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Rock mass quality prediction on tunnel faces with incomplete multi-source dataset via tree-augmented naive Bayesian network 被引量:1
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作者 Hongwei Huang Chen Wu +3 位作者 Mingliang Zhou Jiayao Chen Tianze Han Le Zhang 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第3期323-337,共15页
Rock mass quality serves as a vital index for predicting the stability and safety status of rock tunnel faces.In tunneling practice,the rock mass quality is often assessed via a combination of qualitative and quantita... Rock mass quality serves as a vital index for predicting the stability and safety status of rock tunnel faces.In tunneling practice,the rock mass quality is often assessed via a combination of qualitative and quantitative parameters.However,due to the harsh on-site construction conditions,it is rather difficult to obtain some of the evaluation parameters which are essential for the rock mass quality prediction.In this study,a novel improved Swin Transformer is proposed to detect,segment,and quantify rock mass characteristic parameters such as water leakage,fractures,weak interlayers.The site experiment results demonstrate that the improved Swin Transformer achieves optimal segmentation results and achieving accuracies of 92%,81%,and 86%for water leakage,fractures,and weak interlayers,respectively.A multisource rock tunnel face characteristic(RTFC)dataset includes 11 parameters for predicting rock mass quality is established.Considering the limitations in predictive performance of incomplete evaluation parameters exist in this dataset,a novel tree-augmented naive Bayesian network(BN)is proposed to address the challenge of the incomplete dataset and achieved a prediction accuracy of 88%.In comparison with other commonly used Machine Learning models the proposed BN-based approach proved an improved performance on predicting the rock mass quality with the incomplete dataset.By utilizing the established BN,a further sensitivity analysis is conducted to quantitatively evaluate the importance of the various parameters,results indicate that the rock strength and fractures parameter exert the most significant influence on rock mass quality. 展开更多
关键词 Rock mass quality Tunnel faces Incomplete multi-source dataset Improved Swin Transformer Bayesian networks
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A multi-source information fusion layer counting method for penetration fuze based on TCN-LSTM
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作者 Yili Wang Changsheng Li Xiaofeng Wang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第3期463-474,共12页
When employing penetration ammunition to strike multi-story buildings,the detection methods using acceleration sensors suffer from signal aliasing,while magnetic detection methods are susceptible to interference from ... When employing penetration ammunition to strike multi-story buildings,the detection methods using acceleration sensors suffer from signal aliasing,while magnetic detection methods are susceptible to interference from ferromagnetic materials,thereby posing challenges in accurately determining the number of layers.To address this issue,this research proposes a layer counting method for penetration fuze that incorporates multi-source information fusion,utilizing both the temporal convolutional network(TCN)and the long short-term memory(LSTM)recurrent network.By leveraging the strengths of these two network structures,the method extracts temporal and high-dimensional features from the multi-source physical field during the penetration process,establishing a relationship between the multi-source physical field and the distance between the fuze and the target plate.A simulation model is developed to simulate the overload and magnetic field of a projectile penetrating multiple layers of target plates,capturing the multi-source physical field signals and their patterns during the penetration process.The analysis reveals that the proposed multi-source fusion layer counting method reduces errors by 60% and 50% compared to single overload layer counting and single magnetic anomaly signal layer counting,respectively.The model's predictive performance is evaluated under various operating conditions,including different ratios of added noise to random sample positions,penetration speeds,and spacing between target plates.The maximum errors in fuze penetration time predicted by the three modes are 0.08 ms,0.12 ms,and 0.16 ms,respectively,confirming the robustness of the proposed model.Moreover,the model's predictions indicate that the fitting degree for large interlayer spacings is superior to that for small interlayer spacings due to the influence of stress waves. 展开更多
