N-Perfluoroalkanesulfonyl S,S-dialkyl sulfilimines R_fSO_2N=SR^1R^2 were prepared in high yields by condensation of N-sulfinylperfluoroalkane- sulfonamides R_fSO_2NSO with sulfones.The X-ray structrue analysis of R_fS...N-Perfluoroalkanesulfonyl S,S-dialkyl sulfilimines R_fSO_2N=SR^1R^2 were prepared in high yields by condensation of N-sulfinylperfluoroalkane- sulfonamides R_fSO_2NSO with sulfones.The X-ray structrue analysis of R_fSO_2N=SMe_2 shows that the S^IVNs^VI group contains a delocalized d-π bond system.展开更多
文摘N-Perfluoroalkanesulfonyl S,S-dialkyl sulfilimines R_fSO_2N=SR^1R^2 were prepared in high yields by condensation of N-sulfinylperfluoroalkane- sulfonamides R_fSO_2NSO with sulfones.The X-ray structrue analysis of R_fSO_2N=SMe_2 shows that the S^IVNs^VI group contains a delocalized d-π bond system.
