Cyber-physical power system(CPPS)has significantly improved the operational efficiency of power systems.However,cross-space cascading failures may occur due to the coupling characteristics,which poses a great threat t...Cyber-physical power system(CPPS)has significantly improved the operational efficiency of power systems.However,cross-space cascading failures may occur due to the coupling characteristics,which poses a great threat to the safety and reliability of CPPS,and there is an acute need to reduce the probability of these failures.Towards this end,this paper first proposes a cascading failure index to identify and quantify the importance of different information in the same class of communication services.On this basis,a joint improved risk-balanced service function chain routing strategy(SFC-RS)is proposed,which is modeled as a robust optimization problem and solved by column-and-constraint generation(C-CG)algorithm.Compared with the traditional shortest-path routing algorithm,the superiority of SFC-RS is verified in the IEEE 30-bus system.The results demonstrate that SFC-RS effectively mitigates the risk associated with information transmission in the network,enhances information transmission accessibility,and effectively limits communication disruption from becoming the cause of cross-space cascading failures.展开更多
Metal oxide charge transport materials are preferable for realizing long-term stable and potentially low-cost perovskite solar cells(PSCs).However,due to some technical difficulties(e.g.,intricate fabrication protocol...Metal oxide charge transport materials are preferable for realizing long-term stable and potentially low-cost perovskite solar cells(PSCs).However,due to some technical difficulties(e.g.,intricate fabrication protocols,high-temperature heating process,incompatible solvents,etc.),it is still challenging to achieve efficient and reliable all-metal-oxide-based devices.Here,we developed efficient inverted PSCs(IPSCs)based on solution-processed nickel oxide(NiO_(x))and tin oxide(SnO_(2))nanoparticles,working as hole and electron transport materials respectively,enabling a fast and balanced charge transfer for photogenerated charge carriers.Through further understanding and optimizing the perovskite/metal oxide interfaces,we have realized an outstanding power conversion efficiency(PCE)of 23.5%(the bandgap of the perovskite is 1.62 eV),which is the highest efficiency among IPSCs based on all-metal-oxide charge transport materials.Thanks to these stable metal oxides and improved interface properties,ambient stability(retaining 95%of initial PCE after 1 month),thermal stability(retaining 80%of initial PCE after 2 weeks)and light stability(retaining 90%of initial PCE after 1000 hours aging)of resultant devices are enhanced significantly.In addition,owing to the low-temperature fabrication procedures of the entire device,we have obtained a PCE of over 21%for flexible IPSCs with enhanced operational stability.展开更多
Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic...Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic limestone reservoirs of Cretaceous in Iran-Iraq as an example,this paper proposes a balanced waterflooding development technology for thick and complex carbonate reservoirs.This technology includes the fine division of development units by concealed baffles and barriers,the combination of multi well type and multi well pattern,and the construction of balanced water injection and recovery system.Thick carbonate reservoirs in Iran-Iraq are characterized by extremely vertical heterogeneity,development of multi-genesis ultra-high permeability zones,and highly concealed baffles and barriers.Based on the technologies of identification,characterization,and sealing evaluation for concealed baffles and barriers,the balanced waterflooding development technology is proposed,and three types of balanced waterflooding development modes/techniques are formed,namely,conventional stratigraphic framework,fine stratigraphic framework,and deepened stratigraphic framework.Numerical simulations show that this technology is able to realize a fine and efficient waterflooding development to recover,in a balanced manner,the reserves of thick and complex carbonate reservoirs in Iran and Iraq.The proposed technology provides a reference for the development optimization of similar reservoirs.展开更多
Background:With public health emergencies(PHE)worldwide increasing,the perceived risk of PHE has been one of the critical factors influencing college students’psychological distress.However,the mechanisms by which th...Background:With public health emergencies(PHE)worldwide increasing,the perceived risk of PHE has been one of the critical factors influencing college students’psychological distress.However,the mechanisms by which the perceived risk of PHE affects college students’psychological distress are not clear.The study’s purpose was to investigate the mediation roles of deviation from a balanced time perspective(DBTP)and negative coping styles between the perceived risk of PHE and psychological distress.Methods:A convenience sampling method was used to survey 1054 Chinese college students with self-reporting.Data was collected using the Public Risk Perception Scale(PRPS),the Zimbardo Time Perspective Inventory(ZTPI),the Simplified Coping Style Questionnaire(SCSQ),the PHE Anxiety Scale,and the Chinese version of the Patient Health Questionnaire(PHQ).The associations between the perceived risk of PHE,DBTP,negative coping styles,and psychological distress were clarified using the correlation analysis.Additionally,the mediating roles of DBTP and negative coping styles between the perceived risk of PHE and psychological distress were investigated using a structural equation model.Results:The findings revealed low to moderate correlations between the variables studied.Students’perceived risk of PHE was a positive predictor of their psychological distress(b=0.219,p<0.01).DBTP and negative coping styles played chain mediation roles between them with the effect being 0.009 and a 95%Boot CI of[0.003,0.023].This chain mediation model had an excellent fit index(χ^(2)/df=4.732,CFI=0.973,TLI=0.930,RMSEA=0.048,SRMR=0.047).Conclusion:These findings showed how the perceived risk of PHE affected college students’psychological distress.Specifically,these results suggested that improving students’mental ability to switch effectively among different time perspectives depending on task features and situational considerations and reducing their negative coping styles might be effective ways to promote their mental health.展开更多
With the rapid development of our country’s economy,education has gradually become the focus of social attention.The problem of unbalanced distribution of urban and rural educational resources has become increasingly...With the rapid development of our country’s economy,education has gradually become the focus of social attention.The problem of unbalanced distribution of urban and rural educational resources has become increasingly prominent,urban educational resources are relatively rich,while rural educational resources are relatively scarce,and the balanced development of urban and rural compulsory education has become an urgent task.This paper mainly investigates and studies the distribution of urban and rural educational resources,discusses the unbalanced distribution of urban and rural educational resources and analyzes the reasons,and puts forward a series of corresponding solutions to promote the balanced development of urban and rural compulsory education.展开更多
