The conductivity of non-crystalline fast ionic conductor for B_2O_3-Li_2O-LiCl-Al_2O_3 system is studiedin this paper. The glass structure of this system is discussed by means of infrared spectrum and X-ray fluorescen...The conductivity of non-crystalline fast ionic conductor for B_2O_3-Li_2O-LiCl-Al_2O_3 system is studiedin this paper. The glass structure of this system is discussed by means of infrared spectrum and X-ray fluorescence analysis, and the effects of LiCl and A1_2O_3 on the conductivity of Li^+ in the system are studied as well. Adding Li_2O to the system gives rise to transfer from [BO_3] triangular units to [BO_4] tetrahedral. When Li_2O content exceeds 30mol%, the main group of the glass is the diborate group with more [BO_4] tetrahedra. The adding of LiCl has no obvious influence on the glass structure, and LiCl is under a state dissociated by network, but with the increase of LiCl, the increase of conductivity is obvious. By adding A1_2O_3, the glass can be formed when the room-temperature is cooling down,the conductivity decreases while the conductive activatory energy increases for the glass. The experiment shows that conductivity in the room-temperature is σ= 6.2×10^(-6)Ω^(-1)cm^(-1), when at 300℃, the σ=6.8×10^(-3)Ω^(-1)cm^(-1). The conductive activatory energy computed is 0.6～1.0eV.展开更多
Data collection with microcrystals at synchrotron radiation facilities is challenging because it is difficult to harvest and locate microcrystals. Moreover,microcrystals are sensitive to radiation damage; thus, typica...Data collection with microcrystals at synchrotron radiation facilities is challenging because it is difficult to harvest and locate microcrystals. Moreover,microcrystals are sensitive to radiation damage; thus, typically, a complete data set cannot be obtained with a single microcrystal. Herein, we report a new method for data collection with multiple microcrystals having a crystal size ranging from 1 to 30 lm. This method is suitable for not only low-temperature(100 K) data collection but also room-temperature data collection. Thin Kapton membranes were used to capture multiple crystals simultaneously. The microcrystals were visible under an optical microscope and easily located because the membrane was transparent and sufficiently thin. The film was fixed to a bracket that was prepared using a three-dimensional printer. The bracket was fixed on a magnetic base via screwing and employed by the goniometer system for data collection. Multiple data sets of fatty acid-binding protein 4(FABP4) and lysozyme microcrystals were collected using this novel designed device. Finally, the structures of protein FABP4 and lysozyme were obtained from these data via the molecule replacement method. The data statistics reveal that this method provides a comparable result to traditional methods such as a nylon loop.展开更多
文摘The conductivity of non-crystalline fast ionic conductor for B_2O_3-Li_2O-LiCl-Al_2O_3 system is studiedin this paper. The glass structure of this system is discussed by means of infrared spectrum and X-ray fluorescence analysis, and the effects of LiCl and A1_2O_3 on the conductivity of Li^+ in the system are studied as well. Adding Li_2O to the system gives rise to transfer from [BO_3] triangular units to [BO_4] tetrahedral. When Li_2O content exceeds 30mol%, the main group of the glass is the diborate group with more [BO_4] tetrahedra. The adding of LiCl has no obvious influence on the glass structure, and LiCl is under a state dissociated by network, but with the increase of LiCl, the increase of conductivity is obvious. By adding A1_2O_3, the glass can be formed when the room-temperature is cooling down,the conductivity decreases while the conductive activatory energy increases for the glass. The experiment shows that conductivity in the room-temperature is σ= 6.2×10^(-6)Ω^(-1)cm^(-1), when at 300℃, the σ=6.8×10^(-3)Ω^(-1)cm^(-1). The conductive activatory energy computed is 0.6～1.0eV.
基金supported by the Strategic Priority Research program of the Chinese Academy of Sciences(No.XDB08030101)
文摘Data collection with microcrystals at synchrotron radiation facilities is challenging because it is difficult to harvest and locate microcrystals. Moreover,microcrystals are sensitive to radiation damage; thus, typically, a complete data set cannot be obtained with a single microcrystal. Herein, we report a new method for data collection with multiple microcrystals having a crystal size ranging from 1 to 30 lm. This method is suitable for not only low-temperature(100 K) data collection but also room-temperature data collection. Thin Kapton membranes were used to capture multiple crystals simultaneously. The microcrystals were visible under an optical microscope and easily located because the membrane was transparent and sufficiently thin. The film was fixed to a bracket that was prepared using a three-dimensional printer. The bracket was fixed on a magnetic base via screwing and employed by the goniometer system for data collection. Multiple data sets of fatty acid-binding protein 4(FABP4) and lysozyme microcrystals were collected using this novel designed device. Finally, the structures of protein FABP4 and lysozyme were obtained from these data via the molecule replacement method. The data statistics reveal that this method provides a comparable result to traditional methods such as a nylon loop.
