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Innovative Solutions for High-Performance Silicon Anodes in Lithium-Ion Batteries:Overcoming Challenges and Real-World Applications 被引量:1
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作者 Mustafa Khan Suxia Yan +6 位作者 Mujahid Ali Faisal Mahmood Yang Zheng Guochun Li Junfeng Liu Xiaohui Song Yong Wang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期341-384,共44页
Silicon(Si)has emerged as a potent anode material for lithium-ion batteries(LIBs),but faces challenges like low electrical conductivity and significant volume changes during lithiation/delithiation,leading to material... Silicon(Si)has emerged as a potent anode material for lithium-ion batteries(LIBs),but faces challenges like low electrical conductivity and significant volume changes during lithiation/delithiation,leading to material pulverization and capacity degradation.Recent research on nanostructured Si aims to mitigate volume expansion and enhance electrochemical performance,yet still grapples with issues like pulverization,unstable solid electrolyte interface(SEI)growth,and interparticle resistance.This review delves into innovative strategies for optimizing Si anodes’electrochemical performance via structural engineering,focusing on the synthesis of Si/C composites,engineering multidimensional nanostructures,and applying non-carbonaceous coatings.Forming a stable SEI is vital to prevent electrolyte decomposition and enhance Li^(+)transport,thereby stabilizing the Si anode interface and boosting cycling Coulombic efficiency.We also examine groundbreaking advancements such as self-healing polymers and advanced prelithiation methods to improve initial Coulombic efficiency and combat capacity loss.Our review uniquely provides a detailed examination of these strategies in real-world applications,moving beyond theoretical discussions.It offers a critical analysis of these approaches in terms of performance enhancement,scalability,and commercial feasibility.In conclusion,this review presents a comprehensive view and a forward-looking perspective on designing robust,high-performance Si-based anodes the next generation of LIBs. 展开更多
关键词 Silicon anode Energy storage NANOSTRUCTURE Prelithiation BINDER
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Improved Flexible Triboelectric Nanogenerator Based on Tile-Nanostructure for Wireless Human Health Monitor 被引量:1
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作者 Huamin Chen Shujun Guo +9 位作者 Shaochun Zhang Yu Xiao Wei Yang Zhaoyang Sun Xu Cai Run Fang Huining Wang Yun Xu Jun Wang Zhou Li 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第4期386-395,共10页
Triboelectric nanogenerators(TENGs)have emerged as promising candidates for integrating with flexible electronics as self-powered systems owing to their intrinsic flexibility,biocompatibility,and miniaturization.In th... Triboelectric nanogenerators(TENGs)have emerged as promising candidates for integrating with flexible electronics as self-powered systems owing to their intrinsic flexibility,biocompatibility,and miniaturization.In this study,an improved flexible TENG with a tile-nanostructured MXene/polymethyl methacrylate(PMMA)composite electrode(MP-TENG)is proposed for use in wireless human health monitor.The multifunctional tile-nanostructured MXene/PMMA film,which is self-assembled through vacuum filtration,exhibits good conductivity,excellent charge capacity,and high flexibility.Thus,the MXene/PMMA composite electrode can simultaneously function as a charge-generating,charge-trapping,and charge-collecting layer.Furthermore,the charge-trapping capacity of a tile nanostructure can be optimized on the basis of the PMMA concentration.At a mass fraction of 4%PMMA,the MP-TENG achieves the optimal output performance,with an output voltage of 37.8 V,an output current of 1.8μA,and transferred charge of 14.1 nC.The output power is enhanced over twofold compared with the pure MXene-based TENG.Moreover,the MP-TENG has sufficient power capacity and durability to power small electronic devices.Finally,a wireless human motion monitor based on the MP-TENG is utilized to detect physiological signals in various kinematic motions.Consequently,the proposed performance-enhanced MP-TENG proves a considerable potential for use in health monitoring,telemedicine,and self-powered systems. 展开更多
关键词 flexible electrode MXene tile nanostructure triboelectric nanogenerator wireless monitor
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Ambient-Condition Strategy for Production of Hollow Ga_(2)O_(3)@rGO Crystalline Nanostructures Toward Efficient Lithium Storage 被引量:1
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作者 Dongdong Zhang Qiliang Wei +7 位作者 Haili Huang Lan Jiang Jie Teng Ruizhi Yu Qing Zhang Shengxing Liu Lin Wang Weiyou Yang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期75-82,共8页
