An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method（HPCD）, is stud...An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method（HPCD）, is studied by an inductively coupled plasma optical emission spectrometry（ICP-OES） and an inductively coupled plasma mass spectrometry（ICP-MS）. The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error（RE） for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials（GBW07309, GBW07311, GBW07313）, rock reference materials（GBW07103, GBW07104,GBW07105）, and cobalt-rich crust reference materials（GBW07337, GBW07338, GBW07339）, the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation（RSD） and the relative error（RE） are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.展开更多
Standard reference material and different geological samples were dissolved by system A (the mixture of nitric and perchloric acids) and system B (mixture of nitric, perchloric and hydrofluoric acids), and total Se in...Standard reference material and different geological samples were dissolved by system A (the mixture of nitric and perchloric acids) and system B (mixture of nitric, perchloric and hydrofluoric acids), and total Se in all samples was measured by hydride-generation atomic fluorescence spectrometry (HG-AFS) after concentration with thiol cotton fiber (TCF). The analytical results obtained by the two digestion method are in good agreement (within the limit of errors) for most of the samples, particularly for those having recommended values. The Se concentrations determined by the two methods are of no difference, and the correlation coefficient is 0.9986; the relative standard deviation (RSD) for the determination of 0.04 μg/g Se is 10.2%. The recovery rates of systems A and B by the stan- dard-addition method were 96%–106% and 99%–104%, respectively.展开更多
In recent years, the modern methods of multi-element analysis of precious metals have attracted wide attention in scientific research and industry. The application and development in the decomposition of samples, sepa...In recent years, the modern methods of multi-element analysis of precious metals have attracted wide attention in scientific research and industry. The application and development in the decomposition of samples, separation and enrichment, and modern instrumental analysis of the platinum-group elements (PGEs) and gold in geological and environmental samples have been reviewed. Finally, the tendency of analysis of precious metals is also prospected.展开更多
The conventional saponification method could result in lower recoveries and artificial changes of longchain fatty acids. The main reason is the error judgment of the intermediate layer suspended between the aqueous an...The conventional saponification method could result in lower recoveries and artificial changes of longchain fatty acids. The main reason is the error judgment of the intermediate layer suspended between the aqueous and organic layer during the liquid–liquid extraction process.This study shows that the intermediate layer consists of lots of medium- to long-chain carboxylic salts for their special physical and chemical properties. An improved saponification extraction method is also developed and the results show that the carboxylic salts distributed in the intermediate layer could be obtained completely, which greatly enhances the authenticity and accuracy of fatty acid analysis. Additionally, the possible reasons of formation of the intermediate layer are also discussed.展开更多
The material composition of geological samples is very complicated. Generally, the method for accurately determining trace elements in geological samples needs to digest the solid samples into liquid state, which is c...The material composition of geological samples is very complicated. Generally, the method for accurately determining trace elements in geological samples needs to digest the solid samples into liquid state, which is convenient for inductively coupled plasma mass spectrometry. The previous digestion method takes a long time and the operation process is complicated. The Ultra CLAVE microwave digestion instrument was used to digest the geological samples. The types and dosages of the acid used for digestion and the optimal conditions for instrumental testing were published. The results show that this method has short processing time, small data error, safer operation and good digestion effect. This method is suitable for geological sample analysis.展开更多
Using the quantitative error probability density method we studied the S/N ratio of alternately sampled signals digitized by a 4-channel A/D. A complete expression for the S/N ratio of a 4-channel A/D non-uniform samp...Using the quantitative error probability density method we studied the S/N ratio of alternately sampled signals digitized by a 4-channel A/D. A complete expression for the S/N ratio of a 4-channel A/D non-uniform sampling signal was deduced. First we obtained an expression for the S/N ratio of a 1-channel A/D uniform sampling signal when the sampling frequency was equal to or greater than 2 times the frequency of the sampled signal. Based on the S/N ratio of a 2-channel A/D,alternating,non-uniform sampling signal,we analyzed the distribution of quantitative error using the quantitative error probability density method and the distribution convolution formula. From this the S/N ratio expression of a 4-channel A/D sampling signal was deduced. The simulation result shows that the deduced expression is correct.展开更多
