Ammonium dinitramide(ADN),which has the advantages of high energy density,no halogen and low characteristic signal,is not only considered as a new high-energy oxidizer that is expected to replace the traditional oxidi...Ammonium dinitramide(ADN),which has the advantages of high energy density,no halogen and low characteristic signal,is not only considered as a new high-energy oxidizer that is expected to replace the traditional oxidizer ammonium perchlorate(AP)in solid propellants,but also a good performance explosive in itself.However,due to the strong hygroscopicity of ADN,its application in solid propellants and explosives is greatly limited.Solving the hygroscopicity of ADN is the key to realize the wide application of ADN.In this paper,we systematically review the research progress of anti-hygroscopic strategies of ADN coating.The surface coating methods are focusing on solvent volatilization,solvent-non-solvent,melt crystallization and atomic layer deposition technology.The characteristics of the different methods are compared and analyzed,and the basis for the classification and selection of the coating materials are introduced in detail.In addition,the feasibility of material for surface coating of ADN is evaluated by several compatibility analysis methods.It is highly expected that the liquid phase method(solvent volatilization method,solvent-non-solvent method)would be the promising method for future ADN coating because of its effective,safety and facile operation.Furthermore,polymer materials,are the preferred coating materials due to their high viscosity,easy adhesion,good anti-hygroscopic effect,and heat resistance,which make ADN weak hygroscopicity,less sensitive,easier to preserve and good compatibility.展开更多
The constant-volume combustion energy, cUD(GUDN, s, 298.15 K), enthalpy of solution in acetic ether, solmHQD and kinetic behavior of the exothermic decomposition reaction of the title compound (GUDN) are deter-mined b...The constant-volume combustion energy, cUD(GUDN, s, 298.15 K), enthalpy of solution in acetic ether, solmHQD and kinetic behavior of the exothermic decomposition reaction of the title compound (GUDN) are deter-mined by a precise rotating bomb calorimeter, a Calvet microcalorimeter and DSC, respectively. Its standard en-thalpy of combustion, cmHQD (GUDN, s, 298.15 K), standard enthalpy of formation, fHQDm (GUDN, s, 298.15 K) and kinetic parameters of the exothermic main decomposition reaction in a temperature-programmed mode [the apparent activation energy (aE) and pre-exponential factor (A)] are calculated. The values of cUD (GUDN, s, 298.15 K), cmHQD (GUDN, s, 298.15 K), fmHQD(GUDN, s, 298.15 K) and solmHQD of GUDN are (-7068.64±2.37) J·g-1, (-1467.66±0.50) kJ·mol-1, (-319.76±0.58) kJ·mol-1 and (165.737±0.013) kJ·mol-1, respectively. The kinetic model function in integral form and the value of aEand A of the exothermic main decomposition reaction of GUDN are 220.20 kJ·mol-1 and 1021.18 s-1, respectively. The critical temperature of thermal explosion of GUDN is 217.6 ℃展开更多
Ammonium dinitramide(ADN)is considered as a potential substitute for ammonium perchlorate in energetic materials due to its high density,positive oxygen balance,and halogen-free characteristics.However,its application...Ammonium dinitramide(ADN)is considered as a potential substitute for ammonium perchlorate in energetic materials due to its high density,positive oxygen balance,and halogen-free characteristics.However,its application has been severely limited because of its strong hygroscopicity,difficult storage,and incompatibility with isocyanate curing agents.In order to better bloom the advantages of the highly energetic and environment-friendly ADN in the fields of energetic materials,an in-depth analysis of the current situation and discussion of key research points are particularly important.In this paper,a detailed overview on the synthesis,thermal decomposition,hygroscopic mechanism,and antihygroscopicity of ADN has been discussed,its application in powdes and explosives are also presented,and its future research directions are proposed.展开更多
