In this review, we briefly survey the historical development of gene editing techniques, such as ZFNs, TALENs, MGNs and CRISPR/Cas; summarize its appli- cation and development in rice genome editing, research achievem...In this review, we briefly survey the historical development of gene editing techniques, such as ZFNs, TALENs, MGNs and CRISPR/Cas; summarize its appli- cation and development in rice genome editing, research achievements of rice quali- ty traits. At end, the prospect of gene editing technology and its application in rice quality traits improvement are also discussed.展开更多
It is extremely important for photocatalysts to exhibit intelligent responsiveness to their environment. Herein, a poly N-isopropyl acrylamide(PNIPAM)-modified Ag/Ag3PO4-20/CN hybrid material with excellent convertibl...It is extremely important for photocatalysts to exhibit intelligent responsiveness to their environment. Herein, a poly N-isopropyl acrylamide(PNIPAM)-modified Ag/Ag3PO4-20/CN hybrid material with excellent convertible photocatalytic activity is prepared. PNIPAM has good hydrophilicity below the lower critical solution temperature(LCST);this increases the capacity of the photocatalyst for adsorbing tetracycline(TC) molecules. In addition, the PNIPAM-modified Ag/Ag3PO4-20/CN can prevent the loss of Ag3PO4. The dispersity is improved by loading g-C3N4 nanosheets(CN) for enhancing the efficiency of photocatalytic activity. Furthermore, a Z-scheme heterostructure is formed between CN and Ag3PO4, accelerating the separation efficiency of the holes and electrons. Ag nanoparticles can be used as electron-shuttle mediators, and electrons receiving more energy are transferred via the localized surface plasmon resonance(LSPR) effect. Furthermore, the PNIPAM@Ag/Ag3PO4-20/CN photocatalyst exhibits an excellent degradation rate for the degradation of TC when the temperature is lower than the LCST. The photoluminescence spectra and photocurrent curves prove that the carrier-separation efficiency of PNIPAM@Ag/Ag3PO4-20/CN is higher than those of Ag/Ag3PO4/CN and CN. The main active species of ·O2-and h+ are detected to reveal the plausible mechanism of the PNIPAM@Ag/Ag3PO4-20/CN hybrid material system. This work provides a way to develop intelligent materials for switchable photocatalytic applications.展开更多
An important consideration when using hot-dip galvanized tubular structures is the uncertainty of the joint behaviour due to the possible reduction in the global joint resistance produced by the vent holes required fo...An important consideration when using hot-dip galvanized tubular structures is the uncertainty of the joint behaviour due to the possible reduction in the global joint resistance produced by the vent holes required for the galvanizing process. This paper assesses the effect on the joint strength of the angle between the brace members and the chord in a K- or N-joints made with rectangular hollow sections. The study is focused on the case when those brace members include characteristic holes required for the hot-dip galvanizing process. To accomplish the objective of the proposed work, some tests on full-scale K- and N-joints, including angles of 35°, 45°, 55° and 90°, were carried out. The experimental work was complemented by a validated numerical simulation in order to give some design recommendations and to extend the research to other joint configurations.展开更多
Exploring high-activity electrocatalyst for oxygen reduction reaction (ORR) is of great significance for a variety of renewable energy conversion and storage technologies. Herein, we fabricated novel ORR electrocataly...Exploring high-activity electrocatalyst for oxygen reduction reaction (ORR) is of great significance for a variety of renewable energy conversion and storage technologies. Herein, we fabricated novel ORR electrocatalysts derived from Ni-Co nanoparticles encapsulated in hollow tubular C-N composites (ht-CN) through an easy and scalable pyrolysis route utilizing nickel acetate and cobalt acetate as metal precursors, 2-cyanoguanidine as the nitrogen source, and sucrose as the carbon source. Among the prepared nanocomposite catalysts with different molar ratios ofNi/Co, the catalyst Ni2Co3@ht-CN exhibits an outstanding ORR electroactivity comparable to Pt/C catalyst both in alkaline and neutral media. Home-made zinc-air battery with the Ni2Co3@ht-CN as cathode electrocatalyst presents excellent performance and superior durability either in neutral or alkaline medium. The Ni2Co3@ht-CN battery delivers an open circuit voltage of 1.08 V and a maximum power density of 47 mW cm^-2 in 0.5 mol L^-1 KNO3 solution, while 1.51 V and 314 mW cm^-2 in 6 mol L-^1 KOH solution. In addition, whether in neutral or alkaline solution, the constant current discharge curves of the Ni2Co3@ht-CN battery at different current densities exhibit higher voltage plateau and stability than the Pt/C battery. Results demonstrate the potential application of the catalysts of the present investigation to Zn-air batteries both in alkaline and neutral media.展开更多
文摘In this review, we briefly survey the historical development of gene editing techniques, such as ZFNs, TALENs, MGNs and CRISPR/Cas; summarize its appli- cation and development in rice genome editing, research achievements of rice quali- ty traits. At end, the prospect of gene editing technology and its application in rice quality traits improvement are also discussed.