关键词 Penetration fuze Temporal convolutional network(TCN) Long short-term memory(LSTM) Layer counting multi-source fusion
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Multi-source heterogeneous data access management framework and key technologies for electric power Internet of Things
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作者 Pengtian Guo Kai Xiao +1 位作者 Xiaohui Wang Daoxing Li 《Global Energy Interconnection》 EI CSCD 2024年第1期94-105,共12页
The power Internet of Things(IoT)is a significant trend in technology and a requirement for national strategic development.With the deepening digital transformation of the power grid,China’s power system has initiall... The power Internet of Things(IoT)is a significant trend in technology and a requirement for national strategic development.With the deepening digital transformation of the power grid,China’s power system has initially built a power IoT architecture comprising a perception,network,and platform application layer.However,owing to the structural complexity of the power system,the construction of the power IoT continues to face problems such as complex access management of massive heterogeneous equipment,diverse IoT protocol access methods,high concurrency of network communications,and weak data security protection.To address these issues,this study optimizes the existing architecture of the power IoT and designs an integrated management framework for the access of multi-source heterogeneous data in the power IoT,comprising cloud,pipe,edge,and terminal parts.It further reviews and analyzes the key technologies involved in the power IoT,such as the unified management of the physical model,high concurrent access,multi-protocol access,multi-source heterogeneous data storage management,and data security control,to provide a more flexible,efficient,secure,and easy-to-use solution for multi-source heterogeneous data access in the power IoT. 展开更多
关键词 Power Internet of Things Object model High concurrency access Zero trust mechanism multi-source heterogeneous data
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Runout prediction of potential landslides based on the multi-source data collaboration analysis on historical cases
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作者 Jun Sun Yu Zhuang Ai-guo Xing 《China Geology》 CAS CSCD 2024年第2期264-276,共13页
Long runout landslides involve a massive amount of energy and can be extremely hazardous owing to their long movement distance,high mobility and strong destructive power.Numerical methods have been widely used to pred... Long runout landslides involve a massive amount of energy and can be extremely hazardous owing to their long movement distance,high mobility and strong destructive power.Numerical methods have been widely used to predict the landslide runout but a fundamental problem remained is how to determine the reliable numerical parameters.This study proposes a framework to predict the runout of potential landslides through multi-source data collaboration and numerical analysis of historical landslide events.Specifically,for the historical landslide cases,the landslide-induced seismic signal,geophysical surveys,and possible in-situ drone/phone videos(multi-source data collaboration)can validate the numerical results in terms of landslide dynamics and deposit features and help calibrate the numerical(rheological)parameters.Subsequently,the calibrated numerical parameters can be used to numerically predict the runout of potential landslides in the region with a similar geological setting to the recorded events.Application of the runout prediction approach to the 2020 Jiashanying landslide in Guizhou,China gives reasonable results in comparison to the field observations.The numerical parameters are determined from the multi-source data collaboration analysis of a historical case in the region(2019 Shuicheng landslide).The proposed framework for landslide runout prediction can be of great utility for landslide risk assessment and disaster reduction in mountainous regions worldwide. 展开更多
关键词 Landslide runout prediction Drone survey multi-source data collaboration DAN3D numerical modeling Jianshanying landslide Guizhou Province Geological hazards survey engineering
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A Web-Based Approach for the Efficient Management of Massive Multi-source 3D Models
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作者 ZHAO Qiansheng TANG Ruibing +1 位作者 PENG Mingjun GUO Mingwu 《Journal of Geodesy and Geoinformation Science》 CSCD 2024年第3期24-41,共18页
