Rechargeable Li-O2 batteries have attracted considerable interests because of their exceptional energy density. However, the short lifetime still remained as one of the bottle-neck obstacles for the practical applicat...Rechargeable Li-O2 batteries have attracted considerable interests because of their exceptional energy density. However, the short lifetime still remained as one of the bottle-neck obstacles for the practical application of rechargeable Li-O2 batteries. The development of efficient cathode catalyst is highly desirable to reduce the energy barrier of Li-O2 reaction and electrode failure. In this work, we report a facile strategy for the fabrication of a high-per- formance cathode catalyst for rechargeable Li-O2 batteries by the encapsulation of high content of active Fe nanorods into N-doped carbon nanotubes with high stability （denoted as Fe@NCNTs）. First-principles calculations reveal that the synergistic charge transfer and redistribution between the interface of Fe nanorods, the CNT walls and the active N dopants greatly facilitate the chemisorption and subsequent dissociation of O2 molecules into the epoxy intermediates on the carbon surface, which benefits the uniform growth of nanosized discharge products on CNT surface and thus boosts the reversibility of Li-O2 reactions. As a result, the cathode with Fe@NCNT catalyst exhibRs long cycling sta- bility with high capacities （1000 mA h g-1 for 160 cycles and 600 mA h g-t for 270 cycles）. Based on the total mass of Fe@NCNTs ＋ Li2O2, high gravimetric energy densities of 2120-2600 W h kg-~ can be achieved at the power densities of 50-795 W kg-1.展开更多
基金supported by the National Natural Science Foundation of China (NSFC, 51522203)Fok Ying Tung Education Foundation (151047)+2 种基金the Recruitment Program of Global Youth Experts (2014)Xinghai Scholarship of Dalian University of Technologythe support by the Opening Project of State Key Lab of Polymer Materials Engineering, China (Sklpme2015-4-25)
文摘Rechargeable Li-O2 batteries have attracted considerable interests because of their exceptional energy density. However, the short lifetime still remained as one of the bottle-neck obstacles for the practical application of rechargeable Li-O2 batteries. The development of efficient cathode catalyst is highly desirable to reduce the energy barrier of Li-O2 reaction and electrode failure. In this work, we report a facile strategy for the fabrication of a high-per- formance cathode catalyst for rechargeable Li-O2 batteries by the encapsulation of high content of active Fe nanorods into N-doped carbon nanotubes with high stability （denoted as Fe@NCNTs）. First-principles calculations reveal that the synergistic charge transfer and redistribution between the interface of Fe nanorods, the CNT walls and the active N dopants greatly facilitate the chemisorption and subsequent dissociation of O2 molecules into the epoxy intermediates on the carbon surface, which benefits the uniform growth of nanosized discharge products on CNT surface and thus boosts the reversibility of Li-O2 reactions. As a result, the cathode with Fe@NCNT catalyst exhibRs long cycling sta- bility with high capacities （1000 mA h g-1 for 160 cycles and 600 mA h g-t for 270 cycles）. Based on the total mass of Fe@NCNTs ＋ Li2O2, high gravimetric energy densities of 2120-2600 W h kg-~ can be achieved at the power densities of 50-795 W kg-1.
