from zincate solution with zinc sulfate and zinc oxide respectively,together with the consequent deposit was observed with SEM and back scattering electron image.EDS was applied to analyze the components of zinc alloy layer and the interface of high-Si aluminum alloy substrate-zinc alloy-deposit.Besides,the surface morphology of the zincated aluminum alloy after immersing in 3.5% NaCl solution for 7 d,is observed and the corrosion rate was calculate.Finally,tension test is conducted to quantify the adhesion between high-Si aluminum cast substrate and the deposit.The results show that,the zinc oxide contained zincating solution with sodium potassium tartrate and sodium citrate is a better one in multi-metal zincating solutions.The zinc alloy layer from this one gets stable performance,perfect adhesion with deposit,and good corrosion resistance.展开更多
Arrhenius formula was applied to calculate the apparent activation energy of zincate reaction. The standard electrode potential of all the metal coordinating ions and the order of galvanic couple of different metals i...Arrhenius formula was applied to calculate the apparent activation energy of zincate reaction. The standard electrode potential of all the metal coordinating ions and the order of galvanic couple of different metals in zincate solution were also calculated. Electrochemical behavior of zincate process was studied by Tafel polarization curves, E—t curves, and electrochemical impedance spectroscopy(EIS). The results show that the apparent activation energy of zincate reaction in non-cyanide multi-metal zincate solution is smaller than that in simple zincate solution, and precipitation sequence of all the metals in zincate solution is Cu, Ni, Fe and Zn. Relationship between the potential at 30 s before zincate and coverage was attained according to the change of potential of zincate. EIS shows that inductive reactance is produced during zincate.展开更多
A kinetic study on the sulfuric acid leaching of multi-metal oxide, which is the product of multi-metal copper alloy with iron trioxide roasted in oxygen, was carried out. The effects of leaching time, stirring speed,...A kinetic study on the sulfuric acid leaching of multi-metal oxide, which is the product of multi-metal copper alloy with iron trioxide roasted in oxygen, was carried out. The effects of leaching time, stirring speed, sulfuric acid concentration, reaction temperature, and particle size of the multi-metal oxide on the kinetics and mechanism of copper extraction were studied. It was found that the reaction kinetic model about the copper extraction from multi-metal oxide follows the mixed kinetic shrinking core mode: 1/3ln(1–X)+(1–X)^(–1/3)–1=680.5C(H_2SO_4)^(0.4297)d_P^(–0.75115)exp(–E_a/RT)t.展开更多
The precise control on the combination of multiple metal atoms in the structure of metal-organic frameworks(MOFs)endowed by reticular chemistry,allows the obtaining of materials with compositions that are programmed f...The precise control on the combination of multiple metal atoms in the structure of metal-organic frameworks(MOFs)endowed by reticular chemistry,allows the obtaining of materials with compositions that are programmed for achieving enhanced reactivity.The present work illustrates how through the transformation of MOFs with desired arrangements of metal cations,multi-metal spinel oxides with precise compositions can be obtained,and used as catalyst precursor for the reverse water-gas shift reaction.The differences in the spinel initial composition and structure,determined by neutron powder diffraction,influence the overall catalytic activity with changes in the process of in s itu formation of active,metal-oxide supported metal nanoparticles,which have been monitored and characterized with in situ X-ray diffraction and photoelectron spectroscopy studies.展开更多