Crystallineγ-Ga_(2)O_(3)@rGO core-shell nanostructures are synthesized in gram scale,which are accomplished by a facile sonochemical strategy under ambient condition.They are composed of uniformγ-Ga_(2)O_(3)nanosphe... Crystallineγ-Ga_(2)O_(3)@rGO core-shell nanostructures are synthesized in gram scale,which are accomplished by a facile sonochemical strategy under ambient condition.They are composed of uniformγ-Ga_(2)O_(3)nanospheres encapsulated by reduced graphene oxide(rGO)nanolayers,and their formation is mainly attributed to the existed opposite zeta potential between the Ga_(2)O_(3)and rGO.The as-constructed lithium-ion batteries(LIBs)based on as-fabricatedγ-Ga_(2)O_(3)@rGO nanostructures deliver an initial discharge capacity of 1000 mAh g^(-1)at 100 mA g^(-1)and reversible capacity of 600 mAh g^(-1)under 500 mA g^(-1)after 1000 cycles,respectively,which are remarkably higher than those of pristineγ-Ga_(2)O_(3)with a much reduced lifetime of 100 cycles and much lower capacity.Ex situ XRD and XPS analyses demonstrate that the reversible LIBs storage is dominant by a conversion reaction and alloying mechanism,where the discharged product of liquid metal Ga exhibits self-healing ability,thus preventing the destroy of electrodes.Additionally,the rGO shell could act robustly as conductive network of the electrode for significantly improved conductivity,endowing the efficient Li storage behaviors.This work might provide some insight on mass production of advanced electrode materials under mild condition for energy storage and conversion applications. 展开更多
关键词 ambient condition core-shell nanostructures Ga_(2)O_(3) Li-ion batteries rGO
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Recent progress in thermodynamic and kinetics modification of magnesium hydride hydrogen storage materials 被引量:1
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作者 Yafei Liu Yusang Guo +3 位作者 Yaru Jiang Lizhuang Feng Yu Sun Yijing Wang 《Materials Reports(Energy)》 EI 2024年第1期3-22,共20页
Hydrogen energy has emerged as a pivotal solution to address the global energy crisis and pave the way for a cleaner,low-carbon,secure,and efficient modern energy system.A key imperative in the utilization of hydrogen... Hydrogen energy has emerged as a pivotal solution to address the global energy crisis and pave the way for a cleaner,low-carbon,secure,and efficient modern energy system.A key imperative in the utilization of hydrogen energy lies in the development of high-performance hydrogen storage materials.Magnesium-based hydrogen storage materials exhibit remarkable advantages,including high hydrogen storage density,cost-effectiveness,and abundant magnesium resources,making them highly promising for the hydrogen energy sector.Nonetheless,practical applications of magnesium hydride for hydrogen storage face significant challenges,primarily due to their slow kinetics and stable thermodynamic properties.Herein,we briefly summarize the thermodynamic and kinetic properties of MgH2,encompassing strategies such as alloying,nanoscaling,catalyst doping,and composite system construction to enhance its hydrogen storage performance.Notably,nanoscaling and catalyst doping have emerged as more effective modification strategies.The discussion focuses on the thermodynamic changes induced by nanoscaling and the kinetic enhancements resulting from catalyst doping.Particular emphasis lies in the synergistic improvement strategy of incorporating nanocatalysts with confinement materials,and we revisit typical works on the multi-strategy optimization of MgH2.In conclusion,we conduct an analysis of outstanding challenges and issues,followed by presenting future research and development prospects for MgH2 as hydrogen storage materials. 展开更多
关键词 Magnesium hydride Thermodynamics and kinetics Catalyst doping NANOSTRUCTURES Hydrogenation and dehydrogenation
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Recent progress on nanomaterial-based electrochemical dissolved oxygen sensors
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作者 Shaoqi Zhang Tao Liu +1 位作者 Zhenyu Chu Wanqin Jin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期103-119,共17页
Dissolved oxygen(DO)usually refers to the amount of oxygen dissolved in water.In the environment,medicine,and fermentation industries,the DO level needs to be accurate and capable of online monitoring to guide the pre... Dissolved oxygen(DO)usually refers to the amount of oxygen dissolved in water.In the environment,medicine,and fermentation industries,the DO level needs to be accurate and capable of online monitoring to guide the precise control of water quality,clinical treatment,and microbial metabolism.Compared with other analytical methods,the electrochemical strategy is superior in its fast response,low cost,high sensitivity,and portable device.However,an electrochemical DO sensor faces a trade-off between sensitivity and long-term stability,which strongly limits its practical applications.To solve this problem,various advanced nanomaterials have been proposed to promote detection performance owing to their excellent electrocatalysis,conductivity,and chemical stability.Therefore,in this review,we focus on