Peer-to-peer(P2P)energy trading refers to a type of decentralized transaction,where the energy from distributed energy resources is directly traded between peers.A key challenge in peer-to-peer energy trading is desig...Peer-to-peer(P2P)energy trading refers to a type of decentralized transaction,where the energy from distributed energy resources is directly traded between peers.A key challenge in peer-to-peer energy trading is designing a safe,efficient,and transparent trading model and operating mechanism.In this study,we consider a P2P trading environment based on blockchain technology,where prosumers can submit bids or offers without knowing the reports of others.We propose an Arrow-d’Aspremont-Gerard-Varet(AGV)-based mechanism to encourage prosumers to submit their real reserve price and determine the P2P transaction price.We demonstrate that the AGV mechanism can achieve Bayesian incentive compatibility and budget balance.Kernel density estimation(KDE)is used to derive the prior distribution from the historical bid/offer information of the agents.Case studies are carried out to analyze and evaluate the proposed mechanism.Simulation results verify the effectiveness of the proposed mechanism in guiding agents to report the true reserve price while maximizing social welfare.Moreover,we discuss the advantages of budget balance for decentralized trading by comparing the Vickrey-Clarke-Groves(VCG)and AGV mechanisms.展开更多
Mobile Edge Computing(MEC)-based computation offloading is a promising application paradigm for serving large numbers of users with various delay and energy requirements.In this paper,we propose a flexible MECbased re...Mobile Edge Computing(MEC)-based computation offloading is a promising application paradigm for serving large numbers of users with various delay and energy requirements.In this paper,we propose a flexible MECbased requirement-adaptive partial offloading model to accommodate each user's specific preference regarding delay and energy consumption.To address the dimensional differences between time and energy,we introduce two normalized parameters and then derive the computational overhead of processing tasks.Different from existing works,this paper considers practical variations in the user request patterns,and exploits a flexible partial offloading mode to minimize computation overheads subject to tolerable delay,task workload and power constraints.Since the resulting problem is non-convex,we decouple it into two convex subproblems and present an iterative algorithm to obtain a feasible offloading solution.Numerical experiments show that our proposed scheme achieves a significant improvement in computation overheads compared with existing schemes.展开更多
In recent years,the introduction of fused rings own high density and low sensitivity has promoted the development of energetic materials.However,the development of energetic compounds containing fused and bridged ring...In recent years,the introduction of fused rings own high density and low sensitivity has promoted the development of energetic materials.However,the development of energetic compounds containing fused and bridged rings by introducing multiple nitrogen heterocycles at different sites of fused rings is still difficult to progress,which seriously limits the emergence of advanced energetic compounds.In this study,a series of energetic materials choosing different nitrogen rich heterocycles at the vacancies of the fused ring,i.e.,neutral compound 5,6 and their ionic derivatives(compounds 7-12)were designed and synthesized.Compounds 5 and 6 were further confirmed by single crystal X-ray diffraction,while the crystal analysis and theoretical calculations were carried out to explore the relationship between crystal structure and physicochemical properties.All of the newly synthesized compounds(5-12)are insensitive to mechanical stimulation(IS>40 J;FS≥342 N)and they own the high detonation velocity(D:8322-9075 m/s).Notably,hydrazine salt 11 own the higher detonation velocity(9075 m/s)and powder density(1.83 g/cm^(3)),but exhibits lower sensitivity(IS>40 J)than the classical energetic compound RDX(8795 m/s,1.80 g/cm^(3),7.5 J).It is obvious that the combination of 5,6-fused triazolo-triazine and nitropyrazole-tetrazole may be a new energetic skeleton for synthesising the heterocyclic compounds with balanced energy-stability.展开更多
The amount of oxygen blown into the converter is one of the key parameters for the control of the converter blowing process,which directly affects the tap-to-tap time of converter. In this study, a hybrid model based ...The amount of oxygen blown into the converter is one of the key parameters for the control of the converter blowing process,which directly affects the tap-to-tap time of converter. In this study, a hybrid model based on oxygen balance mechanism (OBM) and deep neural network (DNN) was established for predicting oxygen blowing time in converter. A three-step method was utilized in the hybrid model. First, the oxygen consumption volume was predicted by the OBM model and DNN model, respectively. Second, a more accurate oxygen consumption volume was obtained by integrating the OBM model and DNN model. Finally, the converter oxygen blowing time was calculated according to the oxygen consumption volume and the oxygen supply intensity of each heat. The proposed hybrid model was verified using the actual data collected from an integrated steel plant in China, and compared with multiple linear regression model, OBM model, and neural network model including extreme learning machine, back propagation neural network, and DNN. The test results indicate that the hybrid model with a network structure of 3 hidden layer layers, 32-16-8 neurons per hidden layer, and 0.1 learning rate has the best prediction accuracy and stronger generalization ability compared with other models. The predicted hit ratio of oxygen consumption volume within the error±300 m^(3)is 96.67%;determination coefficient (R^(2)) and root mean square error (RMSE) are0.6984 and 150.03 m^(3), respectively. The oxygen blow time prediction hit ratio within the error±0.6 min is 89.50%;R2and RMSE are0.9486 and 0.3592 min, respectively. As a result, the proposed model can effectively predict the oxygen consumption volume and oxygen blowing time in the converter.展开更多
Sensors are considered as important elements of electronic devices.In many applications and service,Wireless Sensor Networks(WSNs)are involved in significant data sharing that are delivered to the sink node in energy ...Sensors are considered as important elements of electronic devices.In many applications and service,Wireless Sensor Networks(WSNs)are involved in significant data sharing that are delivered to the sink node in energy efficient man-ner using multi-hop communications.But,the major challenge in WSN is the nodes are having limited battery resources,it is important to monitor the consumption rate of energy is very much needed.However,reducing energy con-sumption can increase the network lifetime in effective manner.For that,clustering methods are widely used for optimizing the rate of energy consumption among the sensor nodes.In that concern,this paper involves in deriving a novel model called Improved Load-Balanced Clustering for Energy-Aware Routing(ILBC-EAR),which mainly concentrates on optimal energy utilization with load-balanced process among cluster heads and member nodes.For providing equal rate of energy consumption among nodes,the dimensions of framed clusters are measured.Moreover,the model develops a Finest Routing Scheme based on Load-Balanced Clustering to transmit the sensed information to the sink or base station.The evaluation results depict that the derived energy aware model attains higher rate of life time than other works and also achieves balanced energy rate among head node.Additionally,the model also provides higher throughput and minimal delay in delivering data packets.展开更多