Ammonium dinitramide(ADN)is a promising oxidizer with high energy characteristic,which is a relatively new environmentally friendly oxidizer without halogens and carbon elements.However,ADN has high hygroscopicity whe...Ammonium dinitramide(ADN)is a promising oxidizer with high energy characteristic,which is a relatively new environmentally friendly oxidizer without halogens and carbon elements.However,ADN has high hygroscopicity when exposed to high humidity air,restricting its applications on the solid propellants.In this paper,a novel energetic cocrystal composed of ammonium dinitramide and 3,4-diaminofurazan(DAF)was proposed and successfully synthesized by antisolvent crystallization method,and the properties of the cocrystal were systematically investigated by analytical characterization and theoretical simulation calculations.The formation of the cocrystal was confirmed by powder X-ray diffraction,differential scanning calorimetry,scanning electron microscopy,infrared spectroscopy and Raman spectroscopy,indicating that the synthesized product was a cocrystal.Through theoretical studies,the ADN/DAF cocrystal structure was predicted,and the powder X-ray diffraction,morphology,water sorption capacity of ADN/DAF cocrystal were calculated,which was consistent with experimental phenomena.The results showed that newly prepared cocrystal of ADN/DAF had lower hygroscopicity compared to pure ADN,and the water sorption capacity was reduced from 15.35%to 7.90%.This may be due to the formation of N-H…O medium-strength hydrogen bonds between the ammonium ion of ADN and the O atom of DAF in the cocrystal,which prevents the binding of water molecules in the air and ammonium ions and reduces the probability of ADN binding to water molecules,leading to the reduction of cocrystal hygroscopicity.The newly prepared energetic cocrystal can provide theoretical and technical guidance for the study of the anti-hygroscopicity of ADN and advance the practical application of ADN.展开更多
Recently,an emerging category green of energetic material ammonium dinitramide(ADN)has exhibited promising application in propellants due to its outstanding merits in energy release and environmental friendliness.It c...Recently,an emerging category green of energetic material ammonium dinitramide(ADN)has exhibited promising application in propellants due to its outstanding merits in energy release and environmental friendliness.It can be considered to substitute traditional oxidizer of ammonium perchlorate(AP)in military systems and aerospace.In this paper,a novel spherical energetic composite ADN/copper alginate(CA)with a microporous structure was designed and prepared by the W/O gel emulsion method,and a desirable porous microsphere structure was obtained.Multiple characterization techniques were used to investigate the structure and properties of ADN/CA composites.The results showed that ADN crystals were homogeneously encapsulated in an alginate-gel matrix.Thermal decomposition temperature was reduced to 151.7℃compared to ADN,while the activation energy of them was reduced from 129.73 k J/mol(ADN)to 107.50 k J/mol(ADN/CA-4).In addition,as-prepared samples had lower impact and frictional sensitivity than ADN.The mechanism of sensitivity reduction and decomposition are also discussed.Constant-volume combustion tests show that peak pressure of the ADN/CA-4 achieves 253.4 k Pa and pressurization rate of 2750.4 k Pa/s.Hence,this has a promising application in improving the combustion performance and safety performance of solid propellants.展开更多
Although ammonium dinitramide(ADN)has been targeted as a potential green monopropellant in future space vehicles,its application potential in Micro-electrical–Mechanical System(MEMS)thrusters or microthrusters has be...Although ammonium dinitramide(ADN)has been targeted as a potential green monopropellant in future space vehicles,its application potential in Micro-electrical–Mechanical System(MEMS)thrusters or microthrusters has been seldom reported in open literature.In this paper,electrolytic decomposition of Ammonium Dinitramide(ADN)-based liquid monopropellant FLP-103 was carried out in an open chamber and MEMS thrusters were fabricated from poly-dimethylsiloxane(PDMS)to characterize the power consumption.Two thrust measurement methods were employed to investigate the electrolytic decomposition of FLP-103 in MEMS microthrusters.The results show that the monopropellant can be successfully ignited at room temperature through 80 V,0.1 A(8 W)using copper wire as electrodes.In the current thruster design,low thrust was obtained at FLP-103 flowrate of 40μl·min^(-1)but it generated the highest specific impulse,Isp,among all the flowrates tested.The experiments successfully demonstrated the potential application of electrolytic decomposition of FLP-103 in MEMS thrusters.展开更多
The investigation aims at the expansion of the basis of formulations of solid composite propellants by introducing new compositions with lower sensitivity to mechanic impact and improved thermal stability.The formulat...The investigation aims at the expansion of the basis of formulations of solid composite propellants by introducing new compositions with lower sensitivity to mechanic impact and improved thermal stability.The formulations based on trinitropyrazole(TNP)contains a binder(a hydrocarbon or active one),aluminum and inorganic oxidizer ADN.The results show that a binary formulation TNP+active binder(18%-19%)(volume fraction)with no metal is well designed which would achieve high specific impulse(at Pc∶Pa=40∶1)of 248s,high density of 1.80g/cm3 and combustion temperature Tcabout 3 450K.In terms of energy,metal-free compositions with TNP lose a bit to those with HMX,only if HMX fraction in formulation is higher than 45%-50%.展开更多