the recent progress of advanced nanomaterial-based electrochemical DO sensors.Through the comparison of the working principles on the main analysis techniques toward DO,the advantages of the electrochemical method are discussed.Emphasis is placed on recently developed nanomaterials that exhibit special characteristics,including nanostructures and preparation routes,to benefit DO determination.Specifically,we also introduce some interesting research on the configuration design of the electrode and device,which is rarely introduced.Then,the different requirements of the electrochemical DO sensors in different application fields are included to provide brief guidance on the selection of appropriate nanomaterials.Finally,the main challenges are evaluated to propose future development prospects and detection strategies for nanomaterial-based electrochemical sensors. 展开更多
关键词 NANOMATERIAL Dissolved oxygen Electrochemical sensor NANOSTRUCTURES Detection principles
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Modeling the performance of perovskite solar cells with inserting porous insulating alumina nanoplates
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作者 潘赵耀 杨金彭 沈小双 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期668-671,共4页
Peng et al.[Science 379683(2023)]reported an effective method to improve the performance of perovskite solar cells by using thicker porous insulator contact(PIC)-alumina nanoplates.This method overcomes the trade-off ... Peng et al.[Science 379683(2023)]reported an effective method to improve the performance of perovskite solar cells by using thicker porous insulator contact(PIC)-alumina nanoplates.This method overcomes the trade-off between the open-circuit voltage and the fill factor through two mechanisms:reduced surface recombination velocity and increased bulk recombination lifetime due to better perovskite crystallinity.From arguments of drift-diffusion simulations,we find that an increase in mobility and carrier recombination lifetime in bulk are the key factors for minimizing the resistance-effect from thicker PICs and achieving a maximum power conversion efficiency(PCE)at approximately 25%reduced contact area.Furthermore,the partially replacement of perovskite films with thicker PICs would result in a reduction in short-current density,but the relative low refractive index of the PICs imbedded into the high refractive index perovskite creates light trapping structures that compensate for this loss. 展开更多
关键词 perovskite solar cells NANOSTRUCTURE CRYSTALLINE mobility
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Effect of trace oxygen on plasma nitriding of titanium foil
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作者 周海涛 熊希雅 +3 位作者 马可欣 罗炳威 罗飞 申承民 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期548-551,共4页
Titanium nitride films are prepared by plasma enhanced chemical vapor deposition method on titanium foil using N_(2) as precursor. In order to evaluate the effect of oxygen on the growth of titanium nitride films, a s... Titanium nitride films are prepared by plasma enhanced chemical vapor deposition method on titanium foil using N_(2) as precursor. In order to evaluate the effect of oxygen on the growth of titanium nitride films, a small amount of O_(2) is introduced into the preparation process. The study indicates that trace O_(2) addition into the reaction chamber gives rise to significant changes on the color and micro-morphology of the foil, featuring dense and long nano-wires. The as-synthesized nanostructures are characterized by various methods and identified as TiN, Ti_(2) N, and TiO_(2) respectively. Moreover, the experiment results show that oxide nanowire has a high degree of crystallinity and the nitrides present specific orientation relationships with the titanium matrix. 展开更多
关键词 NITRIDE OXIDE NANOSTRUCTURE CRYSTALLINE plasma-enhanced chemical vapor deposition system(PECVD)
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Synthesis of boron nitride nanorod and its performance as a metalfree catalyst for oxidative desulfurization of diesel fuel
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作者 Tanaz Ghanadi Gholamreza Moradi Alimorad Rashidi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期120-132,共13页
In order to reduce the sulfur compounds in diesel fuel,boron nitride(BN)has been used as a novel metal-free catalyst in the present research.This nanocatalyst was synthesized via template-free approach followed by hea... In order to reduce the sulfur compounds in diesel fuel,boron nitride(BN)has been used as a novel metal-free catalyst in the present research.This nanocatalyst was synthesized via template-free approach followed by heating treatment at 900℃ in nitrogen atmosphere that the characteristics of the sample were identified by the X-ray diffraction,Fourier-transform infrared spectroscopy,Raman spectroscopy,field emission scanning electron microscopy,transmission electron microscopy,atomic force microscopy,and N2 adsorption-desorption isotherms.The results of