An orthogonal 2D training image is constructed from the geological analysis results of well logs and sedimentary facies;the 2 D probabilities in three directions are obtained through linear pooling method and then agg...An orthogonal 2D training image is constructed from the geological analysis results of well logs and sedimentary facies;the 2 D probabilities in three directions are obtained through linear pooling method and then aggregated by the logarithmic linear pooling to determine the 3 D multi-point pattern probabilities at the unknown points,to realize the reconstruction of a 3 D model from 2D cross-section.To solve the problems of reducing pattern variability in the 2 D training image and increasing sampling uncertainty,an adaptive spatial sampling method is introduced,and an iterative simulation strategy is adopted,in which sample points from the region with higher reliability of the previous simulation results are extracted to be additional condition points in the following simulation to improve the pattern probability sampling stability.The comparison of lateral accretion layer conceptual models shows that the reconstructing algorithm using self-adaptive spatial sampling can improve the accuracy of pattern sampling and rationality of spatial structure characteristics,and accurately reflect the morphology and distribution pattern of the lateral accretion layer.Application of the method in reconstructing the meandering river reservoir of the Cretaceous McMurray Formation in Canada shows that the new method can accurately reproduce the shape,spatial distribution pattern and development features of complex lateral accretion layers in the meandering river reservoir under tide effect.The test by sparse wells shows that the simulation accuracy is above 85%,and the coincidence rate of interpretation and prediction results of newly drilled horizontal wells is up to 80%.展开更多
The basis of accurate mineral resource estimates is to have a geological model which replicates the nature and style of the orebody. Key inputs into the generation of a good geological model are the sample data and ma...The basis of accurate mineral resource estimates is to have a geological model which replicates the nature and style of the orebody. Key inputs into the generation of a good geological model are the sample data and mapping information. The Obuasi Mine sample data with a lot of legacy issues were subjected to a robust validation process and integrated with mapping information to generate an accurate geological orebody model for mineral resource estimation in Block 8 Lower. Validation of the sample data focused on replacing missing collar coordinates, missing assays, and correcting magnetic declination that was used to convert the downhole surveys from true to magnetic, fix missing lithology and finally assign confidence numbers to all the sample data. The missing coordinates which were replaced ensured that the sample data plotted at their correct location in space as intended from the planning stage. Magnetic declination data, which was maintained constant throughout all the years even though it changes every year, was also corrected in the validation project. The corrected magnetic declination ensured that the drillholes were plotted on their accurate trajectory as per the planned azimuth and also reflected the true position of the intercepted mineralized fissure(s) which was previously not the case and marked a major blot in the modelling of the Obuasi orebody. The incorporation of mapped data with the validated sample data in the wireframes resulted in a better interpretation of the orebody. The updated mineral resource generated by domaining quartz from the sulphides and compared with the old resource showed that the sulphide tonnes in the old resource estimates were overestimated by 1% and the grade overestimated by 8.5%.展开更多
Oxide interference correction plays a vital role in the accurate determination of trace element compositions of geological samples by inductively coupled plasma-mass spectrometry(ICP-MS).In this study,we found that th...Oxide interference correction plays a vital role in the accurate determination of trace element compositions of geological samples by inductively coupled plasma-mass spectrometry(ICP-MS).In this study,we found that the oxide production is mainly controlled by the gas flow of the ICP-MS and a constant oxide correction factor(OCF)can be measured during a routine analysis.Thus,we can obtain the oxide production by just investigating the gas flow for a fixed ICP-MS system with monitoring of OCF.Si,Ba and LREE oxide interferences on the Sc,Eu and Gd of four geological standard samples GSP-2,JP-1,GBW03112 and GBW03113 were corrected by such method and the results were in good agreement with the recommended values.Therefore,the present study provides a simple and fast correction method for the oxide interferences of the geological samples during the routine analyses.Furthermore,a Microsoft Excel spreadsheet template integrating the correction equations was developed in an in-house software(ICPMSData Cal)for effective calibration.展开更多
Laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS),which is a rapidly developing analytical technique for the analyses of trace elements and isotopes,plays an important role in advancing the study ...Laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS),which is a rapidly developing analytical technique for the analyses of trace elements and isotopes,plays an important role in advancing the study of Earth science,especially with respect to micro-geochemistry.This article reviews the application of LA-ICP-MS in the elemental analysis of solid geological samples.Although LA-ICP-MS has been widely used in the spatial resolution analysis of element compositions and rapid bulk analysis of whole-rock and soil samples,the analysis accuracy is restricted by numerous factors,including the instrumental conditions,the elemental fractionation and matrix effects,the lack of sufficient matrix-matched reference materials,and the strategies for quantitative calibration and sensitivity drift correction.According to the type of samples and the analyte elements,the analysis accuracy can be improved through the optimization of instrument conditions and the adoption of suitable correction strategies and reference materials.展开更多
Detection and tracking of multi-target with unknown and varying number is a challenging issue, especially under the condition of low signal-to-noise ratio(SNR). A modified multi-target track-before-detect(TBD) method ...Detection and tracking of multi-target with unknown and varying number is a challenging issue, especially under the condition of low signal-to-noise ratio(SNR). A modified multi-target track-before-detect(TBD) method was proposed to tackle this issue using a nonstandard point observation model. The method was developed from sequential Monte Carlo(SMC)-based probability hypothesis density(PHD) filter, and it was implemented by modifying the original calculation in update weights of the particles and by adopting an adaptive particle sampling strategy. To efficiently execute the SMC-PHD based TBD method, a fast implementation approach was also presented by partitioning the particles into multiple subsets according to their position coordinates in 2D resolution cells of the sensor. Simulation results show the effectiveness of the proposed method for time-varying multi-target tracking using raw observation data.展开更多
基金The China Ocean Mineral Resources Research and Development Association Research Program of the State Oceanic Administration of China under contract No.DY125-13-R-07the National Natural Science Foundation of China under contract Nos 41322036 and 41230960+1 种基金the Shandong Provincial Natural Science Foundation of China under contract No.ZR2014DP009the Special Basic Research Funds for Central Public Research Institutes for The First Institute of Oceanography,State Oceanic Administration of China under contract Nos GY0213G06 and GY02-2012G35
文摘An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method（HPCD）, is studied by an inductively coupled plasma optical emission spectrometry（ICP-OES） and an inductively coupled plasma mass spectrometry（ICP-MS）. The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error（RE） for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials（GBW07309, GBW07311, GBW07313）, rock reference materials（GBW07103, GBW07104,GBW07105）, and cobalt-rich crust reference materials（GBW07337, GBW07338, GBW07339）, the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation（RSD） and the relative error（RE） are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.
基金the Knowledge-Innovation Program of the Chinese Academy of Sciences（KZCX3-SW-125）；the National Natural Science Foundation of China（Grant Nos.60633110,40003008）.
文摘Standard reference material and different geological samples were dissolved by system A (the mixture of nitric and perchloric acids) and system B (mixture of nitric, perchloric and hydrofluoric acids), and total Se in all samples was measured by hydride-generation atomic fluorescence spectrometry (HG-AFS) after concentration with thiol cotton fiber (TCF). The analytical results obtained by the two digestion method are in good agreement (within the limit of errors) for most of the samples, particularly for those having recommended values. The Se concentrations determined by the two methods are of no difference, and the correlation coefficient is 0.9986; the relative standard deviation (RSD) for the determination of 0.04 μg/g Se is 10.2%. The recovery rates of systems A and B by the stan- dard-addition method were 96%–106% and 99%–104%, respectively.