Real-time applications based on Wireless Sensor Network(WSN)tech-nologies are quickly increasing due to intelligent surroundings.Among the most significant resources in the WSN are battery power and security.Clustering...Real-time applications based on Wireless Sensor Network(WSN)tech-nologies are quickly increasing due to intelligent surroundings.Among the most significant resources in the WSN are battery power and security.Clustering stra-tegies improve the power factor and secure the WSN environment.It takes more electricity to forward data in a WSN.Though numerous clustering methods have been developed to provide energy consumption,there is indeed a risk of unequal load balancing,resulting in a decrease in the network’s lifetime due to network inequalities and less security.These possibilities arise due to the cluster head’s limited life span.These cluster heads(CH)are in charge of all activities and con-trol intra-cluster and inter-cluster interactions.The proposed method uses Lifetime centric load balancing mechanisms(LCLBM)and Cluster-based energy optimiza-tion using a mobile sink algorithm(CEOMS).LCLBM emphasizes the selection of CH,system architectures,and optimal distribution of CH.In addition,the LCLBM was added with an assistant cluster head(ACH)for load balancing.Power consumption,communications latency,the frequency of failing nodes,high security,and one-way delay are essential variables to consider while evaluating LCLBM.CEOMS will choose a cluster leader based on the influence of the fol-lowing parameters on the energy balance of WSNs.According to simulatedfind-ings,the suggested LCLBM-CEOMS method increases cluster head selection self-adaptability,improves the network’s lifetime,decreases data latency,and bal-ances network capacity.展开更多
Internet of Things(IoT)empowers imaginative applications and permits new services when mobile nodes are included.For IoT-enabled low-power and lossy networks(LLN),the Routing Protocol for Low-power and Lossy Networks(...Internet of Things(IoT)empowers imaginative applications and permits new services when mobile nodes are included.For IoT-enabled low-power and lossy networks(LLN),the Routing Protocol for Low-power and Lossy Networks(RPL)has become an established standard routing protocol.Mobility under standard RPL remains a difficult issue as it causes continuous path disturbance,energy loss,and increases the end-to-end delay in the network.In this unique circumstance,a Balanced-load and Energy-efficient RPL(BE-RPL)is proposed.It is a routing technique that is both energy-efficient and mobility-aware.It responds quicker to link breakage through received signal strength-based mobility monitoring and selecting a new preferred parent reactively.The proposed system also implements load balancing among stationary nodes for leaf node allocation.Static nodes with more leaf nodes are restricted from participating in the election for a new preferred parent.The performance of BE-RPL is assessed using the COOJA simulator.It improves the energy use,network control overhead,frame acknowledgment ratio,and packet delivery ratio of the network.展开更多
Hydrological models are very useful tools for evaluating water resources, and the hydroclimatic hazards associated with the water cycle. However, their calibration and validation require the use of performance criteri...Hydrological models are very useful tools for evaluating water resources, and the hydroclimatic hazards associated with the water cycle. However, their calibration and validation require the use of performance criteria which choice is not straightforward. This paper aims to evaluate the influence of the performance criteria on water balance components and water extremes using two global rainfall-runoff models (HBV and GR4J) over the Ouémé watershed at the Bonou and Savè outlets. Three (3) Efficacy criteria (Nash, coefficient of determination, and KGE) were considered for calibration and validation. The results show that the Nash criterion provides a good assessment of the simulation of the different parts of the hydrograph. KGE is better for simulating peak flows and water balance elements than other efficiency criteria. This study could serve as a basis for the choice of performance criteria in hydrological modelling.展开更多
This paper focuses on the scheduling problem of workflow tasks that exhibit interdependencies.Unlike indepen-dent batch tasks,workflows typically consist of multiple subtasks with intrinsic correlations and dependenci...This paper focuses on the scheduling problem of workflow tasks that exhibit interdependencies.Unlike indepen-dent batch tasks,workflows typically consist of multiple subtasks with intrinsic correlations and dependencies.It necessitates the distribution of various computational tasks to appropriate computing node resources in accor-dance with task dependencies to ensure the smooth completion of the entire workflow.Workflow scheduling must consider an array of factors,including task dependencies,availability of computational resources,and the schedulability of tasks.Therefore,this paper delves into the distributed graph database workflow task scheduling problem and proposes a workflow scheduling methodology based on deep reinforcement learning(DRL).The method optimizes the maximum completion time(makespan)and response time of workflow tasks,aiming to enhance the responsiveness of workflow tasks while ensuring the minimization of the makespan.The experimental results indicate that the Q-learning Deep Reinforcement Learning(Q-DRL)algorithm markedly diminishes the makespan and refines the average response time within distributed graph database environments.In quantifying makespan,Q-DRL achieves mean reductions of 12.4%and 11.9%over established First-fit and Random scheduling strategies,respectively.Additionally,Q-DRL surpasses the performance of both DRL-Cloud and Improved Deep Q-learning Network(IDQN)algorithms,with improvements standing at 4.4%and 2.6%,respectively.With reference to average response time,the Q-DRL approach exhibits a significantly enhanced performance in the scheduling of workflow tasks,decreasing the average by 2.27%and 4.71%when compared to IDQN and DRL-Cloud,respectively.The Q-DRL algorithm also demonstrates a notable increase in the efficiency of system resource utilization,reducing the average idle rate by 5.02%and 9.30%in comparison to IDQN and DRL-Cloud,respectively.These findings support the assertion that Q-DRL not only upholds a lower average idle rate but also effectively curtails the average response time,thereby substantially improving processing efficiency and optimizing resource utilization within distributed graph database systems.展开更多
Unbalanced traffic distribution in cellular networks results in congestion and degrades spectrum efficiency.To tackle this problem,we propose an Unmanned Aerial Vehicle(UAV)-assisted wireless network in which the UAV ...Unbalanced traffic distribution in cellular networks results in congestion and degrades spectrum efficiency.To tackle this problem,we propose an Unmanned Aerial Vehicle(UAV)-assisted wireless network in which the UAV acts as an aerial relay to divert some traffic from the overloaded cell to its adjacent underloaded cell.To fully exploit its potential,we jointly optimize the UAV position,user association,spectrum allocation,and power allocation to maximize the sum-log-rate of all users in two adjacent cells.To tackle the complicated joint optimization problem,we first design a genetic-based algorithm to optimize the UAV position.Then,we simplify the problem by theoretical analysis and devise a low-complexity algorithm according to the branch-and-bound method,so as to obtain the optimal user association and spectrum allocation schemes.We further propose an iterative power allocation algorithm based on the sequential convex approximation theory.The simulation results indicate that the proposed UAV-assisted wireless network is superior to the terrestrial network in both utility and throughput,and the proposed algorithms can substantially improve the network performance in comparison with the other schemes.展开更多