structural and morphological analysis represented that BN has been successfully synthesized.The efficacy of the main operating parameters on the process was studied by using response surface methodology based on the Box-Behnken design method.The prepared catalyst showed high efficiency in oxidative desulfurization of diesel fuel with initial sulfur content of 8040 mg·kg^(-1)S.From statistical analysis,a significant quadratic model was obtained to predict the sulfur removal as a function of efficient parameters.The maximum efficiency of 72.4%was achieved under optimized conditions at oxidant/sulfur molar ratio of 10.2,temperature of 71℃,reaction time of 113 min,and catalyst dosage of 0.36 g.Also,the reusability of the BN was studied,and the result showed little reduction in activity of the catalyst after 10 times regeneration.Moreover,a plausible mechanism was proposed for oxidation of sulfur compounds on the surface of the catalyst.The present study shows that BN materials can be selected as promising metal-free catalysts for desulfurization process. 展开更多
关键词 DESULFURIZATION Boron nitride(BN)nanostructure Experimental design BoxeBehnken
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Formation of Natural Melanin/TiO_(2) Nanostructure Hybrids with Enhanced Optical,Thermal and Magnetic Properties as a Soft Material
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作者 Saja Algessair Nawal Madkhali 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期613-620,共8页
The natural Melanin/TiO_(2) was synthesized by the use of ultrasonication under UV radiation.The influence of natural melanin on the structural,optical and thermal properties of TiO_(2) nanoparticles was investigated ... The natural Melanin/TiO_(2) was synthesized by the use of ultrasonication under UV radiation.The influence of natural melanin on the structural,optical and thermal properties of TiO_(2) nanoparticles was investigated by using Fourier transform infrared spectroscopy,thermogravimetric analysis and UV-Vis spectroscopy.It was observed that incorporating natural melanin on TiO_(2) nanoparticles(TiO_(2)-Mel)occurred at 2.01 eV with a low value of Urbach energy around 100 meV indicating improvement in the crystalline structure.Magnetic measurement at room temperature showed diamagnetic behavior.Furthermore,thermal results showed that TiO_(2)-Mel is stable even at temperatures up to 400℃.According to the results obtained by the thermal stability of melanin with titanium dioxide,it can be a good candidate in many applications such as solar cells and optoelectronics. 展开更多
关键词 natural melanin/TiO_(2) thermal stability OPTOELECTRONIC NANOSTRUCTURE UV radiation
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Superior Anodic Lithium Storage in Core–Shell Heterostructures Composed of Carbon Nanotubes and Schiff-Base Covalent Organic Frameworks
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作者 Nan Jiang Mengpei Qi +3 位作者 Yalong Jiang Yin Fan Shiwei Jin Yingkui Yang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第6期150-157,共8页
Covalent organic frameworks(COFs)after undergoing the superlithiation process promise high-capacity anodes while suffering from sluggish reaction kinetics and low electrochemical utilization of redox-active sites.Here... Covalent organic frameworks(COFs)after undergoing the superlithiation process promise high-capacity anodes while suffering from sluggish reaction kinetics and low electrochemical utilization of redox-active sites.Herein,integrating carbon nanotubes(CNTs)with imine-linked covalent organic frameworks(COFs)was rationally executed by in-situ Schiff-base condensation between 1,1′-biphenyl]-3,3′,5,5′-tetracarbaldehyde and 1,4-diaminobenzene in the presence of CNTs to produce core–shell heterostructured composites(CNT@COF).Accordingly,the redox-active shell of COF nanoparticles around one-dimensional conductive CNTs synergistically creates robust three-dimensional hybrid architectures with high specific surface area,thus promoting electron transport and affording abundant active functional groups accessible for electrochemical utilization throughout the whole electrode.Remarkably,upon the full activation with a superlithiation process,the as-fabricated CNT@COF anode achieves a specific capacity of 2324 mAh g^(−1),which is the highest specific capacity among organic electrode materials reported so far.Meanwhile,the superior rate capability and excellent cycling stability are also obtained.The redox reaction mechanisms for the COF moiety were further revealed by Fourier-transform infrared spectroscopy in conjunction with X-ray photoelectron spectroscopy,involving the reversible redox reactions between lithium ions and C=N groups and gradual electrochemical activation of the unsaturated C=C bonds within COFs. 展开更多
关键词 heterostructured anode core-shell nanostructures carbon nanotubes polymeric Schiff-bases covalent organic frameworks
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First-principles study of electronic and magnetic properties of Fe atoms on Cu_(2)N/Cu(100)
