A new multifunctional testing device for rock fragmentation was introduced, which can conduct many experiments such as single cutting under static load, crushing under impact load, thrusting under static load and cutt...A new multifunctional testing device for rock fragmentation was introduced, which can conduct many experiments such as single cutting under static load, crushing under impact load, thrusting under static load and cutting-impact test under the dynamic and static load. The results of granite and concrete抯 experiments with polycrystalline diamond compact (PDC) flat cutters and carbide alloy cutters under different loadings show that the device has good performance, and the characteristics of broken rock under the combined loads are similar to that under the single static pressure or impact crushing the rock, and the combined loads can increase the effect of rock fragmentation obviously. The experimental methods and effects have the important meaning for studying new drill-ing tool on hard rock fragmentation.展开更多
Electrochromic technology has gained significant attention in various fields such as displays,smart windows,biomedical monitoring,military camouflage,human-machine interaction,and electronic skin due to its ability to...Electrochromic technology has gained significant attention in various fields such as displays,smart windows,biomedical monitoring,military camouflage,human-machine interaction,and electronic skin due to its ability to provide reversible and fast color changes under applied voltage.With the rapid development and increasing demand for flexible electronics,flexible electrochromic devices(FECDs)that offer smarter and more controllable light modulation hold great promise for practical applications.The electrochromic material(ECM)undergoing color changes during the electrochemical reactions is one of the key components in electrochromic devices.Among the ECMs,viologens,a family of organic small molecules with 1,1'-disubstituted-4,4'-dipyridinium salts,have garnered extensive research interest,due to their well-reversible redox reactions,excellent electron acceptance ability,and the ability to produce multiple colors.Notably,viologen-based FECDs demonstrate color changes in the liquid or semisolid electrolyte layer,eliminating the need for two solid electrodes and thus simplifying the device structure.Consequently,viologens offer significant potential for the development of FECDs with high optical contrast,fast response speed,and excellent stability.This review aims to provide a comprehensive overview of the progress and perspectives of viologen-based FECDs.It begins by summarizing the typical structure and recent exciting developments in viologen-based FECDs,along with their advantages and disadvantages.Furthermore,the review discusses recent advancements in FECDs with additional functionalities such as sensing,photochromism,and energy storage.Finally,the remaining challenges and potential research directions for the future of viologen-based FECDs are addressed.展开更多
Multifunctional devices integrated with electrochromism and energy storage or energy production functions are attractive because these devices can be used as an effective approach to address the energy crisis and envi...Multifunctional devices integrated with electrochromism and energy storage or energy production functions are attractive because these devices can be used as an effective approach to address the energy crisis and environmental pollution in society today. In this review, we explain the operation principles of electrochromic energy storage devices including electrochromic supercapacitors,electrochromic batteries, and the photoelectrochromic devices. Furthermore, the material candidates and structure types of these multifunctional devices are discussed in detail. The major challenges of these devices along with a further outlook are highlighted at the end.展开更多
Multifunctional devices are of great interest for integration and miniaturization on the same platform, but simple addition of functionalities would lead to excessively large devices. Here, the photodetection and chem...Multifunctional devices are of great interest for integration and miniaturization on the same platform, but simple addition of functionalities would lead to excessively large devices. Here, the photodetection and chemical sensing device is developed based on two-dimensional(2D) glassygraphene that meets similar property requirements for the two functionalities. An appropriate bandgap arising from the distorted lattice structure enables glassy graphene to exhibit comparable or even improved photodetection and chemical sensing capability, compared with pristine graphene. Due to strong interactions between glassy graphene and the ambient atmosphere, the devices are less sensitive to photoinduced desorption than the ones based on graphene. Consequently,the few-layer glassy graphene device delivers positive photoresponse, with a responsivity of 0.22 A W^(-1) and specific detectivity reaching ~10^(10) Jones under 405 nm illumination.Moreover, the intrinsic defects and strain in glassy graphene can enhance the adsorption of analytes, leading to high chemical sensing performance. Specifically, the extracted signalto-noise-ratio of the glassy graphene device for detecting acetone is 48, representing more than 50% improvement over the device based on graphene. Additionally, bias-voltage-and thickness-dependent volatile organic compound(VOC) sensing features are identified, indicating the few-layer glassy graphene is more sensitive. This study successfully demonstrates the potential of glassy graphene for integrated photodetection and chemical sensing, providing a promising solution for multifunctional applications further beyond.展开更多
