Two isomers ofnitrochlorobenzene （o- andp-NCB） were treated by a Pd/Fe catalyst in aqueous solutions through catalytic amination and dechlorination. Nitrochlorobenzenes are rapidly converted to form chloroanilines ...Two isomers ofnitrochlorobenzene （o- andp-NCB） were treated by a Pd/Fe catalyst in aqueous solutions through catalytic amination and dechlorination. Nitrochlorobenzenes are rapidly converted to form chloroanilines （CAN） first through an amination process, and then rapidly dechlorinated to become aniline （AN） and CI^-, without the involvement of any other intermediate reaction products. The amination and dechlorination reaction are believed to take place predominantly on the surface site of the Pd/Fe catalysts. The dechlorination rate of the reductive degradation of the two isomers of nitrochlorobenzene （o-, and p-NCB） in the presence of Pd/Fe as a catalyst was measured experimentally. In all cases, the reaction rate constants were found to increase with the decrease in the Gibbs free energy （correlation with the activation energy） of NCBs formation; the activation energy of each dechlorination reaction was measured to be 95.83 and 77.05 kJ/mol, respectively for o- and p-NCB. The results demonstrated that p-NCBs were reduced more easily than o-NCBs.展开更多
A diamond-like carbon circular target is proposed to improve γ-ray emission and pair production with a laser intensity of 8×1022 W cm-2by using 2D particle-in-cell simulations with quantum electrodynamics.It is ...A diamond-like carbon circular target is proposed to improve γ-ray emission and pair production with a laser intensity of 8×1022 W cm-2by using 2D particle-in-cell simulations with quantum electrodynamics.It is found that the circular target can enhance the density of γ-photons significantly more than a plane target, when two colliding circularly polarized lasers irradiate the target.By multi-laser irradiating the circular target, the optical trap of lasers can prevent the high energy electrons accelerated by laser radiation pressure from escaping.Hence, γ-photons with a high density of beyond 5000 ncare obtained through nonlinear Compton backscattering.Meanwhile, 2.7×1011 positrons with an average energy of 230 MeV are achieved via the multiphoton Breit-Wheeler process.Such an ultrabright γ-ray source and dense positron source can be useful in many applications.The optimal target radius and laser mismatching deviation parameters are also discussed in detail.展开更多
基金Project (No. 20407015) supported by the National Natural ScienceFoundation of China
文摘Two isomers ofnitrochlorobenzene （o- andp-NCB） were treated by a Pd/Fe catalyst in aqueous solutions through catalytic amination and dechlorination. Nitrochlorobenzenes are rapidly converted to form chloroanilines （CAN） first through an amination process, and then rapidly dechlorinated to become aniline （AN） and CI^-, without the involvement of any other intermediate reaction products. The amination and dechlorination reaction are believed to take place predominantly on the surface site of the Pd/Fe catalysts. The dechlorination rate of the reductive degradation of the two isomers of nitrochlorobenzene （o-, and p-NCB） in the presence of Pd/Fe as a catalyst was measured experimentally. In all cases, the reaction rate constants were found to increase with the decrease in the Gibbs free energy （correlation with the activation energy） of NCBs formation; the activation energy of each dechlorination reaction was measured to be 95.83 and 77.05 kJ/mol, respectively for o- and p-NCB. The results demonstrated that p-NCBs were reduced more easily than o-NCBs.
基金supported by the National Natural Science Foundation of China (Nos.11875007, 11305010)supported by the STFC Cockcroft Institute core grant
文摘A diamond-like carbon circular target is proposed to improve γ-ray emission and pair production with a laser intensity of 8×1022 W cm-2by using 2D particle-in-cell simulations with quantum electrodynamics.It is found that the circular target can enhance the density of γ-photons significantly more than a plane target, when two colliding circularly polarized lasers irradiate the target.By multi-laser irradiating the circular target, the optical trap of lasers can prevent the high energy electrons accelerated by laser radiation pressure from escaping.Hence, γ-photons with a high density of beyond 5000 ncare obtained through nonlinear Compton backscattering.Meanwhile, 2.7×1011 positrons with an average energy of 230 MeV are achieved via the multiphoton Breit-Wheeler process.Such an ultrabright γ-ray source and dense positron source can be useful in many applications.The optimal target radius and laser mismatching deviation parameters are also discussed in detail.