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作者 陈佳乐 胡军 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第8期498-503,共6页
First-principles calculations were conducted to investigate the structural,electronic,and magnetic properties of single Fe atoms and Fe dimers on Cu_(2)N/Cu(100).Upon adsorption of an Fe atom onto Cu_(2)N/Cu(100),robu... First-principles calculations were conducted to investigate the structural,electronic,and magnetic properties of single Fe atoms and Fe dimers on Cu_(2)N/Cu(100).Upon adsorption of an Fe atom onto Cu_(2)N/Cu(100),robust Fe-N bonds form,resulting in the incorporation of both single Fe atoms and Fe dimers within the surface Cu_(2)N layer.The partial occupancy of Fe-3d orbitals lead to large spin moments on the Fe atoms.Interestingly,both single Fe atoms and Fe dimers exhibit in-plane magnetic anisotropy,with the magnetic anisotropy energy(MAE)of an Fe dimer exceeding twice that of a single Fe atom.This magnetic anisotropy can be attributed to the predominant contribution of the component along the x direction of the spin-orbital coupling Hamiltonian.Additionally,the formation of Fe-Cu dimers may further boost the magnetic anisotropy,as the energy levels of the Fe-3d orbitals are remarkably influenced by the presence of Cu atoms.Our study manifests the significance of uncovering the origin of magnetic anisotropy in engineering the magnetic properties of magnetic nanostructures. 展开更多
关键词 magnetic nanostructures magnetic anisotropy spin–orbital coupling ultrathin substrate
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Integrated adsorption and photocatalytic removal of methylene blue dye from aqueous solution by hierarchical Nb_(2)O_(5)@PAN/PVDF/ANO composite nanofibers
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作者 Aditya Rianjanu Kurniawan Deny Pratama Marpaung +8 位作者 Elisabeth Kartini Arum Melati Rizky Aflaha Yudha Gusti Wibowo I Putu Mahendra Nursidik Yulianto Januar Widakdo Kuwat Triyana Hutomo Suryo Wasisto Tarmizi Taher 《Nano Materials Science》 EI CAS CSCD 2024年第1期96-105,共10页
This work presents the development of hierarchical niobium pentoxide(Nb_(2)O_(5))-based composite nanofiber membranes for integrated adsorption and photocatalytic degradation of methylene blue(MB)pollutants from aqueo... This work presents the development of hierarchical niobium pentoxide(Nb_(2)O_(5))-based composite nanofiber membranes for integrated adsorption and photocatalytic degradation of methylene blue(MB)pollutants from aqueous solutions.The Nb_(2)O_(5) nanorods were vertically grown using a hydrothermal process on a base electrospun nanofibrous membrane made of polyacrylonitrile/polyvinylidene fluoride/ammonium niobate(V)oxalate hydrate(Nb_(2)O_(5)@PAN/PVDF/ANO).They were characterized using field-emission scanning electron microscopy(FE-SEM),X-ray diffraction(XRD)analysis,and Fourier transform infrared(FTIR)spectroscopy.These composite nanofibers possessed a narrow optical bandgap energy of 3.31 eV and demonstrated an MB degradation efficiency of 96%after 480 min contact time.The pseudo-first-order kinetic study was also conducted,in which Nb_(2)O_(5)@PAN/PVDF/ANO nanofibers have kinetic constant values of 1.29×10^(-2) min^(-1) and 0.30×10^(-2) min^(-1) for adsorption and photocatalytic degradation of MB aqueous solutions,respectively.These values are 17.7 and 7.8 times greater than those of PAN/PVDF/ANO nanofibers without Nb_(2)O_(5) nanostructures.Besides their outstanding photocatalytic performance,the developed membrane materials exhibit advantageous characteristics in recycling,which subsequently widen their practical use in environmental remediation applications. 展开更多
关键词 Hierarchical nanostructure Composite nanofiber Niobium pentoxide Dye degradation Synergetic adsorption and photocatalysis
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Universal architecture and defect engineering dual strategy for hierarchical antimony phosphate composite toward fast and durable sodium storage
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作者 Jiawei Wu Gaoyu Wang +7 位作者 Wei Zhang Lixiang Wang Jian Peng Qinghua Li Zhixin Liang Wenbo Fan Jiazhao Wang Shaoming Huang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期110-119,I0004,共11页
Antimony(Sb)-ba sed anode materials are feasible candidates for sodium-ion batteries(SIBs) due to their high theoretical specific capacity and excellent electrical conductivity.However,they still suffer from volume di... Antimony(Sb)-ba sed anode materials are feasible candidates for sodium-ion batteries(SIBs) due to their high theoretical specific capacity and excellent electrical conductivity.However,they still suffer from volume distortion,structural collapse,and ionic conduction interruption upon cycling.Herein,a hierarchical array-like nanofiber structure was designed to address these limitations by combining architecture engineering and anion tuning strategy,in which SbPO_(4-x) with oxygen vacancy nanosheet arrays are anchored on the surface of interwoven