文摘In recent years, the modern methods of multi-element analysis of precious metals have attracted wide attention in scientific research and industry. The application and development in the decomposition of samples, separation and enrichment, and modern instrumental analysis of the platinum-group elements (PGEs) and gold in geological and environmental samples have been reviewed. Finally, the tendency of analysis of precious metals is also prospected.
基金supports by the National Natural Science Foundation of China (No.41003021)the Key Laboratory Project of Gansu Province (Grant No.1309RTSA041)
文摘The conventional saponification method could result in lower recoveries and artificial changes of longchain fatty acids. The main reason is the error judgment of the intermediate layer suspended between the aqueous and organic layer during the liquid–liquid extraction process.This study shows that the intermediate layer consists of lots of medium- to long-chain carboxylic salts for their special physical and chemical properties. An improved saponification extraction method is also developed and the results show that the carboxylic salts distributed in the intermediate layer could be obtained completely, which greatly enhances the authenticity and accuracy of fatty acid analysis. Additionally, the possible reasons of formation of the intermediate layer are also discussed.
文摘The material composition of geological samples is very complicated. Generally, the method for accurately determining trace elements in geological samples needs to digest the solid samples into liquid state, which is convenient for inductively coupled plasma mass spectrometry. The previous digestion method takes a long time and the operation process is complicated. The Ultra CLAVE microwave digestion instrument was used to digest the geological samples. The types and dosages of the acid used for digestion and the optimal conditions for instrumental testing were published. The results show that this method has short processing time, small data error, safer operation and good digestion effect. This method is suitable for geological sample analysis.
基金Projects 07KJZ11 supported by the President Fund of Xuzhou Medical School07KJB310117 by the Education Department of Jiangsu Province
文摘Using the quantitative error probability density method we studied the S/N ratio of alternately sampled signals digitized by a 4-channel A/D. A complete expression for the S/N ratio of a 4-channel A/D non-uniform sampling signal was deduced. First we obtained an expression for the S/N ratio of a 1-channel A/D uniform sampling signal when the sampling frequency was equal to or greater than 2 times the frequency of the sampled signal. Based on the S/N ratio of a 2-channel A/D,alternating,non-uniform sampling signal,we analyzed the distribution of quantitative error using the quantitative error probability density method and the distribution convolution formula. From this the S/N ratio expression of a 4-channel A/D sampling signal was deduced. The simulation result shows that the deduced expression is correct.
基金Supported by the China National Science and Technology Major Project(2017ZX05005-004-002,2016ZX05031-002-001)National Natural Science Foundation of China(41872138)Open Foundation of Top Disciplines in Yangtze University(2019KFJJ0818029)。
文摘An orthogonal 2D training image is constructed from the geological analysis results of well logs and sedimentary facies;the 2 D probabilities in three directions are obtained through linear pooling method and then aggregated by the logarithmic linear pooling to determine the 3 D multi-point pattern probabilities at the unknown points,to realize the reconstruction of a 3 D model from 2D cross-section.To solve the problems of reducing pattern variability in the 2 D training image and increasing sampling uncertainty,an adaptive spatial sampling method is introduced,and an iterative simulation strategy is adopted,in which sample points from the region with higher reliability of the previous simulation results are extracted to be additional condition points in the following simulation to improve the pattern probability sampling stability.The comparison of lateral accretion layer conceptual models shows that the reconstructing algorithm using self-adaptive spatial sampling can improve the accuracy of pattern sampling and rationality of spatial structure characteristics,and accurately reflect the morphology and distribution pattern of the lateral accretion layer.Application of the method in reconstructing the meandering river reservoir of the Cretaceous McMurray Formation in Canada shows that the new method can accurately reproduce the shape,spatial distribution pattern and development features of complex lateral accretion layers in the meandering river reservoir under tide effect.The test by sparse wells shows that the simulation accuracy is above 85%,and the coincidence rate of interpretation and prediction results of newly drilled horizontal wells is up to 80%.