We present a theoretical study of the medium modifications of the p_(T)balance (x_(J)) of dijets in Xe+Xe collisions at■.The initial production of dijets was carried out using the POWHEG+PYTHIA8 prescription,which ma...We present a theoretical study of the medium modifications of the p_(T)balance (x_(J)) of dijets in Xe+Xe collisions at■.The initial production of dijets was carried out using the POWHEG+PYTHIA8 prescription,which matches the next-toleading-order (NLO) QCD matrix elements with the parton shower (PS) effect.The SHELL model described the in-medium evolution of nucleus–nucleus collisions using a transport approach.The theoretical results of the dijet xJin the Xe+Xe collisions exhibit more imbalanced distributions than those in the p+p collisions,consistent with recently reported ATLAS data.By utilizing the Interleaved Flavor Neutralisation,an infrared-and-collinear-safe jet flavor algorithm,to identify the flavor of the reconstructed jets,we classify dijets processes into three categories:gluon–gluon (gg),quark–gluon (qg),and quark–quark (qq),and investigated the respective medium modification patterns and fraction changes of the gg,qg,and qq components of the dijet sample in Xe+Xe collisions.It is shown that the increased fraction of qg component at a small x_(J)contributes to the imbalance of the dijet;in particular,the q_(1)g_(2)(quark-jet-leading) dijets experience more significant asymmetric energy loss than the g_(1)q_(2)(gluon-jet-leading) dijets traversing the QGP.By comparing the■of inclusive,■ dijets in Xe+Xe collisions,we observe■.Moreover,ρ_(Xe),P_(b),the ratios of the nuclear modification factors of dijets in Xe+Xe to those in Pb+Pb,were calculated,which indicates that the yield suppression of dijets in Pb+Pb is more pronounced than that in Xe+Xe owing to the larger radius of the lead nucleus.展开更多
Evapotranspiration is an important parameter used to characterize the water cycle of ecosystems.To under-stand the properties of the evapotranspiration and energy balance of a subalpine forest in the southeastern Qing...Evapotranspiration is an important parameter used to characterize the water cycle of ecosystems.To under-stand the properties of the evapotranspiration and energy balance of a subalpine forest in the southeastern Qinghai-Tibet Plateau,an open-path eddy covariance system was set up to monitor the forest from November 2020 to October 2021 in a core area of the Three Parallel Rivers in the Qing-hai-Tibet Plateau.The results show that the evapotranspira-tion peaked daily,the maximum occurring between 11:00 and 15:00.Environmental factors had significant effects on evapotranspiration,among them,net radiation the greatest(R^(2)=0.487),and relative humidity the least(R^(2)=0.001).The energy flux varied considerably in different seasons and sensible heat flux accounted for the main part of turbulent energy.The energy balance ratio in the dormant season was less than that in the growing season,and there is an energy imbalance at the site on an annual time scale.展开更多
Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do ...Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do not involve any special data structure,and do not induce savings in memory requirements,they are easily implemented on existing codes and are recommended for 1D and 2D simulations when intensive testing is required.The multilevel technique can also be applied to balance laws,but in this case,numerical errors may be induced by the technique.We present a series of numerical tests that point out that the use of monotonicity-preserving interpolatory techniques eliminates the numerical errors observed when using the usual 4-point centered Lagrange interpolation,and leads to a more robust multilevel code for balance laws,while maintaining the efficiency rates observed forhyperbolic conservation laws.展开更多
A Josephson traveling wave parametric amplifier(JTWPA),which is a quantum-limited amplifier with high gain and large bandwidth,is the core device of large-scale measurement and control systems for quantum computing.A ...A Josephson traveling wave parametric amplifier(JTWPA),which is a quantum-limited amplifier with high gain and large bandwidth,is the core device of large-scale measurement and control systems for quantum computing.A typical JTWPA consists of thousands of Josephson junctions connected in series to form a transmission line and hundreds of shunt LC resonators periodically loaded along the line for phase matching.Because the variation of these capacitors and inductors can be detrimental to their high-frequency characteristics,the fabrication of a JTWPA typically necessitates precise processing equipment.To guide the fabrication process and further improve the design for manufacturability,it is necessary to understand how each electronic component affects the amplifier.In this paper,we use the harmonic balance method to conduct a comprehensive study on the impact of nonuniformity and fabrication yield of the electronic components on the performance of a JTWPA.The results provide insightful and scientific guidance for device design and fabrication processes.展开更多
The balance between metal and acid sites directly affects the preparation of high-performance cracking catalysts with high heat sink and low coking.Nevertheless,how to control acid-metal sites balance and its relation...The balance between metal and acid sites directly affects the preparation of high-performance cracking catalysts with high heat sink and low coking.Nevertheless,how to control acid-metal sites balance and its relationship with cracking performance are reported scarcely.In this work,a series of Pt/Al_(2)O_(3)-SiO_(2) dual sites catalysts with different metal to acid active sites ratio(C_(M)/C_(SA))were constructed by ethanolassisted impregnation method and the impact on n-decane cracking under supercritical conditions was systematically and deeply investigated.The results showed that the conversion and carbon deposition increased gradually with varied C_(M)/C_(SA)and reached the balance at C_(M)/C_(SA)of 0.13.The proper ratio C_(M)/C_(SA)(0.13)can balance the deep dehydrogenation coking over metal active sites and high heat sink of cracking over acid active sites,the chemical heat sink reaches amazing 1.75 MJ/kg and carbon deposition is only22.03 mg/cm^(2) at 750℃.Meanwhile,the few metal sites at low C_(M)/C_(SA)and the few strong acid sites at high C_(M)/C_(SA)are the main factors limiting the cracking activity.Low C_(M)/C_(SA)limit the activation of C-H bond and deep dehydrogenation of coking precursor,resulting in relative low cracking activity and carbon deposition,while high C_(M)/C_(SA)limit the activation of C-C bond and increase the deep dehydrogenation.In this contribution,design and construction of metal-acid dual sites can not only provide the technical solution for the preparation of high heat sink and low coking cracking catalyst,but also deepen the understanding of the cracking path of hydrocarbon fuel.展开更多
基金funded by the National Natural Science Foundation of China under Grant 52177074.