carbon nanofibers(SbPO_(4-x)@CNFs).In particular,bulky PO_(4)^(3-) anions mitigate the large volume distortion and generate Na_(3)PO_(4) with high ionic conductivity,collectively improving cyclic stability and ionic transport efficiency.The abundant oxygen vacancies substantially boost the intrinsic electronic conductivity of SbPO_4,further accelerating the reaction dynamics.In addition,hierarchical fibrous structures provide abundant active sites,construct efficient conducting networks,and enhance the electron/ion transport capacity.Benefiting from the advanced structural design,the SbPO_(4-x)@CNFs electrodes exhibit outstanding cycling stability(1000 cycles at 1.0 A g^(-1) with capacity decay of 0.05% per cycle) and rapid sodium storage performance(293.8 mA h g^(-1) at 5.0 A g^(-1)).Importantly,systematic in-/ex-situ techniques have revealed the "multi-step conversion-alloying" reaction process and the "battery-capacitor dual-mode" sodium-storage mechanism.This work provides valuable insights into the design of anode materials for advanced SIBs with elevated stability and superior rate performance. 展开更多
关键词 SbPO_(4) anodes Hierarchical nanostructures Oxygen vacancy Stress dispersion Sodium-ion batteries
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Two-Dimensional Metallophthalocyanine Nanomaterials for Electrocatalytic Energy Conversion
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作者 Xinqi Wang Shaohui Sun +3 位作者 Jiahao Yao Hao Wan Renzhi Ma Wei Ma 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第4期364-385,共22页
Growing energy demand drives the rapid development of clean and reliable energy sources.In the past years,the exploration of novel materials with considerable efficiency and durability has drawn attention in the area ... Growing energy demand drives the rapid development of clean and reliable energy sources.In the past years,the exploration of novel materials with considerable efficiency and durability has drawn attention in the area of electrochemical energy conversion.Transition metal macrocyclic metallophthalocyanines(MPcs)-based catalysts with a peculiar 2D constitution have emerged with a promising future account of their highly structural tailorability and molecular functionality which greatly extend their functionalities as electrocatalytic materials for energy conversion.This review summarizes the systematic engineering of synthesis of MPcs and their analogs in detail,and mostly pays attention to the frontier research of MPc-based high-performance catalysts toward different electrocatalytic processes concerning hydrogen,oxygen,water,carbon dioxide,and nitrogen,with a particular focus on discussing the interrelationship between the electrocatalytic activity and component/structure,as well as functional applications of MPcs.Finally,we give the gaps that need to be addressed after much thought. 展开更多
关键词 conjugated nanostructure ELECTROCATALYSIS 2D metallophthalocyanines
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Mass-Based Environmental Factor and Energy Assessment of Microwave-Assisted Synthesized Transition Metal Nanostructures
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作者 Victor J. Law 《American Journal of Analytical Chemistry》 CAS 2024年第6期201-218,共18页
This paper describes mass-based energy phase-space projection of microwave-assisted synthesis of transition metals (zinc oxide, palladium, silver, platinum, and gold) nanostructures. The projection uses process energy... This paper describes mass-based energy phase-space projection of microwave-assisted synthesis of transition metals (zinc oxide, palladium, silver, platinum, and gold) nanostructures. The projection uses process energy budget (measured in kJ) on the horizontal axes and process density (measured in kJg−1) on the vertical axes. These two axes allow both mass usage efficiency (Environmental-Factor) and energy efficiency to be evaluated for a range of microwave applicator and metal synthesis. The metrics are allied to the: second, sixth and eleventh principle of the twelve principle of Green Chemistry. This analytical approach to microwave synthesis (widely considered as a useful Green Chemistry energy source) allows a quantified dynamic environmental quotient to be given to renewable plant-based biomass associated with the reduction of the metal precursors. Thus allowing a degree of quantification of claimed “eco-friendly” and “sustainable” synthesis with regard to waste production and energy usage. 展开更多
关键词 Microwave-Assisted Synthesis Transition Metals Nanostructures Allometry Scaling Power-Law Signature Green Chemistry
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Building stabilized Cu_(0.17)Mn_(0.03)V_(2)O_(5−□)·2.16H_(2)O cathode enables an outstanding room‐/low‐temperature aqueous Zn‐ion batteries
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作者 Ao Wang Dai‐Huo Liu +9 位作者 Lin Yang Fang Xu Dan Luo Haozhen Dou Mengqin Song Chunyan Xu Beinuo Zhang Jialin Zheng Zhongwei Chen Zhengyu Bai 《Carbon Energy》 SCIE EI CAS CSCD 2024年第8期25-35,共11页
