Aluminium matrix composite reinforced by Al2O3 particles was produced by adding NH4AlO(OH)HCO3 into molten aluminum.The mechanical properties and wear behavior of the as-fabricated composites were studied.The result...Aluminium matrix composite reinforced by Al2O3 particles was produced by adding NH4AlO(OH)HCO3 into molten aluminum.The mechanical properties and wear behavior of the as-fabricated composites were studied.The results show that during stirring γ-Al2O3 particles were formed via decomposition reaction of NH4AlO(OH)HCO3,and the distribution of Al2O3 particles is more uniform in the matrix aluminum than directly added Al2O3 into molten aluminum.The density and the hardness values of the as-fabricated composites increase with increasing the particle volume fraction,while the tensile strength of the composites decreases with increasing the volume fraction of the Al2O3 particles.The wear rate of the composites decreases with increasing the volume fraction of the particle and loading.The in situ formed Al2O3/Al composite by adding NH4AlO(OH)HCO3 shows more superior mechanical and wear behaviors than that prepared by directly adding Al2O3 particles.展开更多
A simple one-pot approach to synthesizing 5-ethyl-2-methylpyridine(EMP) was established using NHaHCO3 and C2H5OH as starting materials and commercial Cu2O as catalyst and oxidant under hydrothermal con- dition. Diff...A simple one-pot approach to synthesizing 5-ethyl-2-methylpyridine(EMP) was established using NHaHCO3 and C2H5OH as starting materials and commercial Cu2O as catalyst and oxidant under hydrothermal con- dition. Different reaction conditions were researched and the optimal ones were achieved by studying the parameters, that could affect the yield of product and by considering the energy and resource saving. The present study provided an eco-friendlv way to obtaining EMP with lower volatility using fewer toxic starting materials.展开更多
基金Project(2009BAE80B01)supported by the Ministry of Science and Technology,China
文摘Aluminium matrix composite reinforced by Al2O3 particles was produced by adding NH4AlO(OH)HCO3 into molten aluminum.The mechanical properties and wear behavior of the as-fabricated composites were studied.The results show that during stirring γ-Al2O3 particles were formed via decomposition reaction of NH4AlO(OH)HCO3,and the distribution of Al2O3 particles is more uniform in the matrix aluminum than directly added Al2O3 into molten aluminum.The density and the hardness values of the as-fabricated composites increase with increasing the particle volume fraction,while the tensile strength of the composites decreases with increasing the volume fraction of the Al2O3 particles.The wear rate of the composites decreases with increasing the volume fraction of the particle and loading.The in situ formed Al2O3/Al composite by adding NH4AlO(OH)HCO3 shows more superior mechanical and wear behaviors than that prepared by directly adding Al2O3 particles.
基金Supported by the Natural Science Foundation of Jilin Province, China(No.201215028), the S&T Development Program of Jilin Province, China(Nos.20130522128JH, 20140520078JH, 20150204030GX) and the National Natural Science Foundation of China(Nos.21201073, 21401070).
文摘A simple one-pot approach to synthesizing 5-ethyl-2-methylpyridine(EMP) was established using NHaHCO3 and C2H5OH as starting materials and commercial Cu2O as catalyst and oxidant under hydrothermal con- dition. Different reaction conditions were researched and the optimal ones were achieved by studying the parameters, that could affect the yield of product and by considering the energy and resource saving. The present study provided an eco-friendlv way to obtaining EMP with lower volatility using fewer toxic starting materials.