In 1960, Palmer et al. suggested that the rates of the base-catalyzed proton exchange （deuteration, k<sub>D</sub>） at the chiral nitrogen centers of the octahedral complexes in aqueous solution increase ...In 1960, Palmer et al. suggested that the rates of the base-catalyzed proton exchange （deuteration, k<sub>D</sub>） at the chiral nitrogen centers of the octahedral complexes in aqueous solution increase with the increase of the positive charges in the complex. However, we recently found out that the rate of[Co（ox）<sub>2</sub>（Me-en）]<sup>+</sup> was about 20 times larger than that展开更多
文摘In 1960, Palmer et al. suggested that the rates of the base-catalyzed proton exchange （deuteration, k<sub>D</sub>） at the chiral nitrogen centers of the octahedral complexes in aqueous solution increase with the increase of the positive charges in the complex. However, we recently found out that the rate of[Co（ox）<sub>2</sub>（Me-en）]<sup>+</sup> was about 20 times larger than that