Laser additive manufacturing(LAM)is promising for fabricating multi-metallic component,but the mechanism of microstructural evolution at the interface of two metals is still needed to research further.In this study,a ...Laser additive manufacturing(LAM)is promising for fabricating multi-metallic component,but the mechanism of microstructural evolution at the interface of two metals is still needed to research further.In this study,a 316L stainless steel/Ti6Al4V alloy multi-metal was fabricated by LAM,and the mechanism of intermetallic phase transformation was deeply investigated.Results show that a strong reaction zone(SRZ)can be induced at the interface of the multi-metal.The phase constituents at the SRZ vary fromχ(Ti_(5)Fe_(17)Cr_(5))+Fe_(2)Ti+α′-Ti+β-Ti or FeTi to Fe_(2)Ti+χwhen the laser power is increased.When the scanning speed is further decreased,the thickness of the SRZ is significantly increased,andα′-Ti phase is also formed at this region besides Fe_(2)Ti andχphases.Moreover,the micro-hardness at the SRZ is increased,caused by the intermetallic phase transformation and elemental interdiffusion at the interface.展开更多
Bioinspired Multi-Metal Structures(MMSs)combine distinct properties of multiple materials,benefiting from improved properties and providing superior designs.Additive Manufacturing(AM)exhibits enormous advantages in ap...Bioinspired Multi-Metal Structures(MMSs)combine distinct properties of multiple materials,benefiting from improved properties and providing superior designs.Additive Manufacturing(AM)exhibits enormous advantages in applying different materials and geometries according to the desired functions at specific locations of the structure,having great potential in fabricating multi-materials structures.However,current AM techniques have difficulty manufacturing 3D MMSs without material cross-contamination flexibly and reliably.This study demonstrates a reliable,fast,and flexible direct ink writing method to fabricate 3D MMSs.The in-situ material-switching system enables the deposition of multiple metallic materials across different layers and within the same layer.3D Fe-Cu MMSs with complex geometries and fine details are fabricated as proof of concept.The microstructures,chemical and phase compositions,and tensile fracture surfaces of the Fe-Cu interfaces indicate a well-bonded interface without cracks,delamination,or material cross-contamination.We envision this novel method making other metallic combinations and even metal-ceramic components.It paves the way for manufacturing 3D MMSs using AM and establishes the possibilities of numerous MMSs applications in engineering fields.展开更多
The results of research on the effects of anions on the biosorption of microelement cations by the edible marine macroalga Enteromorpha prolifera in singleand multi-metal systems are discussed in this paper. It was sh...The results of research on the effects of anions on the biosorption of microelement cations by the edible marine macroalga Enteromorpha prolifera in singleand multi-metal systems are discussed in this paper. It was shown that the maximum biosorption capacity (qmax) in a single-metal system of Co(II) ions decreased in the following sequence: Cl- (46.0 mg g-1) > SO42- (42.8 mg g-1) > NO3- (41.9 mg g-1). In multi-metal systems, in which the ratios of Cl-, NO3-, and SO42- were 0:0:4, 1:1:2, 3:0:1, and 4:0:0, there were clear differences among the biosorption capacities. In all the examined systems (other than the 0:0:4 system), inhibition of the binding of microelement cations by the macroalga was observed. In all the systems, the highest value of qmax was obtained for Cu(II) cations; the value ranged from 31.9 mg g-1 in 0:0:4 (SO42- only) to 18.2 mg g-1 in 4:0:0 (Cl-only).展开更多
随着全球制造业竞争的日益激烈,我国提出了“中国制造2025”制造强国战略,其重点发展的十大领域中,与焊接技术密切相关的就高达八个,不仅极大地推动了焊接技术的革新发展,而且对焊接效率和质量均提出了更高的要求。由于熔化极气体保护焊...随着全球制造业竞争的日益激烈,我国提出了“中国制造2025”制造强国战略,其重点发展的十大领域中,与焊接技术密切相关的就高达八个,不仅极大地推动了焊接技术的革新发展,而且对焊接效率和质量均提出了更高的要求。由于熔化极气体保护焊(Gas metal arc welding,GMAW)易于实现自动化焊接,具有生产效率高、焊接质量好及位置适应性好等优点,所以广泛应用于机械制造业中。实现高效GMAW的主要途径有提高焊接速度以及焊接熔敷率。针对以上两种途径,国内外焊接工作者在双丝GMAW的基础上,引入了第三根甚至多根焊丝,研发了各种多丝GMAW工艺。本文针对国内外研发的各类多丝GMAW工艺进行了分析,重点介绍了多丝GMAW工艺的焊接原理、工艺特点及其应用,通过上述分析对各类多丝GMAW工艺进行归纳总结,并进一步展望了多丝焊接的发展方向,即多丝GMAW工艺亟需在电弧物理理论、设备开发和新焊材研发等方面展开深入的研究工作。展开更多
