Urbanization is one of the driving forces for the land use change in type and structure, and its prominent effect is to convert rural land to urban land. This paper takes Shan-dong Province as an example to analyze th...Urbanization is one of the driving forces for the land use change in type and structure, and its prominent effect is to convert rural land to urban land. This paper takes Shan-dong Province as an example to analyze the current situation of the mutual conversion between the urban and rural areas from the aspects of the structure of land use, the decreasing tendency of the cultivated land, the changes of land use in urban and rural residential areas. It points out that cultivated land is converted to residential area land, industrial and/or mining area land. The relationship between the urban area land and the cultivated land is more direct; meanwhile, the changes of rural residential area lag behind obviously. The decrease of the cultivated land and the decline of soil quality will be the two difficult problems in the process of urbanization.展开更多
Due to the high specific capacity and energy density, lithium–sulfur battery is regarded as a potential energy storage conversion system. However, the serious shuttle effect and the sluggish electrochemical reaction ...Due to the high specific capacity and energy density, lithium–sulfur battery is regarded as a potential energy storage conversion system. However, the serious shuttle effect and the sluggish electrochemical reaction kinetics impede the practical use of lithium–sulfur battery. In the interests of breaking through the above knotty problems, herein we propose to use the polar flower-like Zn O modified by Bi OI nanoparticles as bifunctional host with catalytic and adsorption ability for polysulfides in lithium–sulfur battery.It can be found that this adsorption/catalytic host integrates the functions of adsorption and mutual catalytic conversion of polysulfides, in which the polar flower-like Zn O can effectively capture the polysulfides through strong polar-polar interaction, simultaneously the BiOI nanoparticles can accelerate the mutual conversion of polysulfides to Li2 S through reducing the activation energy and conversion energy barrier required for the electrochemical reaction. As a result, under a sulfur loading of 2.5 mg cm^(-2), the lithium–sulfur battery with Zn O/Bi OI/CNT/S as cathode reveals a considerable initial specific capacity of1267 mAh g^(-1) at a current density of 0.1 C. Even the current density increased to 1 C, the capacity can reach as 873.4 mAh g^(-1), together with a good capacity retention of 67.1% after 400 cycles. Therefore,after systematically study the positive effects of the flower-like ZnO modified by catalytic BiOI nanoparticles on the adsorption and catalytic conversion of polysulfides, this work provides a new idea for the development and application of high-performance lithium–sulfur batteries.展开更多
We propose and experimentally demonstrate mutual optical format conversion between signals characterized as 10-Gb/s nonreturn-to-zero on-of-keying(NRZ-OOK) and NRZ binary phase-shift keying(BPSK) types. The conversion...We propose and experimentally demonstrate mutual optical format conversion between signals characterized as 10-Gb/s nonreturn-to-zero on-of-keying(NRZ-OOK) and NRZ binary phase-shift keying(BPSK) types. The conversion is based on stimulated Brillouin scattering(SBS) in a single-mode optical fber. An OOK signal is converted into a BPSK signal through optical carrier absorption, for which a SBS loss of 30 MHz is used in long-haul transmission. The converted BPSK signal is reverted to an OOK signal with a corresponding SBS gain of 30 MHz for direct detection. The proposed OOK-to-BPSK and BPSK-to-OOK format conversions can be implemented in transmitter and receiver nodes by using a laser source as the Brillouin pump.展开更多
文摘Urbanization is one of the driving forces for the land use change in type and structure, and its prominent effect is to convert rural land to urban land. This paper takes Shan-dong Province as an example to analyze the current situation of the mutual conversion between the urban and rural areas from the aspects of the structure of land use, the decreasing tendency of the cultivated land, the changes of land use in urban and rural residential areas. It points out that cultivated land is converted to residential area land, industrial and/or mining area land. The relationship between the urban area land and the cultivated land is more direct; meanwhile, the changes of rural residential area lag behind obviously. The decrease of the cultivated land and the decline of soil quality will be the two difficult problems in the process of urbanization.
基金supported financially by the National Key Research and Development Program of China (2018YFB0104200)the Key Project of Strategic New Industry of Hunan Province (No. 2019GK2032)。
文摘Due to the high specific capacity and energy density, lithium–sulfur battery is regarded as a potential energy storage conversion system. However, the serious shuttle effect and the sluggish electrochemical reaction kinetics impede the practical use of lithium–sulfur battery. In the interests of breaking through the above knotty problems, herein we propose to use the polar flower-like Zn O modified by Bi OI nanoparticles as bifunctional host with catalytic and adsorption ability for polysulfides in lithium–sulfur battery.It can be found that this adsorption/catalytic host integrates the functions of adsorption and mutual catalytic conversion of polysulfides, in which the polar flower-like Zn O can effectively capture the polysulfides through strong polar-polar interaction, simultaneously the BiOI nanoparticles can accelerate the mutual conversion of polysulfides to Li2 S through reducing the activation energy and conversion energy barrier required for the electrochemical reaction. As a result, under a sulfur loading of 2.5 mg cm^(-2), the lithium–sulfur battery with Zn O/Bi OI/CNT/S as cathode reveals a considerable initial specific capacity of1267 mAh g^(-1) at a current density of 0.1 C. Even the current density increased to 1 C, the capacity can reach as 873.4 mAh g^(-1), together with a good capacity retention of 67.1% after 400 cycles. Therefore,after systematically study the positive effects of the flower-like ZnO modified by catalytic BiOI nanoparticles on the adsorption and catalytic conversion of polysulfides, this work provides a new idea for the development and application of high-performance lithium–sulfur batteries.
基金supported by the National Natural Science Foundation of China(Nos.61007041,61090393,and 61132004)the Shanghai Chen Guang Scholars Program(No.11CG11)the Excellent PhD Holders in China Program(No.201155)
文摘We propose and experimentally demonstrate mutual optical format conversion between signals characterized as 10-Gb/s nonreturn-to-zero on-of-keying(NRZ-OOK) and NRZ binary phase-shift keying(BPSK) types. The conversion is based on stimulated Brillouin scattering(SBS) in a single-mode optical fber. An OOK signal is converted into a BPSK signal through optical carrier absorption, for which a SBS loss of 30 MHz is used in long-haul transmission. The converted BPSK signal is reverted to an OOK signal with a corresponding SBS gain of 30 MHz for direct detection. The proposed OOK-to-BPSK and BPSK-to-OOK format conversions can be implemented in transmitter and receiver nodes by using a laser source as the Brillouin pump.