Photo-induced intramolecular electron transfer （PIET） and intramolecular vibrational relaxation （IVR） dynamics of the excited state of rhodamine 6G （Rh6G＋） in DMSO are investigated by multiplex transient gratin...Photo-induced intramolecular electron transfer （PIET） and intramolecular vibrational relaxation （IVR） dynamics of the excited state of rhodamine 6G （Rh6G＋） in DMSO are investigated by multiplex transient grating. Two major compo- nents are resolved in the dynamics of Rh6G＋. The first component, with a lifetime τTPIET = 140 fs-260 fs, is attributed to PIET from the phenyl ring to the xanthene plane. The IVR process occurring in the range ZIVR = 3.3 ps-5.2 ps is much slower than the first component. The PIET and IVR processes occurring in the excited state of Rh6G＋ are quantitatively determined, and a better understanding of the relationship between these processes is obtained.展开更多
为了降低水声信道强多径效应、大多普勒频移等特性对水声通信系统的影响,提出一种基于极化码的正交频分复用(Orthogonal Frequency Division Multiplexing,OFDM)的水声通信系统。选择极化(Polar)码作为信道编码方案,通过量化信道输出直...为了降低水声信道强多径效应、大多普勒频移等特性对水声通信系统的影响,提出一种基于极化码的正交频分复用(Orthogonal Frequency Division Multiplexing,OFDM)的水声通信系统。选择极化(Polar)码作为信道编码方案,通过量化信道输出直接统计信道转移概率,替代通过信道估计得到的信道冲激响应,再计算转移概率,以降低通信系统的复杂度。在特性随时不变、时变、快时变的3种类型水声信道模型下,分别基于蒙特卡罗算法构造Polar码。仿真结果表明,Polar码在3种信道上的编码增益优于同码长同码率的低密度奇偶校验(Low Density Parity Check,LDPC)码和Turbo码,且信道条件越复杂,取得的编码增益越大,所提系统能够明显降低信道多径效应、多普勒频移对水声通信系统的扰乱,提高系统的可靠性。展开更多
Iodine-doped (C22H16N2SO2) was prepared by doping the dye with iodine vapor. The following characteristics were obtained by structure analysis.1. The doped iodine exists as I3-anion and I2.2. Because the electron loca...Iodine-doped (C22H16N2SO2) was prepared by doping the dye with iodine vapor. The following characteristics were obtained by structure analysis.1. The doped iodine exists as I3-anion and I2.2. Because the electron located on the sulphur atom was transferred to iodine, a charge transfer complx of (C22H16N2SO2I5) was formed.3. The complex was proved to exist in a quasi-one dimension conductor state, forming two ordered molecular stacks.4. From the volt-ampere curve with sandwich cell, the room temperature resistivity (ρ)and the exciting energe (ΔE) of the doped complex were shown to he 3.47×107Ω·cm-1and 0.4eV respectivily.5. Its electrical behavior obeys the fomula ρ = ρ0exp(ΔE/kt), showing the behavior of a typical semicanductor.展开更多
针对目前应用在感应耦合电能传输ICPT(inductive coupling power transfer)系统中数据传输技术的传输速率低、系统电路复杂等问题,提出一种基于部分能量线圈和正交频分复用OFDM(orthogonal frequency division multiplexing)技术的ICPT...针对目前应用在感应耦合电能传输ICPT(inductive coupling power transfer)系统中数据传输技术的传输速率低、系统电路复杂等问题,提出一种基于部分能量线圈和正交频分复用OFDM(orthogonal frequency division multiplexing)技术的ICPT系统高速数据传输方案。该方案利用能量耦合线圈的一部分来构建高速数据传输通道,使得主要的电路拓扑具有带通滤波器的特性,并且数据传输通道对信号载波呈现低阻抗特性,对电能载波呈现高阻抗特性,从而减小了电能载波对信号载波的影响;采用OFDM技术提高数据载波频带利用率及抗干扰性,实现高速数据传输。实验结果验证了系统在保证电能传输不受影响的同时实现了高达10Mbps的数据传输速率。展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.21003033 and 21203047)the Guangxi Provincial Natural Science Foundation,China(Grant Nos.2012GXNSFBA053012 and 2014GXNSFAA118019)the Research Foundation of Education Bureau of Guangxi Zhuang Autonomous Region,China(Grant No.ZD2014127)
文摘Photo-induced intramolecular electron transfer （PIET） and intramolecular vibrational relaxation （IVR） dynamics of the excited state of rhodamine 6G （Rh6G＋） in DMSO are investigated by multiplex transient grating. Two major compo- nents are resolved in the dynamics of Rh6G＋. The first component, with a lifetime τTPIET = 140 fs-260 fs, is attributed to PIET from the phenyl ring to the xanthene plane. The IVR process occurring in the range ZIVR = 3.3 ps-5.2 ps is much slower than the first component. The PIET and IVR processes occurring in the excited state of Rh6G＋ are quantitatively determined, and a better understanding of the relationship between these processes is obtained.
文摘为了降低水声信道强多径效应、大多普勒频移等特性对水声通信系统的影响,提出一种基于极化码的正交频分复用(Orthogonal Frequency Division Multiplexing,OFDM)的水声通信系统。选择极化(Polar)码作为信道编码方案,通过量化信道输出直接统计信道转移概率,替代通过信道估计得到的信道冲激响应,再计算转移概率,以降低通信系统的复杂度。在特性随时不变、时变、快时变的3种类型水声信道模型下,分别基于蒙特卡罗算法构造Polar码。仿真结果表明,Polar码在3种信道上的编码增益优于同码长同码率的低密度奇偶校验(Low Density Parity Check,LDPC)码和Turbo码,且信道条件越复杂,取得的编码增益越大,所提系统能够明显降低信道多径效应、多普勒频移对水声通信系统的扰乱,提高系统的可靠性。
文摘Iodine-doped (C22H16N2SO2) was prepared by doping the dye with iodine vapor. The following characteristics were obtained by structure analysis.1. The doped iodine exists as I3-anion and I2.2. Because the electron located on the sulphur atom was transferred to iodine, a charge transfer complx of (C22H16N2SO2I5) was formed.3. The complex was proved to exist in a quasi-one dimension conductor state, forming two ordered molecular stacks.4. From the volt-ampere curve with sandwich cell, the room temperature resistivity (ρ)and the exciting energe (ΔE) of the doped complex were shown to he 3.47×107Ω·cm-1and 0.4eV respectivily.5. Its electrical behavior obeys the fomula ρ = ρ0exp(ΔE/kt), showing the behavior of a typical semicanductor.
文摘针对目前应用在感应耦合电能传输ICPT(inductive coupling power transfer)系统中数据传输技术的传输速率低、系统电路复杂等问题,提出一种基于部分能量线圈和正交频分复用OFDM(orthogonal frequency division multiplexing)技术的ICPT系统高速数据传输方案。该方案利用能量耦合线圈的一部分来构建高速数据传输通道,使得主要的电路拓扑具有带通滤波器的特性,并且数据传输通道对信号载波呈现低阻抗特性,对电能载波呈现高阻抗特性,从而减小了电能载波对信号载波的影响;采用OFDM技术提高数据载波频带利用率及抗干扰性,实现高速数据传输。实验结果验证了系统在保证电能传输不受影响的同时实现了高达10Mbps的数据传输速率。