Effectively managing extensive,multi-source,and multi-level real-scene 3D models for responsive retrieval scheduling and rapid visualization in the Web environment is a significant challenge in the current development... Effectively managing extensive,multi-source,and multi-level real-scene 3D models for responsive retrieval scheduling and rapid visualization in the Web environment is a significant challenge in the current development of real-scene 3D applications in China.In this paper,we address this challenge by reorganizing spatial and temporal information into a 3D geospatial grid.It introduces the Global 3D Geocoding System(G_(3)DGS),leveraging neighborhood similarity and uniqueness for efficient storage,retrieval,updating,and scheduling of these models.A combination of G_(3)DGS and non-relational databases is implemented,enhancing data storage scalability and flexibility.Additionally,a model detail management scheduling strategy(TLOD)based on G_(3)DGS and an importance factor T is designed.Compared with mainstream commercial and open-source platforms,this method significantly enhances the loadable capacity of massive multi-source real-scene 3D models in the Web environment by 33%,improves browsing efficiency by 48%,and accelerates invocation speed by 40%. 展开更多
关键词 massive multi-source real-scene 3D model non-relational database global 3D geocoding system importance factor massive model management
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Multi-Source Data Privacy Protection Method Based on Homomorphic Encryption and Blockchain 被引量:3
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作者 Ze Xu Sanxing Cao 《Computer Modeling in Engineering & Sciences》 SCIE EI 2023年第7期861-881,共21页
Multi-Source data plays an important role in the evolution of media convergence.Its fusion processing enables the further mining of data and utilization of data value and broadens the path for the sharing and dissemin... Multi-Source data plays an important role in the evolution of media convergence.Its fusion processing enables the further mining of data and utilization of data value and broadens the path for the sharing and dissemination of media data.However,it also faces serious problems in terms of protecting user and data privacy.Many privacy protectionmethods have been proposed to solve the problemof privacy leakage during the process of data sharing,but they suffer fromtwo flaws:1)the lack of algorithmic frameworks for specific scenarios such as dynamic datasets in the media domain;2)the inability to solve the problem of the high computational complexity of ciphertext in multi-source data privacy protection,resulting in long encryption and decryption times.In this paper,we propose a multi-source data privacy protection method based on homomorphic encryption and blockchain technology,which solves the privacy protection problem ofmulti-source heterogeneous data in the dissemination ofmedia and reduces ciphertext processing time.We deployed the proposedmethod on theHyperledger platformfor testing and compared it with the privacy protection schemes based on k-anonymity and differential privacy.The experimental results showthat the key generation,encryption,and decryption times of the proposedmethod are lower than those in data privacy protection methods based on k-anonymity technology and differential privacy technology.This significantly reduces the processing time ofmulti-source data,which gives it potential for use in many applications. 展开更多
关键词 Homomorphic encryption blockchain technology multi-source data data privacy protection privacy data processing
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Recent trends of machine learning applied to multi-source data of medicinal plants 被引量:2
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作者 Yanying Zhang Yuanzhong Wang 《Journal of Pharmaceutical Analysis》 SCIE CAS CSCD 2023年第12期1388-1407,共20页
In traditional medicine and ethnomedicine,medicinal plants have long been recognized as the basis for materials in therapeutic applications worldwide.In particular,the remarkable curative effect of traditional Chinese... In traditional medicine and ethnomedicine,medicinal plants have long been recognized as the basis for materials in therapeutic applications worldwide.In particular,the remarkable curative effect of traditional Chinese medicine during corona virus disease 2019(COVID-19)pandemic has attracted extensive attention globally.Medicinal plants have,therefore,become increasingly popular among the public.However,with increasing demand for and profit with medicinal plants,commercial fraudulent events such as adulteration or counterfeits sometimes occur,which poses a serious threat to the clinical outcomes and interests of consumers.With rapid advances in artificial intelligence,machine learning can be used to mine information on various medicinal plants to establish an ideal resource database.We herein present a review that mainly introduces common machine learning algorithms and discusses their application in multi-source data analysis of medicinal plants.The combination of machine learning algorithms and multi-source data analysis facilitates a comprehensive analysis and aids in the effective evaluation of the quality of medicinal plants.The findings of this review provide new possibilities for promoting the development and utilization of medicinal plants. 展开更多