文摘Cyber-physical power system(CPPS)has significantly improved the operational efficiency of power systems.However,cross-space cascading failures may occur due to the coupling characteristics,which poses a great threat to the safety and reliability of CPPS,and there is an acute need to reduce the probability of these failures.Towards this end,this paper first proposes a cascading failure index to identify and quantify the importance of different information in the same class of communication services.On this basis,a joint improved risk-balanced service function chain routing strategy(SFC-RS)is proposed,which is modeled as a robust optimization problem and solved by column-and-constraint generation(C-CG)algorithm.Compared with the traditional shortest-path routing algorithm,the superiority of SFC-RS is verified in the IEEE 30-bus system.The results demonstrate that SFC-RS effectively mitigates the risk associated with information transmission in the network,enhances information transmission accessibility,and effectively limits communication disruption from becoming the cause of cross-space cascading failures.
基金UK Engineering and Physical Sciences Research Council(EPSRC)New Investigator Award(2018,EP/R043272/1)Newton Advanced Fellowship(192097)for financial support+3 种基金the Royal Society,the Engineering and Physical Sciences Research Council(EPSRC,EP/R023980/1,EP/V027131/1)the European Research Council(ERC)under the European Union's Horizon 2020 research and innovation program(HYPERION,Grant Agreement Number 756962)the Royal Society and Tata Group(UF150033)EPSRC SPECIFIC IKC(EP/N020863/1)
文摘Metal oxide charge transport materials are preferable for realizing long-term stable and potentially low-cost perovskite solar cells(PSCs).However,due to some technical difficulties(e.g.,intricate fabrication protocols,high-temperature heating process,incompatible solvents,etc.),it is still challenging to achieve efficient and reliable all-metal-oxide-based devices.Here,we developed efficient inverted PSCs(IPSCs)based on solution-processed nickel oxide(NiO_(x))and tin oxide(SnO_(2))nanoparticles,working as hole and electron transport materials respectively,enabling a fast and balanced charge transfer for photogenerated charge carriers.Through further understanding and optimizing the perovskite/metal oxide interfaces,we have realized an outstanding power conversion efficiency(PCE)of 23.5%(the bandgap of the perovskite is 1.62 eV),which is the highest efficiency among IPSCs based on all-metal-oxide charge transport materials.Thanks to these stable metal oxides and improved interface properties,ambient stability(retaining 95%of initial PCE after 1 month),thermal stability(retaining 80%of initial PCE after 2 weeks)and light stability(retaining 90%of initial PCE after 1000 hours aging)of resultant devices are enhanced significantly.In addition,owing to the low-temperature fabrication procedures of the entire device,we have obtained a PCE of over 21%for flexible IPSCs with enhanced operational stability.
基金Supported by the Major Science and Technology Project of CNPC(2023ZZ19-01).
文摘Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic limestone reservoirs of Cretaceous in Iran-Iraq as an example,this paper proposes a balanced waterflooding development technology for thick and complex carbonate reservoirs.This technology includes the fine division of development units by concealed baffles and barriers,the combination of multi well type and multi well pattern,and the construction of balanced water injection and recovery system.Thick carbonate reservoirs in Iran-Iraq are characterized by extremely vertical heterogeneity,development of multi-genesis ultra-high permeability zones,and highly concealed baffles and barriers.Based on the technologies of identification,characterization,and sealing evaluation for concealed baffles and barriers,the balanced waterflooding development technology is proposed,and three types of balanced waterflooding development modes/techniques are formed,namely,conventional stratigraphic framework,fine stratigraphic framework,and deepened stratigraphic framework.Numerical simulations show that this technology is able to realize a fine and efficient waterflooding development to recover,in a balanced manner,the reserves of thick and complex carbonate reservoirs in Iran and Iraq.The proposed technology provides a reference for the development optimization of similar reservoirs.
文摘Background:With public health emergencies(PHE)worldwide increasing,the perceived risk of PHE has been one of the critical factors influencing college students’psychological distress.However,the mechanisms by which the perceived risk of PHE affects college students’psychological distress are not clear.The study’s purpose was to investigate the mediation roles of deviation from a balanced time perspective(DBTP)and negative coping styles between the perceived risk of PHE and psychological distress.Methods:A convenience sampling method was used to survey 1054 Chinese college students with self-reporting.Data was collected using the Public Risk Perception Scale(PRPS),the Zimbardo Time Perspective Inventory(ZTPI),the Simplified Coping Style Questionnaire(SCSQ),the PHE Anxiety Scale,and the Chinese version of the Patient Health Questionnaire(PHQ).The associations between the perceived risk of PHE,DBTP,negative coping styles,and psychological distress were clarified using the correlation analysis.Additionally,the mediating roles of DBTP and negative coping styles between the perceived risk of PHE and psychological distress were investigated using a structural equation model.Results:The findings revealed low to moderate correlations between the variables studied.Students’perceived risk of PHE was a positive predictor of their psychological distress(b=0.219,p<0.01).DBTP and negative coping styles played chain mediation roles between them with the effect being 0.009 and a 95%Boot CI of[0.003,0.023].This chain mediation model had an excellent fit index(χ^(2)/df=4.732,CFI=0.973,TLI=0.930,RMSEA=0.048,SRMR=0.047).Conclusion:These findings showed how the perceived risk of PHE affected college students’psychological distress.Specifically,these results suggested that improving students’mental ability to switch effectively among different time perspectives depending on task features and situational considerations and reducing their negative coping styles might be effective ways to promote their mental health.
文摘With the rapid development of our country’s economy,education has gradually become the focus of social attention.The problem of unbalanced distribution of urban and rural educational resources has become increasingly prominent,urban educational resources are relatively rich,while rural educational resources are relatively scarce,and the balanced development of urban and rural compulsory education has become an urgent task.This paper mainly investigates and studies the distribution of urban and rural educational resources,discusses the unbalanced distribution of urban and rural educational resources and analyzes the reasons,and puts forward a series of corresponding solutions to promote the balanced development of urban and rural compulsory education.
基金supported by National Natural Science Foundation of China(U2066211,52177124,52107134)the Institute of Electrical Engineering,CAS(E155610101)+1 种基金the DNL Cooperation Fund,CAS(DNL202023)the Youth Innovation Promotion Association of CAS(2019143).