文摘It is extremely important for photocatalysts to exhibit intelligent responsiveness to their environment. Herein, a poly N-isopropyl acrylamide(PNIPAM)-modified Ag/Ag3PO4-20/CN hybrid material with excellent convertible photocatalytic activity is prepared. PNIPAM has good hydrophilicity below the lower critical solution temperature(LCST);this increases the capacity of the photocatalyst for adsorbing tetracycline(TC) molecules. In addition, the PNIPAM-modified Ag/Ag3PO4-20/CN can prevent the loss of Ag3PO4. The dispersity is improved by loading g-C3N4 nanosheets(CN) for enhancing the efficiency of photocatalytic activity. Furthermore, a Z-scheme heterostructure is formed between CN and Ag3PO4, accelerating the separation efficiency of the holes and electrons. Ag nanoparticles can be used as electron-shuttle mediators, and electrons receiving more energy are transferred via the localized surface plasmon resonance(LSPR) effect. Furthermore, the PNIPAM@Ag/Ag3PO4-20/CN photocatalyst exhibits an excellent degradation rate for the degradation of TC when the temperature is lower than the LCST. The photoluminescence spectra and photocurrent curves prove that the carrier-separation efficiency of PNIPAM@Ag/Ag3PO4-20/CN is higher than those of Ag/Ag3PO4/CN and CN. The main active species of ·O2-and h+ are detected to reveal the plausible mechanism of the PNIPAM@Ag/Ag3PO4-20/CN hybrid material system. This work provides a way to develop intelligent materials for switchable photocatalytic applications.
文摘An important consideration when using hot-dip galvanized tubular structures is the uncertainty of the joint behaviour due to the possible reduction in the global joint resistance produced by the vent holes required for the galvanizing process. This paper assesses the effect on the joint strength of the angle between the brace members and the chord in a K- or N-joints made with rectangular hollow sections. The study is focused on the case when those brace members include characteristic holes required for the hot-dip galvanizing process. To accomplish the objective of the proposed work, some tests on full-scale K- and N-joints, including angles of 35°, 45°, 55° and 90°, were carried out. The experimental work was complemented by a validated numerical simulation in order to give some design recommendations and to extend the research to other joint configurations.
基金financially supported by the National Natural Science Foundation of China(21875062)State Key Laboratory of Pressure Hydrometallurgical Technology of Associated Nonferrous Metal Resources(yy20160012),China
文摘Exploring high-activity electrocatalyst for oxygen reduction reaction (ORR) is of great significance for a variety of renewable energy conversion and storage technologies. Herein, we fabricated novel ORR electrocatalysts derived from Ni-Co nanoparticles encapsulated in hollow tubular C-N composites (ht-CN) through an easy and scalable pyrolysis route utilizing nickel acetate and cobalt acetate as metal precursors, 2-cyanoguanidine as the nitrogen source, and sucrose as the carbon source. Among the prepared nanocomposite catalysts with different molar ratios ofNi/Co, the catalyst Ni2Co3@ht-CN exhibits an outstanding ORR electroactivity comparable to Pt/C catalyst both in alkaline and neutral media. Home-made zinc-air battery with the Ni2Co3@ht-CN as cathode electrocatalyst presents excellent performance and superior durability either in neutral or alkaline medium. The Ni2Co3@ht-CN battery delivers an open circuit voltage of 1.08 V and a maximum power density of 47 mW cm^-2 in 0.5 mol L^-1 KNO3 solution, while 1.51 V and 314 mW cm^-2 in 6 mol L-^1 KOH solution. In addition, whether in neutral or alkaline solution, the constant current discharge curves of the Ni2Co3@ht-CN battery at different current densities exhibit higher voltage plateau and stability than the Pt/C battery. Results demonstrate the potential application of the catalysts of the present investigation to Zn-air batteries both in alkaline and neutral media.