关键词 Machine learning Medicinal plant multi-source data Data fusion Application
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Multi-source Data-driven Identification of Urban Functional Areas:A Case of Shenyang,China 被引量:3
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作者 XUE Bing XIAO Xiao +2 位作者 LI Jingzhong ZHAO Bingyu FU Bo 《Chinese Geographical Science》 SCIE CSCD 2023年第1期21-35,共15页
Urban functional area(UFA)is a core scientific issue affecting urban sustainability.The current knowledge gap is mainly reflected in the lack of multi-scale quantitative interpretation methods from the perspective of ... Urban functional area(UFA)is a core scientific issue affecting urban sustainability.The current knowledge gap is mainly reflected in the lack of multi-scale quantitative interpretation methods from the perspective of human-land interaction.In this paper,based on multi-source big data include 250 m×250 m resolution cell phone data,1.81×105 Points of Interest(POI)data and administrative boundary data,we built a UFA identification method and demonstrated empirically in Shenyang City,China.We argue that the method we built can effectively identify multi-scale multi-type UFAs based on human activity and further reveal the spatial correlation between urban facilities and human activity.The empirical study suggests that the employment functional zones in Shenyang City are more concentrated in central cities than other single functional zones.There are more mix functional areas in the central city areas,while the planned industrial new cities need to develop comprehensive functions in Shenyang.UFAs have scale effects and human-land interaction patterns.We suggest that city decision makers should apply multi-sources big data to measure urban functional service in a more refined manner from a supply-demand perspective. 展开更多
关键词 human-land relationship multi-source big data urban functional area identification method Shenyang City
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Classifying Cardiac Anomalies in Right and Left Isomerism:Concordant and Discordant Patterns
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作者 Lilia Oreto Giuseppe Mandraffino +11 位作者 Paolo Ciliberti Teresa P.Santangelo Placido Romeo Antonio Celona Placido Gitto Lorenzo Galletti Fiore S.Iorio Alfredo Di Pino Aurelio Secinaro Paolo Guccione Robert H.Anderson Salvatore Agati 《Congenital Heart Disease》 SCIE 2023年第1期97-111,共15页
Aims:Evidence is emerging that,in the setting of isomerism,the atrial and bronchial arrangement are not always concordant,nor are these patterns always harmonious with the arrangement of the abdominal organs.We aimed ... Aims:Evidence is emerging that,in the setting of isomerism,the atrial and bronchial arrangement are not always concordant,nor are these patterns always harmonious with the arrangement of the abdominal organs.We aimed to evaluate the concordance between these features in a cohort of patients with cardiac malformations in the setting of known isomerism,seeking to determine whether it was feasible to assess complexity on this basis,in this regard taking note of the potential value of bronchial as opposed to appendage morphology.Methods and Results:We studied 78 patients known to have isomerism of the bronchuses,43 with right and 35 with left isomerism.Appendage anatomy could be determined in 49 cases(63%),all but one of these being concordant with bronchial anatomy.When assessing abdominal features,in only 59 cases(76%)was splenic morphology in keeping with the thoracic findings.As expected,right isomerism was associated with greater complexity of cardiac malformations,with an odds ratio of 6.53,with confidence intervals from 2.2–19.3(p<0.001).The odds were slightly decreased with thoraco-abdominal disharmony,when lesions shown to carry higher risk were then found in the setting of left isomerism.Conclusion:Harmony is excellent between bronchial and appendage isomerism,but less so with the arrangement of the abdominal organs.Right isomerism in our cohort,was indicative of a sixfold increase in intracardiac complexity.When discordance was found between the systems,however,the cardiac anomalies were less typical of the anticipated findings for right vs.left isomerism of the appendages. 展开更多
关键词 isomerism ASPLENIA POLYSPLENIA congenital heart disease bronchial isomerism atrial appendages