文摘Peer-to-peer(P2P)energy trading refers to a type of decentralized transaction,where the energy from distributed energy resources is directly traded between peers.A key challenge in peer-to-peer energy trading is designing a safe,efficient,and transparent trading model and operating mechanism.In this study,we consider a P2P trading environment based on blockchain technology,where prosumers can submit bids or offers without knowing the reports of others.We propose an Arrow-d’Aspremont-Gerard-Varet(AGV)-based mechanism to encourage prosumers to submit their real reserve price and determine the P2P transaction price.We demonstrate that the AGV mechanism can achieve Bayesian incentive compatibility and budget balance.Kernel density estimation(KDE)is used to derive the prior distribution from the historical bid/offer information of the agents.Case studies are carried out to analyze and evaluate the proposed mechanism.Simulation results verify the effectiveness of the proposed mechanism in guiding agents to report the true reserve price while maximizing social welfare.Moreover,we discuss the advantages of budget balance for decentralized trading by comparing the Vickrey-Clarke-Groves(VCG)and AGV mechanisms.
基金This work was supported in part by the National Natural Science Foundation of China under Grant 62171113 and 61941113in part by the Fundamental Research Funds for the Central Universities under Grant N2116003 and N2116011.
文摘Mobile Edge Computing(MEC)-based computation offloading is a promising application paradigm for serving large numbers of users with various delay and energy requirements.In this paper,we propose a flexible MECbased requirement-adaptive partial offloading model to accommodate each user's specific preference regarding delay and energy consumption.To address the dimensional differences between time and energy,we introduce two normalized parameters and then derive the computational overhead of processing tasks.Different from existing works,this paper considers practical variations in the user request patterns,and exploits a flexible partial offloading mode to minimize computation overheads subject to tolerable delay,task workload and power constraints.Since the resulting problem is non-convex,we decouple it into two convex subproblems and present an iterative algorithm to obtain a feasible offloading solution.Numerical experiments show that our proposed scheme achieves a significant improvement in computation overheads compared with existing schemes.
基金supported by the National Natural Science Foundation of China(Grant No.21875110,22075143)the Science Challenge Projectthe Qing Lan Project for the grant。
文摘In recent years,the introduction of fused rings own high density and low sensitivity has promoted the development of energetic materials.However,the development of energetic compounds containing fused and bridged rings by introducing multiple nitrogen heterocycles at different sites of fused rings is still difficult to progress,which seriously limits the emergence of advanced energetic compounds.In this study,a series of energetic materials choosing different nitrogen rich heterocycles at the vacancies of the fused ring,i.e.,neutral compound 5,6 and their ionic derivatives(compounds 7-12)were designed and synthesized.Compounds 5 and 6 were further confirmed by single crystal X-ray diffraction,while the crystal analysis and theoretical calculations were carried out to explore the relationship between crystal structure and physicochemical properties.All of the newly synthesized compounds(5-12)are insensitive to mechanical stimulation(IS>40 J;FS≥342 N)and they own the high detonation velocity(D:8322-9075 m/s).Notably,hydrazine salt 11 own the higher detonation velocity(9075 m/s)and powder density(1.83 g/cm^(3)),but exhibits lower sensitivity(IS>40 J)than the classical energetic compound RDX(8795 m/s,1.80 g/cm^(3),7.5 J).It is obvious that the combination of 5,6-fused triazolo-triazine and nitropyrazole-tetrazole may be a new energetic skeleton for synthesising the heterocyclic compounds with balanced energy-stability.
基金financially supported by the National Natural Science Foundation of China (Nos.51974023 and52374321)the funding of State Key Laboratory of Advanced Metallurgy,University of Science and Technology Beijing,China (No.41620007)。
文摘The amount of oxygen blown into the converter is one of the key parameters for the control of the converter blowing process,which directly affects the tap-to-tap time of converter. In this study, a hybrid model based on oxygen balance mechanism (OBM) and deep neural network (DNN) was established for predicting oxygen blowing time in converter. A three-step method was utilized in the hybrid model. First, the oxygen consumption volume was predicted by the OBM model and DNN model, respectively. Second, a more accurate oxygen consumption volume was obtained by integrating the OBM model and DNN model. Finally, the converter oxygen blowing time was calculated according to the oxygen consumption volume and the oxygen supply intensity of each heat. The proposed hybrid model was verified using the actual data collected from an integrated steel plant in China, and compared with multiple linear regression model, OBM model, and neural network model including extreme learning machine, back propagation neural network, and DNN. The test results indicate that the hybrid model with a network structure of 3 hidden layer layers, 32-16-8 neurons per hidden layer, and 0.1 learning rate has the best prediction accuracy and stronger generalization ability compared with other models. The predicted hit ratio of oxygen consumption volume within the error±300 m^(3)is 96.67%;determination coefficient (R^(2)) and root mean square error (RMSE) are0.6984 and 150.03 m^(3), respectively. The oxygen blow time prediction hit ratio within the error±0.6 min is 89.50%;R2and RMSE are0.9486 and 0.3592 min, respectively. As a result, the proposed model can effectively predict the oxygen consumption volume and oxygen blowing time in the converter.
文摘Sensors are considered as important elements of electronic devices.In many applications and service,Wireless Sensor Networks(WSNs)are involved in significant data sharing that are delivered to the sink node in energy efficient man-ner using multi-hop communications.But,the major challenge in WSN is the nodes are having limited battery resources,it is important to monitor the consumption rate of energy is very much needed.However,reducing energy con-sumption can increase the network lifetime in effective manner.For that,clustering methods are widely used for optimizing the rate of energy consumption among the sensor nodes.In that concern,this paper involves in deriving a novel model called Improved Load-Balanced Clustering for Energy-Aware Routing(ILBC-EAR),which mainly concentrates on optimal energy utilization with load-balanced process among cluster heads and member nodes.For providing equal rate of energy consumption among nodes,the dimensions of framed clusters are measured.Moreover,the model develops a Finest Routing Scheme based on Load-Balanced Clustering to transmit the sensed information to the sink or base station.The evaluation results depict that the derived energy aware model attains higher rate of life time than other works and also achieves balanced energy rate among head node.Additionally,the model also provides higher throughput and minimal delay in delivering data packets.