Vanadium oxide cathode materials with stable crystal structure and fast Zn^(2+) storage capabilities are extremely important to achieving outstanding electrochemical performance in aqueous zinc‐ion batteries.In this ... Vanadium oxide cathode materials with stable crystal structure and fast Zn^(2+) storage capabilities are extremely important to achieving outstanding electrochemical performance in aqueous zinc‐ion batteries.In this work,a one‐step hydrothermal method was used to manipulate the bimetallic ion intercalation into the interlayer of vanadium oxide.The pre‐intercalated Cu ions act as pillars to pin the vanadium oxide(V‐O)layers,establishing stabilized two‐dimensional channels for fast Zn^(2+) diffusion.The occupation of Mn ions between V‐O interlayer further expands the layer spacing and increases the concentration of oxygen defects(Od),which boosts the Zn^(2+) diffusion kinetics.As a result,as‐prepared Cu_(0.17)Mn_(0.03)V_(2)O_(5−□)·2.16H_(2)O cathode shows outstanding Zn‐storage capabilities under room‐and lowtemperature environments(e.g.,440.3 mAh g^(−1) at room temperature and 294.3 mAh g^(−1)at−60°C).Importantly,it shows a long cycling life and high capacity retention of 93.4%over 2500 cycles at 2 A g^(−1) at−60°C.Furthermore,the reversible intercalation chemistry mechanisms during discharging/charging processes were revealed via operando X‐ray powder diffraction and ex situ Raman characterizations.The strategy of a couple of 3d transition metal doping provides a solution for the development of superior room‐/lowtemperature vanadium‐based cathode materials. 展开更多
关键词 aqueous zinc‐ion batteries Cu_(0.17)Mn_(0.03)V_(2)O_(5−□)·2.16H_(2)O oxygen defects room‐/lowtemperature performance stabilized nanostructure
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Electricity Generation from Heatwaves
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作者 Diandong Ren Mervyn J. Lynch 《International Journal of Geosciences》 CAS 2024年第5期449-457,共9页
We chose a definition of heatwaves (HWs) that has ~4-year recurrence frequency at world hot spots. We first examined the 1940-2022 HWs climatology and trends in lifespan, severity, spatial extent, and recurrence frequ... We chose a definition of heatwaves (HWs) that has ~4-year recurrence frequency at world hot spots. We first examined the 1940-2022 HWs climatology and trends in lifespan, severity, spatial extent, and recurrence frequency. HWs are becoming more frequent and more severe for extratropical mid- and low-latitudes. To euphemize HWs, we here propose a novel clean energy-tapping concept that utilizes the available nano-technology, micro-meteorology knowledge of temperature distribution within/without buildings, and radiative properties of earth atmosphere. The key points for a practical electricity generation scheme from HWs are defogging, insulation, and minimizing the absorption of infrared downward radiation at the cold legs of the thermoelectric generators. One sample realization is presented which, through relay with existing photovoltaic devices, provides all-day electricity supply sufficient for providing air conditioning requirement for a residence (~2000-watt throughput). The provision of power to air conditioning systems, usually imposes a significant stress on traditional city power grids during heatwaves. 展开更多
关键词 Heatwaves Climate Warming Clean Energy Generation by Thermoelectric Generator Ameliorate and Transcend Heatwaves Climate Warming Mitigation and Adaptation Thermoelectric Generator (TEG) IR Interaction with Periodically Arranged Nanostructures Optical Properties of Nano Fabricating Passive Clean Energy Tapping/Generation
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Preparation and characterization of a nanostructured lipid carrier for phenylethyl resorcinol
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作者 Danyang Zheng Lihua Cai +4 位作者 Mengyi Xu Shihao Lan Yongchuang Zhu Shengzhao Gong Wanxian Liang 《Journal of Dermatologic Science and Cosmetic Technology》 2024年第3期20-31,共12页
Phenylethyl resorcinol(PR)demonstrates inhibitory effects on multiple targets in the melanin synthesis pathway,resulting in a strong whitening effect.However,challenges such as limited solubility in water and suscepti... Phenylethyl resorcinol(PR)demonstrates inhibitory effects on multiple targets in the melanin synthesis pathway,resulting in a strong whitening effect.However,challenges such as limited solubility in water and susceptibility to oxidation and discoloration restrict its practical application in the cosmetics industry.In order to enhance stability and performance characteristics,a whitening nanostructured lipid carrier(NLC)was synthesized through high-pressure homogenization.This method entailed the incorporation of solid lipids,a liquid lipid,and a compound emulsifier,with deionized water fulfilling the roles of solid phase,liquid phase,and water phase,respectively.The NLC's particle size,Zeta potential,stability,encapsulation efficiency,and other parameters were assessed using techniques such as particle sizer,stability analyzer,and HPLC.The results showed that the NLC for phenylethyl resorcinol prepared by using the optimal formula(7.50%solid lipids,3.00%ethylhexyl palmitate,and 2.00%Tween 80 and soybean lecithin)has an encapsulation efficiency of 87.11%,a particle size of 157.2±0.70 nm,a kinetic instability of less than 1.2,and a greatly improved stability,thereby successfully solving the problems of unstable storage and poor solubility of phenylethyl resorcinol. 展开更多