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Threat Modeling and Application Research Based on Multi-Source Attack and Defense Knowledge
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作者 Shuqin Zhang Xinyu Su +2 位作者 Peiyu Shi Tianhui Du Yunfei Han 《Computers, Materials & Continua》 SCIE EI 2023年第10期349-377,共29页
Cyber Threat Intelligence(CTI)is a valuable resource for cybersecurity defense,but it also poses challenges due to its multi-source and heterogeneous nature.Security personnel may be unable to use CTI effectively to u... Cyber Threat Intelligence(CTI)is a valuable resource for cybersecurity defense,but it also poses challenges due to its multi-source and heterogeneous nature.Security personnel may be unable to use CTI effectively to understand the condition and trend of a cyberattack and respond promptly.To address these challenges,we propose a novel approach that consists of three steps.First,we construct the attack and defense analysis of the cybersecurity ontology(ADACO)model by integrating multiple cybersecurity databases.Second,we develop the threat evolution prediction algorithm(TEPA),which can automatically detect threats at device nodes,correlate and map multisource threat information,and dynamically infer the threat evolution process.TEPA leverages knowledge graphs to represent comprehensive threat scenarios and achieves better performance in simulated experiments by combining structural and textual features of entities.Third,we design the intelligent defense decision algorithm(IDDA),which can provide intelligent recommendations for security personnel regarding the most suitable defense techniques.IDDA outperforms the baseline methods in the comparative experiment. 展开更多
关键词 multi-source data fusion threat modeling threat propagation path knowledge graph intelligent defense decision-making
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Li-promoted C_(3)N_(4) catalyst for efficient isomerization of glucose into fructose at 50℃ in water 被引量:1
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作者 Wang Liu Yanfei Zhang +5 位作者 Mengya Sun Xinpeng Zhao Shenggang Li Xinqing Chen Liangshu Zhong Lingzhao Kong 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第9期1419-1426,共8页
Efficient and selective glucose-to-fructose isomerization is a crucial step for production of oxygenated chemicals derived from sugars,which is usually catalyzed by base or Lewis acid heterogeneous catalyst.However,hi... Efficient and selective glucose-to-fructose isomerization is a crucial step for production of oxygenated chemicals derived from sugars,which is usually catalyzed by base or Lewis acid heterogeneous catalyst.However,high yield and selectivity of fructose cannot be simultaneously obtained under mild conditions which hamper the scale of application compared with enzymatic catalysis.Herein,a Li-promoted C_(3)N_(4) catalyst was exploited which afforded an excellent fructose yield(40.3 wt%)and selectivity(99.5%)from glucose in water at 50℃,attributed to the formation of stable Li–N bond to strengthen the basic sites of catalysts.Furthermore,the so-formed N_(6)–Li–H_(2)O active site on Li–C_(3)N_(4) catalyst in aqueous phase changes the local electronic structure and strengthens the deprotonation process during glucose isomerization into fructose.The superior catalytic performance which is comparable to biological pathway suggests promising applications of lithium containing heterogeneous catalyst in biomass refinery. 展开更多
关键词 GLUCOSE FRUCTOSE isomerIZATION Li–C_(3)N_(4) Density functional theory calculations
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Risk Analysis Using Multi-Source Data for Distribution Networks Facing Extreme Natural Disasters
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作者 Jun Yang Nannan Wang +1 位作者 Jiang Wang Yashuai Luo 《Energy Engineering》 EI 2023年第9期2079-2096,共18页
Distribution networks denote important public infrastructure necessary for people’s livelihoods.However,extreme natural disasters,such as earthquakes,typhoons,and mudslides,severely threaten the safe and stable opera... Distribution networks denote important public infrastructure necessary for people’s livelihoods.However,extreme natural disasters,such as earthquakes,typhoons,and mudslides,severely threaten the safe and stable operation of distribution networks and power supplies needed for daily life.Therefore,considering the requirements for distribution network disaster prevention and mitigation,there is an urgent need for in-depth research on risk assessment methods of distribution networks under extreme natural disaster conditions.This paper accessesmultisource data,presents the data quality improvement methods of distribution networks,and conducts data-driven active fault diagnosis and disaster damage analysis and evaluation using data-driven theory.Furthermore,the paper realizes real-time,accurate access to distribution network disaster information.The proposed approach performs an accurate and rapid assessment of cross-sectional risk through case study.The minimal average annual outage time can be reduced to 3 h/a in the ring network through case study.The approach proposed in this paper can provide technical support to the further improvement of the ability of distribution networks to cope with extreme natural disasters. 展开更多