文摘Real-time applications based on Wireless Sensor Network(WSN)tech-nologies are quickly increasing due to intelligent surroundings.Among the most significant resources in the WSN are battery power and security.Clustering stra-tegies improve the power factor and secure the WSN environment.It takes more electricity to forward data in a WSN.Though numerous clustering methods have been developed to provide energy consumption,there is indeed a risk of unequal load balancing,resulting in a decrease in the network’s lifetime due to network inequalities and less security.These possibilities arise due to the cluster head’s limited life span.These cluster heads(CH)are in charge of all activities and con-trol intra-cluster and inter-cluster interactions.The proposed method uses Lifetime centric load balancing mechanisms(LCLBM)and Cluster-based energy optimiza-tion using a mobile sink algorithm(CEOMS).LCLBM emphasizes the selection of CH,system architectures,and optimal distribution of CH.In addition,the LCLBM was added with an assistant cluster head(ACH)for load balancing.Power consumption,communications latency,the frequency of failing nodes,high security,and one-way delay are essential variables to consider while evaluating LCLBM.CEOMS will choose a cluster leader based on the influence of the fol-lowing parameters on the energy balance of WSNs.According to simulatedfind-ings,the suggested LCLBM-CEOMS method increases cluster head selection self-adaptability,improves the network’s lifetime,decreases data latency,and bal-ances network capacity.
文摘Internet of Things(IoT)empowers imaginative applications and permits new services when mobile nodes are included.For IoT-enabled low-power and lossy networks(LLN),the Routing Protocol for Low-power and Lossy Networks(RPL)has become an established standard routing protocol.Mobility under standard RPL remains a difficult issue as it causes continuous path disturbance,energy loss,and increases the end-to-end delay in the network.In this unique circumstance,a Balanced-load and Energy-efficient RPL(BE-RPL)is proposed.It is a routing technique that is both energy-efficient and mobility-aware.It responds quicker to link breakage through received signal strength-based mobility monitoring and selecting a new preferred parent reactively.The proposed system also implements load balancing among stationary nodes for leaf node allocation.Static nodes with more leaf nodes are restricted from participating in the election for a new preferred parent.The performance of BE-RPL is assessed using the COOJA simulator.It improves the energy use,network control overhead,frame acknowledgment ratio,and packet delivery ratio of the network.
文摘Hydrological models are very useful tools for evaluating water resources, and the hydroclimatic hazards associated with the water cycle. However, their calibration and validation require the use of performance criteria which choice is not straightforward. This paper aims to evaluate the influence of the performance criteria on water balance components and water extremes using two global rainfall-runoff models (HBV and GR4J) over the Ouémé watershed at the Bonou and Savè outlets. Three (3) Efficacy criteria (Nash, coefficient of determination, and KGE) were considered for calibration and validation. The results show that the Nash criterion provides a good assessment of the simulation of the different parts of the hydrograph. KGE is better for simulating peak flows and water balance elements than other efficiency criteria. This study could serve as a basis for the choice of performance criteria in hydrological modelling.
基金funded by the Science and Technology Foundation of State Grid Corporation of China(Grant No.5108-202218280A-2-397-XG).
文摘This paper focuses on the scheduling problem of workflow tasks that exhibit interdependencies.Unlike indepen-dent batch tasks,workflows typically consist of multiple subtasks with intrinsic correlations and dependencies.It necessitates the distribution of various computational tasks to appropriate computing node resources in accor-dance with task dependencies to ensure the smooth completion of the entire workflow.Workflow scheduling must consider an array of factors,including task dependencies,availability of computational resources,and the schedulability of tasks.Therefore,this paper delves into the distributed graph database workflow task scheduling problem and proposes a workflow scheduling methodology based on deep reinforcement learning(DRL).The method optimizes the maximum completion time(makespan)and response time of workflow tasks,aiming to enhance the responsiveness of workflow tasks while ensuring the minimization of the makespan.The experimental results indicate that the Q-learning Deep Reinforcement Learning(Q-DRL)algorithm markedly diminishes the makespan and refines the average response time within distributed graph database environments.In quantifying makespan,Q-DRL achieves mean reductions of 12.4%and 11.9%over established First-fit and Random scheduling strategies,respectively.Additionally,Q-DRL surpasses the performance of both DRL-Cloud and Improved Deep Q-learning Network(IDQN)algorithms,with improvements standing at 4.4%and 2.6%,respectively.With reference to average response time,the Q-DRL approach exhibits a significantly enhanced performance in the scheduling of workflow tasks,decreasing the average by 2.27%and 4.71%when compared to IDQN and DRL-Cloud,respectively.The Q-DRL algorithm also demonstrates a notable increase in the efficiency of system resource utilization,reducing the average idle rate by 5.02%and 9.30%in comparison to IDQN and DRL-Cloud,respectively.These findings support the assertion that Q-DRL not only upholds a lower average idle rate but also effectively curtails the average response time,thereby substantially improving processing efficiency and optimizing resource utilization within distributed graph database systems.
基金supported in part by the National Key Research and Development Program of China under Grant 2020YFB1807003in part by the National Natural Science Foundation of China under Grants 61901381,62171385,and 61901378+3 种基金in part by the Aeronautical Science Foundation of China under Grant 2020z073053004in part by the Foundation of the State Key Laboratory of Integrated Services Networks of Xidian University under Grant ISN21-06in part by the Key Research Program and Industrial Innovation Chain Project of Shaanxi Province under Grant 2019ZDLGY07-10in part by the Natural Science Fundamental Research Program of Shaanxi Province under Grant 2021JM-069.
文摘Unbalanced traffic distribution in cellular networks results in congestion and degrades spectrum efficiency.To tackle this problem,we propose an Unmanned Aerial Vehicle(UAV)-assisted wireless network in which the UAV acts as an aerial relay to divert some traffic from the overloaded cell to its adjacent underloaded cell.To fully exploit its potential,we jointly optimize the UAV position,user association,spectrum allocation,and power allocation to maximize the sum-log-rate of all users in two adjacent cells.To tackle the complicated joint optimization problem,we first design a genetic-based algorithm to optimize the UAV position.Then,we simplify the problem by theoretical analysis and devise a low-complexity algorithm according to the branch-and-bound method,so as to obtain the optimal user association and spectrum allocation schemes.We further propose an iterative power allocation algorithm based on the sequential convex approximation theory.The simulation results indicate that the proposed UAV-assisted wireless network is superior to the terrestrial network in both utility and throughput,and the proposed algorithms can substantially improve the network performance in comparison with the other schemes.
基金Guangdong Major Project of Basic and Applied Basic Research(No.2020B0301030008)National Natural Science Foundation of China with Project(Nos.11935007,12035007,12247127,and 12247132)China Postdoctoral Science Foundation supports S.Wang under project No.2021M701279.