Metasurface-based nanoprinting(meta-nanoprinting)has fully demonstrated its advantages in ultrahigh-density gray-scale/color image recording and display.A typical meta-nanoprinting device usually has image resolutions...Metasurface-based nanoprinting(meta-nanoprinting)has fully demonstrated its advantages in ultrahigh-density gray-scale/color image recording and display.A typical meta-nanoprinting device usually has image resolutions reaching 80 k dots per inch(dpi),far exceeding conventional technology such as gravure printing(typ.5 k dpi).Besides,by fully exploit-ing the design degrees of freedom of nanostructured metasurfaces,meta-nanoprinting has been developed from previ-ous single-channel to multiple-channels,to current multifunctional integration or even dynamic display.In this review,we overview the development of meta-nanoprinting,including the physics of nanoprinting to manipulate optical amplitude and spectrum,single-functional meta-nanoprinting,multichannel meta-nanoprinting,dynamic meta-nanoprinting and mul-tifunctional metasurface integrating nanoprinting with holography or metalens,etc.Applications of meta-nanoprinting such as image display,vortex beam generation,information decoding and hiding,information encryption,high-density optical storage and optical anti-counterfeiting have also been discussed.Finally,we conclude the opportunities and chal-lenges/perspectives in this rapidly developing research field of meta-nanoprinting.展开更多
Electrochromic devices(ECDs)have exhibited promising applications in the fields of energy-saving intelligent buildings and next-generation displays because of their simple structure,low power consumption,and multicolo...Electrochromic devices(ECDs)have exhibited promising applications in the fields of energy-saving intelligent buildings and next-generation displays because of their simple structure,low power consumption,and multicolor displays.W_(18)O_(49)/polyaniline(PANI)hybrid films are prepared and assembled to ECDs.Compared with pure PANI and W_(18)O_(49) films,the hybrid film exhibits superior electrochemical and electrochromic performance,including high optical modulation(70.2%),large areal capacity(79.6 mF/cm^(2)),and good capacitance retention.The excellent electrochemical and electrochromic performance is ascribed to the formation of the donor(PANI)-acceptor(W_(18)O_(49))pair,the porous structure in the nanowires,and the large surface area,which enhance electron delocalization of the W_(18)O_(49)/PANI,improve the ion diffusion rate,and increase the charge storage sites.Furthermore,benefitting from the outstanding optical,electrical,and multifunctional properties,the W_(18)O_(49)/PANI hybrid film-based ECD platform is expected to play an important role in electrochromism and energy storage.展开更多
The growing demand of sustainable and biocompatible optical devices is stimulating the development of naturally derived biomaterials for optics and photonics. As a versatile biomaterial, silk provides excellent materi...The growing demand of sustainable and biocompatible optical devices is stimulating the development of naturally derived biomaterials for optics and photonics. As a versatile biomaterial, silk provides excellent material characteristics that are favorable towards the generation of advanced optical systems. This review examines the use of silk as a material platform in optical applications. Recent advances in silk-based optical devices and multifunctional devices are summarized. The challenges and directions in further designing and fabricating silk optics are also discussed. We envision that silk will play a pivotal role in the future exploitation of sustainable, intelligent, wearable/implantable, and multifunctional optical devices.展开更多
文摘A new multifunctional testing device for rock fragmentation was introduced, which can conduct many experiments such as single cutting under static load, crushing under impact load, thrusting under static load and cutting-impact test under the dynamic and static load. The results of granite and concrete抯 experiments with polycrystalline diamond compact (PDC) flat cutters and carbide alloy cutters under different loadings show that the device has good performance, and the characteristics of broken rock under the combined loads are similar to that under the single static pressure or impact crushing the rock, and the combined loads can increase the effect of rock fragmentation obviously. The experimental methods and effects have the important meaning for studying new drill-ing tool on hard rock fragmentation.
基金financial support from the National Natural Science Foundation of China(22105106)the Natural Science Foundation of Jiangsu Province of China(BK20210603)+1 种基金the Nanjing Science and Technology Innovation Project for overseas Students(NJKCZYZZ2022–05)the Start-up Funding from NUPTSF(NY221003)。
文摘Electrochromic technology has gained significant attention in various fields such as displays,smart windows,biomedical monitoring,military camouflage,human-machine interaction,and electronic skin due to its ability to provide reversible and fast color changes under applied voltage.With the rapid development and increasing demand for flexible electronics,flexible electrochromic devices(FECDs)that offer smarter and more controllable light modulation hold great promise for practical applications.The electrochromic material(ECM)undergoing color changes during the electrochemical reactions is one of the key components in electrochromic devices.Among the ECMs,viologens,a family of organic small molecules with 1,1'-disubstituted-4,4'-dipyridinium salts,have garnered extensive research interest,due to their well-reversible redox reactions,excellent electron acceptance ability,and the ability to produce multiple colors.Notably,viologen-based FECDs demonstrate color changes in the liquid or semisolid electrolyte layer,eliminating the need for two solid electrodes and thus simplifying the device structure.Consequently,viologens offer significant potential for the development of FECDs with high optical contrast,fast response speed,and excellent stability.This review aims to provide a comprehensive overview of the progress and perspectives of viologen-based FECDs.It begins by summarizing the typical structure and recent exciting developments in viologen-based FECDs,along with their advantages and disadvantages.Furthermore,the review discusses recent advancements in FECDs with additional functionalities such as sensing,photochromism,and energy storage.Finally,the remaining challenges and potential research directions for the future of viologen-based FECDs are addressed.