关键词 Distribution network disaster damage analysis fault judgment multi-source data
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Evaluation and Improvement Strategies for Slow Traffic Systems Based on Multi-source Big Data:A Case Study of Shijingshan District of Beijing City
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作者 LI Yiwen 《Journal of Landscape Research》 2023年第4期62-64,68,共4页
The slow traffic system is an important component of urban transportation,and the prerequisite and necessary condition for Beijing to continue promoting“green priority”are establishing a good urban slow traffic syst... The slow traffic system is an important component of urban transportation,and the prerequisite and necessary condition for Beijing to continue promoting“green priority”are establishing a good urban slow traffic system.Shijingshan District of Beijing City is taken as a research object.By analyzing and processing population distribution data,POI data,and shared bicycle data,the shortcomings and deficiencies of the current slow traffic system in Shijingshan District are explored,and corresponding solutions are proposed,in order to provide new ideas and methods for future urban planning from the perspective of data. 展开更多
关键词 multi-source data Slow traffic system Shijingshan District
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Classification of Beijing Line 10 Subway Living Circle Based on Multi-source Big Data
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作者 SUN Shuai LI Ziying 《Journal of Landscape Research》 2023年第3期53-58,共6页
In the first-tier cities,subway has become an important carrier and life focus of people’s daily travel activities.By studying the distribution of POIs of public service facilities around Metro Line 10,using GIS to q... In the first-tier cities,subway has become an important carrier and life focus of people’s daily travel activities.By studying the distribution of POIs of public service facilities around Metro Line 10,using GIS to quantitatively analyze the surrounding formats of subway stations,discussing the functional attributes of subway stations,and discussing the distribution of urban functions from a new perspective,this paper provided guidance and advice for the construction of service facilities. 展开更多
关键词 multi-source big data Subway living circle BEIJING GIS
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Critical approaches in the catalytic transformation of sugar isomerization and epimerization after Fischer-History,challenges,and prospects
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作者 Da-Ming Gao Xun Zhang +5 位作者 Haichao Liu Hidemi Fujino Tingzhou Lei Fuan Sun Jie Zhu Taoli Huhe 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第3期435-453,共19页
The transformation of aldose to ketose or common sugars into rare saccharides,including rare ketoses and aldoses,is of great value and interest to the food industry and for saccharidic biomass utilization,medicine,and... The transformation of aldose to ketose or common sugars into rare saccharides,including rare ketoses and aldoses,is of great value and interest to the food industry and for saccharidic biomass utilization,medicine,and the synthesis of drugs.Nowadays,high-fructose corn syrup(HFCS)is industrially produced in more than 10 million tons annually using immobilized glucose isomerase.Some low-calorie saccharides such as tagatose and psicose,which are becoming popular sweeteners,have also been produced on a pilot scale in order to replace sucrose and HFCS.However,current catalysts and catalytic processes are still difficult to utilize in biomass conversion and also have strong substrate dependence in producing high-value,rare sugars.Considering the specific reaction properties of saccharides and catalysts,since the pioneering discovery by Fischer,various catalysts and catalytic systems have been discovered or developed in attempts to extend the reaction pathways,improve the reaction efficiency,and to potentially produce commercial products.In this review,we trace the history of sugar isomerization/epimerization reactions and summarize the important breakthroughs for each reaction as well as the difficulties that remain unresolved to date. 展开更多