文摘We present a theoretical study of the medium modifications of the p_(T)balance (x_(J)) of dijets in Xe+Xe collisions at■.The initial production of dijets was carried out using the POWHEG+PYTHIA8 prescription,which matches the next-toleading-order (NLO) QCD matrix elements with the parton shower (PS) effect.The SHELL model described the in-medium evolution of nucleus–nucleus collisions using a transport approach.The theoretical results of the dijet xJin the Xe+Xe collisions exhibit more imbalanced distributions than those in the p+p collisions,consistent with recently reported ATLAS data.By utilizing the Interleaved Flavor Neutralisation,an infrared-and-collinear-safe jet flavor algorithm,to identify the flavor of the reconstructed jets,we classify dijets processes into three categories:gluon–gluon (gg),quark–gluon (qg),and quark–quark (qq),and investigated the respective medium modification patterns and fraction changes of the gg,qg,and qq components of the dijet sample in Xe+Xe collisions.It is shown that the increased fraction of qg component at a small x_(J)contributes to the imbalance of the dijet;in particular,the q_(1)g_(2)(quark-jet-leading) dijets experience more significant asymmetric energy loss than the g_(1)q_(2)(gluon-jet-leading) dijets traversing the QGP.By comparing the■of inclusive,■ dijets in Xe+Xe collisions,we observe■.Moreover,ρ_(Xe),P_(b),the ratios of the nuclear modification factors of dijets in Xe+Xe to those in Pb+Pb,were calculated,which indicates that the yield suppression of dijets in Pb+Pb is more pronounced than that in Xe+Xe owing to the larger radius of the lead nucleus.
基金supported by the CAS"Light of West China"Program (2021XBZG-XBQNXZ-A-007)the National Natural Science Foundation of China (31971436)the State Key Laboratory of Cryospheric Science,Northwest Institute of Eco-Environment and Resources,Chinese Academy Sciences (SKLCS-OP-2021-06).
文摘Evapotranspiration is an important parameter used to characterize the water cycle of ecosystems.To under-stand the properties of the evapotranspiration and energy balance of a subalpine forest in the southeastern Qinghai-Tibet Plateau,an open-path eddy covariance system was set up to monitor the forest from November 2020 to October 2021 in a core area of the Three Parallel Rivers in the Qing-hai-Tibet Plateau.The results show that the evapotranspira-tion peaked daily,the maximum occurring between 11:00 and 15:00.Environmental factors had significant effects on evapotranspiration,among them,net radiation the greatest(R^(2)=0.487),and relative humidity the least(R^(2)=0.001).The energy flux varied considerably in different seasons and sensible heat flux accounted for the main part of turbulent energy.The energy balance ratio in the dormant season was less than that in the growing season,and there is an energy imbalance at the site on an annual time scale.
基金supported by Grant PID2020-117211GB-I00funded by MCIN/AEI/10.13039/501100011033+4 种基金by Grant CIAICO/2021/227funded by the Generalitat Valencianasupported by the Ministerio de Ciencia e Innovacion of Spain(Grant Ref.PID2021-125709OB-C21)funded by MCIN/AEI/10.13039/501100011033/FEDER,UEby the Generalitat Valenciana(CIAICO/2021/224).
文摘Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do not involve any special data structure,and do not induce savings in memory requirements,they are easily implemented on existing codes and are recommended for 1D and 2D simulations when intensive testing is required.The multilevel technique can also be applied to balance laws,but in this case,numerical errors may be induced by the technique.We present a series of numerical tests that point out that the use of monotonicity-preserving interpolatory techniques eliminates the numerical errors observed when using the usual 4-point centered Lagrange interpolation,and leads to a more robust multilevel code for balance laws,while maintaining the efficiency rates observed forhyperbolic conservation laws.
基金support from the Youth Innovation Promotion Association of Chinese Academy of Sciences (Grant No.2019319)support from the Start-up Foundation of Suzhou Institute of Nano-Tech and Nano-Bionics,CAS,Suzhou (Grant No.Y9AAD110)。
文摘A Josephson traveling wave parametric amplifier(JTWPA),which is a quantum-limited amplifier with high gain and large bandwidth,is the core device of large-scale measurement and control systems for quantum computing.A typical JTWPA consists of thousands of Josephson junctions connected in series to form a transmission line and hundreds of shunt LC resonators periodically loaded along the line for phase matching.Because the variation of these capacitors and inductors can be detrimental to their high-frequency characteristics,the fabrication of a JTWPA typically necessitates precise processing equipment.To guide the fabrication process and further improve the design for manufacturability,it is necessary to understand how each electronic component affects the amplifier.In this paper,we use the harmonic balance method to conduct a comprehensive study on the impact of nonuniformity and fabrication yield of the electronic components on the performance of a JTWPA.The results provide insightful and scientific guidance for device design and fabrication processes.
基金subsidized by Sichuan Province Science and Technology Program (2023NSFSC0093)Enterprises Entrust Technology Development Program (FJF22KX0055,202302914)。
文摘The balance between metal and acid sites directly affects the preparation of high-performance cracking catalysts with high heat sink and low coking.Nevertheless,how to control acid-metal sites balance and its relationship with cracking performance are reported scarcely.In this work,a series of Pt/Al_(2)O_(3)-SiO_(2) dual sites catalysts with different metal to acid active sites ratio(C_(M)/C_(SA))were constructed by ethanolassisted impregnation method and the impact on n-decane cracking under supercritical conditions was systematically and deeply investigated.The results showed that the conversion and carbon deposition increased gradually with varied C_(M)/C_(SA)and reached the balance at C_(M)/C_(SA)of 0.13.The proper ratio C_(M)/C_(SA)(0.13)can balance the deep dehydrogenation coking over metal active sites and high heat sink of cracking over acid active sites,the chemical heat sink reaches amazing 1.75 MJ/kg and carbon deposition is only22.03 mg/cm^(2) at 750℃.Meanwhile,the few metal sites at low C_(M)/C_(SA)and the few strong acid sites at high C_(M)/C_(SA)are the main factors limiting the cracking activity.Low C_(M)/C_(SA)limit the activation of C-H bond and deep dehydrogenation of coking precursor,resulting in relative low cracking activity and carbon deposition,while high C_(M)/C_(SA)limit the activation of C-C bond and increase the deep dehydrogenation.In this contribution,design and construction of metal-acid dual sites can not only provide the technical solution for the preparation of high heat sink and low coking cracking catalyst,but also deepen the understanding of the cracking path of hydrocarbon fuel.