基金financially supported by the National Natural Science Foundation of China(Grant Nos.21805139,12102194 and 22005144)the Joint Funds of the National Natural Science Foundation of China(Grant No.U2141202)+1 种基金the Fundamental Research Funds for the Central Universities(Grant No.30921011203)the Young Elite Scientists Sponsorship Program by CAST(YESS Program,2021QNRC001)。
文摘Ammonium dinitramide(ADN),which has the advantages of high energy density,no halogen and low characteristic signal,is not only considered as a new high-energy oxidizer that is expected to replace the traditional oxidizer ammonium perchlorate(AP)in solid propellants,but also a good performance explosive in itself.However,due to the strong hygroscopicity of ADN,its application in solid propellants and explosives is greatly limited.Solving the hygroscopicity of ADN is the key to realize the wide application of ADN.In this paper,we systematically review the research progress of anti-hygroscopic strategies of ADN coating.The surface coating methods are focusing on solvent volatilization,solvent-non-solvent,melt crystallization and atomic layer deposition technology.The characteristics of the different methods are compared and analyzed,and the basis for the classification and selection of the coating materials are introduced in detail.In addition,the feasibility of material for surface coating of ADN is evaluated by several compatibility analysis methods.It is highly expected that the liquid phase method(solvent volatilization method,solvent-non-solvent method)would be the promising method for future ADN coating because of its effective,safety and facile operation.Furthermore,polymer materials,are the preferred coating materials due to their high viscosity,easy adhesion,good anti-hygroscopic effect,and heat resistance,which make ADN weak hygroscopicity,less sensitive,easier to preserve and good compatibility.
基金Project supported by the Science and Technology Foundation of Shaanxi Key Laboratory of Physico-Inorganic Chemistry (No. 29-3 2001) the Science and Technology Foundation of the National Defence Key Laboratory of Propellant and Explosive Combustion of
文摘The constant-volume combustion energy, cUD(GUDN, s, 298.15 K), enthalpy of solution in acetic ether, solmHQD and kinetic behavior of the exothermic decomposition reaction of the title compound (GUDN) are deter-mined by a precise rotating bomb calorimeter, a Calvet microcalorimeter and DSC, respectively. Its standard en-thalpy of combustion, cmHQD (GUDN, s, 298.15 K), standard enthalpy of formation, fHQDm (GUDN, s, 298.15 K) and kinetic parameters of the exothermic main decomposition reaction in a temperature-programmed mode [the apparent activation energy (aE) and pre-exponential factor (A)] are calculated. The values of cUD (GUDN, s, 298.15 K), cmHQD (GUDN, s, 298.15 K), fmHQD(GUDN, s, 298.15 K) and solmHQD of GUDN are (-7068.64±2.37) J·g-1, (-1467.66±0.50) kJ·mol-1, (-319.76±0.58) kJ·mol-1 and (165.737±0.013) kJ·mol-1, respectively. The kinetic model function in integral form and the value of aEand A of the exothermic main decomposition reaction of GUDN are 220.20 kJ·mol-1 and 1021.18 s-1, respectively. The critical temperature of thermal explosion of GUDN is 217.6 ℃
基金financially supported by the National Natural Science Foundation of China (Project No. 21805139, 12102194, 22005144 and 22005145)the Joint Funds of the National Natural Science Foundation of China (No. U2141202)+1 种基金Natural Science Foundation of Jiangsu Province (No. BK20200471)the Fundamental Research Funds for the Central Universities (No. 30920041106, 30921011203)
文摘Ammonium dinitramide(ADN)is considered as a potential substitute for ammonium perchlorate in energetic materials due to its high density,positive oxygen balance,and halogen-free characteristics.However,its application has been severely limited because of its strong hygroscopicity,difficult storage,and incompatibility with isocyanate curing agents.In order to better bloom the advantages of the highly energetic and environment-friendly ADN in the fields of energetic materials,an in-depth analysis of the current situation and discussion of key research points are particularly important.In this paper,a detailed overview on the synthesis,thermal decomposition,hygroscopic mechanism,and antihygroscopicity of ADN has been discussed,its application in powdes and explosives are also presented,and its future research directions are proposed.