关键词 Rare sugars isomerIZATION KETONIZATION EPIMERIZATION Catalytic transformation
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Developing a highly scalable synthetic strategy for 5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,b-dioxide(CL-18)and investigating the influence of crystal engineering and positional isomerization on its safety and laser ignition performance
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作者 Lei Yang Zhenqi Zhang +2 位作者 Wei Du Jinshan Li Qing Ma 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第11期13-21,共9页
5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and ... 5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and safety risks.In this study,we have developed a simple and safe synthetic route for CL-18.It was synthesized from 3,5-dihaloanisole in a four-step reaction with an overall yield exceeding 60%,surpassing all reported yields in the literature.Subsequently,recrystallization of CL-18 was successfully achieved by carefully selecting appropriate solvents and antisolvents to reduce its mechanical sensitivity.Ultimately,when DMF-ethanol was employed as the recrystallization solvent system,satisfactory product yield(>90%)and reduced mechanical sensitivity(IS=15 J;FS=216 N)were obtained.Additionally,CL-18 is derived from the rearrangement of oxygen atoms on i-CL-18 furoxan,and a comparative analysis of their physicochemical properties was conducted.The thermal stability of both compounds is similar,with onset decomposition temperatures recorded at 186 and 182℃respectively.Similarly,they exhibit 5 s breaking point temperatures of 236 and 237℃.Additionally,we present novel insights into the positional-isomerization-laser-ignition performance of CL-18 and its isomer i-CL-18 using laser irradiation for the first time.Remarkably,our findings demonstrate that i-CL-18 exhibits enhanced laser sensitivity,as it can be directly ignited by a 1064 nm wavelength laser,whereas CL-18 lacks this characteristic. 展开更多
关键词 Initiating explosive Synthetic method Crystal engineering Positional isomerization Laser ignition
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Co-Harvest Phase-Change Enthalpy and Isomerization Energy for High-Energy Heat Output by Controlling Crystallization of Alkyl-Grafted Azobenzene Molecules
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作者 Jian Gao Yiyu Feng +6 位作者 Wenyu Fang Hui Wang Jing Ge Xiaoyu Yang Huitao Yu Mengmeng Qin Wei Feng 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期415-424,共10页
Photoisomerization-induced phase change are important for co-harvesting the latent heat and isomerization energy of azobenzene molecules.Chemically optimizing heat output and energy delivery at alternating temperature... Photoisomerization-induced phase change are important for co-harvesting the latent heat and isomerization energy of azobenzene molecules.Chemically optimizing heat output and energy delivery at alternating temperatures are challenging because of the differences in crystallizability and isomerization.This article reports two series of asymmetrically alkyl-grafted azobenzene(Azo-g),with and without a methyl group,that have an optically triggered phase change.Three exothermic modes were designed to utilize crystallization enthalpy(△H_(c))and photothermal(isomerization)energy(△H_(p))at different temperatures determined by the crystallization.Azo-g has high heat output(275-303 J g^(-1))by synchronously releasing△H_(c)and△H_(p)over a wide temperature range(-79℃to 25℃).We fabricated a new distributed energy utilization and delivery system to realize a temperature increase of 6.6℃at a temperature of-8℃.The findings offer insight into selective utilization of latent heat and isomerization energy by molecular optimization of crystallization and isomerization processes. 展开更多
关键词 crystallizability distributed energy utilization system energy density exothermic modes isomerIZATION
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Synthesis of Pt/PMA-MIL-101 Catalyst and Its Performance in n-Heptane Isomerization
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作者 Zhang Wei Guo Qiang +5 位作者 Wang Yingjun Suo Yanhua Lin Wenqiu Hu Tengyu Li Tong Liu Shetian 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第3期63-72,共10页
