Catalytic amination of aryl bromides with in situ generated dimethylamines from N, N- dimethylacetamide (DMA) has been successfully carried out using Ni(Phen)Cl2 as catalyst. Both electron-rich and electron-poor aroma...Catalytic amination of aryl bromides with in situ generated dimethylamines from N, N- dimethylacetamide (DMA) has been successfully carried out using Ni(Phen)Cl2 as catalyst. Both electron-rich and electron-poor aromatic system reacted smoothly under the conditions to give N,N-dimethylarylamines in good yields.展开更多
文摘Catalytic amination of aryl bromides with in situ generated dimethylamines from N, N- dimethylacetamide (DMA) has been successfully carried out using Ni(Phen)Cl2 as catalyst. Both electron-rich and electron-poor aromatic system reacted smoothly under the conditions to give N,N-dimethylarylamines in good yields.