基金supported by the National Natural Science Foundation of China(22125802)Beijing Natural Science Foundation(2222017)National key research and development program(2021YFC2101202)。
文摘Ammonium dinitramide(ADN)is a promising oxidizer with high energy characteristic,which is a relatively new environmentally friendly oxidizer without halogens and carbon elements.However,ADN has high hygroscopicity when exposed to high humidity air,restricting its applications on the solid propellants.In this paper,a novel energetic cocrystal composed of ammonium dinitramide and 3,4-diaminofurazan(DAF)was proposed and successfully synthesized by antisolvent crystallization method,and the properties of the cocrystal were systematically investigated by analytical characterization and theoretical simulation calculations.The formation of the cocrystal was confirmed by powder X-ray diffraction,differential scanning calorimetry,scanning electron microscopy,infrared spectroscopy and Raman spectroscopy,indicating that the synthesized product was a cocrystal.Through theoretical studies,the ADN/DAF cocrystal structure was predicted,and the powder X-ray diffraction,morphology,water sorption capacity of ADN/DAF cocrystal were calculated,which was consistent with experimental phenomena.The results showed that newly prepared cocrystal of ADN/DAF had lower hygroscopicity compared to pure ADN,and the water sorption capacity was reduced from 15.35%to 7.90%.This may be due to the formation of N-H…O medium-strength hydrogen bonds between the ammonium ion of ADN and the O atom of DAF in the cocrystal,which prevents the binding of water molecules in the air and ammonium ions and reduces the probability of ADN binding to water molecules,leading to the reduction of cocrystal hygroscopicity.The newly prepared energetic cocrystal can provide theoretical and technical guidance for the study of the anti-hygroscopicity of ADN and advance the practical application of ADN.
基金supported by the National Natural Science Foundation of China(Grant No.22005253)。
文摘Recently,an emerging category green of energetic material ammonium dinitramide(ADN)has exhibited promising application in propellants due to its outstanding merits in energy release and environmental friendliness.It can be considered to substitute traditional oxidizer of ammonium perchlorate(AP)in military systems and aerospace.In this paper,a novel spherical energetic composite ADN/copper alginate(CA)with a microporous structure was designed and prepared by the W/O gel emulsion method,and a desirable porous microsphere structure was obtained.Multiple characterization techniques were used to investigate the structure and properties of ADN/CA composites.The results showed that ADN crystals were homogeneously encapsulated in an alginate-gel matrix.Thermal decomposition temperature was reduced to 151.7℃compared to ADN,while the activation energy of them was reduced from 129.73 k J/mol(ADN)to 107.50 k J/mol(ADN/CA-4).In addition,as-prepared samples had lower impact and frictional sensitivity than ADN.The mechanism of sensitivity reduction and decomposition are also discussed.Constant-volume combustion tests show that peak pressure of the ADN/CA-4 achieves 253.4 k Pa and pressurization rate of 2750.4 k Pa/s.Hence,this has a promising application in improving the combustion performance and safety performance of solid propellants.
基金Supported by the Project of Ministry of Science,Technology and Innovation,Malaysia(MOSTI)(No.04-02-12-SF0160)
文摘Although ammonium dinitramide(ADN)has been targeted as a potential green monopropellant in future space vehicles,its application potential in Micro-electrical–Mechanical System(MEMS)thrusters or microthrusters has been seldom reported in open literature.In this paper,electrolytic decomposition of Ammonium Dinitramide(ADN)-based liquid monopropellant FLP-103 was carried out in an open chamber and MEMS thrusters were fabricated from poly-dimethylsiloxane(PDMS)to characterize the power consumption.Two thrust measurement methods were employed to investigate the electrolytic decomposition of FLP-103 in MEMS microthrusters.The results show that the monopropellant can be successfully ignited at room temperature through 80 V,0.1 A(8 W)using copper wire as electrodes.In the current thruster design,low thrust was obtained at FLP-103 flowrate of 40μl·min^(-1)but it generated the highest specific impulse,Isp,among all the flowrates tested.The experiments successfully demonstrated the potential application of electrolytic decomposition of FLP-103 in MEMS thrusters.
基金Ministry of Education and Science of the Russian Federation(14.613.21.0043)
文摘The investigation aims at the expansion of the basis of formulations of solid composite propellants by introducing new compositions with lower sensitivity to mechanic impact and improved thermal stability.The formulations based on trinitropyrazole(TNP)contains a binder(a hydrocarbon or active one),aluminum and inorganic oxidizer ADN.The results show that a binary formulation TNP+active binder(18%-19%)(volume fraction)with no metal is well designed which would achieve high specific impulse(at Pc∶Pa=40∶1)of 248s,high density of 1.80g/cm3 and combustion temperature Tcabout 3 450K.In terms of energy,metal-free compositions with TNP lose a bit to those with HMX,only if HMX fraction in formulation is higher than 45%-50%.
