利用SCIAMACHY和GOME-2卫星观测的对流层HCHO数据以及INTEX-B(The Intercontinental Chemical Transport Experiment Phase B)污染源清单,探讨了2003—2009年中国非甲烷挥发性有机化合物(NMVOC)的分布特征和变化趋势及其成因.结果表明,...利用SCIAMACHY和GOME-2卫星观测的对流层HCHO数据以及INTEX-B(The Intercontinental Chemical Transport Experiment Phase B)污染源清单,探讨了2003—2009年中国非甲烷挥发性有机化合物(NMVOC)的分布特征和变化趋势及其成因.结果表明,中国NMVOC区域分布与其污染源分布不具一致性,具有明显汇聚特征,主要集中在盆地、河谷和山前地区的汇聚带区.中国各区域的NMVOC浓度具有明显的周期性月际变化,华中、华北、华东分别在5月,6月和7月达到各自NMVOC浓度的峰值,该现象同MODIS观测的地面燃烧火点分布具有相关性,生物源的燃烧是造成NMVOC浓度上升并达到峰值的主要原因.展开更多
As the key precursors of O_(3),anthropogenic non-methane volatile organic compounds(NMVOCs)have been studied intensively.This paper performed a meta-analysis on the spatial and temporal variations of NMVOCs,their role...As the key precursors of O_(3),anthropogenic non-methane volatile organic compounds(NMVOCs)have been studied intensively.This paper performed a meta-analysis on the spatial and temporal variations of NMVOCs,their roles in photochemical reactions,and their sources in China,based on published research.The results showed that both nonmethane hydrocarbons(NMHCs)and oxygenated VOCs(OVOCs)in China have higher mixing ratios in the eastern developed cities compared to those in the central and western areas.Alkanes are the most abundant NMHCs species in all reported sites while formaldehyde is the most abundant among the OVOCs.OVOCs have the highest mixing ratios in summer and the lowest in winter,which is opposite to NMHCs.Among all NMVOCs,the top eight species account for 50%−70%of the total ozone formation potential(OFP)with different compositions and contributions in different areas.In devolved regions,OFP-NMHCs are the highest in winter while OFP-OVOCs are the highest in summer.Based on positive matrix factorization(PMF)analysis,vehicle exhaust,industrial emissions,and solvent usage in China are the main sources for NMHCs.However,the emission trend analysis showed that solvent usage and industrial emissions will exceed vehicle exhaust and become the two major sources of NMVOCs in near future.Based on the meta-analysis conducted in this work,we believe that the spatio-temporal variations and oxidation mechanisms of atmospheric OVOCs,as well as generating a higher spatial resolution of emission inventories of NMVOCs represent an area for future studies on NMVOCs in China.展开更多
文摘利用SCIAMACHY和GOME-2卫星观测的对流层HCHO数据以及INTEX-B(The Intercontinental Chemical Transport Experiment Phase B)污染源清单,探讨了2003—2009年中国非甲烷挥发性有机化合物(NMVOC)的分布特征和变化趋势及其成因.结果表明,中国NMVOC区域分布与其污染源分布不具一致性,具有明显汇聚特征,主要集中在盆地、河谷和山前地区的汇聚带区.中国各区域的NMVOC浓度具有明显的周期性月际变化,华中、华北、华东分别在5月,6月和7月达到各自NMVOC浓度的峰值,该现象同MODIS观测的地面燃烧火点分布具有相关性,生物源的燃烧是造成NMVOC浓度上升并达到峰值的主要原因.
基金This work was financially supported by the National Key R&D Plan programs(Grant No.2017YFC0210005)the National Natural Science Foundation of China(Grant No.41773117).
文摘As the key precursors of O_(3),anthropogenic non-methane volatile organic compounds(NMVOCs)have been studied intensively.This paper performed a meta-analysis on the spatial and temporal variations of NMVOCs,their roles in photochemical reactions,and their sources in China,based on published research.The results showed that both nonmethane hydrocarbons(NMHCs)and oxygenated VOCs(OVOCs)in China have higher mixing ratios in the eastern developed cities compared to those in the central and western areas.Alkanes are the most abundant NMHCs species in all reported sites while formaldehyde is the most abundant among the OVOCs.OVOCs have the highest mixing ratios in summer and the lowest in winter,which is opposite to NMHCs.Among all NMVOCs,the top eight species account for 50%−70%of the total ozone formation potential(OFP)with different compositions and contributions in different areas.In devolved regions,OFP-NMHCs are the highest in winter while OFP-OVOCs are the highest in summer.Based on positive matrix factorization(PMF)analysis,vehicle exhaust,industrial emissions,and solvent usage in China are the main sources for NMHCs.However,the emission trend analysis showed that solvent usage and industrial emissions will exceed vehicle exhaust and become the two major sources of NMVOCs in near future.Based on the meta-analysis conducted in this work,we believe that the spatio-temporal variations and oxidation mechanisms of atmospheric OVOCs,as well as generating a higher spatial resolution of emission inventories of NMVOCs represent an area for future studies on NMVOCs in China.