气体绝缘金属封闭开关设备(gas insulated metal enclosed switchgear,GIS)机械缺陷是导致设备故障的重要因素,针对单测点、单证据机械缺陷诊断模型信息缺失和精度不足问题,该文提出一种多层融合振动数据分析的GIS设备机械缺陷诊断方法...气体绝缘金属封闭开关设备(gas insulated metal enclosed switchgear,GIS)机械缺陷是导致设备故障的重要因素,针对单测点、单证据机械缺陷诊断模型信息缺失和精度不足问题,该文提出一种多层融合振动数据分析的GIS设备机械缺陷诊断方法。首先,基于真型GIS设备振动模拟平台试验研究测点位置与缺陷类型对振动行为的影响特性;然后,联合统计分析、模态分解、尺度变换方法提出机械振动信号整体与局部信息关注的复合参数分析方法,引入主成分分析开展多测点振动信息的特征层融合降维;最后,提出改进放缩权重的Dempster-Shafer(DS)证据理论和Bagging投票机制的强/弱基学习器决策层融合机制,联合构建多层融合振动数据分析的GIS设备机械缺陷诊断模型。结果表明:不同类型机械缺陷信号的响应幅值、特征频点和畸变程度存在显著差异,复合特征参量大小及分散程度各不相同;同时,测点位置对缺陷信号的复合振动特征参量的表现形式及分布区间也具有一定影响;基于多层融合数据分析的诊断模型实现缺陷有效识别,辨识准确率为98.66%,相比单一分类器诊断效果提升5.83%。该文可为GIS设备机械缺陷诊断方法提供有价值的参考。展开更多
基金supported by the National Natural Science Foundation of China(No.50972149,61138004,51402316)the National Instrumentation Program(No.2012YQ120048)
文摘Two new isostructural multi-metal beryllium borates, m^3 Li Na4Be4B10O24F(M = Sr(1), Cd(2)), have been synthesized by spontaneous crystallization. The structures were verified by single-crystal X-ray crystallography. The compounds crystallize in the trigonal space group R 3, with a = b = 9.4645(1) A, c = 38.842(8) A, V = 3013.2(6) A3, Z = 6, F(000) = 2568, Dc = 3.005 g/cm^3, Mr = 908.9, R = 0.0327, w R = 0.0678, μ = 8.160 mm-1 for Sr3 Li Na4Be4B10O24F and a = b = 9.3019(8) A, c = 37.782(7) A, V = 2831.12(9) A3, Z = 6, F(000) = 2748, Dc = 3.459 g/cm^3, Mr = 983.24, R = 0.0158, w R = 0.0455, μ = 3.586 mm-1 for Cd3 Li Na4Be4B10O24F. The structures are characterized by an infinite two-dimensional [Be8B16O40F2]∞ double layer bridged by [B12O24] groups like a sandwich structure, while the cations reside in tunnels along different directions. UV-vis-IR diffuse reflectance spectroscopy demonstrates that their cut-off edges are below 200 nm. Thermal analysis shows that they melt incongruently and their melting points are around 740-770 ℃.
基金This work is financially supported by the Foundation of Basic Research of Harbin Engineering Universi-ty( HEUFT06030)
文摘Morphology of zinc alloy layer,from zincate solution with zinc sulfate and zinc oxide respectively,together with the consequent deposit was observed with SEM and back scattering electron image.EDS was applied to analyze the components of zinc alloy layer and the interface of high-Si aluminum alloy substrate-zinc alloy-deposit.Besides,the surface morphology of the zincated aluminum alloy after immersing in 3.5% NaCl solution for 7 d,is observed and the corrosion rate was calculate.Finally,tension test is conducted to quantify the adhesion between high-Si aluminum cast substrate and the deposit.The results show that,the zinc oxide contained zincating solution with sodium potassium tartrate and sodium citrate is a better one in multi-metal zincating solutions.The zinc alloy layer from this one gets stable performance,perfect adhesion with deposit,and good corrosion resistance.
文摘Arrhenius formula was applied to calculate the apparent activation energy of zincate reaction. The standard electrode potential of all the metal coordinating ions and the order of galvanic couple of different metals in zincate solution were also calculated. Electrochemical behavior of zincate process was studied by Tafel polarization curves, E—t curves, and electrochemical impedance spectroscopy(EIS). The results show that the apparent activation energy of zincate reaction in non-cyanide multi-metal zincate solution is smaller than that in simple zincate solution, and precipitation sequence of all the metals in zincate solution is Cu, Ni, Fe and Zn. Relationship between the potential at 30 s before zincate and coverage was attained according to the change of potential of zincate. EIS shows that inductive reactance is produced during zincate.