基金the National Natural Science Foundation of China (51572058, 91216123, 51174063, 51502057)the Natural Science Foundation of Heilongjiang Province (E201436)+1 种基金the International Science & Technology Cooperation Program of China(2013DFR10630, 2015DFE52770)the Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP 20132302110031)
文摘Multifunctional devices integrated with electrochromism and energy storage or energy production functions are attractive because these devices can be used as an effective approach to address the energy crisis and environmental pollution in society today. In this review, we explain the operation principles of electrochromic energy storage devices including electrochromic supercapacitors,electrochromic batteries, and the photoelectrochromic devices. Furthermore, the material candidates and structure types of these multifunctional devices are discussed in detail. The major challenges of these devices along with a further outlook are highlighted at the end.
基金supported by the National Natural Science Foundation of China (61974014)the EPSRC Future Compound Semiconductor Manufacturing Hub (EP/P006973/1)。
文摘Multifunctional devices are of great interest for integration and miniaturization on the same platform, but simple addition of functionalities would lead to excessively large devices. Here, the photodetection and chemical sensing device is developed based on two-dimensional(2D) glassygraphene that meets similar property requirements for the two functionalities. An appropriate bandgap arising from the distorted lattice structure enables glassy graphene to exhibit comparable or even improved photodetection and chemical sensing capability, compared with pristine graphene. Due to strong interactions between glassy graphene and the ambient atmosphere, the devices are less sensitive to photoinduced desorption than the ones based on graphene. Consequently,the few-layer glassy graphene device delivers positive photoresponse, with a responsivity of 0.22 A W^(-1) and specific detectivity reaching ~10^(10) Jones under 405 nm illumination.Moreover, the intrinsic defects and strain in glassy graphene can enhance the adsorption of analytes, leading to high chemical sensing performance. Specifically, the extracted signalto-noise-ratio of the glassy graphene device for detecting acetone is 48, representing more than 50% improvement over the device based on graphene. Additionally, bias-voltage-and thickness-dependent volatile organic compound(VOC) sensing features are identified, indicating the few-layer glassy graphene is more sensitive. This study successfully demonstrates the potential of glassy graphene for integrated photodetection and chemical sensing, providing a promising solution for multifunctional applications further beyond.
基金We are grateful for financial supports from the National Key Research and Development Program of China(Grant No.2021YFE0205800)National Natural Science Foundation of China(Grant Nos.12174292,62205252,11904267 and 91950110)the Fundamental Research Funds for the Central Universities(Grant Nos.2042022kf0024,2042022kf1013 and 2042022kf1011).
文摘Metasurface-based nanoprinting(meta-nanoprinting)has fully demonstrated its advantages in ultrahigh-density gray-scale/color image recording and display.A typical meta-nanoprinting device usually has image resolutions reaching 80 k dots per inch(dpi),far exceeding conventional technology such as gravure printing(typ.5 k dpi).Besides,by fully exploit-ing the design degrees of freedom of nanostructured metasurfaces,meta-nanoprinting has been developed from previ-ous single-channel to multiple-channels,to current multifunctional integration or even dynamic display.In this review,we overview the development of meta-nanoprinting,including the physics of nanoprinting to manipulate optical amplitude and spectrum,single-functional meta-nanoprinting,multichannel meta-nanoprinting,dynamic meta-nanoprinting and mul-tifunctional metasurface integrating nanoprinting with holography or metalens,etc.Applications of meta-nanoprinting such as image display,vortex beam generation,information decoding and hiding,information encryption,high-density optical storage and optical anti-counterfeiting have also been discussed.Finally,we conclude the opportunities and chal-lenges/perspectives in this rapidly developing research field of meta-nanoprinting.
基金supported by the National Natural Scientific Foundation of China(No.21804074)China Postdoctoral Science Foundation(No.2020T130331)the Open Funds of the State Key Laboratory of Physical Chemistry of Solid Surfaces(No.202023).
文摘Electrochromic devices(ECDs)have exhibited promising applications in the fields of energy-saving intelligent buildings and next-generation displays because of their simple structure,low power consumption,and multicolor displays.W_(18)O_(49)/polyaniline(PANI)hybrid films are prepared and assembled to ECDs.Compared with pure PANI and W_(18)O_(49) films,the hybrid film exhibits superior electrochemical and electrochromic performance,including high optical modulation(70.2%),large areal capacity(79.6 mF/cm^(2)),and good capacitance retention.The excellent electrochemical and electrochromic performance is ascribed to the formation of the donor(PANI)-acceptor(W_(18)O_(49))pair,the porous structure in the nanowires,and the large surface area,which enhance electron delocalization of the W_(18)O_(49)/PANI,improve the ion diffusion rate,and increase the charge storage sites.Furthermore,benefitting from the outstanding optical,electrical,and multifunctional properties,the W_(18)O_(49)/PANI hybrid film-based ECD platform is expected to play an important role in electrochromism and energy storage.
文摘The growing demand of sustainable and biocompatible optical devices is stimulating the development of naturally derived biomaterials for optics and photonics. As a versatile biomaterial, silk provides excellent material characteristics that are favorable towards the generation of advanced optical systems. This review examines the use of silk as a material platform in optical applications. Recent advances in silk-based optical devices and multifunctional devices are summarized. The challenges and directions in further designing and fabricating silk optics are also discussed. We envision that silk will play a pivotal role in the future exploitation of sustainable, intelligent, wearable/implantable, and multifunctional optical devices.