The extraction behavior of N,N,N’,N’-tetrabutylglutaramide（TBGA）employing cyclohexane as diluent toward La（Ⅲ）,Pr（Ⅲ）,Gd（Ⅲ）and Er（Ⅲ） investigated.The effect of the concentrations of nitric acid,lithium n...The extraction behavior of N,N,N’,N’-tetrabutylglutaramide（TBGA）employing cyclohexane as diluent toward La（Ⅲ）,Pr（Ⅲ）,Gd（Ⅲ）and Er（Ⅲ） investigated.The effect of the concentrations of nitric acid,lithium nitrate and extractant and also the temperature on the extraction distribution ratio was studied.The stoichiometry of the extracted species was Found to be M（NO3）3·3TBGA（M=La,Pr,Gd,Er）.The extraction mechanism was also discussed and the values of the enthalpy of extraction reaction was calculated.展开更多
The degradation and fate of pesticide N' (2,4 dimethylphenyl) N methylformamidine hydrochloride in simulated aquatic ecosystem were investigated. The results showed that the pesticide was not stable in simula...The degradation and fate of pesticide N' (2,4 dimethylphenyl) N methylformamidine hydrochloride in simulated aquatic ecosystem were investigated. The results showed that the pesticide was not stable in simulated aquatic ecosystem with pH value of 7.4—8.9 and water temperature of 18.0—26.5℃. In the first 9 days, 95% of DMAH was disappeared, whereas the concentration of its degradation product 2,4 dimethylformanilide increased with time and was of a maximum value at about 9 days and then decreased. The concentration of 2, 4 dimethylaniline, which is another degradation product of DMAH, nearly did not change in the early of experiment. However, it decreased rapidly after 9 days. The experiment lasted 51 days. At the end of experiment, there were no N' 2, 4 dimethylphenyl) N methylformamidine, 2, 4 dimethylformanilide and 2, 4 dimethylaniline detected in water, but they were all detected in the sediment and water grass, and the total amount of them covered 2%—3% of application amount of DMAH. It indicated that water grass and sediment could absorb and concentrate these compounds.展开更多
以Cu/Ni为主活性组分,γ-Al2O3球为载体,考察了Mn助剂对N,N-二甲基乙醇胺(DMEA)固定床连续催化胺化制备N,N,N',N'-四甲基乙二胺(TMEDA)催化剂性能的影响,并通过XRD、BET/BJH、H2-TPR、H2-TPD等对催化剂结构进行表征,结果表明,M...以Cu/Ni为主活性组分,γ-Al2O3球为载体,考察了Mn助剂对N,N-二甲基乙醇胺(DMEA)固定床连续催化胺化制备N,N,N',N'-四甲基乙二胺(TMEDA)催化剂性能的影响,并通过XRD、BET/BJH、H2-TPR、H2-TPD等对催化剂结构进行表征,结果表明,Mn能够抑制脱氢而促进加氢反应的发生,随着Mn含量的增加,选择性会提高,而活性相对会受到抑制,当n(Cu)∶n(Ni)∶n(Mn)=4∶1∶0.2时催化剂性能较佳。采用4Cu-1Ni-0.2Mn/γ-Al2O3球作为催化胺化催化剂,在反应温度为240℃,DMEA空速为0.15 h-1,胺醇摩尔比为1∶1,常压,氢速为30 m L/min时,DMEA转化率和TMEDA选择性分别达到92%和83%左右。展开更多
The N,N,N’,N’-tetrabutsuccinylamide（TBSA） was synthesized and purified.The extractability of this diamide for Terbium（Ⅲ） has been studied.The effects of concentrations of nitric acid,extractant,and LiNO3 as wel...The N,N,N’,N’-tetrabutsuccinylamide（TBSA） was synthesized and purified.The extractability of this diamide for Terbium（Ⅲ） has been studied.The effects of concentrations of nitric acid,extractant,and LiNO3 as well as the temperature influence on the extraction distribution ratios were investgated in detail.The apparent equilibrium constant of extraction has been determined to be（0.77±0.02）L6/mol6at 298K.The enthalpy of the extraction was -25.64kJ·mol-1.The composition of the extracted species was found to be Tb（NO3）3·3TBSA,which was characterized by IR spectromery.展开更多
The title compound N,N,N’,N’-tetra[(diphenylphosphine)methyl]-1,4-phenylenediamine is synthesized by reaction of [Ph2P(CH2OH)2]Cl and 1,4-phenylenediamine.It is characterized by elemental analysis,IR,31PNMR,1HNMR.Si...The title compound N,N,N’,N’-tetra[(diphenylphosphine)methyl]-1,4-phenylenediamine is synthesized by reaction of [Ph2P(CH2OH)2]Cl and 1,4-phenylenediamine.It is characterized by elemental analysis,IR,31PNMR,1HNMR.Single crystal X-ray diffraction analysis reveals that it is centro-symmetric with the inversion center at the centroid of phenylene.Intermolecular π–π stacking interactions between phenyl rings make molecules arrange along the b axis into one-dimensional chains,while these chains are further extended by intermolecular C-H…π interactions into three-dimensional supramolecular structure.The crystal is orthorhombic system with space group Pbca,Mr: 900.90,a=12.215(1),b=14.460(2),c=27.821(3),β=90°,v=4914.0(9)3,z=4,Dc=1.218 mg·m-3,F(000)=1896,R=0.0487,wR=0.1245.展开更多
Terbium and N,N′,N' tri(3,5 diamino benzenesulfonyl) 1,4,7 triazacyclononane (TDABS Tacn) form a stable chelate having a 1∶1 molar ratio in dilute aqueous solution. The fluorescence property of the chelate ...Terbium and N,N′,N' tri(3,5 diamino benzenesulfonyl) 1,4,7 triazacyclononane (TDABS Tacn) form a stable chelate having a 1∶1 molar ratio in dilute aqueous solution. The fluorescence property of the chelate was studied under the experimental conditions (pH 8.4 in H 3BO 3 KCl NaOH buffer, λ EX =309 nm, λ EM =374 nm). The fluorescence intensity is a linear function of concentration in the range of 5.0×10 -6 to 4.2×10 -4 mol/L for terbium. The relative standard deviation is less than ±2.0%. When tolerable amount of other metal ions were added to the solution of terbium chelate, the fluorescence intensity can be determined without interference. These results suggest that aromatic armed polyazamacrocycle can be used for the terbium determination.展开更多
文摘The extraction behavior of N,N,N’,N’-tetrabutylglutaramide（TBGA）employing cyclohexane as diluent toward La（Ⅲ）,Pr（Ⅲ）,Gd（Ⅲ）and Er（Ⅲ） investigated.The effect of the concentrations of nitric acid,lithium nitrate and extractant and also the temperature on the extraction distribution ratio was studied.The stoichiometry of the extracted species was Found to be M（NO3）3·3TBGA（M=La,Pr,Gd,Er）.The extraction mechanism was also discussed and the values of the enthalpy of extraction reaction was calculated.