基金Project(2011AA061003)supported by Hi-Tech Research and Development Program of China
文摘A kinetic study on the sulfuric acid leaching of multi-metal oxide, which is the product of multi-metal copper alloy with iron trioxide roasted in oxygen, was carried out. The effects of leaching time, stirring speed, sulfuric acid concentration, reaction temperature, and particle size of the multi-metal oxide on the kinetics and mechanism of copper extraction were studied. It was found that the reaction kinetic model about the copper extraction from multi-metal oxide follows the mixed kinetic shrinking core mode: 1/3ln(1–X)+(1–X)^(–1/3)–1=680.5C(H_2SO_4)^(0.4297)d_P^(–0.75115)exp(–E_a/RT)t.
基金We acknowledge Institut Laue-Langevin and Spanish initiatives on Neutron Scattering(ILL-SpINS)for beamtime at instrum ent D2B and G.Cuellofor assistance during data acquisition(10.5291/ILL-DATA.5-21-1114).We thank M.C.Capel for the TEM images and TEM-EDS analysis acquisition at Instituto de Catalisis y Petroleoquimica(CSIC).Funding:Work at Instituto de Ciencia de Materiales de Madrid-Consejo Superior de Instigaciones Cientfficas(CSIC)has been supported by the Spanish Research Agency(Agenda Estatal de Investigacion,AEI),Projects MAT2016-78465-R,CTQ2017-87262-R.This work was supported by the EU(ERC CoG HyMAP 648319)and Spanish MINECO(ENE2016-79608-C2-1-R).Authors also wish to thank to“Com unidad de Madrid”and European Structural Funds for their financial support to FotoArt-CM project(S2018/NMT-4367).F.G.acknowledges financial support from MINECO Ramon y Cajal program(RyC-2015-18384).
文摘The precise control on the combination of multiple metal atoms in the structure of metal-organic frameworks(MOFs)endowed by reticular chemistry,allows the obtaining of materials with compositions that are programmed for achieving enhanced reactivity.The present work illustrates how through the transformation of MOFs with desired arrangements of metal cations,multi-metal spinel oxides with precise compositions can be obtained,and used as catalyst precursor for the reverse water-gas shift reaction.The differences in the spinel initial composition and structure,determined by neutron powder diffraction,influence the overall catalytic activity with changes in the process of in s itu formation of active,metal-oxide supported metal nanoparticles,which have been monitored and characterized with in situ X-ray diffraction and photoelectron spectroscopy studies.
基金supported by the Key Research and Develop Program of Anhui Province(No.202004b11020030)the China Postdoctoral Science Foundation(No.2020M680292)。
文摘Laser additive manufacturing(LAM)is promising for fabricating multi-metallic component,but the mechanism of microstructural evolution at the interface of two metals is still needed to research further.In this study,a 316L stainless steel/Ti6Al4V alloy multi-metal was fabricated by LAM,and the mechanism of intermetallic phase transformation was deeply investigated.Results show that a strong reaction zone(SRZ)can be induced at the interface of the multi-metal.The phase constituents at the SRZ vary fromχ(Ti_(5)Fe_(17)Cr_(5))+Fe_(2)Ti+α′-Ti+β-Ti or FeTi to Fe_(2)Ti+χwhen the laser power is increased.When the scanning speed is further decreased,the thickness of the SRZ is significantly increased,andα′-Ti phase is also formed at this region besides Fe_(2)Ti andχphases.Moreover,the micro-hardness at the SRZ is increased,caused by the intermetallic phase transformation and elemental interdiffusion at the interface.
基金National Natural Science Foundation of China,China(Grant ID:52105343 and 52021003)China Postdoctoral Science Foundation,China(Grant ID:2021M701387 and 2022T150259)Department of Science and Technology of Jilin Province,China(Grant ID:2020122214JC).