文摘The basis of accurate mineral resource estimates is to have a geological model which replicates the nature and style of the orebody. Key inputs into the generation of a good geological model are the sample data and mapping information. The Obuasi Mine sample data with a lot of legacy issues were subjected to a robust validation process and integrated with mapping information to generate an accurate geological orebody model for mineral resource estimation in Block 8 Lower. Validation of the sample data focused on replacing missing collar coordinates, missing assays, and correcting magnetic declination that was used to convert the downhole surveys from true to magnetic, fix missing lithology and finally assign confidence numbers to all the sample data. The missing coordinates which were replaced ensured that the sample data plotted at their correct location in space as intended from the planning stage. Magnetic declination data, which was maintained constant throughout all the years even though it changes every year, was also corrected in the validation project. The corrected magnetic declination ensured that the drillholes were plotted on their accurate trajectory as per the planned azimuth and also reflected the true position of the intercepted mineralized fissure(s) which was previously not the case and marked a major blot in the modelling of the Obuasi orebody. The incorporation of mapped data with the validated sample data in the wireframes resulted in a better interpretation of the orebody. The updated mineral resource generated by domaining quartz from the sulphides and compared with the old resource showed that the sulphide tonnes in the old resource estimates were overestimated by 1% and the grade overestimated by 8.5%.
基金supported by the National Natural Science Foundation of China (Nos. 41473031,41530211)the MOST Special Fund from the State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan (No. MSFGPMR01)
文摘Oxide interference correction plays a vital role in the accurate determination of trace element compositions of geological samples by inductively coupled plasma-mass spectrometry(ICP-MS).In this study,we found that the oxide production is mainly controlled by the gas flow of the ICP-MS and a constant oxide correction factor(OCF)can be measured during a routine analysis.Thus,we can obtain the oxide production by just investigating the gas flow for a fixed ICP-MS system with monitoring of OCF.Si,Ba and LREE oxide interferences on the Sc,Eu and Gd of four geological standard samples GSP-2,JP-1,GBW03112 and GBW03113 were corrected by such method and the results were in good agreement with the recommended values.Therefore,the present study provides a simple and fast correction method for the oxide interferences of the geological samples during the routine analyses.Furthermore,a Microsoft Excel spreadsheet template integrating the correction equations was developed in an in-house software(ICPMSData Cal)for effective calibration.
基金supported by the National Natural Science Foundation of China(90914007and 41125013)111 Plans of Ministry of Education(B07039)+1 种基金the MOST Special Funds of the State Key Laboratory of Geological Processes and Mineral Resources(MSFGPMR201303)the Fundamental Research Funds for the Central Universities
文摘Laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS),which is a rapidly developing analytical technique for the analyses of trace elements and isotopes,plays an important role in advancing the study of Earth science,especially with respect to micro-geochemistry.This article reviews the application of LA-ICP-MS in the elemental analysis of solid geological samples.Although LA-ICP-MS has been widely used in the spatial resolution analysis of element compositions and rapid bulk analysis of whole-rock and soil samples,the analysis accuracy is restricted by numerous factors,including the instrumental conditions,the elemental fractionation and matrix effects,the lack of sufficient matrix-matched reference materials,and the strategies for quantitative calibration and sensitivity drift correction.According to the type of samples and the analyte elements,the analysis accuracy can be improved through the optimization of instrument conditions and the adoption of suitable correction strategies and reference materials.
基金Projects(61002022,61471370)supported by the National Natural Science Foundation of China
文摘Detection and tracking of multi-target with unknown and varying number is a challenging issue, especially under the condition of low signal-to-noise ratio(SNR). A modified multi-target track-before-detect(TBD) method was proposed to tackle this issue using a nonstandard point observation model. The method was developed from sequential Monte Carlo(SMC)-based probability hypothesis density(PHD) filter, and it was implemented by modifying the original calculation in update weights of the particles and by adopting an adaptive particle sampling strategy. To efficiently execute the SMC-PHD based TBD method, a fast implementation approach was also presented by partitioning the particles into multiple subsets according to their position coordinates in 2D resolution cells of the sensor. Simulation results show the effectiveness of the proposed method for time-varying multi-target tracking using raw observation data.
