The title complex, （1S）-1,1＇-bis{[N-ethyl-N-（1-methylethyl）-amino]carbonyl}-2- （hydroxyldiphenylmethyl）-ferrocene （[Fe（C24H22NO2）（C11H16NO）]2·H2O, Mr = 1207.13）, was synthesized via （-）-Sparteine-m...The title complex, （1S）-1,1＇-bis{[N-ethyl-N-（1-methylethyl）-amino]carbonyl}-2- （hydroxyldiphenylmethyl）-ferrocene （[Fe（C24H22NO2）（C11H16NO）]2·H2O, Mr = 1207.13）, was synthesized via （-）-Sparteine-mediated enantioselective directed ortho-lithiation of 1,1‘-bis{[N- ethyl-N-（1-methylethyl）-amino]carbonyl}-2-（hydroxydiphenylmethyl）-ferrocene. The structure of the rifle compound was determined by X-ray single-crystal diffraction. The crystal belongs to the orthorhombic system, space group P212121, with a = 10.266（2）, b = 17.676（4）, c = 34.097（7）A, V = 6187（2）A3, Z = 4, C70H86Fe2N4O7, Dc = 1.296 g/cm^3,μ = 0.527 mm^-1, T= 113（2） K, F（000） = 2568, the final R = 0.0469 and wR = 0.0984 for 13940 observed reflections with I 〉 2σ（I）. The neighboring ferrocene derivatives are joined into dimers via O-H…O=C intermolecular hydrogen bonding by a water molecule. Besides, the dimers form neat rows along the a axis.展开更多
The title compound N-（（6-chloropyridin-3-yl）methyl）-6-ethoxy-N-ethyl-3-nitropyri-din-2-amine（4） was synthesized by reacting the mixture of 6-chloro-2-ethoxy-3-nitropyridine（1） and 2-chloro-6-ethoxy-3-nitropyri...The title compound N-（（6-chloropyridin-3-yl）methyl）-6-ethoxy-N-ethyl-3-nitropyri-din-2-amine（4） was synthesized by reacting the mixture of 6-chloro-2-ethoxy-3-nitropyridine（1） and 2-chloro-6-ethoxy-3-nitropyridine（2） with 3,and its structure was determined by X-ray single-crystal diffraction.The crystal belongs to the monoclinic system,space group P21/n with a = 7.3441（2）,b = 9.9041（3）,c = 11.7368（3） ,α = 101.410（2）,β = 102.1340（10）,γ = 99.594（2）o,μ = 0.260 mm^-1,Mr = 336.78,V = 798.58（4）（A°）^3,Z = 2,Dc = 1.401g/cm^3,F（000） = 352,T = 296（2） K,R = 0.0210 and wR = 0.1053.展开更多
基金supported by the Major Program of National Natural Science Foundation of China (200572009)Beijing Natural Science Foundation Program and Scientific Research Key Program of Beijing Municipal Commission of Education (KZ200610011006)
文摘The title complex, （1S）-1,1＇-bis{[N-ethyl-N-（1-methylethyl）-amino]carbonyl}-2- （hydroxyldiphenylmethyl）-ferrocene （[Fe（C24H22NO2）（C11H16NO）]2·H2O, Mr = 1207.13）, was synthesized via （-）-Sparteine-mediated enantioselective directed ortho-lithiation of 1,1‘-bis{[N- ethyl-N-（1-methylethyl）-amino]carbonyl}-2-（hydroxydiphenylmethyl）-ferrocene. The structure of the rifle compound was determined by X-ray single-crystal diffraction. The crystal belongs to the orthorhombic system, space group P212121, with a = 10.266（2）, b = 17.676（4）, c = 34.097（7）A, V = 6187（2）A3, Z = 4, C70H86Fe2N4O7, Dc = 1.296 g/cm^3,μ = 0.527 mm^-1, T= 113（2） K, F（000） = 2568, the final R = 0.0469 and wR = 0.0984 for 13940 observed reflections with I 〉 2σ（I）. The neighboring ferrocene derivatives are joined into dimers via O-H…O=C intermolecular hydrogen bonding by a water molecule. Besides, the dimers form neat rows along the a axis.
基金Supported by the National Basic Research Program of China (973 Program,2010CB126104)the NNSFC (Nos. 20572019 and 20872033)+3 种基金National Twelfth-five Key Project of China (Nos. 2011BAE06B01 and 2011BAE06B02)the NSF of Hunan Province (11JJ2006, 11JJ3022 and 10JJ3053)Science Plan of Hunan Province (2010FJ2003)research condition innovation of Hunan Province (2010PT2058)
文摘The title compound N-（（6-chloropyridin-3-yl）methyl）-6-ethoxy-N-ethyl-3-nitropyri-din-2-amine（4） was synthesized by reacting the mixture of 6-chloro-2-ethoxy-3-nitropyridine（1） and 2-chloro-6-ethoxy-3-nitropyridine（2） with 3,and its structure was determined by X-ray single-crystal diffraction.The crystal belongs to the monoclinic system,space group P21/n with a = 7.3441（2）,b = 9.9041（3）,c = 11.7368（3） ,α = 101.410（2）,β = 102.1340（10）,γ = 99.594（2）o,μ = 0.260 mm^-1,Mr = 336.78,V = 798.58（4）（A°）^3,Z = 2,Dc = 1.401g/cm^3,F（000） = 352,T = 296（2） K,R = 0.0210 and wR = 0.1053.