文摘Bioinspired Multi-Metal Structures(MMSs)combine distinct properties of multiple materials,benefiting from improved properties and providing superior designs.Additive Manufacturing(AM)exhibits enormous advantages in applying different materials and geometries according to the desired functions at specific locations of the structure,having great potential in fabricating multi-materials structures.However,current AM techniques have difficulty manufacturing 3D MMSs without material cross-contamination flexibly and reliably.This study demonstrates a reliable,fast,and flexible direct ink writing method to fabricate 3D MMSs.The in-situ material-switching system enables the deposition of multiple metallic materials across different layers and within the same layer.3D Fe-Cu MMSs with complex geometries and fine details are fabricated as proof of concept.The microstructures,chemical and phase compositions,and tensile fracture surfaces of the Fe-Cu interfaces indicate a well-bonded interface without cracks,delamination,or material cross-contamination.We envision this novel method making other metallic combinations and even metal-ceramic components.It paves the way for manufacturing 3D MMSs using AM and establishes the possibilities of numerous MMSs applications in engineering fields.
基金supported by the Polish Ministry of Science and Higher Education (R05 014 01 and N N209 146136)
文摘The results of research on the effects of anions on the biosorption of microelement cations by the edible marine macroalga Enteromorpha prolifera in singleand multi-metal systems are discussed in this paper. It was shown that the maximum biosorption capacity (qmax) in a single-metal system of Co(II) ions decreased in the following sequence: Cl- (46.0 mg g-1) > SO42- (42.8 mg g-1) > NO3- (41.9 mg g-1). In multi-metal systems, in which the ratios of Cl-, NO3-, and SO42- were 0:0:4, 1:1:2, 3:0:1, and 4:0:0, there were clear differences among the biosorption capacities. In all the examined systems (other than the 0:0:4 system), inhibition of the binding of microelement cations by the macroalga was observed. In all the systems, the highest value of qmax was obtained for Cu(II) cations; the value ranged from 31.9 mg g-1 in 0:0:4 (SO42- only) to 18.2 mg g-1 in 4:0:0 (Cl-only).
文摘随着全球制造业竞争的日益激烈,我国提出了“中国制造2025”制造强国战略,其重点发展的十大领域中,与焊接技术密切相关的就高达八个,不仅极大地推动了焊接技术的革新发展,而且对焊接效率和质量均提出了更高的要求。由于熔化极气体保护焊(Gas metal arc welding,GMAW)易于实现自动化焊接,具有生产效率高、焊接质量好及位置适应性好等优点,所以广泛应用于机械制造业中。实现高效GMAW的主要途径有提高焊接速度以及焊接熔敷率。针对以上两种途径,国内外焊接工作者在双丝GMAW的基础上,引入了第三根甚至多根焊丝,研发了各种多丝GMAW工艺。本文针对国内外研发的各类多丝GMAW工艺进行了分析,重点介绍了多丝GMAW工艺的焊接原理、工艺特点及其应用,通过上述分析对各类多丝GMAW工艺进行归纳总结,并进一步展望了多丝焊接的发展方向,即多丝GMAW工艺亟需在电弧物理理论、设备开发和新焊材研发等方面展开深入的研究工作。
文摘气体绝缘金属封闭开关设备(gas insulated metal enclosed switchgear,GIS)机械缺陷是导致设备故障的重要因素,针对单测点、单证据机械缺陷诊断模型信息缺失和精度不足问题,该文提出一种多层融合振动数据分析的GIS设备机械缺陷诊断方法。首先,基于真型GIS设备振动模拟平台试验研究测点位置与缺陷类型对振动行为的影响特性;然后,联合统计分析、模态分解、尺度变换方法提出机械振动信号整体与局部信息关注的复合参数分析方法,引入主成分分析开展多测点振动信息的特征层融合降维;最后,提出改进放缩权重的Dempster-Shafer(DS)证据理论和Bagging投票机制的强/弱基学习器决策层融合机制,联合构建多层融合振动数据分析的GIS设备机械缺陷诊断模型。结果表明:不同类型机械缺陷信号的响应幅值、特征频点和畸变程度存在显著差异,复合特征参量大小及分散程度各不相同;同时,测点位置对缺陷信号的复合振动特征参量的表现形式及分布区间也具有一定影响;基于多层融合数据分析的诊断模型实现缺陷有效识别,辨识准确率为98.66%,相比单一分类器诊断效果提升5.83%。该文可为GIS设备机械缺陷诊断方法提供有价值的参考。