A new complex of N,N?-bis(p-nitrophenyl)-2,2?-(p-phenylene-dioxy) diacetamide DMF monohydrate, C25H25N5O9·H2O (Mr = 557.52), has been synthesized and its structure was determined by X-ray crystallography method. ...A new complex of N,N?-bis(p-nitrophenyl)-2,2?-(p-phenylene-dioxy) diacetamide DMF monohydrate, C25H25N5O9·H2O (Mr = 557.52), has been synthesized and its structure was determined by X-ray crystallography method. The crystal belongs to monoclinic system, space group P21/c with a = 7.2812, b = 25.5894, c = 14.3434 ?, β = 91.110(1)o, V = 2672.0(2) ?3, Dc = 1.386 g/cm3, F(000) = 1168, μ = 0.109 mm-1 and Z = 4. The final R = 0.0493 and wR = 0.1173 for 3389 observed reflections with I > 2σ(I). The asymmetric unit of the title complex consists of monomeric N,N?-bis(p-nitrophenyl)-2,2?-(p-phenyleneioxy)diacetamide 1, one DMF and one water molecule, which are incorporated during recrystallization. The molecules are linked into a three-dimensional network by π…π interactions as well as intermolecular interactions among DMF, water molecule and 1.展开更多
The steady state and transient state absorption spectra and fluorescence spectra of N,N’-bis(2-hy-droxy-1-napbthylidcne)-1,4-phenyldiamme ( BNP ) in cyclohexane and acetonitrile were determined.The pho-tochromic mech...The steady state and transient state absorption spectra and fluorescence spectra of N,N’-bis(2-hy-droxy-1-napbthylidcne)-1,4-phenyldiamme ( BNP ) in cyclohexane and acetonitrile were determined.The pho-tochromic mechanism was discussed In nonpolar solvents,BNP exists mainly in the enol form and has the absorption maximum in the UV region In polar solvents,however,both the enol and proton transfer tautomer are formed,but the farmer is the main one Fluorescence emissions result from the excited state of proton transfer product.展开更多
基金The project was supported by the National Natural Science Foundation of China(20275020,20475030)the Outstanding Adult-young Scientific Research Encouraging Foundation of Shandong Province(No.03BS081).
文摘A new complex of N,N?-bis(p-nitrophenyl)-2,2?-(p-phenylene-dioxy) diacetamide DMF monohydrate, C25H25N5O9·H2O (Mr = 557.52), has been synthesized and its structure was determined by X-ray crystallography method. The crystal belongs to monoclinic system, space group P21/c with a = 7.2812, b = 25.5894, c = 14.3434 ?, β = 91.110(1)o, V = 2672.0(2) ?3, Dc = 1.386 g/cm3, F(000) = 1168, μ = 0.109 mm-1 and Z = 4. The final R = 0.0493 and wR = 0.1173 for 3389 observed reflections with I > 2σ(I). The asymmetric unit of the title complex consists of monomeric N,N?-bis(p-nitrophenyl)-2,2?-(p-phenyleneioxy)diacetamide 1, one DMF and one water molecule, which are incorporated during recrystallization. The molecules are linked into a three-dimensional network by π…π interactions as well as intermolecular interactions among DMF, water molecule and 1.
基金Project supported by the National Natural Science Foundation of Chinathe Foundation of Chinese Academy of Sciences
文摘The steady state and transient state absorption spectra and fluorescence spectra of N,N’-bis(2-hy-droxy-1-napbthylidcne)-1,4-phenyldiamme ( BNP ) in cyclohexane and acetonitrile were determined.The pho-tochromic mechanism was discussed In nonpolar solvents,BNP exists mainly in the enol form and has the absorption maximum in the UV region In polar solvents,however,both the enol and proton transfer tautomer are formed,but the farmer is the main one Fluorescence emissions result from the excited state of proton transfer product.