Hydroisomerization of n-heptane is an efficient method for producing gasoline with a high octane number.The focus of this study was to find a highly efficient catalyst that could both promote the conversion of n-hepta... Hydroisomerization of n-heptane is an efficient method for producing gasoline with a high octane number.The focus of this study was to find a highly efficient catalyst that could both promote the conversion of n-heptane and inhibit the cracking side reaction.MIL-101(Cr)is a chromium-based metal-organic framework(MOF)with good hydrothermal stability,and exhibits a three-dimensional pore structure that is similar to that of zeolites.Using phosphomolybdic acid(PMA;H3PMo12O40·xH2O)can increase the number of Brønsted acid sites on MIL-101(Cr),which contributes to improving the catalytic performance during isomerization.In this study,0.4%Pt/PMA-MIL-101(Cr)catalyst was successfully crystallized at 220℃using a hydrothermal synthetic method.The results showed that the synthesized samples were mesoporousmicroporous composite materials with the typical octahedral structure,and the MIL-101(Cr)framework was not damaged following modification with PMA.It was found that 0.4%Pt30%PMA-MIL-101(Cr)exhibited the best performance for isomerization of n-heptane,with a conversion rate and selectivity at 260°C of 47.6%and 96.6%,respectively.After five hours of reaction,the conversion rate and selectivity of the catalyst remained above 38%and 80%,respectively. 展开更多
关键词 MIL-101(Cr) N-HEPTANE isomerIZATION phosphomolybdic acid CATALYSIS
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Separation method for multi-source blended seismic data
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作者 王汉闯 陈生昌 +1 位作者 张博 佘德平 《Applied Geophysics》 SCIE CSCD 2013年第3期251-264,357,共15页
Multi-source seismic technology is an efficient seismic acquisition method that requires a group of blended seismic data to be separated into single-source seismic data for subsequent processing. The separation of ble... Multi-source seismic technology is an efficient seismic acquisition method that requires a group of blended seismic data to be separated into single-source seismic data for subsequent processing. The separation of blended seismic data is a linear inverse problem. According to the relationship between the shooting number and the simultaneous source number of the acquisition system, this separation of blended seismic data is divided into an easily determined or overdetermined linear inverse problem and an underdetermined linear inverse problem that is difficult to solve. For the latter, this paper presents an optimization method that imposes the sparsity constraint on wavefields to construct the object function of inversion, and the problem is solved by using the iterative thresholding method. For the most extremely underdetermined separation problem with single-shooting and multiple sources, this paper presents a method of pseudo-deblending with random noise filtering. In this method, approximate common shot gathers are received through the pseudo-deblending process, and the random noises that appear when the approximate common shot gathers are sorted into common receiver gathers are eliminated through filtering methods. The separation methods proposed in this paper are applied to three types of numerical simulation data, including pure data without noise, data with random noise, and data with linear regular noise to obtain satisfactory results. The noise suppression effects of these methods are sufficient, particularly with single-shooting blended seismic data, which verifies the effectiveness of the proposed methods. 展开更多
关键词 multi-source data separation linear inverse problem sparsest constraint pseudo-deblending filtering
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Effects of Rotational Isomerism and Bond Length Alternation on Optical Spectra of FTC Chromophore in Solution
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作者 赵珂 韩广超 +1 位作者 张立立 贾海洪 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第1期75-81,I0004,共8页
Rotational isomerism effects on the optical spectra of a push-pull nonlinear optical chro-mophore 2-dicyanomethylen-3-cyano-4-f2-[E-(4-N,N-di(2-acetoxyethyl)-amino)-phenylene-(3,4-dibutyl)-thien-5]-E-vinylg-5,5-... Rotational isomerism effects on the optical spectra of a push-pull nonlinear optical chro-mophore 2-dicyanomethylen-3-cyano-4-f2-[E-(4-N,N-di(2-acetoxyethyl)-amino)-phenylene-(3,4-dibutyl)-thien-5]-E-vinylg-5,5-dimethyl-2,5-dihydrofuran (FTC) in a few solvents have been studied using the time-dependent density functional theory in combination with the polarizable continuum model. It is shown that the maximum absorption peaks of the ro-tamers have difference of nearly 30 nm both in vacuum and in solutions. The population of the rotamers changes a lot in different solvents. Based on the geometries optimized by Hartree-Fock method, the Maxwell-Boltzmann averaged absorption has been calculated and the maximum absorption peak is in good agreement with experiment. It indicates that the bond length alternation can have an important effect on the optical spectra. 展开更多
关键词 Rotational isomerism Bond length alternation One-photon absorption Po-larizable continuum model
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