Novel colloidal processing using thermosensitive poly(N-isopropylacrylamide) (PNIPAM) as a coagulating agent has beendeveloped to prepare complex-shaped ceramic components. In this work, the properties of PNIPAM a...Novel colloidal processing using thermosensitive poly(N-isopropylacrylamide) (PNIPAM) as a coagulating agent has beendeveloped to prepare complex-shaped ceramic components. In this work, the properties of PNIPAM aqueous solutions and therheological behavior of ZnO suspensions with PNIPAM were investigated. The results show that the PNIPAM solutions exhibitobvious thermosensitivity and its transition temperature is around 32℃. When the temperature is above 40℃ (Tc, the criticaltransition temperature of thermosensitive suspension), the 50% ZnO (volume fraction) suspension with 8 mg/mL PNIPAM has asharp increase in viscosity and reaches up to 11.49 Pa·s at 50℃, displaying strong elasticity. The main reasons are the increase ofeffective volume fraction attributed to precipitation of PNIPAM segments and the flocculation between ZnO powder particles. Inaddition, the maximum solid loading (volume fraction) at 20 ℃ is higher than that at 40℃, which proves that the phase transition ofPNIPAM can induce the flocculation of suspension.展开更多
基金Project(51202296)supported by the National Natural Science Foundation of ChinaProject(20120162120006)supported by the Specialized Research Fund for the Doctoral Program of Higher Education,China
文摘Novel colloidal processing using thermosensitive poly(N-isopropylacrylamide) (PNIPAM) as a coagulating agent has beendeveloped to prepare complex-shaped ceramic components. In this work, the properties of PNIPAM aqueous solutions and therheological behavior of ZnO suspensions with PNIPAM were investigated. The results show that the PNIPAM solutions exhibitobvious thermosensitivity and its transition temperature is around 32℃. When the temperature is above 40℃ (Tc, the criticaltransition temperature of thermosensitive suspension), the 50% ZnO (volume fraction) suspension with 8 mg/mL PNIPAM has asharp increase in viscosity and reaches up to 11.49 Pa·s at 50℃, displaying strong elasticity. The main reasons are the increase ofeffective volume fraction attributed to precipitation of PNIPAM segments and the flocculation between ZnO powder particles. Inaddition, the maximum solid loading (volume fraction) at 20 ℃ is higher than that at 40℃, which proves that the phase transition ofPNIPAM can induce the flocculation of suspension.