γ-丁内酯直接脱水催化法合成NVP工艺研究

以γ-丁内酯和乙醇胺为原料,直接脱水催化方法制备出N-乙烯基吡咯烷酮。主要探讨工艺及最佳工艺参数。

Kinetics of Copolymerization of Acrylonitrile with N-Vinylpyrrolidone in H_2O/Dimethyl Sulphoxide Mixture

Kinetics of copolymerization of acrylonitrile(AN) with N-vinylpyrrolidone(NVP) initiated by azodi-isobutyronitrile(AIBN) was investigated in H2O/dimethyl sulphoxide(DMSO) mixture between 50℃ and 70℃ under N2 atmosphere. The rate of copolymerization and particle size were measured respectively. The kinetic equation of copolymerization system is obtained as Rpat 60℃. The overall activation energy for copolymerization system was computed as 87.3kJ.mol-1. Effect of additives of hydroquinone and dioxane on copolymerization was discussed. The polymerization is retarded by hydroquinone and accelerated by dioxane, which confirms the free radical copolymerization of AN with NVP.

Halogen adsorbates on polymer-stabilized gold clusters: Mass spectrometric detection and effects on catalysis

The mass spectrometry of gold clusters stabilized by poly（N‐vinyl‐2‐pyrrolidone） （Au：PVP） re‐vealed the presence of Cl adsorbates derived from synthetic precursors, mainly on the Au34 and Au43 clusters. Changes in the amount of Cl adsorbates on the Au clusters did not affect the catalytic prop‐erties for the aerobic oxidation of benzyl alcohol, suggesting that the Cl atoms were only weakly bound to the Au clusters. In contrast, the replacement of Cl with Br on the Au34 and Au43 clusters significantly suppressed activity, without any influence on the electronic structure. This result indi‐cated that the Br atoms were strongly bound to the Au clusters and sterically blocked their active sites. The substantial reduction of the catalytic activity by the Br adsorbates suggested that the Au34 and Au43 clusters made a major contribution to the catalytic activity of the Au：PVP.

Synthesis and Characterization of Poly(N-Vinyl-2-Pyrrolidone/Itaconic Acid) Hydrogel

With N-vinyl-2-pyrrolidone (NVP) and itaconic acid(IA), poly(N-vinyl-2-pyrrolidone/itaconic acid)[P(NVP/IA)] hydrogel was synthesized by free radical solution polymerization. The structure of this (P(NVP/IA)) was characterized by IR. Effects of concentration of itaconic acid, amount of cross-link agent, N,N′-methylene-bis-acrylamide, reaction temperature, and time on properties of swelling ratio(SR) of the hydrogel were investigated.The results show that the best swelling property of the hydrogel is obtained at 50 ℃ and 1.5 h. pH sensitivity increases as the concentration of itaconic acid in the hydrogel system increases. Swelling ratio of the hydrogel decreases as the amount of cross-link agent increases.

Synthesis and Properties of Novel Surface Active Maleic Monomer Containing Phosphate Group

A novel surface active monomer （surfmer） containing poly（ethylene glycol） chain and terminated phosphate group was synthesized. The copolymerization of synthesized surfmer with NVP （N-vinylpyrrolidone） and with NVP and VEP （5-tert-butylperoxy-5-methyl-2-hexene-3-yne monomer） led to formation of corresponding surface-active copolymers. The capability of application of resulted copolymers as surface active macroinitiators of emulsion polymerization of styrene and as components of polymeric scaffolds was investigated.

Spectroscopic Investigated Interaction between Silver Nanocomposites Based of Poly-N-Vinylpyrrolidone and Doxorubicin for Drug Delivering

It is investigated to synthesis of Ag nanoparticles by presence the synthetic polymer poly-N-vinylpyrrolidone. It was determined with X-ray analyses that the size ofnanoparticles changed between 18-42 nm. Then, the authors studied sorption process of doxorubicine by silver nanocomposites and investigated chemical interaction between antibiotic and poly-N-vinyplyrrolidone with UV-VIS （ultraviolet visible） and FT-IR （Fourier transform infrared） spectroscopy. It is shown that formation of the nanoparticles doxorubicin complex mainly occurs in the 190-208 nm wavelengths on polymers 〉C=O functional groups. Also, the four main absorbing peaks of doxorubicin--234, 253, 288 and 495 nm undergo chemists shift （A2 = 12-15 nm）. When increases to pH = 7-8, the size of Ag-doxorubicin particles decreases. It is determined that the 410 nm absorption peak of Ag nanoparticles undergo 409-418 nm interval and the 3,500, 1,600, 1,645 and 1,190 sm^-1 absorption lines of PVPr （polymer poly-N-vinylpyrrolidone） slightly altered.

One-step preparation of vinyl-functionalized material surfaces:a versatile platform for surface modification

A simple approach has been developed to functionalize various substrates, such as gold and polyvinylchloride, with dopamine methacrylamide—a molecule with adhesive properties that mimic those of mussels—to produce a versatile and general platform for subsequent surface modification. With active double bonds on the surface, various polymers, such as poly([2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) ammonium hydroxide(PMEDSAH) and poly(N-vinylpyrrolidone)(PVP), can be grafted by conventional radical polymerization. Double bond surface functionalization and subsequent polymer grafting have been verified by static water contact angle, Fourier transform infrared–attenuated total reflectance(FTIR-ATR) spectroscopy and X-ray photoelectron spectroscopy(XPS) measurements. Protein adsorption assays showed that the polymermodified substrates have good protein-resistant properties. Considering the advantages of facility, versatility and substrate- independence, this method should be useful in designing functional interfaces for bioengineering applications.

N-vinyl pyrrolidone promoted aqueous-phase dehydrogenation of formic acid over PVP-stabilized Ru nanoclusters

In this work, we fabricated the poly（N-vinyl-2-pyrrolidone） （PVP）-stabilized ruthenium（0） nanoclusters by reduction of RuC13 using different reducing agents, and studied their catalytic activity in hydrogen generation from the decomposition of formic acid. It was demonstrated that N-vinyl-2-pyrrolidone （NVP）, which is a monomer of PVP, could promote the reaction by coordination with Ru nanoparticles. The Ru nanoparticles catalyst reduced by sodium borohydride （NaBH4） exhibited highest catalytic activity for the decomposition of formic acid into H2 and CO2. The turnover of numenber （TOF） value could reach 26113 h-1 at 80 ℃. We believe that the effective catalysts have potential of application in hydrogen storage by formic acid.