文摘The degradation and fate of pesticide N' (2,4 dimethylphenyl) N methylformamidine hydrochloride in simulated aquatic ecosystem were investigated. The results showed that the pesticide was not stable in simulated aquatic ecosystem with pH value of 7.4—8.9 and water temperature of 18.0—26.5℃. In the first 9 days, 95% of DMAH was disappeared, whereas the concentration of its degradation product 2,4 dimethylformanilide increased with time and was of a maximum value at about 9 days and then decreased. The concentration of 2, 4 dimethylaniline, which is another degradation product of DMAH, nearly did not change in the early of experiment. However, it decreased rapidly after 9 days. The experiment lasted 51 days. At the end of experiment, there were no N' 2, 4 dimethylphenyl) N methylformamidine, 2, 4 dimethylformanilide and 2, 4 dimethylaniline detected in water, but they were all detected in the sediment and water grass, and the total amount of them covered 2%—3% of application amount of DMAH. It indicated that water grass and sediment could absorb and concentrate these compounds.
文摘以Cu/Ni为主活性组分,γ-Al2O3球为载体,考察了Mn助剂对N,N-二甲基乙醇胺(DMEA)固定床连续催化胺化制备N,N,N',N'-四甲基乙二胺(TMEDA)催化剂性能的影响,并通过XRD、BET/BJH、H2-TPR、H2-TPD等对催化剂结构进行表征,结果表明,Mn能够抑制脱氢而促进加氢反应的发生,随着Mn含量的增加,选择性会提高,而活性相对会受到抑制,当n(Cu)∶n(Ni)∶n(Mn)=4∶1∶0.2时催化剂性能较佳。采用4Cu-1Ni-0.2Mn/γ-Al2O3球作为催化胺化催化剂,在反应温度为240℃,DMEA空速为0.15 h-1,胺醇摩尔比为1∶1,常压,氢速为30 m L/min时,DMEA转化率和TMEDA选择性分别达到92%和83%左右。
文摘The N,N,N’,N’-tetrabutsuccinylamide（TBSA） was synthesized and purified.The extractability of this diamide for Terbium（Ⅲ） has been studied.The effects of concentrations of nitric acid,extractant,and LiNO3 as well as the temperature influence on the extraction distribution ratios were investgated in detail.The apparent equilibrium constant of extraction has been determined to be（0.77±0.02）L6/mol6at 298K.The enthalpy of the extraction was -25.64kJ·mol-1.The composition of the extracted species was found to be Tb（NO3）3·3TBSA,which was characterized by IR spectromery.
文摘The title compound N,N,N’,N’-tetra[(diphenylphosphine)methyl]-1,4-phenylenediamine is synthesized by reaction of [Ph2P(CH2OH)2]Cl and 1,4-phenylenediamine.It is characterized by elemental analysis,IR,31PNMR,1HNMR.Single crystal X-ray diffraction analysis reveals that it is centro-symmetric with the inversion center at the centroid of phenylene.Intermolecular π–π stacking interactions between phenyl rings make molecules arrange along the b axis into one-dimensional chains,while these chains are further extended by intermolecular C-H…π interactions into three-dimensional supramolecular structure.The crystal is orthorhombic system with space group Pbca,Mr: 900.90,a=12.215(1),b=14.460(2),c=27.821(3),β=90°,v=4914.0(9)3,z=4,Dc=1.218 mg·m-3,F(000)=1896,R=0.0487,wR=0.1245.
文摘Terbium and N,N′,N' tri(3,5 diamino benzenesulfonyl) 1,4,7 triazacyclononane (TDABS Tacn) form a stable chelate having a 1∶1 molar ratio in dilute aqueous solution. The fluorescence property of the chelate was studied under the experimental conditions (pH 8.4 in H 3BO 3 KCl NaOH buffer, λ EX =309 nm, λ EM =374 nm). The fluorescence intensity is a linear function of concentration in the range of 5.0×10 -6 to 4.2×10 -4 mol/L for terbium. The relative standard deviation is less than ±2.0%. When tolerable amount of other metal ions were added to the solution of terbium chelate, the fluorescence intensity can be determined without interference. These results suggest that aromatic armed polyazamacrocycle can be used for the terbium determination.