关键词 Phenylethyl resorcinol STABILITY Particle size Encapsulation efficiency Nanostructured lipid carrier
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Tribological properties of nanostructured Al_2O_3-40%TiO_2 multiphase ceramic particles reinforced Ni-based alloy composite coatings 被引量:9
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作者 何龙 谭业发 +2 位作者 谭华 周春华 高立 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第9期2618-2627,共10页
The Ni-based alloy composite coatings reinforced by nanostructured Al2O3-40%TiO2 multiphase ceramic particles were prepared on the surface of 7005 aluminum alloy by plasma spray technology. The microstructure and trib... The Ni-based alloy composite coatings reinforced by nanostructured Al2O3-40%TiO2 multiphase ceramic particles were prepared on the surface of 7005 aluminum alloy by plasma spray technology. The microstructure and tribological properties of the composite coatings were researched. The results show that the composite coatings mainly consist of γ-Ni, α-Al2O3, γ-Al2O3 and rutile-TiO2 etc, and exhibit lower friction coefficients and wear losses than the Ni-based alloy coatings at different loads and speeds. The composite coating bears low contact stress at 3 N and its wear mechanism is micro-cutting wear. As loads increase to 6-12 N, the contact stress is higher than the elastic limit stress of worn surface, and the wear mechanisms change into multi-plastic deformation wear, micro-brittle fracture wear and abrasive wear. With the increase of speeds, the contact temperature of worn surface increases. The composite coating experiences multi-plastic deformation wear, fatigue wear and adhesive wear. 展开更多
关键词 nanostructured A1203-TiO2 multiphase ceramic particles Ni-based alloy composite coating plasma spray friction wear
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PROPERTY AND THERMOSTABLITY STUDY ON TC6 TITANIUM ALLOY NANOSTRUCTURE PROCESSED BY LSP 被引量:6
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作者 王学德 李应红 +3 位作者 李启鹏 何卫锋 聂祥樊 李玉琴 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2012年第1期68-76,共9页
TC6 titanium alloy samples are processed by laser shock peening (LSP). Then, some samples are vacu- um annealed at 623 K for 10 h for the study on the thermost.ablity of the nanostructure produced by LSP. The charac... TC6 titanium alloy samples are processed by laser shock peening (LSP). Then, some samples are vacu- um annealed at 623 K for 10 h for the study on the thermost.ablity of the nanostructure produced by LSP. The characteristics of the strengthened layer and nanostructure are studied by atomic force microscopy(AFM), scan- ning electron microscope (SEM), electron backscatter diffraction(EBSD), X-ray diffraction(XRD), and transmis- sion electron microscopy(TEM) appliances, meanwhile the enhanced microhardness is tested at cross section. AFM of the processed surface indicates that the deformation is approximately uniform, and LSP slightly increases the roughness. SEM and EBSD of the strengthened cross section show that a phases are compressed to strip- shaped, a proportion of a and ~ phases is shattered to smaller phases from surface to 200 ttm in depth. The sur- face XRD shows that although there is no new produced phase during LSP, the grain size refinement and the in- troduction of lattice micro-strains lead to the broadened peak. The TEM photographs and diffraction patterns in- dicate that the shock wave provides high strain rate deformation and leads to the formation of nanocrystal. Com- pared with the samples before annealing, the dislocation density is lower and the grain-boundary is more distinct in the annealed samples, but the nanocrystal size does not grow bigger after annealing. The microhardness measurement indicates that LSP improves the microhardness of TC6 for about 12.2% on the surface, and the layer affected by LSP is about 500/~m in depth. The microhardness after annealing is 10 HVo.5 lower, but the affected depth does not change. The thermostable study shows that the strengthened layer of TC6 processed by LSP is stable at 623 K. The strengthened thermostable layer can significantly improve the fatigue resistance, wear resis- tance and stress corrosion resistance of the titanium alloy. The study results break the USA standard AMS2546 that titanium parts after LSP are subjected in subsequent processing within 589 K. 展开更多
关键词 laser shock peening(LSP) TC6 titanium alloy NANOSTRUCTURE MICROHARDNESS thermostablity
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